| HS Code | 385819 |
| Density | 0.900 g/cm³ |
| Melt Flow Rate 190 C 2 16 Kg | 0.6 g/10 min |
| Melting Point | 114 °C |
| Vicat Softening Point | 70 °C |
| Tensile Strength At Break | 25 MPa |
| Elongation At Break | 700% |
| Flexural Modulus | 100 MPa |
| Shore A Hardness | 90 |
| Shore D Hardness | 35 |
| Brittleness Temperature | < -70 °C |
| Haze | 7% |
| Gloss 45 | 80% |
| Dart Impact Strength | 200 g |
| Elmendorf Tear Strength Md | 250 g |
| Elmendorf Tear Strength Td | 300 g |
As an accredited Versalis Clearflex VLDPE FF D0 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Versalis Clearflex VLDPE FF D0 packaging: 25 kg polyethylene bags, palletized and stretch-wrapped for secure transport and storage. |
| Container Loading (20′ FCL) | Loading of Versalis Clearflex VLDPE FF D0 in a 20-foot full container load (FCL), packed and secured for export shipment. |
| Shipping | Versalis Clearflex VLDPE FF D0 is shipped as non-hazardous thermoplastic pellets, typically in 25 kg polyethylene bags on pallets or in bulk octabins/containers. It is not classified as dangerous goods. Transport and store dry, away from direct sunlight, heat, moisture, and contamination. |
| Storage | Store Versalis Clearflex VLDPE FF D0 in a cool, dry, well-ventilated warehouse, away from direct sunlight, heat, ignition sources, and moisture. Keep in original sealed bags/packaging on pallets, protected from dust, oils, and other contaminants. Avoid prolonged UV exposure and stacking damage; rotate stock and follow the SDS/manufacturer guidance. |
| Shelf Life | Typically 24 months from production when stored dry, cool, and protected from direct sunlight and UV exposure. |
Clearflex VLDPE FF D0 is placed in the sealant skin of coextruded lidding films where the requirement is not low-temperature sealing alone but the ability to survive high-speed form-fill-seal dwell times under contaminated seal areas. In a three-layer lidding structure for fresh-cut salad, bakery, and chilled sliced-meat thermoform trays, a common starting layer distribution is 15–20 wt% Clearflex VLDPE FF D0 as the sealant surface, 55–70 wt% hexene LLDPE in the core, and 15–25 wt% LDPE on the outer abuse surface. This structure is processed on a three-layer blown film line with die diameter 250–350 mm, die gap 1.8–2.2 mm, blow-up ratio 2.2:1–3.0:1, and melt temperature 190–220 °C. The lower-density VLDPE skin reduces seal initiation temperature compared with LLDPE at equivalent melt index, but hot-tack strength is more sensitive to seal-bar temperature variation. On a 100 cycles/min rotary heat sealer, a seal-bar temperature shift of ±10 °C can move the hot-tack window outside the acceptable range. Seal performance is evaluated by ASTM F1921 for hot tack and ASTM F88 for seal strength; a target hot-tack plateau of at least 1.0 N/25 mm over the seal-bar temperature range 105–130 °C is frequently used, but the verifiable value depends on layer structure, seal bar geometry, dwell time, and contamination level. To control coefficient of friction on the sealant skin, a slip masterbatch containing 5% erucamide in LDPE is let down at 1.5–2.5 wt%. Excessive slip is avoided because migration into the seal area can reduce seal strength after 14 days ageing at 40 °C. The exact nominal density, melt flow rate, and sealing curve should be taken from the supplier technical bulletin and used to calculate screw output and melt residence time.
