Products

Tetrabutylphosphonium Bromide

    • Product Name: Tetrabutylphosphonium Bromide
    • Alias: TBPB
    • Einecs: 248-134-7
    • Mininmum Order: 1 g
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: sales3@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
    • CONTACT NOW
    Specifications

    HS Code

    668355

    Chemical Name Tetrabutylphosphonium Bromide
    Chemical Formula C16H36BrP
    Molecular Weight 339.34 g/mol
    Cas Number 3115-68-2
    Appearance White to off-white crystalline solid
    Melting Point 98-102 °C
    Boiling Point Decomposes before boiling
    Solubility In Water Soluble
    Density 1.10 g/cm3 (at 25 °C)
    Storage Conditions Store in a cool, dry place, tightly closed
    Hazard Classification Irritant
    Ec Number 221-508-0
    Odor Odorless

    As an accredited Tetrabutylphosphonium Bromide factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing 250 g of Tetrabutylphosphonium Bromide packaged in a sealed amber glass bottle with a secure screw cap and clear labeling.
    Shipping Tetrabutylphosphonium Bromide should be shipped in tightly sealed containers, protected from moisture and physical damage. It is classified as non-hazardous for transport but should be handled with care. Store and ship at room temperature in compliance with local regulations. Avoid extreme temperatures and ensure clear labeling to avoid accidental misuse.
    Storage Tetrabutylphosphonium Bromide should be stored in a tightly sealed container, in a cool, dry, and well-ventilated area away from moisture and direct sunlight. Keep it away from strong oxidizing agents and sources of ignition. Store at room temperature and protect from physical damage. Label the container clearly, and restrict access to trained personnel only. Handle with appropriate personal protective equipment.
    Application of Tetrabutylphosphonium Bromide

    Purity 99%: Tetrabutylphosphonium Bromide of purity 99% is used in phase transfer catalysis, where high product yield and selectivity are achieved.

    Melting Point 105°C: Tetrabutylphosphonium Bromide with a melting point of 105°C is used in ionic liquid preparation, where it provides thermal stability for high-temperature processes.

    Molecular Weight 322.29 g/mol: Tetrabutylphosphonium Bromide of molecular weight 322.29 g/mol is used in organic synthesis reactions, where precise stoichiometry and reproducibility are required.

    Particle Size <100 µm: Tetrabutylphosphonium Bromide with particle size below 100 µm is used in solid-phase extraction, where improved dispersion and faster extraction rates are observed.

    Stability Temperature up to 200°C: Tetrabutylphosphonium Bromide with stability temperature up to 200°C is used in electrochemical applications, where sustained ionic conductivity is maintained under elevated temperatures.

    Viscosity Grade Low: Tetrabutylphosphonium Bromide of low viscosity grade is used in polymer electrolyte formulations, where improved ion transport and processability are achieved.

    Hydration Level <0.5%: Tetrabutylphosphonium Bromide with hydration level below 0.5% is used in anhydrous reaction systems, where moisture-sensitive reactions show higher conversion rates.

    Residual Halide <0.1%: Tetrabutylphosphonium Bromide with residual halide content under 0.1% is used in pharmaceutical synthesis, where it ensures minimal impurity levels in the final product.

    High Solubility in Water: Tetrabutylphosphonium Bromide with high solubility in water is used in aqueous biphasic catalysis, where phase separation and catalyst recovery are facilitated.

    Low Volatility: Tetrabutylphosphonium Bromide of low volatility is used in green solvent systems, where reduced emission losses and environmental impact are observed.

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    Certification & Compliance
    More Introduction

    Tetrabutylphosphonium Bromide: Direct from the Manufacturer's Line

    Understanding the Product in Day-to-Day Chemical Production

    As a chemical manufacturer, we get to see firsthand how every bag of Tetrabutylphosphonium Bromide (TBPB) leaves the building: clean, consistent, and tested at every batch. TBPB has grown from a specialty item for a handful of research chemists into a staple for all sorts of applications. Close work with customers has shaped what we deliver today—purity, reliable supply, and full technical support—long before buzzwords like “traceability” or “REACH compliance” started popping up. What matters most to our process engineers is that every drum performs the same day-in, day-out, so downstream production never skips a beat. Customers get material they can trust because as the manufacturer, we can point to every step in the plant and every number from the QC bench.

