| HS Code | 314078 |
| Polymer Type | ASA (acrylonitrile-styrene-acrylate) |
| Density | 1.07 g/cm³ |
| Melt Flow Rate | 4.0 g/10 min (220°C/10 kg) |
| Mold Shrinkage | 0.4-0.6% |
| Tensile Strength | 45 MPa |
| Tensile Elongation At Break | 50% |
| Flexural Modulus | 2200 MPa |
| Flexural Strength | 70 MPa |
| Notched Izod Impact Strength | 10 kJ/m² |
| Heat Deflection Temperature At 1 8 Mpa | 85°C |
| Vicat Softening Temperature | 95°C |
| Rockwell Hardness | R95 |
| Ul94 Flammability Rating | HB |
As an accredited Toray Industries TOYOLAC™ ASA TA50C X50 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Toray Industries TOYOLAC™ ASA TA50C X50 is supplied in 25 kg sealed moisture-barrier bags, palletized for industrial handling and storage. |
| Container Loading (20′ FCL) | Toray TOYOLAC™ ASA TA50C X50 resin is palletized and securely loaded into a 20-foot FCL dry container for safe transport. |
| Shipping | Toray Industries TOYOLAC™ ASA TA50C X50 is shipped as non-hazardous ASA thermoplastic pellets in sealed moisture-barrier bags and cartons/pallets. Store cool and dry, away from sunlight, heat, and moisture. Keep packaging closed and follow the SDS and local transport regulations. No special transport measures required. |
| Storage | Store Toray Industries TOYOLAC™ ASA TA50C X50 in a cool, dry, well-ventilated area away from direct sunlight, heat sources, and open flames. Keep it in original sealed packaging to prevent moisture pickup and contamination. Avoid contact with incompatible chemicals and excessive dust generation. Maintain good housekeeping and follow local storage regulations. |
| Shelf Life | When stored sealed in a cool, dry place away from direct sunlight, typical shelf life is about 24 months. |
When black unpainted exterior components replace painted ABS on passenger vehicle cowl tops, the material is selected for retained impact after xenon exposure and dimensional stability under solar load. TOYOLAC ASA TA50C X50 is injection molded as supplied without post-mold painting, which eliminates a primer and topcoat line and shifts the part validation burden to UV stabilization and gloss retention. On a 1,300 t horizontal injection molding machine with a 70 mm diameter, 24:1 L/D general-purpose screw, the resin is processed at melt temperatures of 240–255°C and mold temperatures of 50–70°C. The cavity is a four-drop valve-gated hot runner with cold sprue elimination; shot-to-shot cushion control is maintained at 2–4 mm to prevent gas burn at the last-filled rib root. Pre-drying in a dehumidifying dryer at 80°C for 3–4 h to a residual moisture content below 0.05% is required; a dew point of −30°C or lower in the drying air is maintained because moisture hydrolysis at melt temperature produces splay and lowers notched impact.
The cowl top and wiper well cover are molded with nominal wall thickness of 2.0–2.5 mm, rib roots limited to 60% of the adjacent wall to reduce sink, and a VDI 27 texture on visible surfaces to suppress gloss variation. Melt residence time is kept below 8 min, and screw retraction speed is capped at 120 rpm to avoid shear-induced black specks. Automotive validation is anchored to ISO 4892-2:2013 cycle 1 xenon-arc exposure with a target of ΔE ≤ 3.0 and 70% gloss retention after 3,000 kJ/m² at 60°C black panel temperature. Low-temperature impact retention is checked by ISO 179-1/1eA at −30°C; if notched Charpy impact drops below 4 kJ/m², the part is rejected for cold-climate application. The finish is unpainted black; external color masterbatch above 1 wt% is not recommended because it disturbs the UV stabilizer balance and changes mold shrinkage. Regrind from sprues and rejected parts may be added up to 20 wt% only after redrying and magnetic separation, with regular melt flow rate checks under ISO 1133-1:2022 at 220°C/10 kg to manage lot-to-lot viscosity drift.
