| HS Code | 313035 |
| Manufacturer | Toray Industries, Inc. |
| Product Name | Toray TOYOLAC® MABS TP90 X02 U |
| Polymer Type | MABS (Methyl Methacrylate-Acrylonitrile-Butadiene-Styrene) |
| Grade | TP90 X02 U |
| Appearance | Transparent/natural pellets (typical) |
| Density | 1.08 g/cm³ (typical) |
| Melt Flow Rate | 20 g/10 min (220°C/10 kg, typical) |
| Tensile Strength | 50 MPa (typical) |
| Flexural Modulus | 2100 MPa (typical) |
| Heat Deflection Temperature | 75°C (1.82 MPa, typical) |
| Vicat Softening Temperature | 90°C (typical) |
| Rockwell Hardness | R 100 (typical) |
| Molding Shrinkage | 0.4-0.7 % (typical) |
| Flammability | UL94 HB (typical) |
| Processing Method | Injection molding |
As an accredited Toray TOYOLAC® MABS TP90 X02 U factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Supplied in 25 kg moisture-barrier bags, palletized for industrial shipment, protecting Toray TOYOLAC® MABS TP90 X02 U resin from contamination. |
| Container Loading (20′ FCL) | 20′ FCL typically loads 17–20 MT of Toray TOYOLAC® MABS TP90 X02 U in 25 kg bags, palletized as required. |
| Shipping | Shipping description: Toray TOYOLAC® MABS TP90 X02 U, methyl methacrylate-acrylonitrile-butadiene-styrene copolymer pellets; non-hazardous, not regulated for transport. No UN number, hazard class, or packing group. Ship in sealed, moisture-resistant original packaging. Keep dry and cool, avoid direct sunlight, heat, and physical damage; follow applicable DOT/IMDG/IATA/ADR rules. Ensure containers are intact and labeled. |
| Storage | Store Toray TOYOLAC® MABS TP90 X02 U in a cool, dry, well-ventilated area away from heat, sparks, flames, and direct sunlight. Keep containers tightly closed to prevent moisture pickup and contamination. Avoid dust generation and accumulation; provide grounding and bonding where appropriate. Separate from incompatible substances, use original packaging, rotate stock, and follow the manufacturer’s SDS and local regulations. |
| Shelf Life | Typically 24 months from manufacture when stored unopened in original packaging under cool, dry conditions. |
Injection molding of Toray TOYOLAC® MABS TP90 X02 U for diagnostic instrument housings and clinical analyzer bezels begins with dehumidified hopper drying at 80–90 °C for 3–4 h; moisture retention above 0.05 % is observed on production lines as silver streaks, surface splay, and a measurable loss of luminous transmittance. On reciprocating-screw injection machines with a screw compression ratio of 2.5:1 to 3:1, melt temperature is held at 230–250 °C and mold temperature at 50–70 °C. Barrel residence time above 5 min causes progressive yellowing because the methacrylate segment degrades at the upper processing limit. Disinfectant resistance is evaluated on molded tensile bars per ASTM D543-21 using 70 % isopropanol, 0.5 % quaternary ammonium compounds, and 3 % hydrogen peroxide. A transparency loss greater than 5 % after 72 h at 23 °C is a common rejection criterion for bezels subjected to repeated wipe-down cycles. Cytotoxicity testing of the finished housing follows ISO 10993-5 and ISO 10993-12 extraction protocols; the raw resin certificate does not confer device-level biocompatibility. Steam autoclaving above 121 °C is outside the continuous-use envelope because methacrylate ester hydrolysis and opacity increase occur; ethylene oxide and e-beam sterilization are preferred. Terminal parts include automated pipetting-station safety shields, benchtop centrifuge lid windows, and laboratory automation front covers.
The substitution of transparent MABS into fragrance caps, lipstick sleeves, and airless pump collars is driven by optical clarity and resistance to common emollient contact. The main process conflict is environmental stress cracking induced by isopropyl myristate, caprylic/capric triglyceride, and citral-containing fragrance oils. Constant-strain screening under ISO 22088-3 bent strip method is performed at 0.5 % and 1.0 % applied strain; cracking at 0.5 % indicates thread-root design or weld-line strength defects that require redesign. Thread roots, snap-fit undercuts, and gate vestiges must be radiused so that local tensile strain remains below the critical value. Processing on a two-plate cold-runner mold with sequential valve gating reduces gas traps; mold temperature of 60–70 °C is preferred for surface gloss and replication of diamond-cut or frosted texture. Drying to 0.03 % moisture before molding is necessary because residual moisture increases splay and reduces transmittance. Compatibility with formaldehyde donors and amine-based neutralizers requires validation because such additives can induce haze. Final quality checks include visual inspection under D65 illumination and luminous transmittance testing per ISO 13468-1. Compliance for cosmetics packaging is assessed under Regulation (EC) No 1223/2009; finished-article extractables testing is required when contact with fragrance-containing emulsions exceeds 24 h at 40 °C.
