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Epoxy Molding Compound (EMC) Electronic/EL Grade

    • Product Name: Epoxy Molding Compound (EMC) Electronic/EL Grade
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 224622
    Resin Type Epoxy cresol novolac / biphenyl epoxy resin
    Filler Content 75-85 wt% fused silica
    Glass Transition Temperature 140-160 °C
    Coefficient Of Thermal Expansion Alpha1 9-15 ppm/°C
    Coefficient Of Thermal Expansion Alpha2 30-55 ppm/°C
    Spiral Flow 80-110 cm
    Melt Viscosity 20-50 poise at 175 °C
    Flexural Strength 150-180 MPa
    Flexural Modulus 15-20 GPa
    Water Absorption ≤0.3 wt% after PCT
    Flame Retardancy UL94 V-0
    Volume Resistivity ≥1e15 ohm·cm
    Dielectric Constant 3.8-4.2 at 1 MHz
    Dissipation Factor 0.005-0.015 at 1 MHz
    Ionic Impurities Na+ ≤5 ppm, Cl- ≤10 ppm

    As an accredited Epoxy Molding Compound (EMC) Electronic/EL Grade factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Epoxy Molding Compound (EMC) Electronic/EL Grade: supplied in 25 kg sealed moisture-barrier bags with desiccant, packed in protective cartons.
    Container Loading (20′ FCL) 20′ FCL: palletized, sealed cartons/bags of Epoxy Molding Compound, securely stowed, protected from moisture, maximizing container weight capacity.
    Shipping Epoxy Molding Compound (EMC) Electronic/EL Grade ships as a non-hazardous solid in sealed, moisture-proof bags within sturdy cartons or drums. Keep dry and store below recommended temperature. Avoid dust generation, static ignition, and direct sunlight. Standard freight; no special hazardous transport documentation required.
    Storage Store Epoxy Molding Compound (EMC) Electronic/EL Grade in its sealed original packaging within a cool, dry environment, ideally refrigerated at 2–8°C. Protect from moisture, heat, and direct sunlight. Before use, allow the container to warm fully to room temperature to prevent condensation. Record receipt dates and follow FIFO to maintain shelf life.
    Shelf Life Shelf life is typically 6 months from manufacture when stored sealed at -10°C or below, preventing premature curing.
    Application of Epoxy Molding Compound (EMC) Electronic/EL Grade

    In leadframe-based semiconductor packaging, epoxy molding compound is processed as a single-component solid thermoset and is not compounded on the molding floor. The standard IC packaging grade is formulated with fused silica filler at 87–90 wt%, phenol-cured epoxy resin at 6–9 wt%, phenolic hardener at 3–5 wt%, and the remaining ≤1.5 wt% comprising cure accelerator, adhesion promoter, release agent, and carbon black; the epoxy-to-phenolic hydroxyl equivalent ratio is controlled within 0.95–1.05 to reduce free epoxide after cure. Compliance for this application segment is governed by UL 94 V-0 at 0.8 mm thickness, IPC/JEDEC J-STD-020E Moisture Sensitivity Level 3 with floor life of 168 h at 30 °C/60% RH, RoHS Directive 2011/65/EU Annex II, and REACH Regulation EC 1907/2006 SVHC restrictions. Production transfer molding is performed on automated multi-plunger presses with clamp force between 80 t and 200 t; pellets are preheated to 75–80 °C before entering the pot, mold temperature is held at 175 ± 3 °C, transfer pressure is set to 7–9 MPa, cavity fill completes in 5–12 s, and in-mold cure time is 90–150 s. Post-mold cure is run at 175 ± 5 °C for 4–6 h to complete phenol–epoxy addition and stabilize glass-transition temperature. On production lines, preheat variation of ±5 °C at the pot is a primary contributor to spiral-flow lot-to-lot variation because the compound’s melt viscosity at 175 °C is typically in the 10–30 Pa·s range and changes sharply with thermal history. Wire sweep on 25 µm gold wire is controlled by maintaining transfer-velocity profiles and gate design rather than by increasing filler concentration alone. Mold chase layouts with balanced runner lengths within 3% are used to avoid flash and short-shot imbalance across multi-cavity blocks. Terminal package formats produced with this standard grade include 0.4 mm-pitch QFP, SOIC-8/16, TSSOP-8/14/16, and QFN with exposed die pad.

