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Toray Industries ABS 100-322

    • Product Name: Toray Industries ABS 100-322
    • Factroy Site: Yinchuan, Ningxia, China
    • Price Inquiry: sales8@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 398798
    Density 1.04 g/cm³
    Melt Flow Rate 220c 10kg 20 g/10 min
    Tensile Strength 45 MPa
    Tensile Elongation At Break 25%
    Flexural Modulus 2300 MPa
    Flexural Strength 75 MPa
    Notched Izod Impact Strength 20 kJ/m²
    Heat Deflection Temperature 1 82mpa 80 °C
    Vicat Softening Temperature 95 °C
    Rockwell Hardness R Scale 105
    Molding Shrinkage 0.4-0.6%
    Water Absorption 24h 0.3%
    Flammability Ul94 HB

    As an accredited Toray Industries ABS 100-322 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Toray Industries ABS 100-322 is supplied in 25 kg moisture-proof paper bags, palletized for industrial handling and storage.
    Container Loading (20′ FCL) 20′ FCL dry container loaded with palletized Toray Industries ABS 100-322 resin bags, evenly distributed and secured for safe ocean transport.
    Shipping Toray Industries ABS 100-322 is shipped as non-hazardous ABS resin pellets in moisture-barrier bags or bulk containers. It is not regulated for transport. Keep dry, avoid sunlight, heat, and contamination; store in a cool, ventilated area. Use original sealed packaging and follow the SDS.
    Storage Store Toray Industries ABS 100-322 in a cool, dry, well-ventilated area away from direct sunlight, heat, moisture, and ignition sources. Keep original packaging sealed and palletized off the floor; prevent bag damage and dust accumulation. Avoid prolonged storage above recommended temperatures and follow first-in, first-out stock rotation. Maintain good housekeeping and keep away from incompatible chemicals.
    Shelf Life Typically stable for 12 months from manufacture when kept dry in original packaging at ambient temperature; avoid moisture and direct sunlight.
    Application of Toray Industries ABS 100-322

    Injection molding of thin-wall consumer electronic enclosures from TOYOLAC ABS 100-322 begins with formal verification of melt volume-flow rate against the lot certificate using ISO 1133-1:2022. The practical advantage of this grade appears when nominal wall sections fall below 1.2 mm and flow length-to-wall thickness ratios exceed 120:1. Production-scale equipment for such parts commonly includes a dehumidifying dryer with supply air dew point no higher than -20 °C, operated at 80 °C for 3 h to 4 h, to reduce residual pellet moisture below 0.05 % by Karl Fischer titration. Residual moisture above this threshold produces splay on visible surfaces and reduces weld-line integrity in multi-cavity tools. Melt temperature measured by an immersion probe at the nozzle is held between 220 °C and 250 °C, with the lower third preferred for large flat covers and the upper third reserved for long flow paths or thin-wall sections below 1.0 mm. Mold temperature is controlled between 40 °C and 60 °C using closed-loop water units capable of holding ±2 °C; lower mold temperatures reduce gloss and increase frozen-in stress, while higher mold temperatures improve melt-front contact but extend cooling time. Injection velocity is profiled so that the melt front advances through the runner at 60 mm/s to 100 mm/s, decelerates across abrupt thickness transitions to 25 mm/s to 50 mm/s, and is reduced over the final 10 % to 15 % of stroke to prevent parting-line flash. Hold pressure is set at 40 % to 60 % of peak injection pressure and maintained until gate freeze is confirmed by shot-to-shot part weight stabilization. Venting is machined to a land depth of 0.025 mm to 0.035 mm at the end of fill and along the runner. If a valve-gated hot runner is used, nozzle tip temperature is kept within 5 °C of the melt set point, and the manifold is purged after any residence time beyond 6 min because stagnation at high temperature causes yellowing and black specks in this unfilled ABS grade. A servo-electric or hydraulic injection unit with screw diameter between 28 mm and 40 mm is appropriate when shot size remains below 60 % of nominal barrel capacity. Back pressure is maintained between 0.5 MPa and 1.5 MPa to stabilize screw recovery without over-shearing the melt.

