| HS Code | 172723 |
| Dielectric Constant Dk | ≤ 3.0 at 10 GHz |
| Dissipation Factor Df | ≤ 0.002 at 10 GHz |
| Glass Transition Temperature Tg | ≥ 200°C |
| Decomposition Temperature Td 5 Weight Loss | ≥ 380°C |
| Water Absorption | ≤ 0.05% after immersion |
| Copper Peel Strength | ≥ 0.8 N/mm for 18 μm foil |
| Thermal Conductivity | 0.6–0.8 W/m·K |
| Coefficient Of Thermal Expansion Cte Below Tg | ≤ 40 ppm/°C |
| Halogen Content | Halogen-free (≤ 900 ppm total) |
| Surface Resistance | ≥ 10^12 Ω |
| Volume Resistivity | ≥ 10^15 Ω·cm |
| Outgassing Total Mass Loss | ≤ 0.1% |
As an accredited Ultra-Low Loss Hydrocarbon Resin for AI Server CCL & OAM Modules factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Supplied in 25 kg nitrogen-purged drums, sealed to preserve ultra-low loss hydrocarbon resin purity for AI modules. |
| Container Loading (20′ FCL) | One 20-foot container securely loaded with ultra-low loss hydrocarbon resin, packaged for AI server CCL and OAM module production. |
| Shipping | Shipment comprises Ultra-Low Loss Hydrocarbon Resin for AI Server CCL & OAM Modules. Supplied in sealed, moisture-barrier drums/boxes, inerted and temperature-controlled to preserve dielectric properties. Avoid exposure to ignition sources; protect from moisture and physical damage. Standard industrial courier or freight, with hazardous goods documentation if applicable. Handle with care. |
| Storage | Store in a tightly sealed container in a cool, dry, well-ventilated area away from direct sunlight, heat sources, and ignition sources. Keep away from moisture, strong oxidizers, and incompatible materials. Maintain temperature below 25°C (77°F). Use within manufacturer’s stated shelf life to preserve low-loss dielectric performance. |
| Shelf Life | Shelf life is 12 months from manufacture when stored sealed in a cool, dry place, away from direct sunlight and moisture. |
In AI server copper-clad laminates operating at 112 Gbps and 224 Gbps PAM4, the core layer resin matrix is formulated with a low-polarity hydrocarbon resin blended into polyphenylene ether or modified polyphenylene ether. The addition level in varnish solids commonly falls between 15 wt% and 35 wt%, depending on glass style, filler loading, and target dielectric constant. Material acceptance is benchmarked against IPC-4101E/126 and IPC-4101E/130 slash sheet requirements. Dielectric constant at 10 GHz is measured by IPC-TM-650 2.5.5.13 and is controlled between 3.0 and 3.4. Dissipation factor at 10 GHz is held between 0.0015 and 0.0025. The hydrocarbon resin functions as a crosslinkable low-viscosity component, enabling higher silica filler loading without destroying varnish shelf life or prepreg flexibility. Spherical silica filler is incorporated at 20 wt% to 60 wt% of total solids. When ambient relative humidity exceeds 60%, the filler is pre-dried at 150 °C for 4 h; failure to do so permits silane coupling agents to hydrolyze and raises cured laminate dissipation factor. Varnish is prepared in jacketed high-shear dispersers using methyl ethyl ketone and toluene. The coated glass is processed through a horizontal treater with zone temperatures from 80 °C to 170 °C. Residual solvent after treating is maintained below 0.5 wt%. The prepreg is laminated against low-profile copper foil with surface roughness Rz below 2.0 µm. Copper foil roughness above this threshold increases conductor loss and obscures the dielectric improvement supplied by the hydrocarbon resin. The lamination cycle is held at 200 °C to 220 °C under 2.5 MPa to 4.0 MPa for 90 min to 120 min. The resulting laminate is converted into 800G and 1.6T switch line cards, router boards, and high-speed backplane panels.
