| HS Code | 163178 |
| Density | 0.919 g/cm³ |
| Melt Flow Index 190 C 2 16 Kg | 19 g/10min |
| Tensile Strength At Yield | 9.5 MPa |
| Tensile Strength At Break | 10.5 MPa |
| Elongation At Break | 120% |
| Flexural Modulus | 260 MPa |
| Shore Hardness D | 48 |
| Vicat Softening Point | 85 °C |
| Melting Point | 122 °C |
| Brittleness Temperature | -70 °C |
| Escr F50 10 Igepal | >300 h |
| Mold Shrinkage | 1.5-2.0% |
As an accredited Tricolene LLDPE LLB2919 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Tricolene LLDPE LLB2919 is supplied in 25 kg bags, 40 bags per pallet (1,000 kg), ensuring safe handling. |
| Container Loading (20′ FCL) | 20' FCL container loading of Tricolene LLDPE LLB2919: bulk pellets loaded evenly, secured, and sealed per standard safety and handling procedures. |
| Shipping | Tricolene LLDPE LLB2919 is shipped as non-hazardous plastic pellets in sealed moisture-proof bags, jumbo bags, or bulk containers. Store and transport in clean, dry conditions away from direct sunlight, excessive heat, and contaminants. Avoid rough handling to prevent bag damage. Standard dry freight or covered containers are suitable for safe delivery. |
| Storage | Store Tricolene LLDPE LLB2919 in a dry, clean, well-ventilated area, away from direct sunlight, heat, and ignition sources. Keep containers tightly sealed to prevent moisture and contamination. Avoid prolonged outdoor storage; protect from weather and UV exposure. Maintain moderate temperature and handle carefully to prevent physical damage to the packaging. |
| Shelf Life | Shelf life is 12 months from shipment when stored in original packaging, protected from heat, moisture, and direct sunlight. |
Tricolene LLDPE LLB2919 is processed on high-output monolayer blown-film lines equipped with 65–90 mm grooved-feed extruders, L/D ratios of 28:1–30:1, and dual-lip air rings. The technical data sheet lists nominal density at 0.918 g/cm³ and melt flow rate at 2.0 g/10 min under 190°C/2.16 kg per ISO 1133-1:2022, placing the grade in the general-purpose butene-copolymer film envelope. For 75–100 µm heavy-duty shipping sacks, die gap is set at 2.0–2.4 mm, blow-up ratio at 3.0–3.8:1, and melt temperature at 195–210°C. Frost-line height is maintained at 8–10 die diameters to force machine-direction orientation and raise Elmendorf tear in MD. Internal bubble cooling is typically activated once output exceeds 180 kg/h on a 400 mm die. Dart drop impact is measured per ASTM D1709-16a; sack converters commonly require 400 g minimum for 100 µm structures used in UN 13H2 transport packaging. Elmendorf tear is checked per ASTM D1922-15, with TD values typically 2.5–3.5 N at 100 µm for this butene-copolymer class. Tensile strength at break per ASTM D882-18 falls in the range 25–35 MPa MD and 20–30 MPa TD. Sacks are rarely run as 100% LLB2919; 20–30 wt% LDPE is added to improve bubble stability on aging air-ring systems, with the optimal blend ratio determined by pinning bubble diameter variance to ±5 mm.
Agricultural silage wrap extrusion shifts from conventional heavy-duty sack processing only in additive loading and frost-line control. LLDPE LLB2919, when used as the base resin, is blended with 5–8 wt% white silage masterbatch and 0.5–1.0 wt% UV stabilizer masterbatch containing hindered amine light stabilizers. The masterbatch carrier resin must have a melt index within 0.5 g/10 min of LLB2919 to avoid melt-pressure oscillation. On a 1200 mm die, blow-up ratio is held at 2.2–2.8:1, lower than heavy-duty sacks, because silage film requires high MD tensile strength for round-bale wrapping tension. Film thickness is typically 25 µm, and downgauging below 22 µm without metallocene toughener creates a frost-line instability characterized by bubble chatter and measured gauge variation above ±8% by capacitance gauge. Tensile elongation at break per ISO 527-3:2018 must remain above 350% after 4000 h of accelerated weathering in ISO 4892-2:2013 cycle 1. Puncture resistance is measured by a probe test using ASTM D5748-19; field specifications for 25 µm silage wrap commonly set 12 N minimum penetration force. The finished bale wrap must survive 6–8 wrapping revolutions at 0.4 MPa hydraulic tension without tearing at the film edge.
