| HS Code | 635114 |
| Density | 1.08 g/cm³ |
| Melt Flow Rate | 15 g/10 min |
| Tensile Strength | 42 MPa |
| Elongation At Break | 20% |
| Flexural Modulus | 1900 MPa |
| Flexural Strength | 65 MPa |
| Notched Izod Impact Strength | 10 kJ/m² |
| Heat Deflection Temperature At 1 82 Mpa | 75 °C |
| Vicat Softening Temperature | 90 °C |
| Rockwell Hardness | R100 |
| Molding Shrinkage | 0.4–0.6% |
| Light Transmittance | 85% |
| Haze | 2% |
| Water Absorption | 0.3% |
As an accredited Toray TOYOLAC® MABS TP92 X06 U factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Toray TOYOLAC® MABS TP92 X06 U is supplied in 25 kg moisture-resistant paper bags, palletized for industrial handling and storage. |
| Container Loading (20′ FCL) | Toray TOYOLAC® MABS TP92 X06 U loaded in a 20′ FCL container, palletized in export bags, secured for ocean shipment. |
| Shipping | Toray TOYOLAC® MABS TP92 X06 U is shipped as non-hazardous thermoplastic pellets, typically in moisture-barrier bags, boxes, or octabins. Transport and store in a cool, dry, well-ventilated area away from direct sunlight and heat. No special UN hazard classification. |
| Storage | Store Toray TOYOLAC® MABS TP92 X06 U in a cool, dry, well-ventilated area away from direct sunlight, heat, ignition sources, and oxidizing materials. Keep original containers tightly closed to prevent moisture absorption and contamination. Protect from prolonged high humidity and temperature extremes. Use first-in-first-out stock rotation, stable stacking, and spill containment; avoid dust generation. |
| Shelf Life | Store sealed in a cool, dry place; typical shelf life is 24 months from production date when protected from moisture. |
In transparent in-vitro diagnostic housings and lateral-flow reader covers, material selection is driven by the simultaneous need for optical clarity, dimensional stability after repeated disinfection, and impact resistance during field service. The TOYOLAC MABS TP92 X06 U grade is considered where polycarbonate is excluded because of stress-cracking risk under alcohol-based disinfectants and where cyclo-olefin copolymers are not cost-competitive for larger housing shells. The material is pre-dried in a desiccant dryer at 80 °C for 3–4 h to a residual moisture content of ≤0.02 wt% before plastication. Melt temperature is maintained between 230 °C and 245 °C with a maximum residence time of 10 min; excursions beyond 250 °C produce measurable yellowing and a reduction in impact strength caused by elastomer-phase degradation. The tool is operated with a mold temperature of 45–55 °C using a medium-shear screw at 20:1 to 24:1 L/D and a back pressure of 5–10 bar.
For optical windows and cuvette sleds, polished S136 steel cavity surfaces are specified, and sequential valve-gate sequencing is used to move the weld line away from the read path. The part design should keep wall sections between 1.5 mm and 2.5 mm; abrupt transitions below 1.0 mm create flow hesitation and anisotropy that can be visualised under polarised light as stress birefringence. Masterbatch letdown is typically 2.0–3.0 wt% of an MABS-carrier colour concentrate. If static dissipation is required in dusty diagnostic environments, a non-ionic antistatic masterbatch is added at 0.2 wt% only after review under ISO 10993-1, because ionic additives can migrate to the surface and interfere with assay optics. The terminal parts include reagent drawer fronts, optical window retainers, and cuvette adapters for bench-top analysers.
Compliance for electrical diagnostic equipment follows IEC 60601-1, with material documentation supporting the highest wall thickness and lowest molded density; REACH 1907/2006 and RoHS 2011/65/EU Annex II apply to import. Cleaning validation uses 70% ethanol, 0.5% quaternary ammonium, and 0.1% sodium hypochlorite in a soaked-wipe protocol; the grade must be screened for stress cracking at 0.5% flexural strain for 48 h at 23 °C per ISO 22088-3. Autoclave sterilisation at 121 °C is not a valid processing route because the material's heat-distortion range is below autoclave temperature; ethylene oxide or electron-beam cycles require project-specific dose mapping and may cause yellowing if the dose exceeds the grade's stabiliser package. Published data for this specific TP92 X06 U configuration under repeated terminal sterilisation is limited, so a production-equivalent validation on molded plaques is mandatory before release.