    Model, Purity, and What Goes into Quality

    Every run of Tetrabutylphosphonium Bromide we produce comes out as a dense white powder or sometimes as crystalline chunks, with a chemical formula of C16H36BrP and a molar mass of 351.34 g/mol. Actual physical form depends on water content and storage—everyone who handles the product knows to keep it tightly sealed. Typical purity for our standard grade is above 98%. We rely on consistent raw material sources, and we have an internal library of NMR, IR, and HPLC data to check every lot. The TBPB takes strength in its thermal stability and low volatility. You can stir it into polar solvents, pull it out with an extraction, or work it up through filtration—it behaves the same no matter if you’re running a kilo-lab or full-scale process.

    What Sets Our TBPB Apart in the Industry

    Some manufacturers push for cost reduction at every stage, but that isn’t always the smart way forward once you’re dealing with projects where the whole batch can get scrapped by a trace impurity. Our response has always centered around repeatable, documentable quality and an open-door approach to process feedback. Process development chemists talk to our plant supervisors about handling issues, residue build-up, and how TBPB interacts with other chemicals. We don’t just ship and forget. Every container is fully traceable back to the raw material batch and reaction vessel, and that’s not something every supplier can offer. We have fought alongside our clients to get through “black specks,” moisture uptake, and caking issues by making real changes in the drying and packaging process. That means practical upgrades—more than a new label or a certificate.

    Where TBPB Works and Why It’s Valued

    Tetrabutylphosphonium Bromide lands primarily in phase-transfer catalysis, ionic liquids, and material science. Some teams use it to shuttle anions across phase boundaries; others deploy its strong basicity as an initiator or a stabilizer. In manufacturing, ease of handling, broad solubility in organics, and lack of significant odor have made TBPB a versatile entrant into reaction screening and scale-up. Organometallic labs lean on its ability to form homogenous mixtures with alkali salts. That means less downtime spent coaxing a reaction mixture to dissolve and fewer surprises in workup later. When handling safety and waste, TBPB brings advantages for those aiming to move away from traditional ammonium or imidazolium salts. In electrochemistry, some firms have dialed in performance using TBPB in supercapacitor prototyping, taking advantage of high polarity and robust ion pairing.

    An Insider’s View on Storage and Handling

    Being the actual manufacturer, we see exactly where things can go sideways. TBPB can cake up if left open to air, especially in high-humidity areas. We have built our packaging to fight that: lined drums, moisture barrier bags, and double seals on every box. Our in-house team answers questions about desiccation, solubility in different solvent systems, and recommended shelf-life based on real-world aging studies. Labs who store open drums in fume hoods soon notice the difference compared to those who keep the inner liner tightly folded. Direct interaction with users allows us to advise on minimizing static charge, on the optimal particle size for slurry handling, or even on best practices in sample transfer. We think a manufacturer’s job ends only when clients have zero rejects and zero headaches, not just when the bill clears.

    TBPB Versus Other Quaternary Salts

    Phosphonium and ammonium salts might sound similar to an outsider, but operationally they drive production in different ways. TBPB stands firm on high thermal stability, and under typical process conditions, it doesn’t decompose the way bulkier ammonium analogs can. Its basicity is more pronounced than that of tetrabutylammonium bromide, which can tip a sensitive process toward conversion or kill a byproduct early. In azeotropic drying or phase transfer work, you’ll spot TBPB’s resistance to hydrolysis and its low tendency to undergo Hoffmann elimination—key features for anyone scaling from a few grams to a reactor that holds hundreds of litres. In comparison to imidazolium salts, TBPB avoids unwanted ring-opening side reactions and carries no trace aromatic odor, so operator complaints stay at zero. Every time a client moves away from ammonium- or imidazolium-based salts, they share immediate feedback about less build-up on process glassware and cleaner downstream chromatography.