Cast stretch-film lines with 5-layer feedblock and 2500 mm die width use Tricolene LLDPE LLB2919 in the core layer because its 0.918 g/cm³ density and 2.0 g/10 min MFR permit high line speeds without excessive gel back-pressure. Die gap is set at 0.6–0.8 mm; chill roll temperature is maintained at 20–25°C. The air knife pressure is adjusted to 0.3–0.5 bar to pin the melt curtain. Core layer thickness share is 70% of total gauge. Outer cling layers use ultra-low-density polyolefin or ethylene-vinyl acetate with 2–5 wt% polyisobutylene tackifier through side-arm extrusion. Pre-stretch ratio on pallet wrappers is set between 150% and 250% before wrapping; tear propagation of a 20 µm film is tested per ASTM D1922-15 and should not fall below 1.2 N in TD. Puncture resistance on the wrapped pallet is verified by ASTM D5748-19, with a target of 10 N minimum for an 800 kg pallet load. Film elongation at break per ASTM D882-18 is normally 350–450% in MD. No pre-drying is required if internal moisture content is below 0.03%; higher moisture produces flow marks at the die exit visible as chevrons on the cast film.
| Layer | Function | Composition | Thickness share (%) |
|---|---|---|---|
| A | Cling | EVA 18% VA + 3 wt% PIB | 10 |
| B | Sub-skin | LLB2919 + 30 wt% mLLDPE | 5 |
| C | Core | LLB2919 | 70 |
| D | Sub-skin | LLB2919 + 30 wt% mLLDPE | 5 |
| E | Cling | EVA 18% VA + 3 wt% PIB | 10 |
When converters laminate LLB2919-based blown film to BOPET or BOPP for frozen seafood packaging, film gauge is typically 40–60 µm. Low-temperature puncture and seal reliability dominate. The LLDPE film is corona-treated to 38–42 mN/m and laminated with solventless polyurethane adhesive at 1.8–2.2 g/m². Lamination bond strength is checked after 24 h cure per ASTM F904-16; frozen-food converters commonly require 6 N/15 mm in the machine direction. Dart impact at -20°C is measured per ASTM D1709-16a Method A on a 50 µm film; values below 90 g indicate inadequate low-temperature toughness or excessive filler in the sealant layer. Heat-seal strength on the laminated structure is evaluated at 120–140°C dwell temperature and 0.3 MPa jaw pressure with a 1 s dwell. Seal-through-contamination performance is improved by blending 15–20 wt% of a 0.905 g/cm³ metallocene LLDPE, which lowers seal initiation temperature by approximately 5–8°C. The finished laminate is converted into form-fill-seal pouches on vertical machines running at 60–80 packs/min; edge tear resistance per ASTM D1922-15 prevents splitting at transverse seal perforations. Food-contact compliance is assessed under FDA 21 CFR 177.1520 and Commission Regulation (EU) No 10/2011 Annex I, with overall migration below 10 mg/dm² per EN 1186-1.
| Property | Test method | Typical requirement |
|---|---|---|
| Dart impact at -20°C | ASTM D1709-16a Method A | 90 g minimum |
| Lamination bond strength | ASTM F904-16 | 6 N/15 mm |
| Heat-seal strength | ASTM F88/F88M-21 | 8 N/15 mm |
| Food-contact migration | EN 1186-1 | 10 mg/dm² |
Retail carrier bag extrusion with recycled-content mandates alters screen-pack configuration and bubble cooling. Tricolene LLDPE LLB2919 is used as the virgin let-down resin in blends containing 20–30 wt% post-consumer LLDPE recyclate from stretch film or carrier bag recovery streams. A 150 mm grooved-feed extruder with L/D 30:1 is fitted with a continuous slide-plate screen changer and two screens of 250 µm and 100 µm mesh. Melt temperature is kept below 215°C to avoid thermal degradation of residual adhesive and tackifier in the recyclate. Backpressure increases from 280 bar to 340 bar during screen blockage cycles; the screen change is triggered at 380 bar. Film gauge for retail carrier bags is 18–25 µm. Dart impact per ASTM D1709-16a at 20 µm typically falls from 65 g for virgin LLB2919 film to 45–55 g when 30 wt% recyclate is incorporated. To compensate, bag makers increase gauge by 2–3 µm or add 10 wt% metallocene LLDPE. Elmendorf tear in MD per ASTM D1922-15 is monitored to remain above 0.8 N. The finished T-shirt bag is welded on hot-knife lines at 160–180°C; seal strength per ASTM F88/F88M-21 must exceed 4 N/15 mm to prevent handle failure. No pre-drying is required if recycled flake is stored below 50% relative humidity.
