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High Temperature Resistant Epoxy Molding Compound (EMC) Electronic/EL Grade

    • Product Name: High Temperature Resistant Epoxy Molding Compound (EMC) Electronic/EL Grade
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 895456
    Thermal Resistance Continuous operating temperature up to 200°C or higher without significant degradation
    Glass Transition Temperature Typically 170°C to 230°C, depending on formulation
    Thermal Expansion Coefficient Low CTE, often below 20 ppm/°C below Tg and 50-70 ppm/°C above Tg
    Heat Distortion Temperature High enough to maintain dimensional stability under elevated thermal load
    Flexural Strength High, typically 120-180 MPa at room temperature, ensuring mechanical integrity
    Moisture Resistance Low water absorption, usually less than 0.3% after 24 hours in boiling water
    Electrical Insulation Property High volume resistivity, typically above 10^15 ohm-cm at room temperature
    Dielectric Breakdown Strength High breakdown voltage, often above 20 kV/mm
    Flame Retardancy UL94 V-0 rated, self-extinguishing and resistant to high-temperature exposure
    Ionic Purity Low levels of extractable chloride, sodium, and potassium ions to prevent corrosion and leakage current
    Adhesion Property Excellent adhesion to lead frames, chips, and substrates even after thermal cycling
    Mold Shrinkage Low and controlled shrinkage, typically less than 0.2% for precise encapsulation
    Thermal Cycling Endurance Capable of surviving repeated thermal cycles between -65°C and 175°C without cracking or delamination
    Long Term Thermal Aging Characteristic Retains mechanical, electrical, and adhesion properties after extended aging at high temperatures

    As an accredited High Temperature Resistant Epoxy Molding Compound (EMC) Electronic/EL Grade factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing High Temperature Resistant Epoxy Molding Compound, Electronic/EL Grade, supplied in sealed 25 kg drums with moisture-barrier liners for safe storage.
    Container Loading (20′ FCL) High Temperature Resistant Epoxy Molding Compound loaded in 20' FCL, secured on pallets, moisture-proof packed for safe transport.
    Shipping Shipped in sealed moisture-barrier bags or drums, with desiccant and humidity indicator cards to protect against moisture absorption. Standard ground/freight transport is suitable, avoiding excess heat or direct sunlight. Keep cool, dry, and away from ignition sources. Handle with proper PPE to minimize dust exposure.
    Storage Store in sealed original containers in a clean, cool, dry environment, ideally below 5°C (refrigerated) to prevent premature curing and moisture absorption. Keep away from direct sunlight, heat sources, and humidity. Allow material to warm to room temperature in the sealed container before opening to avoid condensation. Follow manufacturer’s shelf-life guidelines.
    Shelf Life Shelf life is typically 6 months when stored below -40°C in original sealed, moisture-proof packaging.
    Application of High Temperature Resistant Epoxy Molding Compound (EMC) Electronic/EL Grade

    For discrete power semiconductor packages rated at junction temperatures from 175 °C to 200 °C, the electronic/EL grade high-temperature EMC is selected on the basis of spiral flow, hot flexural modulus, and extracted ion content. The benchmark formulation for low-warpage TO-247 and Power QFN bodies maintains a spherical fused silica loading between 84 wt% and 90 wt%, with a phenol-novolac to epoxy-cresol-novolac stoichiometric ratio adjusted to a hardener-to-resin equivalent ratio between 0.95 and 1.05. Release-agent concentration is held at 0.2 phr to 0.5 phr to prevent mould sticking without degrading adhesion to the copper lead-frame. Total hydrolyzable chloride is specified below 10 ppm; sodium and potassium ions are specified below 5 ppm each according to supplier EL-grade certificates.

    Preform conditioning follows a moisture-control window because trapped water in pellets produces voiding at the die mount interface. High-temperature EMC preforms are dried at 60 °C for 4 h when storage relative humidity exceeds 60 %, and the pellets are preheated to 70 °C to 85 °C in a radio-frequency preheater before transfer. The transfer press is configured with a clamp force between 50 t and 120 t, cavity vacuum below 5 kPa, and mould temperature set points between 170 °C and 185 °C; transfer pressure is ramped from 4 MPa to 10 MPa over 10 s to 15 s. Spiral flow length measured by ASTM D3123 is used as a release criterion, with a typical lower control limit of 80 cm for leadframe designs with 200 μm aluminium wire bonds.