    Power Module Encapsulation Requires Low-Warpage Compounds With Aluminum-Wire Compatibility

    Power discrete and module packaging presents a processing boundary because high filler loadings required for thermal transport reduce melt flow and increase the probability of wire sweep on aluminum bond wires. The formulation ratio for this segment shifts to a fused silica–alumina hybrid filler at 88–93 wt%, with the spherical alumina fraction comprising 40–65 wt% of the total filler mass to raise thermal conductivity into the 2.0–4.0 W/(m·K) range when measured by ASTM D5470; epoxy resin is reduced to 5–8 wt%, phenolic aralkyl hardener is held at 3–5 wt%, and additives remain below 1 wt%. Alumina particle-size distribution with D50 in the 5–15 µm range and spherical morphology is used to limit viscosity increase, while fused silica remains present to retain spiral flow above 70 cm at 175 °C/6.9 MPa. Compliance includes UL 94 V-0 at 0.4–0.8 mm, IEC 60112 comparative tracking index above 600 V for high-voltage module creepage paths, IEC 60664-1 insulation coordination, and RoHS 2011/65/EU Annex II. Carbon black content is controlled narrowly because excessive carbon can degrade tracking resistance and increase electrical leakage across direct-bonded copper features.

    ParameterTest method / conditionStandard IC packaging EMCHigh-thermal power EMC
    Filler loadingThermogravimetric ash content, ASTM E113187–90 wt%88–93 wt%
    Thermal conductivityASTM D54700.6–0.9 W/(m·K)2.0–4.0 W/(m·K)
    Glass-transition temperatureASTM D3418 (DSC)125–150 °C150–180 °C
    CTE α1Thermomechanical analysis, ISO 11359-28–12 ppm/°C7–10 ppm/°C
    Spiral flow at 175 °C/6.9 MPaSpiral flow mold80–120 cm70–110 cm

    Vacuum-assisted transfer molding with clamp force of 150–300 t and multi-pot feed is used to minimize voids around direct-bonded copper regions. Pellets are preheated to 75–85 °C, mold temperature is held at 175–185 °C, transfer speed is reduced relative to standard IC packages, and cure time is extended to 120–180 s to compensate for the lower resin volume. Post-mold cure is 6–8 h at 170–180 °C. Wire sweep on 125–250 µm aluminum wire can exceed 3% lateral displacement when transfer speed is not reduced or when melt viscosity rises above process limits; gate design with wider openings and lower shear rates is therefore specified. Void-rate targets below 0.1 vol% are common for modules with high-voltage termination, but published data for specific module configurations is limited. Moisture uptake above 0.1 wt% in the compound before molding can produce wire sweep and partial discharge voids, so conditioned storage at 5–10 °C or pre-drying is required when factory relative humidity exceeds 60%. Terminal package formats include TO-220, TO-247, DPAK, single- and three-phase IGBT modules, intelligent power modules, and discrete diode packages with aluminum ribbon or heavy aluminum wire interconnects.

    What Limits Cavity Pressure Drop in Panel-Level Compression Molding of Epoxy Molding Compound?

