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ZPC (Zhejiang Petroleum & Chemical) HDPE GC7260

    • Product Name: ZPC (Zhejiang Petroleum & Chemical) HDPE GC7260
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 724303
    Melt Flow Rate 7.0 g/10 min (190°C/2.16 kg)
    Density 0.960 g/cm³ (23°C)
    Tensile Strength At Yield 30 MPa
    Tensile Strength At Break 20 MPa
    Elongation At Break 500%
    Flexural Modulus 1400 MPa
    Notched Izod Impact Strength 50 J/m (23°C)
    Hardness Shore D 65
    Vicat Softening Temperature 126°C
    Heat Deflection Temperature 75°C
    Brittleness Temperature -70°C
    Mold Shrinkage 1.5-3.0%
    Water Absorption <0.01%
    Volume Resistivity >10^16 Ω·cm
    Dielectric Constant 2.3 (1 MHz)
    Melting Point 130-135°C
    Thermal Conductivity 0.4 W/m·K
    Coefficient Of Linear Thermal Expansion 1.2 x 10^-4 /°C
    Specific Heat 1.9 kJ/kg·K
    Environmental Stress Cracking Resistance >1000 h
    Ash Content <0.05%
    Moisture Content <0.1%
    Bulk Density 0.55-0.60 g/cm³
    Particle Size 2-4 mm

    As an accredited ZPC (Zhejiang Petroleum & Chemical) HDPE GC7260 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing
    Shipping
    Storage
    Application of ZPC (Zhejiang Petroleum & Chemical) HDPE GC7260

    At a nominal melt flow index of 7.0 g/10 min determined to ISO 1133-1:2022 and a density of 0.960 g/cm³ measured under ISO 1183-1:2019, GC7260 is introduced directly into multi-cavity crate moulds without predrying when internal moisture is below 0.05 wt%. At ambient relative humidity above 60%, hopper drying at 75–80 °C for 1 h is applied to eliminate splay at rib intersections and around pin gates. The narrow melt-index band reduces shot-to-shot viscosity drift in continuous campaigns extending beyond 72 h. Failure modes observed on production lines include gate blush when injection speed is raised before the melt cushion is fully stabilised, and jetting in the thick base ring when the gate land is worn below 1.5 mm.

    Gate Freeze-Off and Flow Length in High-Speed Crate Tooling

    High-speed crate tooling on toggle clamp machines from 650 t to 1,200 t requires a projected-area clamp force of 4.5–5.5 kN/cm². Melt temperature is maintained at 210–235 °C. Mould temperature is kept between 15 °C and 30 °C. Pin gates of 1.8–2.5 mm diameter are placed at base intersections. Larger gates generate gate blush on textured surfaces. Hold pressure profiles of 55–70 MPa for 6–10 s maintain cavity pressure above 45 MPa at gate freeze-off. When gate freeze-off pressure falls below 45 MPa, sink marks appear at rib-root nodes within 24 h after demoulding. Cavity pressure transducers installed behind the last fill point provide the release signal for holding pressure rather than time-based transfer alone.

    Post-mould shrinkage in 600 mm × 400 mm bottle crates is 1.6–2.0% in the flow direction and 1.2–1.6% in the transverse direction after ageing for 48 h at 23 °C. Moulds are steel-safe by +0.8% in long dimensions and +0.5% in rib thickness. Measurement points are fixed at the base centre, mid-rib, and handle boss. Production batches with wider molecular weight distribution can shift shrinkage by 0.2% and require cavity pressure revalidation.

    Regrind from post-industrial runners and rejected crates is incorporated up to 15 wt% for non-food logistics crates when the regrind stream is contamination-controlled and heat history does not exceed two passes. Higher regrind fractions lower spiral flow length by more than 10% at 210 °C and 100 MPa injection pressure. Tensile yield measured on type 1A specimens under ISO 527-2:2012 is then maintained at or above 24 MPa. Food-contact crate applications are formulated from virgin material or a food-contact-controlled closed-loop regrind stream only. The finished article is subject to an overall migration limit of 10 mg/dm² under Regulation (EU) No 10/2011, Annex I. The polymer is an olefin polymer covered by FDA 21 CFR 177.1520(c). Heavy metal and phthalate screens follow RoHS Directive 2011/65/EU only when electrical ancillary items are assembled to the crate; standard logistics crates fall outside the directive’s electrical scope.