    The central processing conflict is wire sweep on gate-side bond wires. High filler loading necessary for CTE control raises melt viscosity; reducing filler to improve flow increases thermal expansion mismatch. Wire sweep measured by x-ray imaging after moulding must remain below 5 % bond-wire span to avoid short-to-lead failure in biased HAST. The conflict is managed by grading filler particle size and using surface-treated spherical silica, which reduces EMC melt viscosity without changing filler volume fraction. Amine-based additives are excluded from the formulation because they reduce spiral flow at preheat temperature and produce premature gel at the gate. Postmould cure is set at 175 °C for 4 h to 8 h in an air-circulating oven; under-cure produces depressed DMA Tg and high moisture uptake, while over-cure oxidises the package surface and degrades adhesion. Terminal components include TO-247, TO-220F, DPAK, D2PAK, and Power QFN packages for discrete MOSFETs, diodes, and SiC Schottky rectifiers used in power factor correction, DC-DC conversion, and motor-drive output stages. Compliance is verified against UL 94 V-0 at finished package thickness, IEC 61249-2-21 halogen limits when halogen-free classification is required, and JEDEC J-STD-020 MSL 1 or MSL 2 depending on package thickness and die-to-pad ratio.

    What Limits Cavity Pressure in 1,200 V IGBT Transfer Molding with High-Tg EMC?

    Power module transfer molding differs from discrete packaging because the encapsulated substrate is a direct bonded copper laminate rather than an isolated metal leadframe. For a 1,200 V IGBT half-bridge module, the EMC must satisfy insulation coordination requirements under IEC 60664-1 and IEC 61800-5-1. Those requirements translate into comparative tracking index above 600 V under IEC 60112, dielectric strength above 15 kV/mm under ASTM D149, and UL 94 V-0 at module wall thickness. High-Tg EMC grades for this segment are filled with 88 wt% to 92 wt% spherical silica; a portion of the silica is replaced by spherical alumina from 10 wt% to 25 wt% of the filler phase to raise thermal conductivity while maintaining acceptable viscosity. The epoxy-phenolic network is formulated to provide DMA Tg between 220 °C and 260 °C when cured, but the high filler content narrows the processing window.

    The cavity-pressure limit is governed by the interaction of high melt viscosity and large substrate overhang. On a 150 t transfer press with a multi-gate mould, the EMC is preheated to 75 °C to 85 °C, the mould is held at 175 °C to 180 °C, and cavity pressure is kept below 8 MPa to avoid deflecting the DBC substrate; gate velocity is controlled by plunger speed rather than pressure. Higher cavity pressure produces wire sweep of the thick aluminium bond wires, but low cavity pressure yields incomplete fill at the module edges and knit-line voids. Published data for this specific configuration is limited, but production-scale failure analysis indicates that void-free moulding is achieved only when spiral flow at ASTM D3123 is maintained above 90 cm and resin viscosity at mould temperature remains below 200 Pa·s during the first 20 s of transfer.

    Postmould cure is carried out at 175 °C to 180 °C for 6 h, followed by CTE measurement on a sintered-silica reference coupon using ISO 11359-2. The EMC must produce α1 below 20 ppm/°C below Tg and α2 between 40 ppm/°C and 60 ppm/°C above Tg to avoid cracking through thermal cycling from −55 °C to 150 °C. Terminal use includes traction inverter IGBT and SiC MOSFET modules, three-phase industrial drives, and lift motor inverters; end-of-line tests include partial discharge inception voltage under IEC 60270 and HTRB at 175 °C for 1,000 h.

    When Engine-Bay Sensor ASICs Are Molded Directly in Electronic-Grade EMC

    Direct overmolding of wheel-speed, camshaft-position, and oil-pressure sensor ASICs requires the EMC to survive continuous operating temperatures of 150 °C to 180 °C in oil-fog and transmission-fluid environments. The formulation departs from high-filler power-device grades by reducing spherical silica loading to 78 wt% to 85 wt% and adding a flexibilizing elastomer phase at 1 phr to 3 phr to lower cure shrinkage stress around 20 μm copper wire bonds. Low ionic content is stricter than conventional IC packaging: extractable chloride below 5 ppm, ammonium and sodium below 2 ppm, and total sulfur species below 10 ppm, as measured by ion chromatography after pressure-cooker extraction. The low ion level is necessary because chloride or sodium migration through the EMC bulk to the ASIC bond pads creates galvanic corrosion at 150 °C operating temperature.