Cosmetic packaging requires a combination of high gloss, scratch resistance, and resistance to fragrance oils, esters, and alcohol-based formulations that can generate environmental stress cracking in ordinary transparent ABS. The MABS grade is evaluated for lipstick case outer shells, compact bases and lids, and cream jar sidewalls where PMMA is often rejected because drop impact failures occur at cold-fill temperatures. The material is processed at a melt temperature of 235–250 °C with a mold temperature of 50–60 °C; higher mold temperatures improve gloss but extend cycle time. In unscrewing molds for lipstick mechanisms, the core temperature must be controlled with pressurised water at 60 °C to avoid thread cracking.
Colour masterbatch is added at 1.5–3.5 wt% depending on tint depth, and pearlescent masterbatch at 0.5–1.5 wt% when a metallic appearance is required. External release agents based on mineral oil must not be used because they migrate to the surface and cause cissing in subsequent metallisation or lacquering. Stress-crack resistance is screened by applying 0.5% flexural strain in a jig and immersing coupons in 95% ethanol or isopropyl myristate for 24 h at 23 °C; any craze in the gate area is a reject criterion. The terminal products include fragrance caps, lipstick outer cases, compact housings, and jar bodies.
Compliance under EU Regulation 1223/2009 is directed at the finished cosmetic article, but the packaging must not release substances that exceed migration limits under REACH 1907/2006 Annex XVII. Packaging Directive 94/62/EC applies to the carton, not the polymer shell, unless the shell is a disposable item. In practice, converters document raw-material lot declarations and avoid recycled content in contact with the formulation. If the product is intended for refillable packaging, the design must tolerate repeated opening torque and alcohol wet-wipe cleaning; validation uses 50 refill cycles and 0.5 N·m thread torque on an MABS/POM tribological pair.
LED light pipes, router status lenses, and IR remote-control windows require low haze, high luminous transmittance, and stable colour after blue-LED exposure. The grade is processed with polished inserts having surface roughness below 0.05 µm Ra; any release agent or surface defect becomes visible as a bright spot in the light path. Melt temperature is set at 240–255 °C, and the holding-pressure profile is tuned to avoid sink marks around ribs and bosses. For light pipes with a length-to-thickness ratio above 10:1, the part must be designed with a slight taper of 0.5–1.0° and a gate located at the LED coupling face.
Optical diffusion is achieved with 0.5–1.0 wt% of a highly dispersing diffuser masterbatch in an MABS carrier; higher loadings reduce total luminous transmittance below the acceptable limit for most consumer devices. Regrind from runner systems is limited to 10 wt% in non-critical zones because repeated heat history raises yellowness index and reduces light transmission. Conductive or carbon-based masterbatches must be excluded from transparent optical zones. Terminal products include LED light pipes for set-top boxes, router indicator windows, and speaker-control lenses.
Compliance follows IEC 62368-1 for audio/video and ICT equipment; the material is supplied with REACH and RoHS 2011/65/EU Annex II documentation. Optical validation is performed according to ASTM D1003 on molded plaques, and the production part must be measured at actual thickness because haze scales with path length. The flammability rating is normally HB at 1.5 mm; if the enclosure requires a V-0 rating at 1.5 mm, this grade is not suitable without an additional flame-retardant system, which would destroy transparency. Thermal management is also a boundary condition: continuous use at 65 °C is acceptable, but local hot spots above 80 °C near LED heat sinks must be verified by thermocouple mapping on the molded part.
For electric toothbrush travel cases and shaver charging-stand covers, the grade is evaluated because the part must combine transparency with drop resistance in humid environments. Drying and melt conditions follow the general MABS window, but thick travel-case walls of 3–5 mm require lower injection velocity of 30–60 mm/s and extended packing to prevent sink marks. Colourant loading is kept at 1.0–2.0 wt%; higher loadings raise haze and reduce the perceived clarity of the transparent shell. Terminal parts include toothbrush travel cases, charging-stand covers, and water-flosser reservoir windows.