    Starting processing frame for thin-wall electronic enclosures
    ParameterRangeControl basis
    Residual moisture<0.05 %Karl Fischer titration on pellets
    Drying temperature80 °CDehumidifying dryer, dew point ≤-20 °C
    Drying time3 h to 4 hFresh material; longer for cold-start hoppers
    Melt temperature220 °C to 250 °CNozzle immersion probe
    Mold temperature40 °C to 60 °CClosed-loop water unit, ±2 °C
    Injection linear velocity25 mm/s to 100 mm/sProfiled fill; final deceleration last 10 % to 15 %
    Hold pressure40 % to 60 % of peakGate-freeze weight stabilization
    Back pressure0.5 MPa to 1.5 MPaScrew recovery stability
    Vent land depth0.025 mm to 0.035 mmParting line and runner end

    When Do Weld Lines in Appliance Control Panel Covers Fail Under Impact Loading?

    Control panel covers for washing machine consoles, room air-conditioner front panels, and dishwasher fascia present multiple apertures for buttons, displays, and indicator lenses. TOYOLAC ABS 100-322 fills around these core pins readily because of its high melt flow, but the melt fronts meet on the downstream side of each opening and form a weld line that is densified only if local cavity pressure remains sufficient during the packing phase. Weld-line strength in ABS depends on entanglement at the melt front interface; reducing mold temperature from 60 °C to 40 °C can lower notched impact values at the weld position enough to produce occasional cracking during snap-fit assembly. Tooling practice avoids placing the weld line in a rib foot or snap-fit hinge seat. The gate is located so that the melt front reaches each aperture with a temperature no lower than 20 °C above the glass transition temperature of the ABS matrix. This requires short runner paths and, where necessary, heated sprue bushings. The mold parting line around each aperture is vented with a land depth of 0.02 mm to 0.03 mm, and pin vents at the weld line are cleaned after every 1,000 shots because degraded volatiles deposit on vent surfaces and generate gas burns. Impact failure at a weld line is assessed on molded plaques using ISO 179-1, with the weld line positioned at the center of the specimen. Comparison between welded and unwelded specimens provides the weld-line retention factor. If the retention factor drops below 60 %, the first corrective action is to raise mold temperature, followed by an increase in hold pressure and a reduction in injection velocity at the meeting point. The final part is frequently annealed at 70 °C for 1 h to 2 h when the cover is to be subjected to repeated thermal cycling in service, because frozen-in stress at the weld line combines with thermal expansion mismatch around metal inserts to initiate microcracks.

    For laser printer chassis components, automatic document feeder frames, and scanner baseplates, TOYOLAC ABS 100-322 is processed with an emphasis on flatness rather than cosmetic gloss. Long flat parts with wall thickness from 1.8 mm to 3.0 mm are gated through multiple edge gates or fan gates, but gate number is minimized to reduce weld-line count. Melt temperature is kept in the lower half of the recommended range, between 220 °C and 235 °C, to limit differential shrinkage along the flow path. Mold temperature is maintained between 35 °C and 50 °C; higher temperatures improve melt-front contact but prolong cooling. After ejection at part surface temperatures below 85 °C, parts are placed on a flat cooling fixture for 15 min to 30 min to avoid post-mold warpage caused by asymmetric heat removal. Flatness is measured after 24 h conditioning at 23 °C and 50 % relative humidity according to ISO 291. For parts with brass threaded inserts, insert temperature is set to 180 °C to 220 °C before insertion, and surrounding boss thickness is kept above 2.0 mm with a root radius not below 0.5 mm. Insertion is completed within 5 s after heating to prevent localized collapse. Creep under static loading is evaluated for chassis parts carrying paper trays or scanner glass; data from ISO 899-2 flexural creep specimens are compared with design limits, and when service temperature exceeds 50 °C, finite element analysis substitutes the short-term modulus from ISO 527-2 with a reduced secant modulus from the creep curves. TOYOLAC ABS 100-322 is not inherently conductive; static dissipative performance is not obtained without an antistatic additive or external conductive coating. Any such additive must be cleared against the final OEM specification because it can lower melt stability and change impact behavior.