    Spec’ing the Product—Why Formulation Details Matter

    We package TBPB by weight, not by “volume,” since density shifts with particle size and moisture uptake. Every batch goes out packed with a certificate of analysis (COA) tied to actual test results, not canned numbers, including microanalysis data for phosphorus and bromide content. On rare occasions, pharmaceuticals and electronics firms demand tighter specs, so we offer enhanced grades that push limits on volatile residues, heavy metal traces, and sub-percent impurity profiles. Each batch is logged and retained, so forensic checks on archived material can settle disputes—or new process issues—long after the fact. Some users require particle size control for automated feeders, so we produce fine or granular cuts, validated by real sieving and moisture data. Requests vary from small R&D orders under a kilo to multi-metric-ton annual contracts, so scaling logistics gets built into every customer relationship.

    Challenges in Shipping and Why Local Support Counts

    A quaternary phosphonium salt like TBPB carries restrictions on international movement: not every freight line will touch bulk shipments, and ports demand clear paperwork. As a producer, we’ve learned to manage these logistics without “outsourcing and forgetting”—every route, every packaging change, every customs query gets handled from our side. That keeps shipment lead times honest and allows us to avoid last-minute stock-outs. Western, Asian, and South American customers often want technical help at odd hours, so our technical and sales teams work in shifts. This level of support comes from years of hearing about drummed-up “supply assurance” that falls flat during a crunch. Our customers only raise the alarm if there’s a genuine issue, so keeping stock on hand, and keeping it moving, translates to lower risk in any project.

    The Feel of Continuous Improvement

    Nothing illustrates the rhythm of chemical manufacturing more than the constant chase for fewer process exceptions. Our TBPB lines benefit from employee-driven suggestions that flow from the production floor right up to management. Line workers, who have watched the product for years, spot subtle changes—shifts in odor, clumping in packed drums, color changes—that can be early signals for deviation. Out-of-spec product leaves nobody happy, so fixing issues means putting feedback loops in place across teams. When changes to raw material sources forced us to update drying parameters, direct conversations with polymer and pharma clients helped us avoid problems before thousands of kilos were made. The best improvements never come from top-down mandates alone, but also from troubleshooting with user teams live over video, sometimes testing out small changes right then and there. We believe reliability grows through this hands-on technical partnership, not from slogans or stock phrases.

    Environmental Responsibility and Compliance

    Manufacturing TBPB in modern plants means meeting growing compliance rules at every level: wastewater treatment, vapor recovery, product stewardship. Our site design includes closed-loop containment for liquid handling and exhaust scrubbers that knock down any airborne phosphorus or bromine traces. Environmental staff keep tight logs on solvent use, and we meet local and international regulations on hazardous materials. Any downstream user who wants to reduce waste or switch to greener solvents can reach out for process advice—often, reformulations to TBPB have helped some customers cut their use of halogenated solvents, improving plant worker safety and cutting disposal fees. A focus on returnable packaging, drums that resist corrosion, and digital paperwork for every order keeps audits quick and lean. It’s not just for inspectors: it keeps operations cheaper and leaves less for the next generation to clean up.

    Industry Trends: Shaping the Next Generation of Quaternary Salts

    Tetrabutylphosphonium Bromide came up in the literature as a niche catalyst, but lately, its versatility means it lines up with the move toward cleaner, more selective chemistry. As processes tighten—aiming at single-digit ppm impurity levels or following green chemistry guidelines—more labs have started to reevaluate their catalyst and salt choices. What’s changed over the past few years is the pace: electronic materials, batteries, and pharma all now set stricter specs on ion content, trace metals, and particulates. Manufacturers like us saw these trends brewing, so we upgraded both analytical capability and supply chain controls. Instead of chopping old technical sheets, we worked with downstream fields—battery start-ups who tested substitution in coin cells and API plants who ran conversion studies—instead of just waiting for surveys or regulation decrees. You see progress most quickly in those firms willing to share anonymized case studies or work side-by-side with process chemistry teams. Tetrabutylphosphonium Bromide, for its part, continues march into new areas—far beyond its original phase-transfer routes.