Compliance is governed by IEC 60335-1 and IEC 60695-10-2 ball-pressure verification. Transparent covers for hand-held appliances are not subjected to food-contact requirements unless they form a water path intended for oral rinse; in that case, specific migration testing under EU 10/2011 is required, and the material must be evaluated because MABS is not universally listed for all food-contact conditions. The operational boundary is set by detergent exposure: repeated immersion in 1% sodium lauryl sulfate at 40 °C for 100 cycles is used for crack screening, but published data for this grade under toothpaste abrasion is limited.
Automotive climate-control knobs, shift-indicator lenses, and ambient-light guides sit in enclosed cabins where solar load can push surface temperatures beyond 80 °C on dark trim. The grade is specified only for applications where the continuous-use temperature stays below 80 °C and where the part is not exposed to direct summer sunlight for prolonged periods. Melt temperature is controlled at 240–260 °C, and mold temperature at 50–60 °C to reduce moulded-in stress. After molding, parts must be annealed at 70 °C for 2 h if press-fit or screw bosses are present, otherwise stress relaxation during service leads to cracking at the boss base.
Optical grade masterbatch loading is limited to 1.0–2.0 wt% to preserve transmission; any masterbatch containing low-molecular-weight lubricant can increase fogging. Compliance testing follows ISO 3795 for horizontal flammability, VDA 277 for VOC, DIN 75201B for gravimetric fogging, and ISO 4892-2 for accelerated weathering. The U-stabilised grade should retain transmission under light exposure, but the actual colour shift must be verified by cycling 3 mm plaques through 1000 h of xenon-arc exposure at 60 °C black-panel temperature. The terminal products include centre-stack control rings, shift-knob lenses, and interior light-pipe covers.
The most common production failure is splay caused by incomplete drying in high-humidity plants; desiccant dryer dew point must be below -30 °C and the hopper must be sealed. The second common defect is flow mark on polished dark-tinted parts, corrected by increasing mold temperature to 60 °C and reducing injection velocity to 40–80 mm/s. Published data for this particular TP92 X06 U lot under OEM-specific long-term heat aging is limited, so each harness build must use the OEM’s internal PV test plan.
A different set of constraints appears in household appliance transparent reservoirs and sensor covers where ambient humidity and detergent contact dominate. Robot-vacuum dust bins, air-purifier water-tank windows, and coffee-grinder bean-hopper covers are molded with wall stock 2.0–3.5 mm and require snap-fit integrity after 1000 open-close cycles. The melt temperature is set to 230–245 °C for large-area parts; mold temperature is kept at 40–55 °C because higher temperatures increase cycle time without resolving sink marks at rib roots. Regrind is limited to 15 wt% for transparent components; for opaque internal brackets made from the same grade, up to 30 wt% clean production regrind may be used if tensile and impact properties are verified per ISO 527-2 and ISO 179-1.
Compliance follows IEC 60335-1 and RoHS 2011/65/EU Annex II. If the water tank is marketed as a potable water contact part, the material must also satisfy EU 10/2011, and MABS requires specific migration testing because it is not a generic polyolefin. Chemical resistance is screened by immersion in 5% citric acid and 1% sodium bicarbonate for 72 h at 23 °C. The terminal products include dust-bin housings, air-purifier water-tank covers, and bean-hopper transparent windows.
Table 1 summarises production-scale processing windows and primary constraints for the first four downstream groups.
| Downstream group | Drying | Melt temperature | Mold temperature | Typical additive loading | Primary failure mode |
|---|---|---|---|---|---|
| Medical IVD housings | 80 °C, 3–4 h | 230–245 °C | 45–55 °C | 2.0–3.0 wt% colour masterbatch | Disinfectant stress cracking at bosses |
| Cosmetic packaging | 80 °C, 3–4 h | 235–250 °C | 50–60 °C | 1.5–3.5 wt% colour, 0.5–1.5 wt% pearlescent | Fragrance-induced crazing at gate |
| Consumer electronics light guides | 80 °C, 4 h | 240–255 °C | 50–60 °C | 0.5–1.0 wt% diffuser masterbatch | Weld-line optical loss |
| Personal care appliances | 80 °C, 3–4 h | 230–245 °C | 40–55 °C | 1.0–2.0 wt% colour masterbatch | Sink marks in thick sections |
Table 2 maps the limiting compliance and test methods for the downstream groups discussed in the preceding sections.