    When panel-level compression molding replaces transfer molding in fan-out wafer- and panel-level packages, cavity pressure drop is governed by the compound’s low-shear melt viscosity, filler loading, and the available compression stroke. For this segment, the formulation ratio is adjusted to 82–86 wt% fused silica filler, epoxy resin at 8–12 wt%, hardener at 4–6 wt%, and an elastomer stress-relief component at 1–2 wt%, because a lower filler fraction reduces melt viscosity and extends flow distance before gelation. Spiral flow values in the 80–140 cm range and gel times of 30–45 s at 175 °C are typical supplier-controlled windows. Compliance follows UL 94 V-0 at 0.8 mm, RoHS 2011/65/EU Annex II, IPC/JEDEC J-STD-020E, and cleanroom handling under ISO 14644-1 Class 5 for panel-level molding tooling interfaces. Compression molding presses with vacuum chambers maintain chamber pressure below 0.1 kPa during melt flow; mold temperature is set at 150–170 °C, applied compression pressure is 3–5 MPa, and cure time extends to 5–15 min depending on panel thickness and die distribution. On 300 mm round or 600 × 600 mm panel formats, filler loadings above 86 wt% typically produce cavity pressure drops that limit fill before gelation unless mold temperature is raised toward the upper limit. Thickness uniformity across the mold cap is held within ±15 µm to avoid die shift and subsequent solder-joint standoff variation. Terminal formats include 300 mm round fan-out wafer-level packages, 600 × 600 mm panel-level chip-first or chip-last formats, and molded array packages later singulated into 2 × 2 mm to 10 × 10 mm fan-out packages.

    For automotive and underhood high-reliability applications, epoxy molding compound must retain adhesion and pass thermal cycling after exposure to engine-compartment temperature excursions. The formulation ratio for this segment uses a high-Tg phenol-aralkyl resin system at 7–9 wt%, hardener at 3–4.5 wt%, and fused silica filler at 89–91 wt%; residual chloride is held below 5 ppm to limit leadframe corrosion, and the compound is processed without post-mold deflashing acids that could attack exposed copper. Compliance is defined by AEC-Q100 Grade 0 for -40 °C to +150 °C ambient operation, AEC-Q101 for discrete devices, JESD22-A104K temperature cycling at -55 °C to +150 °C for 1000 cycles, JESD22-A110 highly accelerated stress testing at 130 °C/85% RH for 96 h, IPC/JEDEC J-STD-020E, and RoHS 2011/65/EU. Transfer molding on presses with clamp force from 120–220 t uses preheat at 80–85 °C, mold temperature at 180–190 °C, transfer pressure at 7–10 MPa, and cure time of 120–180 s; post-mold cure is 6–8 h at 175 °C to drive phenol–epoxide conversion toward completion and stabilize Tg. C-mode scanning acoustic microscopy is used after thermal shock to detect die-attach or molding-compound delamination, and mold release is adjusted to avoid interfacial contamination. Terminal products include engine control unit packages, transmission sensor ICs, ABS brake pulse modulators, battery management system transceivers, and underhood power-management devices.

    Copper-Clad Leadframe Adhesion and Low-Stress Formulations for MEMS and Sensor Packages

    In MEMS and sensor packaging, silicone-modified epoxy molding compound is used to reduce package-induced offset drift and die stress after post-mold cure. The formulation ratio in this low-stress grade departs from standard semiconductor EMC: filler loading is reduced to 75–84 wt%, silicone-modified epoxy resin is 10–15 wt%, phenolic hardener is 4–5 wt%, and stress-relief additives are 1–3 wt%. This yields tensile modulus in the 8–15 GPa range and α1 coefficient of thermal expansion near 10–14 ppm/°C, reducing die stress after post-mold cure. Adhesion promotion to copper-clad leadframes is rebalanced when silicone content is increased because silicone migration to the leadframe surface can lower shear adhesion; silane coupling agents and controlled release additives are used to maintain interfacial strength. Compliance includes ISO 14644-1 Class 5 cleanroom operation for optical and MEMS device handling, IPC/JEDEC J-STD-020E, UL 94 V-0 at 0.8 mm, and RoHS 2011/65/EU Annex II; for image sensor grades, alpha-particle emission is controlled below 0.01 counts/cm²/h. Transfer molding is performed at lower transfer pressure, typically ≤5 MPa, and 170–180 °C mold temperature, with cure time of 90–150 s and post-mold cure of 4 h at 170–175 °C. Gate design and melt-viscosity control are critical because shear-thinning at gates can locally exceed 200 s⁻¹ and create residual stress concentrations around MEMS cavities. Terminal formats include MEMS pressure sensors, 6-axis inertial measurement units, MEMS microphones, optical proximity sensors, and ambient-light sensor packages; exposed moving MEMS structures are not encapsulated directly but are covered by cap wafers or cavity packages before overmolding.