| Property | Test method | Control window |
|---|---|---|
| Dielectric constant at 10 GHz | IPC-TM-650 2.5.5.13 | 3.0–3.4 |
| Dissipation factor at 10 GHz | IPC-TM-650 2.5.5.13 | 0.0015–0.0025 |
| Glass transition temperature by DMA | IPC-TM-650 2.4.24.5 | > 200 °C |
| Thermal decomposition at 5% weight loss | IPC-TM-650 2.3.40 | > 360 °C |
| Water absorption | IPC-TM-650 2.6.2.1 | < 0.15% |
| Peel strength after solder float | IPC-TM-650 2.4.8 | > 0.70 kN/m |
When ultra-low-loss hydrocarbon resin replaces 20 phr to 40 phr of epoxy solids in a prepreg varnish, the minimum melt viscosity at lamination temperature drops relative to an unmodified epoxy formulation. Parallel-plate rheometry under a 5 °C/min ramp, evaluated in accordance with ASTM D4440-15, records a minimum dynamic viscosity between 1,000 Pa·s and 10,000 Pa·s at 150 °C to 180 °C. The exact minimum depends on filler content, resin molecular weight, and the degree of B-stage advancement. The reduction in melt viscosity improves fill around patterned copper features and buried via holes, but addition above 40 phr reduces B-stage tack and can produce dry glass-bundle edges during horizontal treating. In production, the prepreg is coated onto low-Dk E-glass or quartz glass with a reverse roll coater. The treater line speed is limited by gel time rather than drying capacity. Gel time at 171 °C is controlled between 150 s and 250 s by IPC-TM-650 2.3.18. Volatile content after treating is held below 0.5 wt% by IPC-TM-650 2.3.19. Resin flow is tested to IPC-TM-650 2.3.17 and is typically set between 2% and 8% depending on lamination pressure and copper thickness. The formulation is incompatible with strong amine-based epoxy catalysts when the hydrocarbon resin contains pendant unsaturation. Such catalysts can initiate premature exothermic crosslinking inside the treater and drop gel time below 120 s. The lamination press uses vacuum-assisted heating at 200 °C to 210 °C with 2.5 MPa to 3.5 MPa applied in staged steps to avoid resin starvation. Cool-down under pressure is required when dielectric spacing between adjacent signal layers falls below 100 µm. Direct comparative data for every hydrocarbon-to-epoxy ratio are limited in public literature; the ranges above align with production-scale prepreg line audits and CCL vendor data sheets. The resulting multilayer panels are processed into 24-layer to 36-layer AI server boards with backdrilled high-speed signal vias and buried capacitance layers.
OAM 2.0 accelerator module baseboards do not tolerate the same resin-rich formulations used in thin switch line cards. The stack-up often exceeds 24 layers with board thickness above 3.0 mm. The resin matrix must balance low dielectric loss against high modulus and low coefficient of thermal expansion. Hydrocarbon resin loading is therefore kept at the lower end of the process window, typically 10 wt% to 20 wt% of varnish solids. Higher loadings reduce lamination viscosity but raise Z-axis CTE beyond acceptable limits. Z-axis CTE below glass transition is measured by IPC-TM-650 2.4.24.5 and is controlled below 45 ppm/K. Warpage after simulated reflow is measured by IPC-TM-650 2.4.22 and is kept below 0.75% on panel sizes above 500 mm × 600 mm. The baseboard is pressed in multiple lamination cycles. Inner-layer cores are first laminated and etched, then outer-layer prepregs and copper foil are added in a second press cycle. After each cycle, panels are cooled under 0.5 MPa to 1.0 MPa to reduce residual stress. The low hydrocarbon resin loading improves fill around thick copper planes, which can exceed 70 µm in power distribution layers. However, this resin alone does not eliminate the need for silica filler. Filler content is raised to 55 wt% to 70 wt% in outer prepregs to control CTE and drillability. Mechanical drilling of the thick stack-up uses 0.25 mm to 0.35 mm bits with retraction feed rates below 2.0 m/min to avoid smear. Desmear and via cleaning are carried out in alkaline permanganate at 80 °C for 10 min to 15 min. The finished baseboards are used for OCP OAM 2.0 accelerator modules with high-layer-count differential pairs and dense power delivery networks.