| Downstream group | Primary compliance reference | Critical test method | Limiting parameter |
|---|---|---|---|
| Medical IVD housings | IEC 60601-1, ISO 10993-1 | ISO 22088-3 | Stress cracking at 0.5% strain after disinfectant exposure |
| Cosmetic packaging | EU Regulation 1223/2009, REACH 1907/2006 | ISO 22088-3 | Crazing after 24 h immersion in 95% ethanol |
| Consumer electronics light guides | IEC 62368-1, RoHS 2011/65/EU | ASTM D1003 | Haze increase at 3 mm path length |
| Personal care appliances | IEC 60335-1 | IEC 60695-10-2 | Ball-pressure threshold below 125 °C |
| Automotive interior controls | ISO 3795, VDA 277, DIN 75201B | ISO 4892-2 | Colour shift after 1000 h xenon-arc exposure |
| Household appliance components | IEC 60335-1, RoHS 2011/65/EU | ISO 527-2, ISO 179-1 | Property retention after 1000 snap-fit cycles |
| Laboratory instrument enclosures | IEC 61010-1, REACH 1907/2006 | ISO 22088-3 | Haze after 72 h chemical immersion |
Benchtop analytical instruments use transparent covers that must survive occasional spills of dilute acids, alkalis, and short-chain alcohols without hazing or cracking. The MABS grade is processed with melt temperature 230–245 °C and mold temperature 40–55 °C; the use of a low-shear screw is recommended to avoid local overheating in thick-walled shield designs. For safety shields, the minimum wall thickness is 3 mm, and the part must be stress-relieved at 60 °C for 1 h before any solvent-based adhesive or gasket is assembled.
Compliance is driven by the instrument standard, typically IEC 61010-1, with material documentation supporting REACH 1907/2006 and RoHS 2011/65/EU Annex II. Chemical resistance is tested by immersion of stressed coupons in 10% hydrochloric acid, 10% sodium hydroxide, and 70% ethanol for 72 h; any haze or craze indicates a solvent attack path. For laser-safety covers, a 2.0 wt% blue-tinted masterbatch is used only if the wavelength-specific optical density is verified on a production-equivalent thickness. The terminal products include spectrophotometer covers, pipette carousel shields, and centrifuge lids.
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Toray TOYOLAC® MABS TP92 X06 U is a methyl methacrylate-acrylonitrile-butadiene-styrene copolymer supplied by Toray Industries as a transparent injection-molding grade. The material combines a methacrylate-rich continuous phase with a controlled butadiene-containing graft phase. Unlike standard opaque TOYOLAC ABS, the MABS series uses rubber particle sizing and a selected refractive-index balance to reduce visible-light scattering, but the two-phase morphology still provides higher practical toughness than unmodified PMMA while retaining lower melt viscosity than polycarbonate. The grade is characterized principally under ISO 1183-1:2019, ISO 1133-1:2022, ISO 527-2:2012, ISO 178:2019, ISO 179-1:2010, ISO 306:2022, and ISO 75-2:2013. The suffix U is generally associated in Toray’s transparent MABS nomenclature with an ultraviolet-stabilized additive package, although converters should obtain lot-specific certification for UV absorber content and should not infer outdoor weatherability from the code alone.
| Property | Test method | Typical value |
|---|---|---|
| Density | ISO 1183-1:2019 | 1.09 g/cm3 |
| Melt volume-flow rate | ISO 1133-1:2022 | 17 cm3/10 min at 220 °C / 10.0 kg |
| Tensile yield stress | ISO 527-2:2012 | 42 MPa |
| Tensile elongation at yield | ISO 527-2:2012 | 3.5 % |
| Nominal strain at break | ISO 527-2:2012 | 15 % |
| Flexural modulus | ISO 178:2019 | 2300 MPa |
| Flexural strength | ISO 178:2019 | 66 MPa |
| Charpy notched impact strength | ISO 179-1:2010, 23 °C | 5.5 kJ/m2 |
| Rockwell hardness | ISO 2039-2 | 105 L-scale |
| Total luminous transmittance | ISO 13468-2 | 90 % |
| Haze | ISO 14782:1999 | 1.5 % |
| Vicat softening temperature | ISO 306:2022, B50 | 92 °C |
| Heat deflection temperature | ISO 75-2:2013, 1.8 MPa | 75 °C |
The tabulated values are representative of injection-molded test specimens conditioned under ISO 291 at 23 °C and 50 % relative humidity. They should not be treated as release specifications. Die geometry, pigment load, and regrind content can displace notched impact values by more than 10 % and optical haze by more than 20 %. Incoming inspection should therefore establish internal limits for the production-critical characteristics of the molded part rather than rely on the above values as absolute batch criteria.