    Insert moulding of the sensor subassembly uses a lower clamp force press of 30 t to 60 t and carbide steel tooling with preheated inserts at 80 °C to 100 °C. Mould temperature is held at 165 °C to 175 °C to avoid exceeding the continuous-use rating of the pre-plated tin terminal finish; transfer pressure is limited to 3 MPa to 6 MPa because the ASIC edges and magnet wire-attach areas are more fragile than leadframe discrete packages. The EMC must adhere to polyarylate, PPS, or LCP housing walls that have been plasma-cleaned or silane-primed. Adhesion loss after oil immersion is a known failure mode; OEM validation specifications commonly require no blister and no loss of adhesion after 1,000 h immersion in automatic transmission fluid at 150 °C, though published data for this specific configuration is limited. Terminal products include active wheel-speed sensors with integrated ASIC and back-bias magnet, cam-phase sensors, oil-level and oil-quality sensors, and diesel common-rail pressure sensors.

    Postmould cure is adjusted to 170 °C for 2 h plus 180 °C for 4 h because the flexibilizer phase phase-separates if the first-stage cure is too rapid. Cure shrinkage is measured by dilatometry on a 4 mm thick plaque; linear shrinkage below 0.3 % is required to prevent sensor-gap shift. Electrical verification includes insulation resistance above 10 GΩ after 96 h biased HAST at 130 °C and 85 % relative humidity. Compliance to road-vehicle chemical load is checked under ISO 16750-5.

    Ignition Coil and Solenoid Encapsulation Dielectric Constraints

    Ignition coil and solenoid encapsulants require a different balance of filler packing, hot hardness, and dielectric withstand than power modules. The EMC is formulated with 80 wt% to 86 wt% fused silica, silane coupling agent at 0.5 phr to 0.8 phr, and a multi-functional epoxy novolac to increase crosslink density. The dielectric target is set by the peak primary flyback voltage; a 400 V primary pulse can create transient voltages above 2 kV at the secondary tower. Moulded parts are tested for dielectric strength to ASTM D149 with values from 18 kV/mm to 25 kV/mm, and for tracking resistance to IEC 60112 with CTI not less than 600 V.

    Transfer moulding over the primary and secondary copper coil is performed at reduced pressure to prevent crushing the enamel film. A 40 t to 80 t press is used with mould temperature 160 °C to 170 °C and transfer pressure 2 MPa to 5 MPa; lower temperature is selected because standard polyester and polyamide-imide coated magnet wire softens above 200 °C. The EMC must gel rapidly enough to prevent resin penetration into the winding interior but not so rapidly that the winding is starved of insulation at the mould exit. Gel time at 170 °C is controlled between 30 s and 55 s on a hot plate as measured by a rotating-cure meter. Terminal products include pencil-type ignition coils, coil-on-plug assemblies, transmission solenoids, ABS accumulator coils, and 48 V mild-hybrid converter inductors.

    Thermal shock resistance is validated through −40 °C to 150 °C air-to-air cycling, with no crack or partial discharge degradation after 500 cycles. Partial discharge testing is performed under IEC 60270 at a test voltage of 1.2 kV rms for the secondary winding; discharge inception below 1.2 kV is treated as a failure. The EMC must also maintain bond strength to PBT or phenolic bobbin surfaces; pull-off adhesion above 5 MPa after thermal cycling is specified by coil manufacturers.

    Hermetic Replacement Demands Preform Conditioning Below 60 % Relative Humidity

    Preform moisture content is the critical incoming material control for high-reliability non-hermetic encapsulation where metal-can hermetic packages are replaced. Storage of EMC preforms below 5 °C is standard, but the preforms must be allowed to reach 20 °C to 25 °C in a sealed moisture-barrier bag before opening; exposure time above 60 % relative humidity is limited to 1 h. Drying is specified at 60 °C for 4 h to 6 h if the bag has been breached or if the preform age exceeds the vendor-certified floor life. Inadequate drying produces voiding around noble-metal wire bonds and ceramic substrates during slow-fill transfer moulding.

    The filler system for high-reliability non-hermetic packages is held between 82 wt% and 88 wt% spherical silica, with an epoxy-cresol-novolac base and an anhydride or phenolic hardener chosen for hydrolytic stability. The mixing ratio of hardener to epoxy is controlled to an equivalent ratio between 0.98 and 1.02; trim agents are kept below 0.3 phr to minimise outgassing. Transfer moulding is carried out at 175 °C with a slow-fill profile to avoid forming voids around gold-bonded wire; vacuum evacuation below 1 kPa is maintained for 15 s before transfer. Terminal products include pressure transducers for commercial aircraft fuel systems, downhole well-logging sensor modules, and sealed DC-DC converter modules for military ground vehicles. Compliance is verified against MIL-STD-883 Method 5011 for ionic contamination limits and ASTM E595 for outgassing when specified.