| Property | Test method | OAM baseboard control |
|---|---|---|
| Z-axis CTE below Tg | IPC-TM-650 2.4.24.5 | < 45 ppm/K |
| Warpage after reflow simulation | IPC-TM-650 2.4.22 | < 0.75% |
| Layer-to-layer registration | IPC-6012E Class 3 | ± 75 µm |
| Solder float at 288 °C | IPC-TM-650 2.4.13 | > 180 s without delamination |
For chiplet package substrates used in OAM accelerator modules, the ultra-low-loss hydrocarbon resin is incorporated into build-up dielectric films rather than core laminates. The dielectric film is coated onto a 25 µm to 50 µm PET carrier. Coated thickness after drying is 15 µm to 40 µm. The resin is blended with epoxy or maleimide components at 20 wt% to 35 wt% hydrocarbon resin solids to lower dielectric loss without destroying laser via processability. After vacuum lamination onto a core substrate at 100 °C to 130 °C, the film is thermally cured at 180 °C to 220 °C for 60 min to 120 min. Laser via drilling uses a UV/CO2 hybrid system. Laser fluence is kept below the threshold that produces carbonaceous residue along the via sidewall. Desmear is then performed with alkaline permanganate. The cured dielectric must exhibit a dissipation factor below 0.005 at 10 GHz and water absorption below 0.15 wt% after 24 h at 23 °C. Moisture uptake is measured by IPC-TM-650 2.6.2.1. Higher hydrocarbon resin loadings above 35 wt% reduce film elongation and increase the risk of microcracking during thermal cycling. Peel strength of the build-up dielectric to copper after roughening is checked to IPC-TM-650 2.4.8. The end application is a coreless or thin-core chiplet package substrate with 8 µm to 12 µm line/space routing for die-to-die interconnects.
When an OAM module integrates co-packaged optics, the substrate adjacent to the optical engine routes 56 GBd or 112 GBd PAM4 driver signals. The hydrocarbon resin is loaded at 25 wt% to 35 wt% of the dielectric solids to maintain stable dielectric constant and low dissipation factor at higher frequencies. The substrate is often a thin coreless build-up with laser-drilled microvias. Differential impedance is designed for 100 Ω. The dielectric constant used for stack-up calculation is taken from IPC-TM-650 2.5.5.13 data measured at 10 GHz and extrapolated to 50 GHz. Publicly available data for exact high-frequency performance of every hydrocarbon resin in co-packaged optics substrates are limited. When such data are absent, the design uses the 10 GHz Dk and Df values as conservative inputs. The cured dielectric film must withstand 260 °C reflow for 60 s without void formation or delamination. Moisture absorption is kept below 0.15 wt% to prevent impedance drift of 50 Ω single-ended and 100 Ω differential lines. The laminated substrate is laser drilled with 50 µm to 80 µm vias and filled with copper electroplating. The final optical engine substrate is assembled with VCSEL or silicon photonics chips and terminated by 400G or 800G optical transceivers. The process boundary is narrow: residual solvent above 0.3 wt% in the build-up film causes outgassing and microvoid formation during the 260 °C reflow step.
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Designated ULR-3000HC, the ultra-low-loss hydrocarbon resin is a hydrogenated C9/C5 hydrocarbon backbone with pendent vinyl and styrene-functional groups. The resin is supplied as a free-flowing pale pastille with a ring-and-ball softening point of 148–152°C (ASTM E28-18) and a number-average molecular weight of 1,800–2,400 g/mol by gel permeation chromatography. In a halogen-free copper-clad laminate formulation comprising 20–35 phr of the resin, polyphenylene ether, triallyl isocyanurate, and fused silica, the cured laminate exhibits relative permittivity of 2.28–2.35 and dissipation factor of 0.0009–0.0011 at 10 GHz when tested to IPC-TM-650 2.5.5.13. The resin is intended for AI-server copper-clad laminates and Open Accelerator Module substrates in which differential signalling at 28–112 Gbps per lane imposes narrow dielectric loss and phase-stability margins.