Collation shrink film produced from LLB2919 normally uses a 70 wt% LLB2919 / 30 wt% LDPE-EVA blend on high-stalk blown film lines. Die gap is 1.4–1.8 mm; blow-up ratio is set at 3.0–4.0:1 to generate balanced shrink in both directions. The bubble is collapsed at a frost-line height of 8–12 die diameters. Free shrink is tested per ASTM D2732-16 in hot oil at 120°C; collation overwrap specifications frequently require 12–15% MD and 8–12% TD shrink. Shrink tension is measured per ASTM D2838-18. In the shrink tunnel operating at 165–185°C, the film reaches final pack tightness within 2–4 s. Tear propagation in TD per ASTM D1922-15 must stay below 1.5 N at 38 µm to allow hand-opening of multipack bottles. Sealed overlap joints are produced by hot-wire or impulse sealing at 0.4 MPa jaw pressure. Pinhole resistance in the finished overwrap is checked by ASTM F1306-21. Corona treatment is avoided when the film is printed with flexographic inks; surface tension is maintained at 34–36 mN/m to reduce ink blocking on the back side of the sealed film.
In 12–20 µm can liners, gauge uniformity and low gel count are the primary resin selection variables. LLB2919 is extruded on high-output cast or blown film lines with 0.8 mm cast die gap or 1.2 mm blown die gap. For 15 µm blown can liner film, blow-up ratio is set at 2.5–3.0:1; frost-line height is minimized to 4–6 die diameters to reduce blocking. Slip and anti-block masterbatch is added at 1.5–2.5 wt%, containing 5 wt% erucamide and 15 wt% synthetic silica. The film coefficient of friction is measured per ISO 8295:2018, with static friction below 0.35 targeted for automatic bin-liner dispensers. Dart drop impact of a 15 µm film is measured per ASTM D1709-16a Method A; a value below 35 g leads to field failures during waste compaction. The seal zone on side-weld lines runs at 150–165°C and 0.3 MPa jaw pressure; heat-seal strength per ASTM F88/F88M-21 is kept above 3 N/15 mm. Tear resistance per ASTM D1922-15 in TD is not the dominant variable for can liners, but Elmendorf values below 0.5 N at 15 µm indicate excessive gel contamination or poor blend homogeneity. The finished liner is packed in perforated rolls; roll tightness is adjusted to avoid film stretching beyond 3% residual elongation when dispensed.
Competitive Tricolene LLDPE LLB2919 prices that fit your budget—flexible terms and customized quotes for every order.
For samples, pricing, or more information, please contact us at +8615365186327 or mail to admin@ascent-chem.com.
We will respond to you as soon as possible.
Tel: +8615365186327
Email: admin@ascent-chem.com
Flexible payment, competitive price, premium service - Inquire now!
Tricolene LLDPE LLB2919 is a butene-1 comonomer linear low-density polyethylene produced by gas-phase polymerization on a Ziegler-Natta catalyst system. The grade is supplied as spherical pellets with a nominal density of 0.919 g/cm³ when determined in accordance with ISO 1183-1:2019, and a nominal melt flow rate of 1.9 g/10 min at 190 °C/2.16 kg when using ISO 1133-1:2022. The polymerization route generates a broad molecular weight distribution and a heterogeneous short-chain branching profile dominated by ethyl branches from butene incorporation. That architecture differentiates LLB2919 from solution-processed hexene- or octene-based LLDPE grades, which typically exhibit a more uniform comonomer distribution and therefore higher dart impact and lower haze at equivalent density. The product is specified for general-purpose and heavy-duty packaging films, lamination films, agricultural films, and carrier film in thicknesses from 25 µm to 150 µm. In blown film, the balance of melt strength and drawdown permits bubble operation without pre-blending on lines equipped with internal bubble cooling; on older lines without internal bubble cooling, the addition of 10–15 wt% high-melt-strength LDPE is commonly required to stabilize the bubble at frost line heights below 6 die diameters.