    Paint Adhesion and Solvent-Weld Joint Preparation on ABS 100-322 Automotive Trim Surfaces

    Interior trim components such as center console side panels, instrument cluster surrounds, and door switch bezels are often molded in TOYOLAC ABS 100-322 and subsequently painted or solvent-welded. The high-flow grade permits thin ribs and sharp radii, but surface contamination from mold release agents, particularly silicone-containing external release sprays, interferes with subsequent paint adhesion. If an external release agent is unavoidable, it is selected from fatty acid ester types that can be removed by an alkaline wash, and the first article is checked by water break-free testing before painting. Adhesion primers designed for ABS are applied over a wiped surface cleaned with isopropanol or a proprietary neutral cleaner; aromatic hydrocarbon and ketone cleaners are excluded because they attack stressed areas and cause craze marks that appear only after paint curing. Painted test plaques are evaluated by cross-cut adhesion under ISO 2409 and by steam jet test under ISO 16925 where the OEM specification requires high-pressure cleaning compatibility. Solvent welding of ABS trim parts uses methylene chloride or a formulated solvent containing methyl ethyl ketone, but the joint is fixtured under pressure for 30 s to 60 s and allowed to condition for 24 h at 23 °C before mechanical testing. A solvent-welded lap shear specimen may show joint efficiency above 80 % of the base resin tensile strength when the bond area is free of mold release and internal stress, but heavily stressed gate areas can craze during solvent application and lower the joint efficiency below 50 %. Annealing at 70 °C for 2 h before solvent welding reduces residual stress and raises joint consistency. For UV-exposed interior trim near side glazing, painted surfaces are tested to ISO 4892-2 cycle A1 or equivalent OEM xenon arc protocols. Unpainted TOYOLAC ABS 100-322 undergoes surface chalking and gloss loss over extended UV exposure, and its color stability is not comparable to ASA or acrylic-capped grades. Contact with strong oxidizing acids, concentrated aromatic hydrocarbons, or ketone solvents should be avoided on stressed molded parts because stress cracking may occur in service.

    If Methylene Chloride Solvent Welding Replaces Mechanical Fastening in Appliance Console Seams

    When a manufacturer replaces screws and snap fits with solvent-welded seams on appliance console frames, TOYOLAC ABS 100-322 offers a processing advantage because its melt flow does not correlate directly with resistance to solvent attack; the controlling variables are molded-in stress, joint design, and fixturing pressure. The joint is designed as a close-fit lap with a bond gap no larger than 0.3 mm, because thicker solvent films retard strength development and increase the risk of vapor entrapment. Solvent is applied by capillary action along the bond line using a needle or brush, and the parts are clamped immediately at a pressure between 0.1 MPa and 0.3 MPa. Full handling strength develops after the solvent evaporates from the interface, which at room temperature requires 24 h to 48 h for parts with wall thickness above 2.0 mm. Accelerated cure at 50 °C reduces waiting time to 4 h but increases odor level in the assembly area and requires explosion-proof ventilation. The solvent selected is methylene chloride or a combination of methylene chloride and methyl ethyl ketone; both are classified under workplace exposure limits and require extraction systems designed to maintain airborne concentration below the applicable national occupational exposure limit. Where methylene chloride is restricted by local regulation, formulated substitutes based on methyl ethyl ketone or dioxolane are tested, but joint strength may be lower. Bond strength is evaluated on a pull-off fixture using a tensile tester with crosshead speed of 5 mm/min; failure is interpreted by the percentage of cohesive failure visible on the bond surface. Cohesive failure above 80 % of the bond area is generally considered acceptable. If failure occurs at the surface and reveals a glossy unbonded area, the cause is usually mold release contamination or insufficient clamping time. Because solvent welding introduces volatile organic compounds, the final assembly is not considered a finished material change; the bill of materials should track the solvent as a separate process chemical under the relevant environmental management system.