Outdoor electrical cabinets and solar inverter covers require a balance of UV stability, impact resistance, and consistent color from part to part when multiple molders supply the same SKU across regions. ASA TA50C X50 black is commonly evaluated against UL 746C F1 for UV and water exposure and against UL 94 for flammability at the minimum relevant wall thickness. The material is not inherently flame-retardant; if the enclosure must pass UL 94 V-0 at 1.5 mm, a different flame-retardant ASA/PC or FR-ABS should be considered. For outdoor small enclosures with 2.5–3.5 mm walls, the high-flow characteristics allow filling of long latch bosses and snap-fit features at melt temperatures of 235–255°C and mold temperatures of 40–60°C. Drying at 80°C for 3–4 h is mandatory because flat cabinets expose any splay at gate areas. The part is molded in the supplied X50 black, without external color masterbatch, to keep color stable across production lots.
Injection trials on a 650 t press using a 60 mm, 22:1 L/D screw and a two-cavity cold runner have shown that back pressure of 0.5–0.8 MPa and injection speed of 150–250 mm/s reduce jetting at the gate. Published data for this specific configuration is limited; shot acceptance must be confirmed by short-shot study and gate seal time. The weather seal, PCB standoffs, and cable glands are installed post-mold; the material must hold thread-forming screws at 0.5 N·m installation torque without boss cracking at −20°C. Dimensional checks use ISO 294-3 mold shrinkage measurements after 24 h at 23°C and 50% RH; nominal shrinkage is typically in the 0.4–0.6% range for ASA, but lot-specific datasheets take precedence.
| Check | Standard | Typical acceptance window |
|---|---|---|
| UV color shift | ISO 4892-2:2013 method A, 3,000 kJ/m² | ΔE ≤ 5.0, gloss retention ≥ 50% |
| Notched Charpy impact at 23°C | ISO 179-1/1eA | ≥ 8 kJ/m² |
| Notched Charpy impact at −20°C | ISO 179-1/1eA | ≥ 3 kJ/m² |
| Heat deflection temperature | ISO 75-2/A at 1.80 MPa | ≥ 75°C |
| Flammability | UL 94 at 1.5 mm | HB minimum or better |
| Mold shrinkage | ISO 294-3 | 0.4–0.6% |
In air-blast sprayer applications, contact with dilute pesticide solutions, hydrocarbon-based adjuvants, and agricultural washdown fluids creates a stress-cracking environment that is not present in automotive trim. TOYOLAC ASA TA50C X50 is used for injection-molded hand sprayer bodies, metering housings, nozzle manifolds, and irrigation valve boxes where black UV-stable surfaces are required and the chemical load is intermittent. The part design is thicker than automotive cowl covers, typically 3.0–4.0 mm, with hot-tip gates positioned away from solvent-wetted areas. Melt temperature is set at 240–250°C; mold temperature is held at 50–70°C to reduce frozen-in stress. Holding pressure is profiled in two stages, starting at 50 MPa for 2.5 s and falling to 20 MPa for 6 s to minimize gate area stress that can initiate environmental stress cracking under chemical exposure.
Chemical compatibility is screened by immersion testing under ISO 175:2010 for 7 days at 23°C in dilutions representing field concentrations; mass gain above 3% or visible surface haze triggers rejection. Constant contact with xylene, toluene, methyl ethyl ketone, or acetone is not acceptable because ASA is susceptible to stress cracking in aromatic and ketone solvents. Bent-strip stress cracking tests under ISO 22088-2 are used for each new adjuvant formulation; if cracking appears before 72 h, the chemical is considered incompatible with the molded part. The X50 black pre-compound removes the need for a separate UV masterbatch, but adding external wax-based release packages above 0.2 wt% is not advised because it lowers bond strength at ultrasonic welded joints. Regrind reuse is capped at 15 wt% for wetted components because repeated thermal history reduces elongation at break and increases sensitivity to ESC. Finished parts are assembled by ultrasonic welding at 20 kHz with a 0.4 mm energy director; weld collapse of 0.2–0.3 mm is commonly targeted. Leak tightness is verified by internal air pressure testing at 0.05 MPa after welding.
