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Versalis HDPE MM84

    • Product Name: Versalis HDPE MM84
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 765964
    Density 0.960 g/cm3
    Melt Flow Rate 190 Deg C 2 16 Kg 20 g/10 min
    Tensile Stress At Yield 30 MPa
    Tensile Strain At Break 1000 %
    Tensile Modulus 1400 MPa
    Flexural Modulus 1400 MPa
    Charpy Notched Impact Strength At 23 Deg C 8 kJ/m2
    Charpy Notched Impact Strength At 30 Deg C 4 kJ/m2
    Vicat Softening Temperature A 50 128 deg C
    Heat Deflection Temperature At 0 45 Mpa 75 deg C
    Shore D Hardness 65
    Brittleness Temperature -70 deg C
    Water Absorption <0.01 %
    Molding Shrinkage 1.5-3.0 %
    Thermal Conductivity 0.4 W/mK
    Dielectric Constant 2.3
    Volume Resistivity >10^16 ohm cm

    As an accredited Versalis HDPE MM84 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing
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    Application of Versalis HDPE MM84

    Thin-wall food-contact moulding with Versalis HDPE MM84 is executed on high-speed accumulator-assisted injection machines with clamp force between 1500 kN and 4500 kN depending on cavity count. The grade has a nominal density of 0.953–0.954 g/cm³ and a melt flow rate of 8.0 g/10 min at 190°C/2.16 kg per ISO 1133-1:2022, which permits fill times below 0.5 s in sidewalls of 0.4–0.8 mm. Melt temperature is maintained at 200–230°C and mould temperature at 10–30°C; hot-runner nozzle tips are kept below 250°C to avoid local gel formation. Injection velocity is staged to hold flow-front velocity above 300 mm/s in the sidewall, with pack pressure at 60–80% of peak injection pressure for 0.5–1.5 s. Parting-line vents of 0.01–0.03 mm are used to prevent burn marks at high injection velocity; cavity dimensions carry a shrinkage allowance of 1.5–2.0% in the flow direction. The formulation consists of 100 parts MM84, 2–4 parts of TiO₂-based white masterbatch or 1–3 parts of a 60% TiO₂ concentrate; calcium stearate at 0.05–0.1 phr is added only when ejection drag appears on textured cores. Melt cushion is held at 2–4 mm and back pressure at 0.5–1.0 MPa to avoid pigment inhomogeneity. Compliance is evaluated under EU 10/2011 Annex I and II and FDA 21 CFR 177.1520(c). Overall migration into simulant D1 for fatty spreads and simulant E for aqueous dairy is measured per EN 1186-14 and must remain below 10 mg/dm². Pre-drying is omitted when internal moisture is below 0.05%; if warehouse humidity exceeds 60% RH, a 2 h predry at 70°C is imposed. An incoming MFR shift greater than 0.8 g/10 min against the release value is sufficient to produce short shots in the fastest cavities; each silo batch is checked per ISO 1133-1:2022 before transfer to the press. Finished articles include margarine tubs, dairy cups, thin-wall takeaway containers, and snap-on lids.

    CriterionMethodConditionRelease value
    Melt flow rateISO 1133-1:2022190°C, 2.16 kg8.0 g/10 min
    DensityISO 1183-1:2019Method A, 23°C0.953–0.954 g/cm³
    Overall migration, fatty contactEN 1186-14Simulant D1, 10 days at 40°C< 10 mg/dm²
    Overall migration, aqueous contactEN 1186-14Simulant E, 10 days at 40°C< 10 mg/dm²
    FDA status21 CFR 177.1520(c)Extractables and specification testsConforms

    What Changes When MM84 Moves from Thin-Wall Dairy Cartons to Non-Carbonated Beverage Closures?