    Battery holder components and low-voltage insulation barriers molded from TOYOLAC ABS 100-322 require attention to live-part separation and glow-wire performance because the base resin is not flame-retardant. The material is suitable for AA and AAA battery holders where creepage and clearance distances are defined by the end-product standard such as IEC 60335-1 or IEC 62368-1, but ignition resistance is not improved by the polymer matrix alone. If the end-product standard requires glow-wire ignition temperature at 750 °C with no ignition per IEC 60695-2-13, the holder design must provide physical distance and shielding rather than relying on the resin combustion behavior. Published data for this base grade in glow-wire performance at specific wall thickness is limited; end-product testing according to the final appliance standard is the controlling requirement. Rib thickness below 0.8 mm is avoided for battery retention springs because the notch sensitivity of the material under repeated insertion forces can produce cracks at the root; a minimum root radius of 0.6 mm is maintained unless interrupted by a metal spring retainer. Retention force is controlled by spring design rather than by deflecting thin plastic beams, because creep under continued deflection reduces contact force over time. Multi-cavity tools for battery holders often use a three-plate mold with pin-point gates of 0.8 mm to 1.2 mm diameter. Gate location is placed away from the contact spring anchorage to keep weld lines outside the high-strain zone. The ejection system uses blade ejectors along the sidewalls of the holder cavity, and mold polish is specified to SPI A-2 or finer along the battery insertion path to reduce insertion force and surface scoring. Dimensional inspection after molding is performed after 48 h at 23 °C and 50 % relative humidity because water absorption up to 0.25 % can increase dimensions by amounts that affect the snap closure of the battery lid. The supplier’s lot certificate for heavy metals is checked against RoHS Directive 2011/65/EU Annex II, and the grade-specific REACH SVHC declaration is reviewed before export; however, the final part may contain colorants, metal springs, or plating that move the article under different regulatory categories.

    Compliance verification matrix for electronics and appliance exported parts
    RequirementStandard or methodApplication condition
    Heavy metals screening2011/65/EU Annex II; IEC 62321-5Each color lot and final molded article
    REACH SVHC declarationEC 1907/2006 Article 33Threshold 0.1 % w/w per SVHC
    UL flame classUL 94 Yellow CardNominal wall thickness according to color and grade
    Glow-wire ignitionIEC 60695-2-13End-product standard-specific temperature
    Conditioning for mechanical testsISO 29123 °C, 50 % RH
    Melt flow verificationISO 1133-1:2022Lot certificate comparison
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    Certification & Compliance
    More Introduction

    Toray Industries ABS grade TOYOLAC™ 100-322 is an opaque general-purpose injection-moulding acrylonitrile-butadiene-styrene resin within the TOYOLAC 100 series. The manufacturer’s designation places the material in the medium-to-high melt-fluidity band used for thin-wall technical components; the suffix 322 is a supplier-specific flow modification and is not a direct melt-flow index. Published multi-lot data for this exact grade are limited to supplier certificates and technical datasheets. The property table below therefore consolidates representative ranges for the TOYOLAC 100 series rather than guaranteed lot values; a certificate of analysis is required for production specification.

    For injection moulding, the material is normally processed on reciprocating-screw machines with screw L/D ratios of 20:1 to 24:1 and compression ratios of 2.0:1 to 2.5:1. Melt temperature should be maintained between 220 °C and 250 °C, with mould temperature controlled from 30 °C to 80 °C. Pre-drying at 80 °C for 3–4 h in a desiccant dryer with dew point below -30 °C is required when ambient relative humidity exceeds 60 % or when splay, silver streaks, and weld-line porosity must be prevented. Residual moisture above 0.10 % by Karl Fischer titration causes volatile generation and surface defects during plastication.