The resin’s reduced polar functionality relative to styrene-maleic anhydride and epoxy systems limits moisture-induced dielectric shift. After 24 h immersion in deionized water at 23°C, moisture absorption is 0.07–0.09 wt% when measured according to IPC-TM-650 2.6.2.1. After 168 h at 85°C/85% RH, the dissipation factor increase is 0.0002–0.0004 when measured at 10 GHz by IPC-TM-650 2.5.5.13, compared with 0.0010–0.0015 for unmodified DCPD-based hydrocarbon resin. Batch-to-batch softening-point variation across 12 production lots is ±2°C, and Mw/Mn remains below 1.8. Prolonged storage above 35°C can increase melt viscosity by 5–10% through slow vinyl oligomerization.
During prepreg manufacture on 2116 glass fabric, the resin is let down to 55–65 wt% solids in a methyl ethyl ketone/toluene blend at 80:20 weight ratio. Brookfield viscosity at 25°C ranges from 180–350 mPa·s. The varnish pot life at 25°C/50% RH is approximately 8 h; viscosity drift of 10–15% occurs subsequently as vinyl addition slowly advances. High-shear dispersion in a bead mill at 1,500–2,000 rpm for 45–60 min reduces fused silica agglomerates to a Hegman grind of 5–6. Continuous treater line speed is constrained to 12–15 m/min at oven zone temperatures of 150–165°C. Higher line speeds retain residual solvent above 0.3 wt% and generate microvoids at the glass–resin interface.
Differential scanning calorimetry at 10°C/min shows an exothermic cure peak of 210–240 J/g with onset at 165°C and peak maximum at 185°C. Isothermal conversion at 200°C reaches 85% in 60 min, 92% in 120 min, and 96% in 150 min. Minimum melt viscosity measured on a moving-die rheometer at 1 Hz is 800–1,200 Pa·s at 140°C. Increasing lamination temperature to 160°C before full gel can raise viscosity by 40% within 8 min because vinyl crosslinking advances prematurely. This cliff-edge imposes the ±5°C lamination control band and prohibits ramp rates above 3.0°C/min on 20-panel books without void formation. Press conditions of 2.4–2.8 MPa at 205°C for 120–150 min are required. Core temperature overshoot of 8–10°C above setpoint is typical; therefore the setpoint is reduced to 200°C for thicker books to avoid over-cure and embrittlement.
For masterbatch preparation, the resin is melt-compounded with polyphenylene ether at 40 wt% loading in a co-rotating twin-screw extruder with L/D ratio 44:1. Barrel temperatures of 220–240°C and screw speed of 300 rpm produce melt temperature 245°C; exceeding 245°C causes oxidative gelation and black speck formation. The masterbatch is then let down into MEK/toluene to 55–65 wt% solids for glass fabric impregnation.
Post-lamination characterization yields glass transition temperature of 205–215°C by TMA per IPC-TM-650 2.4.24, z-axis CTE below Tg of 28–32 ppm/°C per IPC-TM-650 2.4.41, and copper peel strength of 0.80–0.90 N/mm per IPC-TM-650 2.4.8. Peel failure occurs cohesively within the resin layer rather than at the treated copper interface, indicating adequate wetting without the use of amine-functional silane coupling agents. Formulators should avoid amine-functional silane additives; addition of 0.5–1.0 wt% 3-aminopropyltriethoxysilane reduces varnish gel time from 220 s to 80 s at 170°C, causing premature crosslinking during treater application.
For Open Accelerator Module substrates with 14–22 layers, via aspect ratios up to 6:1, and trace widths of 75–100 μm, the resin is used in a low-filler build-up film at 15–20 wt% loading. The build-up film is vacuum-laminated at 120°C, then UV laser-drilled at 355 nm, 8 W, and 50 kHz. The low absorption at 355 nm relative to epoxy systems yields via sidewall taper deviation of 2° across a 300 mm panel, compared with 4–5° for standard epoxy build-up films. Desmear using alkaline permanganate at 80°C for 6 min removes 0.4–0.6 μm of resin without roughening the fused silica surface. Electroless copper adhesion after desmear is 0.65–0.75 N/mm; this is lower than epoxy-based build-up films, so an adhesion promotion step with Ar/O₂ 80:20 at 150 W for 60 s is required before redistribution-layer metallization. Published data for this specific configuration is limited; the adhesion values stated are derived from controlled laboratory lamination trials on 300 mm panel format and may vary with desmear chemistry and electroless copper bath age.