    Closure moulding differs from thin-wall container work because the sealing features—plug seal, tamper-evident band, knurl, and thread start—generate local pressure gradients that can distort the seal surface if pack pressure is released too early. On 48- to 96-cavity hot-runner closure tools, the melt temperature is raised to 220–240°C and mould temperature is held at 15–25°C to maintain thread dimensional stability. Valve-gate tip diameters of 0.8–1.2 mm are used; smaller gates shear the melt and can produce flow lines in the tamper-evident band, while larger gates leave a vestige that interferes with drop-on-liner dispensing. Hot-runner balance is controlled to a fill-weight variation below 2% across cavities; unbalance above this value causes uneven seal crush and intermittent leakage in drop tests. Cycle time is controlled at 6–9 s, with packing cavity pressure of 40–60 MPa applied for 0.8–1.5 s. Formulation includes 100 parts MM84, 0.02–0.05 phr primary phenolic antioxidant, 0.02–0.05 phr secondary phosphite antioxidant, 0.02–0.05 phr hydrotalcite acid scavenger, and 1–2 parts TiO₂ masterbatch. Erucamide slip at 0.05–0.1% is introduced only when removal torque measured with a calibrated torque meter falls below 1.0 N·m; above 0.1%, filled-water organoleptic testing per ISO 13302 may show detectable taint, particularly in low-headspace packages. Compliance for food-contact closures is assessed under EU 10/2011 and FDA 21 CFR 177.1520(c), with overall migration below 10 mg/dm² in aqueous simulant. The grade is not specified for carbonated beverage closures requiring sustained CO₂ retention because moulded-in stress at the bridge/band junction can reduce stress-crack resistance under internal pressure; published data for MM84 under carbonated closure conditions is limited. Final products include still-water closures, UHT milk closures, sauce lids, and vitamin bottle caps.

    Industrial Pail Sidewall Stress and Injection Pressure Requirements

    Open-top industrial pails from 5 L to 20 L are produced in single-cavity or two-cavity moulds with shot weights of 400–1200 g and clamp force from 6000 kN to 12000 kN. Melt temperature is set at 200–230°C, mould temperature at 15–35°C. Filling is staged with a slow initial velocity to prevent jetting from the hot sprue; peak cavity pressure is held at 50–70 MPa for 4–8 s to pack the base rim and handle bosses. Cooling time dominates the cycle and is set by the 3.0–4.5 mm nominal wall; total cycle time is typically 25–40 s. Handle bosses are formed with retractable cores that are cooled separately to prevent visible shrinkage at the boss perimeter; ejection drag on textured sidewalls is controlled with 1–2° draft and 0.05–0.15 phr calcium stearate. Compounding for detergent and lubricant pails includes 100 parts MM84, 2.0–2.5% carbon black masterbatch for UV resistance, 0.1–0.3% HALS stabiliser, and a phenolic/phosphite antioxidant package at 0.04–0.08%. Environmental stress-crack resistance is tested following ASTM D1693 condition B in 100% Igepal CO-630; F50 values depend on moulded-in stress and additive package, and published data for MM84 in this specific pail configuration is limited. Finished pails used for dangerous-goods packaging require article-specific drop testing per 49 CFR 178.600 and UN stack tests; resin datasheet compliance alone does not confer UN certification. Field failure data from latex-paint pail storage indicate that cracking generally initiates at the handle boss or rim stiffening rib, where high packing pressure creates local frozen-in stress. Final products include pails for paint, lubricant, detergent, and ready-mix construction compounds.