    Typical application contexts include injection-moulded housings, structural frames, and dimensional-stability parts for office automation, small domestic appliances, consumer electronics, and non-plating automotive interior trim. Examples encountered in production include keyboard frames, point-of-sale terminal bezels, appliance control panels, and automotive door-pocket trims. For thick-wall sections above 3.0 mm, processing is straightforward and a general-purpose screw is sufficient; the grade’s fluidity is less critical in such geometries.

    PropertyTest methodRepresentative range or value
    DensityISO 1183-1:20191.04–1.06 g/cm³
    Melt mass-flow rate, 220 °C/10 kgISO 1133-1:202218–28 g/10 min
    Tensile stress at yield, 50 mm/minISO 527-2:201244–52 MPa
    Tensile elongation at break, 50 mm/minISO 527-2:201210–25 %
    Flexural modulusISO 178:20192400–2700 MPa
    Flexural strengthISO 178:201968–78 MPa
    Charpy notched impact strength, 23 °CISO 179-1eA:201016–24 kJ/m²
    Charpy notched impact strength, −30 °CISO 179-1eA:20108–12 kJ/m²
    Heat deflection temperature, 1.8 MPaISO 75-2:201386–94 °C
    Vicat softening temperature, B50ISO 306:201396–104 °C
    Mould shrinkage, parallel/normalISO 294-4:20180.4–0.7 %
    Linear thermal expansion, 23–80 °CISO 11359-2:199970–85 µm/m·K

    For dimensions, mould shrinkage parallel and normal to flow according to ISO 294-4:2018 is 0.4–0.7 %; anisotropic shrinkage between flow and transverse directions should be compensated in tool design to prevent post-mould warpage. Tensile yield stress from ISO 527-2:2012 is in the range 44–52 MPa, and flexural modulus is 2400–2700 MPa; these values support structural enclosures but are below glass-filled engineering resins. Creep behaviour under continuous load should be assessed by ISO 899-2:2003 for long-term service, particularly for snap-fit arms and heat-staked bosses. Linear thermal expansion between 23 °C and 80 °C is typically 70–85 µm/m·K; this is higher than aluminium and polycarbonate, so long flat housings require expansion gaps or compliant ribs instead of fixed metal inserts across wide spans. Inserts should be preheated to 80–100 °C before overmoulding to reduce hoop stress and stress cracking.

    What limits thin-wall melt-flow selection for electronic enclosures?

    Filling of nominal wall sections below 1.5 mm depends on melt viscosity and solidification rate, not solely melt mass-flow rate. At injection moulding shear rates of 10²–10⁴ s⁻¹, representative medium-flow ABS exhibits shear-thinning; capillary rheometry shows apparent viscosity at 220 °C in the order of 250 Pa·s at 100 s⁻¹ and 70 Pa·s at 1000 s⁻¹. This non-Newtonian response permits rapid filling of thin ribs on presses with projected area clamping requirements of 0.60–0.80 tonnes/cm². Gate freeze time is governed by part thickness; with 1.0 mm walls, hold pressure must be transferred through a gate land of adequate thickness to avoid sink marks. Weld-line Charpy notched impact values measured to ISO 179-1eA:2010 are typically 30–50 % lower than bulk values, so gate placement must be iterated with mould-filling simulation.

    In production-scale electronic enclosures with snap-fit bosses and thin ribs, short shots and sink marks have been observed when the nozzle temperature falls below 225 °C or when the screw cushion is not maintained between 3 mm and 6 mm. Fan gates or tab gates with land thickness between 0.8 mm and 1.2 mm are used for electronic housings; tunnel gates can be used in automated moulding but require higher injection velocity to control weld-line strength. Venting depth of 0.02–0.05 mm at the end of fill reduces diesel effects and burn marks. Mould temperature control with turbulent flow in cooling channels is recommended to maintain surface appearance and reduce differential shrinkage between thin and thick sections.