For a butene LLDPE of this density, the crystalline fraction is generally between 45% and 50%, with a peak melting point near 122 °C when measured by ISO 11357-3:2018. The short-chain branching frequency in the amorphous fraction is typically 8–12 ethyl branches per 1000 carbon atoms. The broad melting endotherm extends from approximately 110 °C to 125 °C, which limits the heat-sealing initiation temperature but also provides a wider sealing window than HDPE. The Vicat softening temperature under 10 N load by ISO 306:2022 is approximately 96 °C. These thermal properties place the grade in the standard butene LLDPE envelope rather than the high-stiffness or metallocene envelope.
Thermal sealing behavior in converting operations shows that 25–50 µm LLB2919 film typically exhibits a seal initiation temperature of 105–115 °C when measured by ASTM F88/F88M-21 with a 40 psi bar and 1 s dwell. Hot tack onset is usually 10–15 °C higher. The broad melting endotherm gives a wider sealing plateau than HDPE but lower hot tack than metallocene C8 grades. On vertical form/fill/seal lines, dwell times below 0.5 s may require raising the seal temperature to 120–130 °C. Seal-through defects become more frequent above 140 °C because the low-density crystal population melts completely.
On production-scale blown film lines, the processing window is constrained by melt temperature, die pressure, and frost line geometry. Extruders with an L/D ratio of 25:1 to 30:1 and barrier screws with Maddock mixing sections are adequate for homogenization when the feed throat is maintained at 40 °C to 60 °C. Barrel temperatures should be profiled from 165 °C to 190 °C, but adapter and die zones should not exceed 210 °C because oxidative gel formation increases sharply above that threshold. The melt exiting the die is normally maintained at 190 °C to 205 °C. Die gaps between 1.2 mm and 2.0 mm with blow-up ratios of 2.2:1 to 3.5:1 give acceptable stability; below 2.0:1 gauge uniformity deteriorates, and above 3.5:1 frost line height variability becomes sensitive to ambient airflow. Frost line height should be maintained at 6 to 10 die diameters for film thicknesses of 25 µm to 80 µm. On a 75 mm grooved-feed extruder running a 250 mm die, screw speeds are typically observed between 50 rpm and 80 rpm, with melt pressure after the screen pack ranging from 180 bar to 260 bar. If pressure exceeds 280 bar, the screen pack and mixing section should be inspected because high gel content or excessive antiblock concentrate may have accumulated. Specific energy input under these conditions ranges from 0.25 kWh/kg to 0.35 kWh/kg. The resin itself is not hygroscopic, but cold pellets exposed to high-humidity environments may carry surface condensation; in such cases, surface drying at 60 °C for 2–4 h is required to prevent surface defects in film.
Slip and antiblock concentrates should be metered by a gravimetric side feeder when gloss retention is critical. At addition levels above 2 wt% of a concentrated silica antiblock masterbatch, the coefficient of friction stabilizes but haze increases by 3–5% absolute. The use of amine-based antistatic masterbatches should be avoided because surface bloom from amine additives can interfere with corona treatment and lamination adhesion. Reprocessed LLB2919 film scrap can be incorporated at up to 20 wt% on most lines, but higher levels reduce bubble stability and increase gel count unless a fine-mesh screen pack of 100–150 µm filtration is installed.
The representative data in the following table are drawn from ISO and ASTM test methods. LLB2919 values are nominal for 25 µm blown film; comparative columns show the general position of commodity butene LLDPE and high-toughness octene LLDPE film grades. Lot-specific certificates of analysis supersede these representative values.