Compared with standard opaque TOYOLAC ABS, TP92 X06 U uses a methyl methacrylate-rich continuous phase to shift the refractive index closer to that of the butadiene graft phase at visible wavelengths. In opaque ABS the continuous styrene-acrylonitrile phase has a refractive index near 1.57, while the butadiene phase is close to 1.52; the mismatch produces intense light scattering and opacity. In MABS the matrix refractive index is moved downward, which reduces scattering intensity but does not eliminate it. The residual haze near 1.5 % under ISO 14782:1999 reflects the incomplete index match across the visible spectrum and the finite size of the rubber domains. As a result, the material should not be selected for critical imaging optics where PMMA-grade clarity below 1.0 % haze is required. For light-pipe housings, cosmetic overcaps, fluid-level sight windows, and protective transparent covers, the optical quality is generally sufficient.
Relative to general-purpose PMMA, TP92 X06 U exhibits lower flexural modulus, approximately 2300 MPa versus 3100–3300 MPa for unmodified PMMA. The butadiene-containing phase reduces stiffness but increases notched impact resistance by roughly a factor of two to three over common PMMA. Compared with bisphenol-A polycarbonate, the MABS grade has a much lower heat deflection temperature at 1.8 MPa, approximately 75 °C versus 125 °C for medium-viscosity polycarbonate, and far lower notched Charpy impact strength. However, its melt viscosity during thin-wall filling is lower, and it is less prone to moisture-induced hydrolysis during processing than polycarbonate. Against opaque ABS, the MABS grade sacrifices maximum notched impact strength for visible-light transmission; high-impact opaque ABS can exceed 20 kJ/m2 notched Charpy, whereas this grade is near 5.5 kJ/m2. These comparisons are valid for preliminary material selection only. Part geometry, wall thickness, chemical exposure, and processing condition can invert the ranking in specific applications.
Pre-drying is mandatory for TP92 X06 U in production. MABS pellets absorb sufficient atmospheric moisture to generate splay, silver streaks, and flow-front haze when residual moisture exceeds approximately 0.05 % by weight at the feed throat. A dehumidifying hopper dryer operated at 80 °C for 3 to 4 hours with a dew point of −30 °C or lower is the standard preparation. Material stored in open containers or under relative humidity above 60 % should be dried even if the supplier packaging is intact, because partial bag use introduces humid air into the headspace. Drying above 90 °C is not recommended because pellet surfaces may soften and form agglomerates in the dryer cone.
The injection molding barrel should be profiled from approximately 190 °C at the rear zone to 220–250 °C at the nozzle. Nozzle temperatures should not exceed 250 °C for extended periods. Melt temperatures above 260 °C or total residence times beyond 5 minutes can produce yellowing, optical haze, and loss of impact due to thermal degradation of the butadiene phase. Screw recovery should be sized so that shot volume is between 30 % and 70 % of barrel capacity. Smaller shots increase residence time per cycle, while larger shots can reduce melt homogeneity and produce surface defects. On production presses with a 40 mm reciprocating screw and clamp force between 800 kN and 1200 kN, the material is best processed with a screw cushion of 3–6 mm and back pressure of 0.5–1.5 MPa. Higher back pressure increases melt temperature and can induce yellowing; lower back pressure may leave unmelted granules in the shot.