    When Halogen-Free Formulations Replace Standard Novolac Systems in Thin Small-Outline Packages

    The substitution of halogen-free epoxy molding compound into thin small-outline packages imposes narrower cure and flow boundaries because phosphorus-based flame retardants alter gel time and mold-release behavior. The formulation ratio for thin packages balances melt flow and flame retardancy with fused silica filler at 88–91 wt%, epoxy resin at 5–7 wt%, hardener at 2.5–3.5 wt%, and halogen-free flame retardant at 1–2.5 wt%; total chlorine is kept below 900 ppm, total bromine below 900 ppm, and total halogens below 1500 ppm according to IEC 61249-2-21. Compliance also includes UL 94 V-0 at 0.25–0.8 mm, RoHS 2011/65/EU Annex II, and IPC/JEDEC J-STD-020E moisture sensitivity classification. In production, thin QFN and TSOP packages are transfer molded at 175–185 °C with transfer pressure of 6–10 MPa and cure time of 60–120 s; shorter cure times are used to reduce die attach film bleed, but gel-time variation can shift spiral flow by more than 10 cm if preheat is not held within ±3 °C. Post-mold cure at 175 °C for 4 h stabilizes adhesion to silver-plated copper leadframes. Published data for this specific configuration is limited for ultra-thin 0.35 mm QFN packages. Terminal product types include TSOP-I/II, thin QFP, QFN, chip-scale packages, and molded packages for consumer, handheld, and industrial control devices.

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    Certification & Compliance
    More Introduction

    Epoxy Molding Compound (EMC) Electronic/EL Grade is a solid, B-staged, mineral-filled thermoset epoxy compound formulated for transfer molding of electrical/electronic components requiring controlled ionic cleanliness, flame retardancy, and dimensional stability. Commercial designations include manufacturer-suffixed EL codes such as EMC-EL-6xx and EMC-EL-9xx series; the EL suffix denotes an electrical/electronic insulation grade rather than a semiconductor IC or optoelectronic grade. The compound is supplied as preformed pellets or cylindrical preforms with a typical spiral flow of 80–120 cm at 175 °C and 6.9 MPa transfer pressure per ASTM D3123. It differs from standard IC-grade EMC principally in filler loading, stress modifier content, and extractable ion limits.

    Model nomenclature is not standardized across suppliers. The EL suffix is used in several datasheets for electrical/electronic insulation grades; the numerical suffix generally indicates filler type, flow length, or flame-retardant system. End users select among standard flame-retarded, low-warpage, high-flow, and high-adhesion variants within the EL family according to part geometry and insert density.

    What Limits the Transfer Molding Process Window for Electronic/EL Grade EMC?

    Transfer molding presses with clamp force from 50 t to 200 t are used for multi-cavity electrical part production. The material is preheated to 60–80 °C and molded at 165–185 °C. The process window is constrained by gel time measured at 175 °C as 30–60 s and by minimum melt viscosity in the range of 10–50 Pa·s at 175 °C. If gel time falls below 25 s, incomplete cavity filling occurs in high-pin-count connector housings; if spiral flow exceeds 130 cm, flash generation increases and mold cleaning frequency rises.

    Molding pressure for thin-wall terminal blocks is typically 7–15 MPa transfer pressure, with cavity fill time of 5–15 s. Cure time for a wall thickness of 1.0–2.0 mm is 90–150 s. The relationship between minimum viscosity and filler packing is nonlinear: raising filler content to reduce CTE increases melt viscosity and narrows the processing window. This trade-off is the primary reason Electronic/EL Grade is segregated from semiconductor-grade compounds in production planning.