| Regulatory framework | Relevant designation | Verification point | Typical obligation |
|---|---|---|---|
| US food contact | FDA 21 CFR 177.1520 | Olefin polymers for direct food contact under conditions of use A–H | Supplier FDA status letter and end-use condition selection |
| EU plastics regulation | Regulation (EU) 10/2011 | Overall migration limit 10 mg/dm²; simulant selection per Annex III | Migration testing according to EN 1186 series |
| REACH | Regulation (EC) 1907/2006 | SVHC candidate list and Annex XVII restrictions | SDS verification and annual supplier SVHC statement |
| Packaging heavy metals | CONEG model legislation | Sum of Pb, Cd, Hg, CrVI below 100 mg/kg | Supplier certificate of compliance for packaging use |
In collation shrink film for bottled water, canned goods, and multipack retail formats, Clearflex VLDPE FF D0 is incorporated as a sub-skin or core layer because its low-density structure deforms around a protruding bottle cap without initiating a tear. The conventional structure is a three-layer or five-layer blown film with LDPE-rich skins and a core containing 20–40 wt% Clearflex VLDPE FF D0 blended with high-strength hexene LLDPE. The film is subsequently oriented in the machine direction and transverse direction on a double-bubble or triple-bubble process; orientation temperature is typically 110–125 °C, with MD orientation ratio 1:3–1:5 and TD orientation ratio 1:4–1:7 depending on the line and gauge target. Shrink force is controlled because a higher VLDPE fraction lowers room-temperature shrink force, which can allow a thinner film to hold a multipack without crushing cartonboard or thin aluminum cans. The processing boundary is measurable: above 40 wt% Clearflex VLDPE FF D0, the oriented film exhibits increased gauge variation and lower high-temperature modulus, causing bag collapse when shrink tunnel air velocities reach 12–18 m/s. Tunnel set points are generally 160–190 °C with residence time 7–12 s; films with excessive VLDPE-rich core show corner burn-through before the pack reaches full dimensional recovery. Free shrink is measured by ASTM D2732, shrink force by ISO 14616, and puncture resistance by ASTM D5748. The core layer must therefore retain a higher-density LLDPE or LDPE fraction, typically 60–80 wt% of total polymer content, to preserve stiffness at tunnel exit temperatures. On a three-layer line with 50 mm screw diameters and L/D ≥ 30:1, melt pressure should not exceed 380 bar because the VLDPE-rich fraction reduces shear heating and can destabilize the bubble when backpressure is excessive. Die gap is commonly set at 1.6–2.0 mm for collation shrink, with blow-up ratio 2.5:1–3.5:1 before orientation. The practical balance is determined on-line by transverse direction gauge profile and residual shrink after 24 h at ambient temperature.
Agricultural silage and bale wrap applications place Clearflex VLDPE FF D0 in the core of a three-layer cast stretch film at 10–25 wt% because outdoor bale wrap must survive puncture from alfalfa stems, frozen ground contact, and tension from multiple wrappings. A typical structure is A/B/A where the two skins contain LLDPE and a cling blend of PIB or EVA, while the core contains a VLDPE-rich fraction to lower elongation force and reduce film snap under high pre-stretch. Cast line parameters commonly include a flat die with deckle width 1.8–3.0 m, die temperature 235–250 °C, chill roll temperature 15–25 °C, and line speed 300–600 m/min. Pre-stretch levels in silage wrapping equipment range from 55–75% of ultimate elongation; machine direction elongation at break above 400% is expected for a 25 µm film according to ISO 527-3. The key requirement is tear retention after field ageing, measured by ASTM D1922 and ASTM D5748 after UV exposure according to ASTM G154. A UV stabilizer package based on hindered amine light stabilizers and a benzotriazole or triazine UV absorber is added at 0.8–1.5 wt% masterbatch, but exact dosage depends on regional UV index, film thickness, and storage duration. Processing moisture limits are stricter than for LDPE-only films because the VLDPE fraction can carry surface moisture from humid silos; pellet moisture above 600 ppm in humid conditions generates bubbles and reduces gauge uniformity. When storage humidity exceeds 60% RH, pre-drying in a desiccant hopper at 40–55 °C for 3–4 h is recommended on cast and blown film lines. Blocking is managed by temperature-controlled winding and by limiting cling additive to the skins; placing cling additives in the core causes telescoping and edge-tack release problems. Long-term field performance is best assessed by monitoring bale-wrap tear resistance after 12 months, although published data for this specific Clearflex grade under high-UV tropical conditions is limited.