Across potable water filtration sight glasses, reverse-osmosis membrane housing caps, and flow-meter inspection windows, the controlling performance factors are water absorption, hydrostatic creep, and oxidative disinfectant attack. Because the resin is amorphous, mold temperatures below 50 °C increase frozen-in orientation and raise the risk of stress whitening at weld lines. Parts designed for momentary exposure at 1.0 MPa and 23 °C should be molded at 55–70 °C mold temperature to minimize molded-in orientation and improve dimensional stability. Specific published creep data for TP90 X02 U in hydrostatic service is limited; processors commonly require tensile creep screening under ASTM D2990-17 and hydrostatic design basis evaluation under ASTM D2992-18 for replacement applications. Drinking-water contact certification is not intrinsic to the resin; each finished component must be evaluated under NSF/ANSI/CAN 61 or the regional equivalent. Chlorine resistance is evaluated by immersion in 5 ppm sodium hypochlorite at 60 °C for 30 days; a transmittance loss greater than 8 % or visible microcrazing rejects the grade for oxidative water service. Hot water above 70 °C is not recommended because hydrolysis and hydrostatic stress together cause whitening at weld lines. Terminal products include filter housing sight windows, flow-meter transparent covers, and sampling port inspection cups.
| Application zone | Chemical/thermal exposure | Test method | Common acceptance/rejection boundary |
|---|---|---|---|
| Diagnostic housings | 70 % isopropanol, 0.5 % quaternary ammonium at 23 °C | ASTM D543-21 | Transmittance loss ≤ 5 % after 72 h |
| Cosmetic closures | 0.5 % constant strain, ester-based fragrance oil | ISO 22088-3 | No surface cracks at 0.5 % strain |
| Water-contact windows | 5 ppm NaOCl at 60 °C | ASTM D543-21 | Transmittance loss ≤ 8 % after 30 days |
| Appliance panels | 1 % Na₂CO₃ + 0.1 % LAS at 60 °C | IEC 60335-1 / IEC 60695-2-11 | Haze development ≤ 3 % after 48 h |
Removal of flame polishing or secondary polishing in washing-machine and refrigerator control-panel windows transfers the quality burden to tool surface condition and packing-phase control. A high-gloss surface is produced by mold inserts finished to SPI/SPE A-1 diamond polish; ejector pin flash, vent residue, or flow-front hesitation becomes immediately visible without a secondary polish step. To prevent blush at ribs and bosses, gate freeze must be confirmed by a short-shot weight plateau, and packing pressure is held until the gate freezes. The processing window is narrower than in general-purpose ABS because excess melt temperature above 250 °C accelerates yellowing, while mold temperature below 50 °C reduces gloss and increases residual stress. For household appliances, compliance with IEC 60335-1:2020 requires glow-wire testing under IEC 60695-2-11 for unattended appliance enclosures. MABS without flame-retardant modification is generally classified HB under UL 94; parts in proximity to live terminals may require additional insulation. Detergent resistance is assessed by immersion in 1 % sodium carbonate and 0.1 % linear alkylbenzene sulfonate solution at 60 °C for 48 h; haze development below 3 % is normally accepted for high-end kitchen appliance windows. Terminal parts include front-load washer display lenses, oven control knobs with transparent inlays, and refrigerator door ice-dispenser bezels.
LED diffuser windows, infrared lens covers, and office automation display panels are molded from transparent MABS where impact resistance and shrinkage data per ISO 294-4 are required. Electric injection machines with cavity pressure sensors reduce sink marks and warp in thin-wall diffusers; melt temperature is kept at 230–240 °C to limit yellowing, and mold temperature is held at 50–60 °C for dimensional stability. The resin is not inherently UV-stable for continuous outdoor electronics; weatherability screening under ISO 4892-2:2013 Method A establishes color shift limits for indoor and shaded outdoor use. Flame-retardant classification is component-dependent and must be verified by the final manufacturer at the exact wall thickness. Terminal parts include printer control-panel windows, handheld scanner lens covers, and LED status-light diffusers.