    When hydrolytic pre-drying and barrel residence-time control determine surface quality

    ABS is hygroscopic; the nitrile and rubber phases absorb water from ambient air. At ambient relative humidity above 60 %, pellets can exceed 0.35 % moisture in less than 8 h in open storage. Pre-drying in a desiccant drier with dew point below -30 °C and hopper temperature 80 °C for 3–4 h reduces moisture to below 0.05 %. The processing window for barrel temperature should not exceed 260 °C at residence times above 6 min; field observations on twin-screw compounding extruders with 40:1 L/D show yellowing, MFR drift, and impact loss when the melt degrades in the barrel. Back pressure should be kept at 0.5–1.5 MPa to homogenise melt without excessive shear heating. If regrind is used in non-appearance parts, clean regrind content up to 20 wt% is common; above 30 wt%, notched impact values measured to ISO 179-1eA:2010 may fall by 10–20 % and must be validated lot by lot.

    Comparative Position Against Flame-Retardant, Plating, and High-Heat ABS Grades

    The 100-322 grade is not a direct substitution for specialty ABS types. It does not contain a halogenated flame-retardant package; UL 94 ratings are typically HB at 1.5 mm or 3.0 mm, whereas V-0 enclosures require FR ABS with brominated or phosphorus-based additives and often a UL Yellow Card entry for the specific colour and thickness. The dispersed butadiene rubber phase makes the material opaque, so transparent components require MABS or PMMA. Electroplating-grade ABS is formulated with a controlled rubber particle size and oxidation-resistant emulsion morphology to promote etch swell and palladium catalyst uptake; 100-322 is not optimised for this surface process. Continuous exposure above 90 °C in load-bearing applications is not recommended because HDT under 1.8 MPa is 86–94 °C; high-heat ABS or PPE/PS alloys are required above 100 °C.

    Application requirement100-322 positionAlternative ABS-based selection
    Continuous service above 100 °CHDT 1.8 MPa 86–94 °C; not recommended without thermal stabilisationHigh-heat ABS or PPE/PS alloy
    UL 94 V-0 at 1.5 mmTypically HB; no halogenated flame-retardant packageFlame-retardant ABS with brominated or phosphorus additive
    Optical transparencyOpaque due to dispersed butadiene rubber phaseTransparent MABS or PMMA
    Electroplating adhesionNot surface-optimised for etch swell and catalyst uptakePlating-grade ABS with controlled rubber particle size
    Low-temperature impact below −30 °CCharpy notched impact 8–12 kJ/m²High-impact ABS or PC/ABS blend

    Mechanical differences between 100-322 and high-impact ABS are visible at low temperature: conventional high-impact ABS can retain Charpy notched impact above 20 kJ/m² at −30 °C, whereas the 100 series falls to 8–12 kJ/m² as shown in the first table. This is because the rubber phase is not as highly grafted or as large in particle size as in high-impact extrusion grades. The trade-off is higher melt fluidity and lower viscosity, which allows thinner walls and lower injection pressure. Compared with low-flow general-purpose ABS used for sheet extrusion and heavy-wall components, 100-322 has a higher melt mass-flow rate; this reduces fill pressure and cycle time but sacrifices some melt strength and low-temperature impact. For parts with wall thickness above 3.0 mm or constant load at elevated temperature, a lower-flow high-impact grade may be more suitable.

    Chemical resistance is governed by the styrene-acrylonitrile matrix and is limited against ketones, esters, aromatic hydrocarbons, and chlorinated solvents; stressed parts exposed to these fluids can exhibit environmental stress cracking. Outdoor weathering without UV-stabilised colorant or painting is not recommended because retained Charpy notched impact values measured to ISO 179-1eA:2010 typically decline after 12–24 months of accelerated or natural weathering. For regulatory compliance, supplier declarations under RoHS Directive 2011/65/EU as amended and REACH Regulation (EC) No 1907/2006 should be obtained from Toray or its authorised distributors for the specific shipment. Food-contact suitability must be confirmed under 21 CFR 180.22 or applicable national migration limits; grade-specific temperature and end-use restrictions apply.

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