    Terminal articles from this moulding route include stackable bottle crates, dairy crates, ventilated fruit and vegetable crates, fish boxes with drainage slits, and high-abuse retail display totes. Crates are matched with injection-moulded PE closure plugs or pressed-in hinge pins. No post-mould machining is required. Wall stock is kept between 2.5 mm and 4.0 mm to balance impact strength under ASTM D256-23 Izod testing with acceptable cycle time.

    Single-cavity and two-cavity open-head pail tools are run at melt temperatures of 200–230 °C and mould temperatures of 20–35 °C. Direct sprue gating with a cold well of 3.0 mm minimum diameter prevents gate blush on the base centre. Wall thickness tapers from 2.0 mm at the seal rim to 4.0 mm at the base. The resulting weight distribution maintains cylindrical roundness below 0.8 mm measured across the opening. For tight-seal pails, the rim is cooled by a separate water circuit at 12–18 °C to reduce differential shrinkage against the lid skirt.

    UN-rated open-head containers for solvent-based coatings are performance-tested under Chapter 6.1.5 of the UN Model Regulations. The pail is subjected to drop, leakproofness, hydrostatic pressure, and stacking tests. Drop test height is derived from filling material density and packing group. Leakproofness is confirmed after conditioning at -18 °C for filled containers. Chemical compatibility is the controlling limitation. Contact with aromatic hydrocarbons, ketones, and halogenated solvents at temperatures above 40 °C accelerates environmental stress cracking. Pails intended for terpene-based cleaners or strong detergents are pre-qualified by ASTM D1693-15 Condition B bent strip testing. If time to 50% failure is below 48 h, a higher-ESCR polyethylene or a barrier liner is required. Published data for GC7260 in aggressive solvent pails is limited.

    Colour masterbatch is added at 1.0–2.0 wt% with an HDPE carrier. UV-stabilized masterbatch is added at 1.5–2.5 wt% for outdoor storage. In 20 L pails on 800 t clamp machines, total cycle time ranges from 38 s to 45 s. Screw plastication time is 4.5–5.5 s at 80 rpm with a general-purpose screw of 20:1 L/D. Melt cushion is held at 3–6 mm to maintain consistent switchover pressure. Holding pressure of 50–65 MPa for 8–12 s is applied before gate freeze. Terminal items include 5–25 L paint pails, grease cartridges, adhesive tubs, ink buckets, and construction chemical containers. Handles are fitted by post-mould insertion or in-the-press assembly. Pail lids use a folded locking skirt requiring no elastomeric gasket for non-hazardous fills.

    What Limits Torque Retention in Polyethylene Closure Bridges?

    Closure moulding with GC7260 targets bridge thicknesses of 1.5–2.5 mm for 26 mm and 28 mm single-piece caps. The melt flow index of 7.0 g/10 min permits filling of 32-cavity hot-runner tools at injection speeds below 100 mm/s. Above this speed, shear heating at the valve gate tips increases melt temperature into the 245–255 °C range and produces flow lines on the cap skirt. The gate tip is sized to deliver a gate freeze time of 1.5–2.0 s so that holding pressure is effective without excessive bridge packing.

    Torque retention after 24 h at 23 °C is controlled by bridge crystallinity and residual stress. Mould temperature below 15 °C freezes orientation into the bridge and reduces torque retention to below 1.2 N·m before tamper removal. Mould temperature between 20 °C and 30 °C maintains bridge torque retention at 1.5–2.0 N·m. Cores are cooled separately from cavities. Core water inlet temperature is set 5–8 °C below cavity water inlet temperature to control skirt shrinkage and strip force. Torque removal values are recorded on calibrated torque analysers with 0.01 N·m resolution. The test head is aligned to the bottle neck finish using a constant axial force of 5 N to avoid cap-to-finish bias.