Accelerated weathering data for black ASA in building louvre and exterior fascia applications indicate that dark colors retain more stable appearance than painted ABS or standard ABS over outdoor exposure. TOYOLAC ASA TA50C X50 is injection molded into louvre blades, end caps, and mounting brackets with wall thickness 2.0–2.5 mm. The tool surface is EDM-textured to VDI 24, which lowers measured initial gloss to 20–30 GU at 60° geometry under ISO 2813; low initial gloss masks weathering-induced micro-crazing and makes gloss retention failure less visible. Processing uses a 450 t injection press with a three-stage fill-hold-screw recovery profile. Melt temperature is limited to 230–245°C because higher heat history accelerates yellowing in styrenic copolymers, while mold temperature is kept at 40–50°C to maintain flatness across 400 mm louvre blades. A cushion of 3–5 mm and screw back pressure of 0.4–0.6 MPa are held to reduce decomposition at the compression section.
The weathering target for façade components may be specified as 2,000 h xenon arc per ISO 4892-2:2013, with ΔE ≤ 5.0 and retained flexural modulus of at least 90% measured by ISO 178. If the louvre needs to meet EN 13501-1 reaction to fire classification, the material must be tested as an assembly because the raw resin has no inherent flame-retardant rating beyond UL 94 HB. For load-bearing brackets under wind load, creep modulus under ISO 899-2 at 40°C and 1.0 MPa stress is used instead of room-temperature flexural data. Batch-to-batch color variation in black is assessed by spectral reflectance at 18 points on flat sample plaques; a ΔE of 0.5 or less is required for adjacent louvre blades from separate production lots. Published data for this specific configuration is limited, so initial production runs should include sentinel parts exposed on a south-facing test rack for 12 months to benchmark laboratory results.
Thermal cycling in outdoor seating shells combines high static load with solar heating and winter impact. The shell is injection molded in TOYOLAC ASA TA50C X50 black at 3.5–4.0 mm nominal wall, with a core out of foamed polyurethane or steel frame insert, which places more demand on encapsulation and insert retention than on tensile strength. On a 900 t machine with a 70 mm screw, melt temperature is set at 245–260°C and mold temperature at 50–70°C; the upper temperature window is used for long flow lengths exceeding 500 mm. Pre-drying at 80°C for 4 h is mandatory when ambient relative humidity exceeds 60%, because black ASA surfaces show silver streaks more readily than light-colored grades. Insert failure in production occurs when the steel frame is below 30°C at the mold face; preheating inserts to 60°C before placement reduces post-mold cracking around the insert bosses. The shell is subjected to a static load of 2.0 kN applied at the center for 10 min without visible cracks; notched Charpy impact at −20°C is required to remain above 5 kJ/m² after 1,000 h UV exposure. If the design includes injection-molded snap hooks for slats, draft angle is held above 2° and gate vestige below 0.1 mm to prevent stress concentration. External regrind is not permitted for load-bearing shells; internally generated runner regrind is limited to 10 wt% because impact retention falls faster in thick sections.
When marine hatch trim is specified for cold-climate service, glass-filled nylon can fail by brittle fracture at sub-zero temperatures, and ASA is evaluated for lower water absorption and better dimensional stability. TOYOLAC ASA TA50C X50 is injection molded into hatch side frames, vent surrounds, and latch covers with wall thickness 2.0–3.0 mm. The material is processed at melt temperature 240–255°C and mold temperature 50–70°C. Because these parts contain multiple snap-fits, the mold is designed with 0.5–0.8 mm snap deflection and 0.5 mm radius at snap roots to prevent crack initiation. The pre-colored black grade eliminates post-mold painting, which reduces volatile organic emissions in enclosed boat interiors. After molding, parts are stored at 23°C and 50% RH for 24 h before assembly to stabilize dimensions.
Low-temperature impact is verified by Izod notched tests under ISO 180/A at −20°C; a typical acceptance is notched impact of at least 4 kJ/m² after 1,000 h salt-fog ageing per ISO 9227. UV exposure is checked by ISO 4892-2:2013 for 1,200 h with ΔE ≤ 5.0 and no visible chalking. The material is not recommended for continuous immersion in bilge water containing diesel or methanol, because ASA can absorb low-polarity liquids and soften; compatibility should be tested under ISO 175 with actual bilge fluid. Regrind use is not permitted for exterior hatch trim due to impact sensitivity. In field failure analysis, gate vestige height above 0.15 mm has been associated with snap-fit cracking, so gate trimming or valve-gated tools are required.
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