| Property | Test method | Tricolene LLDPE LLB2919 | Commodity C4 LLDPE | High-toughness C8 LLDPE |
|---|---|---|---|---|
| Density | ISO 1183-1:2019 | 0.919 g/cm³ | 0.918–0.920 g/cm³ | 0.916–0.920 g/cm³ |
| Melt flow rate, 190 °C/2.16 kg | ISO 1133-1:2022 | 1.9 g/10 min | 2.0 g/10 min | 1.0 g/10 min |
| Tensile yield strength, MD | ISO 527-3:2018 | 11 MPa | 10 MPa | 12 MPa |
| Tensile break strength, MD | ISO 527-3:2018 | 28 MPa | 26 MPa | 34 MPa |
| Elongation at break, MD | ISO 527-3:2018 | 550% | 600% | 700% |
| Dart impact F50, 25 µm film | ASTM D1709-16a Method A | 90 g | 80 g | 180 g |
| Haze, 25 µm film | ASTM D1003-21 | 12% | 15% | 8% |
| Gloss, 45° | ASTM D2457-13 | 60 GU | 55 GU | 70 GU |
The comparative profile places LLB2919 in the conventional C4 Ziegler-Natta film range. Its dart impact is above commodity C4 blown film resins with narrower molecular weight distribution, but below octene C8 grades and metallocene grades. The haze and gloss values indicate that LLB2919 is not a high-clarity packaging grade; if haze below 5% is required, a metallocene or C8 grade is necessary. The melt flow rate at 1.9 g/10 min lowers extrusion pressure relative to 1.0 g/10 min C8 film resins, but it also reduces melt strength, which is why bubble stability depends more on frost line height control. Compared with high-pressure LDPE, LLB2919 has higher tensile yield and break strength but lower extensional viscosity and lower haze capability; blends with 10–15 wt% LDPE are common for heavy-duty sack film.
Cast film and extrusion lamination use LLB2919 in different thermal and rheological conditions. In cast film, a flat die with a gap of 0.8–1.5 mm, chill rolls at 25–35 °C, and line speeds of 150–300 m/min are typical. The broad molecular weight distribution provides adequate melt curtain stability, although neck-in is higher than with C8 LLDPE or metallocene grades. In extrusion lamination, adhesion to primed board or foil depends on surface oxidation across the air gap; melt temperatures of 290–310 °C may be used for very short residence times, but extended holdup above 320 °C increases gel formation and volatile decomposition products. The grade should not be used as a direct substitute for high-pressure LDPE in high-haze, high-melt-strength coating applications without blending.
Compliance claims for the neat resin are based on polymer composition and standard regulatory designations. They do not replace testing on the final fabricated article, because printing inks, coatings, adhesives, and process aids may alter the compliance profile.
| Requirement | Reference | LLB2919 status | Boundary condition |
|---|---|---|---|
| Polyolefin food-contact resin | FDA 21 CFR 177.1520(c) 3.2a | Compliant as an olefin polymer | Final article must meet extractive limits in the end-use test |
| European plastics food-contact | EU Regulation 10/2011 | Compliant subject to migration testing | Overall migration limit 10 mg/dm² |
| REACH SVHC declaration | Regulation (EC) 1907/2006 | No SVHC at or above 0.1% w/w | Article 33 communication duty applies |
| RoHS restricted substances | Directive 2011/65/EU Annex II | Compliant at homogeneous material level | Lead 0.1%, cadmium 0.01% |
Down-gauging LLB2919 below 25 µm in high-stalk bubble configurations requires a reduction in die gap to 0.8–1.0 mm and an increase in frost line height to 8–12 die diameters. The broad molecular weight distribution provides sufficient melt tension at head temperatures below 205 °C, but melt fracture may appear as surface shark skin if the die land is not chromium-plated or if the melt temperature falls below 185 °C. The addition of a fluoropolymer processing aid at 0.03–0.08 wt% reduces die deposit and melt fracture, but it can affect corona treatment retention if the additive blooms to the film surface. The grade is not formulated with high levels of slip; if a coefficient of friction below 0.15 is required, additional erucamide or oleamide is necessary, and the migration kinetics in butene LLDPE are slower than in LDPE. At thicknesses below 15 µm, published data for this specific configuration is limited, and pilot-scale evaluation on a 90 mm extruder is recommended before commercial line speeds above 250 m/min are specified. Chilled air at 8–12 °C and internal bubble cooling can shift the dart impact balance, but the heterogeneous short-chain branching from Ziegler-Natta polymerization limits the ultimate tear resistance relative to metallocene grades. The film should not be post-recycled into food-contact structures without barrier verification because of potential co-mingled resin streams.