    Slip additive masterbatch is limited to 0.3–0.8 wt%. Higher levels reduce cap-body friction but increase migration onto filled contact surfaces. Colour masterbatch is added at 1.0–1.5 wt%. Pearlescent and metallic concentrates are excluded for closures requiring FDA 21 CFR 177.1520 food-contact status. For detergent and trigger sprayer closures, ESCR testing is performed under ASTM D1693-15 Condition A because residual stress concentrates at the bridge hinge roots. Published multi-cavity closure data specific to GC7260 is limited. Production trials should map hold pressure against bridge fill and torque with a two-level factorial design covering melt temperature 210 °C and 240 °C, injection speed 60 mm/s and 90 mm/s, and hold pressure 50 MPa and 70 MPa.

    Terminal closures include beverage screw caps, detergent caps, trigger sprayer bodies, plug seals, and tamper-evident overcaps. The closures are not recommended for carbonated beverage containers requiring sustained 3 bar CO₂ retention unless the closure design includes an EVA liner. Unreinforced HDPE bridges exhibit creep under sustained internal pressure. The application is therefore limited to still drinks, dry products, and atmosphere-vented fills.

    When Demoulding Forces Exceed 25 kN on 1.0 mm Core Blades

    In stacked or tandem moulds, thin-wall food storage containers of 0.9–1.2 mm nominal wall are produced with ejection strokes not exceeding 18 mm beyond the core surface. Demoulding force on textured cores rises from 12 kN at wall 1.2 mm to over 25 kN at wall 0.9 mm when draft angle is below 0.5°. GC7260 fills flow-length/wall-thickness ratios up to 190:1 at 230 °C and 100 MPa injection pressure. The melt is injected through valve gates with a land length of 0.8–1.0 mm to reduce gate vestige on the container base.

    Water-cooled cores are held at 8–12 °C to reduce cycle time. Cavity halves are maintained at 18–25 °C. Differential cooling is applied because a uniform mould temperature above 25 °C extends cycle time beyond 11 s for a 0.9 mm container. Cooling time is removed when the frozen layer reaches 0.45 mm on each surface. Melt temperature is kept between 220 °C and 240 °C. It is not raised above 260 °C; oxidative degradation at higher temperature reduces notched Izod impact under ISO 180:2023 by more than 20%.

    Hold pressure is critical. Packing occurs only while the gate remains unfrozen. For a 0.8 mm side wall with a 1.0 mm gate land, gate freeze time is approximately 2.0–2.5 s at 220 °C. Packing pressure of 60–75 MPa applied for 2.0–3.0 s controls sink marks. Longer hold time is ineffective after gate freeze. On a 500 t electric toggle machine with a 48-cavity thin-wall tool, screw recovery time becomes the cycle-limiting step if screw speed is set below 60 m/min peripheral velocity.

    Food-contact status follows FDA 21 CFR 177.1520(c) for polyethylene and Regulation (EU) No 10/2011 for overall migration. For microwave reheating claims, total migration testing is performed using food simulants selected from Annex III of Regulation (EU) No 10/2011. The container is classified for aqueous, acidic, and low-alcohol foods. Fatty food contact above 40 °C is excluded unless an inner barrier layer is co-moulded. Terminal articles include microwaveable storage bases, freezer boxes, refrigerator trays, disposable thin-wall inserts, and stackable houseware units. Lids are produced from the same grade or paired with LDPE sealing rings.

    Compliance matrix for selected application categories
    ApplicationStandardClause or methodTypical condition
    Food-contact crates and containersFDA 21 CFR 177.1520Olefin polymers, extractives limits under paragraph (c)Food types and use conditions assigned per finished article
    EU food-contact articlesRegulation (EU) No 10/2011Annex I overall migration limit, Annex III simulants10 mg/dm² overall migration
    Toy componentsEN 71-3:2019+A1:2021Element migration by material categoryCategory II limits for dry brittle materials
    UN-rated open-head pailsUN Model RegulationsChapter 6.1.5 performance testsDrop, stacking, leakproofness, hydrostatic pressure

    Toy component moulding uses GC7260 for blocks, activity centres, stacking cups, bath-toy shells, and outdoor play components. Melt temperature is kept between 200 °C and 235 °C. Mould temperature is maintained at 15–25 °C to reduce post-mould shrinkage in tight-fit assemblies. Insert moulding of PP or HDPE axles is avoided when the inserted component has a softening point below 130 °C. Premature deformation is observed during the first reheat cycle in warm-water cleaning at 65 °C.