    TBPB in Research and Development

    R&D labs want two things above all: flexibility and clarity on supply. As direct producers, we enable gram to kilo scaling with consistent specs, so the transition from bench to pilot-plant doesn’t turn up unexpected hurdles. Some labs switch grades mid-project, looking at impurity profiles, moisture, or even isotopic abundance for radiolabeling work. They need timely access to COAs with real test data behind every lot. Supporting them means holding inventory and running priority small-batch production on short notice. This readiness allows research to progress without delay, fostering innovation and partnerships that grow with each successful project. Labs come back because they see no difference moving from bottle to drum, and technical support lines stay on hand even for off-the-wall process tweaks.

    Technical and Practical Questions—Experience Counts

    Over the years, practical questions catch even the most seasoned teams off guard. Why did last month’s TBPB dissolve slower in DMF than expected? What caused that rare off-smell, and is that a warning sign? Can we run a pressure filter with this grade, or switch to a finer cut for the automated feeder? Users don’t want a recitation of “typical” data, they want root causes and action steps—something only a manufacturer who knows the process inside and out can provide. Through hundreds of support calls, plant visits, and emails, our crew has seen all manner of real issues: glass-lined reactors scaling up, chiller line leaks traced to improper TBPB storage, or even sudden, off-spec color due to airborne dust. Our job is to translate that field experience into process improvements and quick, straight answers for every batch shipped.

    Customized Solutions—Direct Dialogue Wins

    Some projects demand more than a stock product. Large-scale polymerizers sometimes need anti-caking agents preblended, while microelectronics clients may want material fine-ground and packed inert. Being the manufacturer means we control these tweaks directly, avoiding the runaround of layer-after-layer of requests through intermediaries. This deep dialogue builds solutions unique to process bottlenecks—giving clients fixed particle size, customized labeling, or alternate packaging materials. These tweaks aren’t “premium options” for us—they come right out of our toolbox, shaped by what plant and lab staff have learned watching TBPB in use. It is the difference between real partnership and just moving boxes.

    Feedback, Quality Claims, and the Manufacturer’s Loop

    Few topics generate more discussion than quality claims. Material isn’t perfect forever. Every so often, drums arrive hot, show dust or pick up excess water. We answer for our shipments, investigate possible root causes right through to plant logbooks, and transparently resolve questions with clear data and real updates. Nobody wants to talk to a black hole—open dialogue is how new improvements stick. Continuous improvement audits—run with our clients and not just inside the factory—drive defect rates lower and set new expectations both ways. Our perspective has always favored honesty: we explain last-minute hurdles from a utility outage or a change of raw material, and customers see faster action in corrective steps. TBPB stays reliable not because issues never arise, but because every issue that ever popped up has set the stage for tighter controls, smarter plant layouts, and braver investments in staff and testing.

    Looking Forward—TBPB in Tomorrow’s Plants

    Years ago, Tetrabutylphosphonium Bromide functioned as a specialized add-on for experimental chemists. Now, as industries chase cleaner, faster, and smarter processes, TBPB has evolved with them. Our experience as the maker puts us right in the flow of change. We see trends shift as customers push reaction limits and hunt for “invisible” additives that replace outdated, less sustainable choices. The future promises even tighter loops between pilot and production, more tailored support for new materials, and more transparent reporting on compliance and sustainability. Our direct role lets us steer these improvements into each batch—bridging the gap between old processes and the new demands on safety, processability, and end-product certification in electronics, petrochemical, and life science fields.

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