    For ventilated fruit crates and cold-chain fish boxes, the limiting processing variable is not melt flow but low-temperature impact after stacking and drop abuse. MM84 is moulded in multicavity tools with wall sections of 2.5–4.0 mm; melt temperature is kept at 220–240°C to counter pressure losses across long hot-runner drops, while mould temperature is maintained at 10–25°C. Cycle time is 25–45 s depending on wall thickness and the number of vent slots. The formulation uses 100 parts MM84, 2–3% colour masterbatch, 0.15–0.4% HALS for outdoor UV exposure, and 0.05% phenolic antioxidant. For fish boxes intended for direct food contact, EU 10/2011 applies; if melt temperature exceeds 230°C, purge time is extended to limit oxidised material carrying into the mould. Low-temperature failures in cold-chain distribution are observed when crates are dropped at temperatures below −10°C, particularly if the tool uses abrupt wall-thickness transitions at the ventilation grid. Mould design should radius each vent rib to at least 0.5 mm and avoid rib height greater than 40% of the adjoining wall to prevent notch-induced crack initiation. In-house regrind from sprues and runners is limited to 10–15% because higher regrind levels reduce cold-temperature impact resistance and increase melt-viscosity drift. Published data for MM84 Charpy impact at −20°C is limited; incoming batches are checked at 23°C per ISO 179-1/1eA, and low-temperature qualification is performed on the finished crate rather than on a resin specimen. Final products include ventilated fruit crates, bakery trays, seafood boxes, and reusable cold-chain containers.

    When MM84 Is Used as a Masterbatch Carrier Rather Than a Finished-Article Resin

    Masterbatch production shifts the critical control parameter from part fill to pigment dispersion and melt filtration. MM84 is compounded on co-rotating twin-screw extruders with L/D 36:1–44:1 and screw speeds of 400–800 rpm; barrel temperature is set to 190–210°C to limit thermal degradation of the carrier. Die-face pelletization is run with water-ring or underwater pelletizers, while strand pelletizing is used for colour formulations requiring rapid grade changes. A typical carbon-black concentrate contains 30–60 parts MM84 as carrier, 40–70 phr carbon black, and 5–10 phr high-density polyethylene wax as wetting agent, with 0.5–1.0 phr calcium stearate as process aid. The 8.0 g/10 min MFR of MM84 permits wetting of high-surface-area pigments without excessive motor amperage; above 70% carbon black loading, dispersion quality and pellet integrity decline unless a lower-viscosity carrier is blended. Dispersion is checked by pressure-rise testing across a 14 µm filter pack or by microtome film inspection against a 10 µm agglomerate threshold. Colour concentrates for food-contact applications must use pigments and additives listed in EU 10/2011 Annex I and 21 CFR 177.1520; heavy-metal migration in toy masterbatches is assessed per EN 71-3. Final products include colour masterbatch, additive concentrates for HDPE extrusion, and carbon black masterbatch used at 2–5% let-down in injection moulding and pipe extrusion.

    Housewares Moulding Pushes the Lower Wall-Thickness Boundary Before Sink Marks Appear

    Housewares and storage articles made from MM84 are moulded at wall thicknesses of 1.2–2.5 mm in open-nozzle moulds without hot runners; melt temperature is set at 200–230°C, mould temperature at 15–30°C. The mould shrinkage allowance is 1.5–2.0% in flow direction and 1.5–2.5% transverse, with the higher value applied to textured surfaces. Sink marks appear at rib intersections when rib thickness exceeds 40–50% of adjoining wall thickness; ribs are therefore cored to limit local mass. Injection speed is moderately high to prevent weld lines at handle apertures, and holding cavity pressure of 30–50 MPa is maintained for 1.5–3.0 s until gate freeze. Textured surfaces require 1° minimum draft on deep cores; ejection problems with thin internal walls are resolved by adding 0.05–0.1 phr calcium stearate, not by increasing melt temperature. The formulation is 100 parts MM84, 1–3 parts colour or pearlescent masterbatch, and 0.05–0.1 phr calcium stearate; outdoor storage boxes use 0.2–0.5% HALS and 0.05% antioxidant. Compliance for housewares includes REACH Annex XVII restricted substances, EU 10/2011 for kitchen storage contact, and EN 71-3 migration limits when the article is marketed as toy-like. Final products include stackable storage boxes, rigid hangers, small household baskets, and drawer organisers.

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