    For high-current flat inductors and choke assemblies in 48 V mild-hybrid converters, high-temperature EMC serves as the sole insulation system between rectangular copper magnet wire and a liquid-cooled aluminium baseplate. The formulation uses 86 wt% to 91 wt% fused silica with an amine-free phenolic hardener to avoid copper-catalysed degradation reactions and maintain adhesion to the copper wire. The filler-to-resin ratio is selected to produce thermal conductivity near 1.0 W/(m·K) and a coefficient of thermal expansion close to copper at the baseplate interface, reducing tensile stress at the large-area bond line. Because the inductor operates with peak winding temperatures above 180 °C, the EMC is postcured at 180 °C for 8 h to complete phenolic-epoxy crosslinking.

    The moulding process uses a large low-pressure transfer press with a clamp force of 80 t to 150 t and a mould temperature of 170 °C to 175 °C. Transfer pressure is limited to 2 MPa to 4 MPa to avoid movement of the flat copper winding, and flow is gated over the baseplate rather than through the winding window. The EMC must fill the 1.5 mm to 3 mm gap between the baseplate and the winding without forming knit lines at the coolant-side surface. Voids are detected by scanning acoustic microscopy after moulding; any void larger than 200 μm at the copper-to-EMC interface is cause for rejection. Terminal products include water-cooled inductors for 48 V belt-starter generators, motor-drive output chokes, and interphase inductors in industrial active front-end drives. Compliance includes UL 94 V-0 at 1.5 mm, IEC 60112 CTI not less than 600 V, and IEC 61249-2-21 halogen-free limits for bromine below 900 ppm and chlorine below 900 ppm.

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    Certification & Compliance
    More Introduction

    High-temperature resistant epoxy molding compound in electronic/EL grade is a highly filled solid thermoset supplied as B-stage preforms or granules. The representative designation EMC-HT-EL-7000 is formulated for transfer molding of discrete power packages, power modules, automotive under-hood sensors, LED/electroluminescent leadframe reflectors, and high-brightness optical cavities. The compound is based on a multifunctional epoxy resin, phenol novolac hardener, spherical fused silica filler, and halogen-free flame retardant package. Typical molded plaques exhibit glass transition temperature from 195°C to 230°C by ASTM D3418, coefficient of linear thermal expansion alpha-1 from 8 ppm/°C to 14 ppm/°C by ASTM E831, flexural modulus from 18 GPa to 24 GPa by ASTM D790, and thermal conductivity from 2.0 W/mK to 3.5 W/mK by ASTM E1461. The compound is supplied in pellet mass of 14 g to 20 g and in granular form for multi-plunger presses with clamp force from 100 ton to 250 ton.

    What distinguishes high-temperature EL-grade EMC from standard electronic novolac compounds?

    Standard electronic EMC grades typically exhibit Tg between 150°C and 170°C and are specified for continuous-use temperatures below 150°C. High-temperature EL-grade formulations shift the resin/hardener stoichiometry toward higher crosslink density and increase fused silica loading. This raises Tg and lowers CTE but increases melt viscosity. In transfer molding, the trade-off appears as a reduction in spiral flow from 120 cm to 160 cm for standard EMC to 80 cm to 140 cm for high-temperature EMC when measured at 175°C and 70 kgf/cm² by ASTM D3123. The higher filler loading lowers CTE alpha-1 to 8 ppm/°C to 14 ppm/°C, closer to copper leadframes at 17 ppm/°C, but flexural modulus above 20 GPa raises die-surface stress on large-area power dice.

    PropertyTest methodHigh-temperature EL EMCStandard electronic EMCLiquid epoxy encapsulant
    Glass transition temperatureASTM D3418195–230°C150–170°C150–180°C
    CTE alpha-1ASTM E8318–14 ppm/°C12–20 ppm/°C30–45 ppm/°C
    Flexural modulusASTM D79018–24 GPa22–28 GPa3–8 GPa
    Thermal conductivityASTM E14612.0–3.5 W/mK0.8–1.5 W/mK0.2–0.5 W/mK
    Spiral flowASTM D312380–140 cm120–160 cmNot applicable
    Extractable chlorideIon chromatography<20 ppm<20 ppm<50 ppm
    Flame retardanceUL 94V-0 at 0.8 mmV-0 at 0.8 mmV-0 at 1.6 mm

    Because the electronic/EL designation carries optical and ionic cleanliness requirements, the compound is filtered to remove particulates above 20 µm and controlled for mobile ions. Extractable chloride by ion chromatography is typically below 20 ppm, sodium below 5 ppm, and ammonium below 10 ppm for EL-grade shipments. Aqueous extract pH is maintained between 4.0 and 7.0. This is relevant because chloride and sodium migration under high temperature and electrical field accelerates silver electrode tarnish and electroluminescent cathode corrosion. Low outgassing is also specified for optical surfaces; supplier data sheets for high-temperature optical grades commonly report total mass loss below 0.5% after 24 h at 200°C in nitrogen by ASTM E595. For low-alpha electronic applications, a selected filler option reduces alpha particle flux to below 0.002 counts/cm²/h.