For wearable medication-delivery device housings and body-contact diagnostic wearables, the polymer is evaluated within a systems framework rather than as a stand-alone raw material. Skin-contact components are extracted according to ISO 10993-12 using polar and non-polar vehicles; the resulting extractables are screened for cytotoxicity under ISO 10993-5 and for irritation under ISO 10993-23. The chemical resistance of MABS to ester-based transdermal penetration enhancers is narrower than that of cyclic olefin copolymers, so drug-excipient contact studies under ISO 22088-3 are required before production release. Processing stress in snap-fit parts is relaxed by annealing at 70 °C for 2 h; this reduces stress-whitening and improves dimension stability during storage. Terminal components include wearable insulin pump windows, continuous glucose monitor transmitter casings, and ECG patch snap covers.
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Toray TOYOLAC® MABS TP90 X02 U is supplied as a transparent methyl methacrylate–modified acrylonitrile-butadiene-styrene injection molding resin. The TP90 series designation denotes a high-light-transmission MABS with controlled rubber-phase morphology; the X02 extension identifies the specific flow-viscosity balance, while the U suffix remains part of Toray’s internal grade coding and is not independently interpreted here. Representative supplier datasheets list density per ISO 1183-1 at 1080 kg/m³ and melt volume-flow rate per ISO 1133-1 at 220°C / 10 kg near 22 cm³/10 min. Published data for this exact configuration are limited to typical release values; molders should obtain lot-specific certificates before setting in-line inspection limits. The resin is positioned for applications requiring total luminous transmittance above 85% and notched impact resistance beyond that of poly(methyl methacrylate).
Moisture uptake in MABS granulate follows hygroscopic behavior similar to ABS. At 23°C and 50% relative humidity, surface and bulk moisture can reach approximately 0.2 wt%, depending on pellet geometry and storage time. Residual moisture above 0.03 wt% at melt temperatures exceeding 230°C produces volatilization-related surface splay and silver streaks, with the visual defect appearing first near the gate where melt pressure and frictional heating are highest. Pre-drying in a desiccant-bed hopper dryer with inlet-air dew point at or below -40°C and inlet-air temperature of 80°C for 3–4 h is required for stable optical surfaces; the target residual moisture is below 0.02 wt% as measured by Karl Fischer titration per ISO 15512. Hopper capacity should be matched to shot-mass throughput so that dried granulate does not dwell in ambient plant air above 60% relative humidity for more than 30 min before entering the feed throat. Production-scale failures commonly involve undersized dryers, dew-point sensors with delayed response, or regrind reintroduction above 20 wt% that carries absorbed moisture and fines. For closed-loop material handling, dry-air conveying with dew point below -30°C is preferred over unfiltered plant-air loaders.
A direct comparison against standard opaque TOYOLAC ABS and other transparent polymers is defined by optical morphology and mechanical balance. In unmodified ABS, the refractive-index mismatch between the styrene-acrylonitrile matrix and polybutadiene rubber particles causes diffuse scattering and low regular transmittance. In MABS, incorporation of methyl methacrylate comonomer shifts the matrix refractive index toward the rubber phase, while rubber particle size distribution is controlled to reduce visible-light scattering; this preserves notched impact without heavy light loss. Industrial benchmarks place total luminous transmittance per ASTM D1003 at 2 mm wall thickness in the 88–91% band for MABS, whereas opaque ABS typically falls below 10% regular transmittance. Haze for MABS is commonly 1.0–2.0% at 2 mm, which is lower than many glass-fiber-reinforced transparent grades. Against PMMA, MABS shows lower flexural modulus, typically 2000–2300 MPa versus 3200–3300 MPa per ISO 178, and higher room-temperature Charpy notched impact of 6–10 kJ/m² versus 2–4 kJ/m² per ISO 179-1/1eA. Against polycarbonate, MABS has lower heat resistance and lower multi-axial toughness, but lower processed viscosity at comparable melt temperatures permits thin-wall filling with reduced injection pressure. The following table summarizes published comparative ranges for typical unfilled transparent and opaque grades.