    Compounding is typically performed on co-rotating twin-screw extruders with an L/D ratio of 40:1 to 48:1 and controlled barrel temperatures of 90–110 °C. Inconsistent filler feeding produces spiral flow variation of approximately ±10 cm and glass transition temperature variation of ±3 °C batch to batch. Manufacturing lines therefore monitor filler feed rate, screw torque, and melt temperature downstream of the kneading block as indicators of dispersion quality.

    High-volume relay and sensor encapsulation lines preheat pellets to 65 °C and mold at 175 °C for 90–120 s, followed by post-mold cure at 175 °C for 4 h. Typical applications include automotive relay housings, ignition coil bobbins, capacitor sleeves, Hall-effect sensor encapsulants, and terminal blocks. In these parts, the critical requirement is electrical insulation combined with thermal cycling resistance from -40 °C to 150 °C. Molded parts are ejected with a typical hot hardness of 85–95 Shore D; post-cure raises glass transition temperature by 5–10 °C and stabilizes residual stress in metal-insert moldings.

    For parts with copper or brass inserts, the Electronic/EL Grade is selected because the cured compound withstands repeated thermal shock without insert pull-out. The insert-to-compound interface is stressed by dissimilar CTE values, and premature ejection before reaching demolding hardness causes interfacial microcracking that is not visible until damp heat exposure. Process control therefore includes a minimum ejection hardness of 85 Shore D and periodic cross-section inspection for insert interfacial voids.

    When Ionic Impurity and Moisture-Uptake Thresholds Dictate Grade Selection

    The Electronic/EL Grade is specified with total extractable chloride below 20 µg/g and combined sodium and potassium below 10 µg/g when tested by pressurized water extraction at 121 °C for 20 h. Sulfur and ammonium cation content is controlled to reduce electrochemical migration across biased interconnects. In damp heat testing at 85 °C and 85% RH with 50 V DC bias, electrochemical migration resistance across 0.5 mm conductor spacing is evaluated using IPC-TM-650 2.6.14.1; the damp heat environment is maintained according to IEC 60068-2-67.

    Moisture absorption after 24 h immersion is 0.20–0.30% per ASTM D570-98. For molding operations in ambient relative humidity above 60%, pre-drying of pellets at 80 °C for 4 h is required to prevent surface porosity and delamination. The compound should not be processed with amine-containing mold release agents or cross-contaminated with phenolic novolac dusts because amine- and phenolate-initiated epoxy homopolymerization shortens gel time and shifts the cure profile outside the validated processing window.

    Incompatible residues include sulfur-vulcanized rubber dust and certain tin-catalyzed silicone greases. If molding equipment is shared with amine-catalyzed or sulfur-vulcanized compounds, a purging sequence with a commercial phenolic-free purge compound is required because residual sulfur compounds can poison the epoxy catalyst and alter gel time. Line audits for contact materials are recommended when batch-to-batch gel time shifts exceed 5 s without a raw material change.

    Thermal-Mechanical Property Shifts Below and Above the Glass Transition Are Not Linear

    Glass transition temperature measured by differential scanning calorimetry per ISO 11357-2:2020 is typically 150–180 °C for Electronic/EL Grade. Below Tg, the coefficient of linear thermal expansion per ISO 11359-2:2021 is 18–28 ppm/°C; above Tg, CTE increases to 55–75 ppm/°C. This discontinuity is the dominant stress generator in metal-insert moldings, where inserted copper expands at 16–18 ppm/°C and the cured compound above Tg expands at more than three times that rate. Cracking at the insert interface is controlled by reducing α1 and by using stress modifiers rather than by increasing filler content alone.

    Flexural strength per ISO 178:2019 is 120–150 MPa, and flexural modulus is 15–25 GPa. The combination of high modulus and intermediate CTE places the material between rigid semiconductor EMC and flexible liquid encapsulants. This is one reason it is selected for stiff connectors and relay housings where mechanical alignment must be maintained during thermal cycling.

    Material Specifications and Incoming-QC Reference Values

    Incoming quality control for Electronic/EL Grade typically uses the following reference values. These are compiled from published datasheets for commercial grades of this class and should be verified against the supplier lot certificate for each specific model.