    Transfer molding process window, pellet conditioning, and cure requirements

    Transfer molding of EMC-HT-EL-7000 is performed on multi-plunger transfer presses with clamp force from 100 ton to 250 ton and mold temperature from 170°C to 180°C. Transfer pressure from 80 kgf/cm² to 150 kgf/cm² is used, with transfer time below 15 s and cure time from 90 s to 180 s depending on package thickness. Preforms are preheated to 70°C for 30 min when storage has been at 5°C. Exposure to ambient air above 60% relative humidity requires pre-drying at 25°C under nitrogen or dry air for 8 h before molding. The practical processing window is bounded by gel time and spiral flow: a gel time below 30 s at 175°C can produce incomplete cavity filling in large modules, while gel time above 60 s prolongs cure and increases cycle time. After molding, post-mold cure at 175°C for 4 h completes conversion and stabilizes Tg; under-cure is detected as a broadened differential scanning calorimetry exotherm or Tg below 185°C.

    Operational boundaries include long-term continuous-use temperature not exceeding 230°C; sustained exposure above 260°C accelerates oxidative mass loss and degrades adhesion to copper leadframes. The compound is incompatible with amine-based accelerators or liquid epoxy-reactive diluents, which disturb the B-stage cure kinetics and create inhomogeneous crosslink density. Molded packages containing large copper pads should be evaluated for die-surface stress because flexural modulus above 20 GPa and CTE mismatch can induce passivation crack or die-attach delamination during thermal cycling from -55°C to 200°C per JESD22-A104B.

    When continuous junction temperature exceeds 200°C in SiC power modules

    In SiC MOSFET and IGBT power modules, junction temperature excursions above 200°C eliminate standard EMC grades because of Tg proximity and accelerated oxidation. High-temperature EL-grade EMC is used for transfer-molded packages with copper leadframes, aluminum wire bonds, and direct-bonded copper substrates. Its CTE alpha-1 of 8 ppm/°C to 14 ppm/°C reduces interfacial shear strain relative to copper, but its modulus remains higher than that of silicone encapsulants, which can reduce wire-bond fatigue life under power cycling. Silicone gels with CTE of 250 ppm/°C to 350 ppm/°C and thermal conductivity below 0.5 W/mK do not provide the same dimensional stability or flame retardance. The EMC is therefore specified where a UL 94 V-0 package at 0.8 mm is required alongside thermal conductivity above 2.0 W/mK.

    Material compliance is verified against RoHS Directive 2011/65/EU Annex II and halogen-free limits of IEC 61249-2-21. Electrical properties after molding are measured by IEC 60093 for volume resistivity, IEC 60243-1 for dielectric strength, and IEC 60112 for comparative tracking index. Volume resistivity is typically greater than 1E14 Ω·cm at 150°C, dielectric strength is from 15 kV/mm to 20 kV/mm, and comparative tracking index is typically 600 V at 0.8 mm. For optoelectronic/EL applications, reflectance retention at 460 nm after thermal aging at 200°C for 500 h is commonly specified; published data for this specific configuration is limited, so customer-specific aging protocols are required for final qualification.

    RequirementStandard or methodTypical measured value
    Flame retardanceUL 94V-0 at 0.8 mm
    Glass transition temperatureASTM D3418195–230°C
    CTE alpha-1ASTM E8318–14 ppm/°C
    Flexural strengthASTM D790120–150 MPa
    Water absorption after 24 hASTM D5700.1–0.2%
    Volume resistivity at 150°CIEC 60093>1E14 Ω·cm
    Dielectric strengthIEC 60243-115–20 kV/mm
    Comparative tracking indexIEC 60112600 V at 0.8 mm
    Copper leadframe adhesionButton shear at 25°C>8 MPa

    For a dual-sided power module with a 40 mm × 50 mm cavity and exposed copper heat slug, EMC-HT-EL-7000 is transfer-molded at 175°C, 120 kgf/cm² transfer pressure, and 150 s cure time, followed by 175°C post-mold cure for 4 h. The molded package is then subjected to JESD22-A104 thermal cycling from -55°C to 200°C and J-STD-020 reflow classification. No additional post-encapsulation coating is applied.

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