Thermo-oxidative aging at 150°C in air for 1,000 h produces dissipation factor shift of 0.0002 and relative permittivity shift of 0.01 when the resin is stabilized with 0.2 wt% hindered phenolic antioxidant and 0.1 wt% organophosphite secondary antioxidant. Oxidation induction time at 190°C is 38–42 min by ISO 11357-6, compared with 15–20 min for unmodified DCPD-based hydrocarbon resin. The improvement arises from hydrogenation of the C9 aromatic fraction, which lowers benzylic hydrogen abstraction during long-time air exposure. Outgassing under vacuum at 125°C for 24 h is 0.12 wt%, measured by ASTM D2369 loss-on-drying. This outgassing ceiling supports optical module sealing applications in which volatile condensation on collimator lenses or photonic integrated circuit facets is unacceptable.
The table below presents property data normalized to a fused silica loading of 35 wt% to permit direct comparison. Values are measured on homogeneous laminates or cast films using identical sample preparation and test conditions.
| Property | Test method | ULR-3000HC | DCPD-modified hydrocarbon | PPE/PPO blend | SMA |
|---|---|---|---|---|---|
| Relative permittivity at 10 GHz | IPC-TM-650 2.5.5.13 | 2.30 | 2.45 | 2.40 | 3.30 |
| Dissipation factor at 10 GHz | IPC-TM-650 2.5.5.13 | 0.0011 | 0.0030 | 0.0020 | 0.0050 |
| Glass transition temperature | IPC-TM-650 2.4.24 | 210°C | 180°C | 205°C | 140°C |
| Z-axis CTE below Tg | IPC-TM-650 2.4.41 | 30 ppm/°C | 46 ppm/°C | 36 ppm/°C | 62 ppm/°C |
| Moisture absorption, 24 h | IPC-TM-650 2.6.2.1 | 0.08 wt% | 0.25 wt% | 0.12 wt% | 0.35 wt% |
| Copper peel strength | IPC-TM-650 2.4.8 | 0.85 N/mm | 0.75 N/mm | 0.70 N/mm | 1.10 N/mm |
Compared with DCPD-modified hydrocarbon tackifiers, ULR-3000HC provides lower dissipation factor at 10 GHz and lower moisture uptake, but its vinyl crosslink density requires tighter lamination pressure control. SMA offers higher copper peel because of polar maleic anhydride groups, but its dissipation factor is 4–5 times higher and moisture absorption is 4 times greater. PPE/PPO blends approach the dielectric performance of ULR-3000HC, but their melt viscosity during lamination is 2–3 times higher at 205°C, limiting flow into high-aspect-ratio laser vias. DCPD-modified systems can be processed at 180–200°C and therefore offer faster throughput, but they do not meet a 0.0015 dissipation factor ceiling at 10 GHz for 100G-class CCL when filler loading exceeds 35 wt%.
The compliance status supports laminate qualification for AI-server and Open Accelerator Module board fabrication under the following regulatory and safety designations.
| Requirement | Standard or method | Result |
|---|---|---|
| RoHS restricted substances | IEC 62321-1:2022 | Pb, Hg, Cr(VI), PBB, PBDE <10 ppm; Cd <5 ppm |
| Halogen-free declaration | EN 14582:2016 | Cl <900 ppm, Br <900 ppm, total <1,500 ppm |
| REACH Candidate List SVHC | REACH (EC) No 1907/2006 Article 33 | No SVHC above 0.1 wt% per substance |
| Flame resistance, halogen-free CCL formulation | UL 94 | V-0 at 0.8 mm |
| Volatile organic content as supplied | ASTM D2369 | <0.5 wt% |
Because the resin contains no halogens in the polymer backbone and is supplied as a solid with volatile organic content below 0.5 wt% by ASTM D2369, it supports EN 61249-2-21 halogen-free declarations when compounded with phosphorus-based flame retardants. The material is not classified as hazardous under GHS Revision 10, but dust generation during handling should be controlled below the ACGIH TLV of 10 mg/m³ total dust. Storage in sealed, moisture-barrier packaging at ≤30°C and ≤60% RH is recommended; if exposed to RH > 60% for more than 12 h, pre-drying at 85°C for 4 h is required before melt blending.