Nonwoven hygiene backsheet laminates use polyolefin skins for printable outer layers and low-gel tie layers, and a 0.900 g/cm³ class VLDPE in the tie layer addresses repeated flexural stress at leg cuffs and elasticized waistbands. On a multi-layer cast coextrusion line with die width 2.2–2.8 m, the Clearflex-containing tie is deposited between a filled LLDPE backsheet and a breathable nonwoven web or between two polyolefin films in air-gap extrusion lamination. Melt temperature at the slot die is usually 215–240 °C; below 210 °C, the resin does not wet the nonwoven fibers sufficiently, and above 250 °C, oxidation gels appear on the die edges within 4–6 h of continuous running. Melt curtain stability is governed by draw ratio and air-gap distance: draw ratio is kept below 15:1 and air gap at 150–250 mm. At line speeds above 250 m/min, edge-thickness fluctuations increase unless die heaters at the edge zones are reduced by 5–10 °C below the center setpoint. The VLDPE tie layer is formulated at 12–18 wt% of the total coating weight, with a coating weight of 12–20 g/m². Adhesion to the nonwoven is measured by laminate T-peel using ASTM D1876 or ISO 11339, with values in the range 1.5–4.0 N/15 mm commonly specified for hygiene lamination. For direct skin-contact claims, migration and irritancy testing is required under ISO 10993-5 when medical devices are involved, but for general hygiene packaging the grade is not automatically medical-grade; this distinction must be verified by the converter against the supplier information statement. Film modulus decreases as the VLDPE fraction increases, and this is measured by ISO 527-3 at 500 mm/min to control transverse direction curl during roll slitting. The main operational incompatibility is the combination of a high VLDPE tie-layer fraction with oversized edge-die heaters, which produces melt resonance and nonwoven burn-through on the edge beads.
In industrial packaging for FIBC liners and shipping sack inserts, Clearflex VLDPE FF D0 is introduced at 10–20 wt% of the core layer in a three-layer blown film to increase the capacity of the layflat to accept a puncturing granule or railcar bulk-loading stream without splitting. Typical dimensions are 800–1200 mm layflat, thickness 70–120 µm, with the core layer containing LLDPE plus Clearflex at 15% and skins containing LDPE or butene LLDPE. On a grooved-feed extruder with L/D 30:1, melt temperatures of 175–200 °C are preferred because lower temperatures preserve melt strength for bubble stability; however, dropping below 170 °C can create unmelts in the die gap and visible fish-eye defects. Blow-up ratio is maintained at 2.2:1–2.5:1, die gap at 2.0–2.4 mm, and frost line height at 8–10 die diameters to align molecular orientation in the hoop direction. Impact resistance is measured by ASTM D1709 Method A or B; a 70 µm liner with the above structure and proper process control typically exceeds 750 g dart impact, but the actual value is not a single-point specification because it drops at low frost line heights and high extrusion temperatures. Static and kinetic coefficient of friction on the outer surface is adjusted with 1.0–2.0 wt% slip masterbatch, targeting 0.25–0.45 kinetic COF on steel according to ISO 8295; higher slip levels cause unstable winding on turret winders and crease formation during gusseting. The resin should not be used as the directly welded surface in FIBC form-fill-seal operations where the dwell time is below 0.8 s, because the low-melting VLDPE surface may not cool fast enough to prevent seam thinning; for this situation a blended LLDPE skin with 10–15 wt% Clearflex is preferred. Pellet handling should avoid long hopper residence time above 50 °C, and silo storage in high-humidity regions should include nitrogen purge or covered transfer to limit surface moisture pickup. The absence of a separate tie layer in the FIBC liner structure means compatibility between the VLDPE core and the LDPE skins is inherent, but mixing Clearflex with amine-containing anti-static masterbatches should be evaluated for lubricant interaction before production campaigns.
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