| Property | Test method | Unit | MABS TP90 X02 U | Opaque TOYOLAC ABS | PMMA | Polycarbonate |
|---|---|---|---|---|---|---|
| Total luminous transmittance | ASTM D1003 | % | 88–91 | <10 | 92 | 89 |
| Haze | ASTM D1003 | % | 1.0–2.0 | not applicable | 1–2 | 1.5 |
| Charpy notched impact | ISO 179-1/1eA | kJ/m² | 6–10 | 15–25 | 2–4 | 30–40 |
| Flexural modulus | ISO 178 | MPa | 2000–2300 | 2200–2500 | 3200–3300 | 2300–2400 |
| Heat deflection temperature | ISO 75-2/B | °C | 84–88 | 92–98 | 95–102 | 130–138 |
| Density | ISO 1183-1 | kg/m³ | 1080 | 1040–1060 | 1180–1190 | 1200 |
Multi-cavity hot-runner tooling exposes the melt to temperature nonuniformities that become visible as optical banding, flow-front distortion, or cavity-to-cavity color shift. Capillary rheometry per ISO 11443 indicates that MABS viscosity at 240°C and 1000 s⁻¹ typically falls in the 70–110 Pa·s band, and a 5°C rise can lower apparent viscosity by 5–8%, altering fill balance in multi-drop systems. Hot-runner manifold zones should be controlled within ±2°C of setpoint, with nozzle tip temperatures held between 230°C and 260°C. Mold temperature should be maintained from 45°C to 80°C; the upper end of this range reduces cooling-rate-induced molecular orientation and birefringence at the expense of longer cycle time. For wall thicknesses from 1.5 mm to 2.5 mm, fill time is commonly set between 0.5 s and 2.0 s, with cavity pressure during packing held at 40–65 MPa. Valve gates should freeze after 2.5–4.0 s to prevent gate-stringing and excessive residual stress. Venting depth should be 0.02–0.03 mm for polished optical surfaces; insufficient venting produces burn marks at the end of fill, while excessive venting creates flash on textured shutoffs. On 100 t to 160 t toggle-clamp injection machines, tools with projected area up to 200 cm² can be filled without exceeding practical clamp-force limits when cavity pressure is controlled. Screw L/D ratios between 18:1 and 22:1 with compression ratios of 2:1 to 2.5:1 are adequate; screw designs with excessive shear heating should be avoided because local melt temperatures above 270°C accelerate yellowing and impact retention loss.
The property set below is abstracted from supplier technical datasheets and general MABS process data; it is not a production release specification. Lot-specific certificates of analysis control final conformance. MABS property values depend on specimen preparation, gate orientation, moisture level, and thermal history. The following table gives representative values or expected ranges for unfilled natural grade.
| Property | Test method | Unit | Typical value / expected range |
|---|---|---|---|
| Density | ISO 1183-1 | kg/m³ | 1080 |
| Melt volume-flow rate | ISO 1133-1 | cm³/10 min | 21–24 |
| Tensile yield stress | ISO 527-2 | MPa | 50–54 |
| Tensile elongation at break | ISO 527-2 | % | 10–18 |
| Flexural modulus | ISO 178 | MPa | 2000–2300 |
| Flexural strength | ISO 178 | MPa | 68–76 |
| Charpy notched impact at 23°C | ISO 179-1/1eA | kJ/m² | 6–10 |
| Heat deflection temperature | ISO 75-2/B | °C | 84–88 |
| Vicat softening temperature | ISO 306/B50 | °C | 93–97 |
| Total luminous transmittance | ASTM D1003 | % | 88–91 |
| Haze | ASTM D1003 | % | 1.0–2.0 |
For optical diagnostic housings and fluid-handling components, the resin is typically processed with polished mold surfaces on ABS-compatible steels, and optical inspection under polarized light is used to reject parts with visible birefringence or gate bloom. The grade is not a substitute for materials requiring autoclave resistance; ISO 75-2/B heat deflection temperature below 90°C is incompatible with 121°C steam sterilization. Ethylene oxide or gamma sterilization may be considered only after material and finished-article validation under the applicable device standards such as ISO 11135 or ISO 11137. When liquid disinfection is specified, compatibility with alcohol-based or quaternary ammonium formulations should be tested per ISO 175 because aromatic ketones, esters, and strong oxidizing disinfectants can initiate stress cracking or haze development. Food-contact and patient-contact applications require formulation-specific regulatory clearance; the natural grade is typically assessed under EU 10/2011, applicable sections of FDA 21 CFR, and ISO 10993-1 for medical devices, but no general clearance should be assumed from polymer type alone. The material should not be used in load-bearing transparent structures requiring polycarbonate-level multi-axial impact or continuous service above 80°C under mechanical load.