Tool temperature control is typically set at 40 °C to 60 °C for transparent parts. Lower mold-surface temperatures reduce cycle time but can freeze flow marks and increase weld-line visibility. Higher mold temperatures above 70 °C improve optical uniformity and reduce molded-in stress, but they extend cooling time and increase the risk of ejection deformation in thick sections. Mold release should be limited; silicone-based sprays can surface-haze the part. Hot-runner processing is possible, but internally heated hot-runner systems without precise tip temperature control can create local overheating in the MABS melt and generate yellow streaks. Externally heated manifolds with thermocouple-controlled tips are preferred.
During changeover from PVC, acetal, or polybutylene terephthalate, the barrel should be purged with a styrenic purge compound or with the incoming MABS itself. Residual PVC releases hydrogen chloride, which causes surface blush and mold corrosion. Residual acetal releases formaldehyde and can accelerate thermal degradation. The reverse changeover from MABS to polycarbonate should not be completed with a simple short purge because the lower-temperature MABS regime can leave degraded residue that appears later as black specks at polycarbonate set-point temperatures.
Optical defect formation in TP92 X06 U is governed less by polymer composition than by tooling stress and contamination. Mold-polishing defects above approximately 0.05 mm depth or draft angles below 0.5° can produce visible drag marks and stress birefringence. Gates should be located where weld lines do not cross primary viewing surfaces. When weld lines are unavoidable, increasing mold temperature and reducing hold-pressure time can lower their visibility but will not eliminate them entirely. Contamination from worn check rings or oil-based barrel lubricants can degrade optical clarity more than a 2 % addition of clean regrind. Piston-type injection units and free graphite should be kept out of the material stream.
Unlike polypropylene or medical polycarbonate grades, a methyl methacrylate-containing MABS can undergo measurable yellowing after gamma sterilization because ionizing radiation generates radicals in both the methacrylate continuous phase and the butadiene-containing domains. Published data for this specific TP92 X06 U configuration under standardized gamma doses is limited. Converters should not assume that a generic ABS gamma-stability claim applies to this transparent MABS. If gamma sterilization is required, dose mapping should cover the minimum required dose and maximum overdose regions, and color shift should be measured under ISO 11664-4 or a defined CIELAB procedure before lot release. Ethylene oxide and vaporized hydrogen peroxide surface sterilization are often less aggressive to optical properties, but residual gas limits must be established under ISO 10993-7 for ethylene oxide and the finished device must be vented after processing. Wiping with 70 % isopropanol is commonly used for housing disinfection; short contact times below one minute are generally accommodated by TP92 X06 U, but continuous immersion or puddle contact in stressed areas can promote environmental stress crazing. Ketone-based cleaners, ester solvents, and aromatic hydrocarbons should be avoided because they attack the matrix phase.
Regulatory evaluation of TP92 X06 U should be application-specific. The resin is subject to REACH Annex XVII and REACH SVHC obligations, and electrical or electronic parts should be assessed under Directive 2011/65/EU as amended. The material is not by default a food-contact grade under FDA 21 CFR 177.1020 solely because it is styrenic; MABS copolymers may require separate migration testing under Regulation (EU) No 10/2011 or FDA food-contact notifications. No broad medical implant claim should be inferred. USP Class VI or ISO 10993 testing is the responsibility of the finished-device manufacturer.
Production applications tend to select TP92 X06 U where PMMA fails by brittle fracture in snap-fit geometries, where polycarbonate is excluded by melt-processing or cost constraints, and where opaque ABS cannot meet a transparency requirement. Representative uses include fluid-level sight tubes, transparent pump housings, cosmetic overcaps, office-equipment covers, and non-load-bearing medical device subassemblies. In each case the part should be evaluated for solvent exposure, sterilization, and impact loading simultaneously. Selecting transparent MABS for a static window is straightforward, but selecting it for a snap-fit that experiences alcohol cleaning and gamma processing requires prototype testing.
Continuous service with mechanical load should not exceed approximately 60 °C for TP92 X06 U if long-term creep and dimensional relaxation are critical, because the heat deflection temperature under 1.8 MPa is near 75 °C. Regrind above 20 % should be validated for optical transmission because repeated thermal cycles lower luminous transmittance and increase haze. Changes from opaque TOYOLAC grades to TP92 X06 U cannot be made by simple nozzle and mold replacement; the lower thermal stability window, different melt rheology, and optical defect sensitivity require revalidation of hot-runner set points, drying, purging, mold cooling, and maintenance.