    Property Test method Typical reference value
    Spiral flow at 175 °C, 6.9 MPa ASTM D3123 80–120 cm
    Gel time at 175 °C Hot plate cure test 30–60 s
    Mold shrinkage ASTM D955-08 0.15–0.30%
    Glass transition temperature ISO 11357-2:2020 150–180 °C
    CTE below Tg ISO 11359-2:2021 18–28 ppm/°C
    Flexural strength ISO 178:2019 120–150 MPa
    Flexural modulus ISO 178:2019 15–25 GPa
    Volume resistivity IEC 62631-3-1:2016 1 × 1015 Ω·cm
    Dielectric strength IEC 60243-1:2013 18–25 kV/mm
    Water absorption, 24 h ASTM D570-98 0.20–0.30%
    Density ISO 1183-1:2019 1.8–2.1 g/cm³
    Flammability UL 94, IEC 60695-11-10 V-0 at 0.8 mm

    Flame-retarded Electronic/EL Grade variants use phosphorus-based or metal-hydrate flame retardants rather than brominated epoxy resins when halogen-free compliance is required. Flammability classification is UL 94 V-0 at 0.8 mm thickness according to IEC 60695-11-10. Halogen-free qualification can be specified by comparing total chlorine and bromine contents to the 900 ppm limit in IEC 61249-2-21; specific electrical/electronic grades may target total halogen below 900 ppm.

    Comparative Behavior Against Semiconductor Molding Compounds and Liquid Encapsulants

    Electronic/EL Grade differs from semiconductor IC-grade EMC primarily in filler content and stress modifier loading. Semiconductor-grade EMC uses crystalline silica filler at 87–92 wt% to achieve CTE near 8–12 ppm/°C and Tg above 175 °C, whereas Electronic/EL Grade uses fused silica and elastomer-modified epoxy at 70–85 wt% filler loading. The lower filler content permits higher flow around inserts and reduces insert cracking but increases mold shrinkage and CTE. These trade-offs are acceptable in electrical/electronic parts but would be rejectable in large-area IC packages requiring die-attach reliability.

    Compared with two-part liquid epoxy encapsulants, Electronic/EL Grade provides a B-staged solid system with no pot life limitation and higher filler loading for lower CTE. The limitation is gap penetration: solid EMC cannot reliably fill gaps below 0.2 mm, whereas unfilled or lightly filled liquid epoxy encapsulants penetrate gaps below 0.05 mm. Therefore, liquid encapsulants remain necessary for narrow-gap potting and underfill, while Electronic/EL Grade is used for transfer-molded housings and discrete component encapsulation.

    Parameter Electronic/EL Grade EMC Semiconductor IC-Grade EMC Two-Part Liquid Epoxy Encapsulant
    Physical form Solid B-staged pellets/preforms Solid B-staged granules Liquid, pot life limited
    Filler content 70–85 wt% 87–92 wt% 40–70 wt%
    Total hydrolyzable chloride <20 µg/g <5 µg/g 10–100 µg/g
    Glass transition temperature 150–180 °C 175–260 °C 100–150 °C
    CTE below Tg 18–28 ppm/°C 8–12 ppm/°C 30–50 ppm/°C
    Flexural modulus 15–25 GPa 25–35 GPa 3–8 GPa
    Effective minimum gap penetration 0.2 mm 0.15 mm 0.05 mm
    Typical use Connectors, relays, sensors, bobbins, terminal blocks IC packages, discrete power packages Potting, narrow-gap filling, underfill

    Storage life is typically 6 months at 5 °C or 3 months at 23 °C in sealed moisture-barrier bags. Bags must be equilibrated to room temperature for 2–4 h before opening to avoid condensation on pellets. Molded parts are not recommended for continuous exposure to strong acids, strong alkalis, or ketone solvents. Post-mold cure at 175 °C for 4 h increases Tg by 5–10 °C, lowers residual free epoxy, and reduces post-mold warpage in asymmetric geometries.

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