    Elemental migration is tested to EN 71-3:2019+A1:2021. Limits depend on material category. Dry, brittle, powder-like toy materials have Category II limits, including 19 mg/kg for antimony and 0.02 mg/kg for mercury. US market compliance uses ASTM F963-23 soluble heavy metal extraction. Phthalate testing is not applicable to neat HDPE but is applied when flexible polymer coatings or inserted parts are present. For toy articles intended for repeated water immersion, dimensional change after 24 h immersion at 23 °C is held below 0.5%.

    Food-contact toy applications follow FDA 21 CFR 177.1520(c). The finished toy is not suitable for repeated boiling-water sterilization above 100 °C because dimensional change exceeds 2.0% in long sections. Warm water at 65 °C is tolerated without measurable distortion. Cycle time for a 120 g toy block on a 250 t machine is 18–22 s. Holding pressure of 45–55 MPa for 4–5 s is sufficient. High-polish cavity surfaces are recommended. Textured surfaces increase ejector pin marks and raise demoulding force by approximately 15%.

    Returnable Transit Packaging Under Constant Compression Set

    Returnable transit packaging, including folding pallet boxes, sleeve-pack frames, and logistics dunnage, is injection moulded with wall stocks from 3.0 mm to 6.0 mm. Compression set under constant load is measured after 7 days at 40 °C using ISO 12048:1994 procedures for complete filled transport packages. Stacked pallet-box corners are tested with top loads derived from the intended distribution environment. Deflection is recorded until the load is stabilised or the corner post is visually compromised.

    GC7260 is processing-limited in thick sections because of its narrow molecular weight distribution. Weld lines at rib intersections develop sink marks if packing pressure is released before gate freeze. A hold pressure of 65–80 MPa for 8–12 s is required in sections above 4.0 mm. Mould temperature is held at 20–30 °C to reduce differential shrinkage between top and bottom faces. Differential shrinkage above 0.5% causes visible warpage in pallet-box side walls after 48 h ageing.

    Regrind reuse in returnable packaging is permitted up to 25 wt% when the PCR stream is plant-controlled and free of polyethylene terephthalate contamination. PET contamination above 0.1 wt% produces visible unmelted specks and weakens weld lines. For long-term outdoor use, UV stabilization masterbatch is added at 2.0–2.5 wt%. Tensile impact retention after 3,000 h xenon arc exposure under ISO 4892-2:2013, method A, is used as release criterion. Retention below 70% triggers a carbon black loading increase or re-compounding.

    Chemical exposure is restricted to dilute acids, alkalis, and neutral aqueous solutions. Ketones, aromatic solvents, and chlorinated hydrocarbons are excluded. The packaging should not be loaded above 55 °C surface temperature for prolonged periods. Terminal examples include collapsible pallet boxes, corner blocks, separator sheets, container dunnage, and automotive returnable trays. In automotive dunnage, oil and grease contact is limited to incidental exposure below 40 °C; sustained contact above this temperature causes surface crazing.

    For outdoor multi-season service, GC7260 is processed into nursery pots, propagation trays, and plant labels with carbon black masterbatch at 1.5–2.0 wt%. The carbon black masterbatch provides UV shielding. Without UV stabilization, tensile impact drops below 50% of initial after 1,200 h of xenon arc exposure under ISO 4892-2:2013. Thin-wall propagation trays with 0.8–1.0 mm cell walls use injection speeds above 80 mm/s. Melt temperature is 220–240 °C. Mould temperature is set to 10–20 °C to prevent sticking on core pins.

    Ejector stroke is limited to 10–15 mm. Trays are pulled by a stripper plate to avoid hole distortion. Plant labels are moulded in high-cavitation tools with cycle times of 8–12 s. Holding pressure is set at 50–65 MPa for 1.5–2.5 s. Compliance for agricultural end use does not require food-contact status. Heavy metal restrictions under EU 2019/1009 fertilising product regulation may apply when trays are sold with growing media as a kit. Published performance data for GC7260 in long-term agricultural UV exposure is limited. Outdoor service predictions should be verified by xenon-arc and field weathering trials before fixed replacement intervals are claimed.

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