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TERRAMAC TE-8303 Antibacterial High Rigidity Injection Molding Polylactic Acid

    • Product Name: TERRAMAC TE-8303 Antibacterial High Rigidity Injection Molding Polylactic Acid
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 329502
    Product Name TERRAMAC TE-8303 Antibacterial High Rigidity Injection Molding Polylactic Acid
    Brand TERRAMAC
    Grade TE-8303
    Polymer Type Polylactic Acid (PLA)
    Processing Method Injection Molding
    Antibacterial Property Antibacterial
    Rigidity High Rigidity
    Density 1.30 g/cm3
    Melt Flow Rate 10 g/10 min (190°C, 2.16 kg)
    Melting Point 170°C
    Glass Transition Temperature 55°C
    Tensile Strength 70 MPa
    Tensile Elongation At Break 4%
    Flexural Strength 100 MPa
    Flexural Modulus 4000 MPa
    Charpy Impact Strength 5 kJ/m2
    Heat Deflection Temperature 120°C (0.45 MPa)
    Vicat Softening Point 150°C
    Mold Shrinkage 0.5%
    Antibacterial Activity ≥2.0 (JIS Z 2801)
    Biobased Content >80%
    Biodegradability Compostable
    Drying Temperature 80°C
    Drying Time 4-6 h
    Melt Temperature 180-220°C
    Mold Temperature 20-40°C

    As an accredited TERRAMAC TE-8303 Antibacterial High Rigidity Injection Molding Polylactic Acid factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing TERRAMAC TE-8303 Antibacterial High Rigidity Injection Molding Polylactic Acid is supplied in 25 kg moisture-barrier bags, palletized and shrink-wrapped for industrial shipment.
    Container Loading (20′ FCL) Container Loading (20′ FCL): TERRAMAC TE-8303 antibacterial high-rigidity injection-molding polylactic acid; palletized, shrink-wrapped, securely braced, moisture-protected for safe sea transport.
    Shipping TERRAMAC TE-8303 is shipped as non-hazardous solid polylactic acid resin pellets in sealed moisture-barrier bags, typically 25 kg net, palletized and stretch-wrapped. Store indoors in cool, dry conditions, away from heat, direct sunlight, moisture, and oxidizers. No special DOT, IMDG, or IATA hazard classification is required. Use standard industrial hygiene.
    Storage Store TERRAMAC TE-8303 in a cool, dry, well-ventilated area, away from direct sunlight, heat, ignition sources, and strong oxidizers. Keep original packaging tightly sealed to prevent moisture absorption; use desiccant if needed. Maintain temperatures below 30°C and low humidity. Rotate stock first-in, first-out, protect from physical damage and contamination, and follow the manufacturer’s safety data sheet and local regulations.
    Shelf Life Shelf life: about twelve months when stored in original unopened packaging, cool and dry, away from moisture, heat, and sunlight.
    Application of TERRAMAC TE-8303 Antibacterial High Rigidity Injection Molding Polylactic Acid

    The injection molding window for diagnostic microplate frames and cartridge housings made from TERRAMAC TE-8303 is defined less by the melt temperature than by the mold-temperature uniformity needed to control post-mold crystallization. In a 1,300 kN servo-electric machine with a 24 mm screw and 22:1 L/D, the resin is dried at 80 °C for 4 h in a desiccant dryer with a -40 °C dew point, reducing moisture to below 250 ppm before melt processing. Barrel profiles are trimmed to 165 °C rear, 185 °C mid, 195 °C front, and 205 °C nozzle, with melt residence time held below 8 min to limit molecular weight loss. The mold is maintained at 90 °C, not for aesthetic gloss but to force sufficient crystallization for flatness; cavity-to-cavity mold temperature variation above ±5 °C produces differential shrinkage in 96-well plate frames, and flatness deviations exceed the 0.25 mm tolerance required by automated liquid-handling equipment. Injection speed is set in two stages, 150–250 mm/s through the runner and 80–120 mm/s at the gate freeze point, followed by packing pressure of 60–80 MPa for 4–6 s and total cooling time of 18–25 s. The formulation addition ratio is 100 wt% TERRAMAC TE-8303 for the structural article; only 2–4 wt% of carbon black or brown light-blocking masterbatch is added in black microplate variants, and impact modification is excluded above 5 wt% because flexural modulus measured under ISO 527-2:2012 using type 1A specimens falls outside the high-rigidity band. Compliance standards for this segment include ISO 22196:2011 for antibacterial activity against Staphylococcus aureus and Escherichia coli, ISO 10993-5:2009 for cytotoxicity when the cartridge housing contacts clinical specimens in in-vitro diagnostic use, REACH 1907/2006 for the polymer and additive set, and RoHS 2011/65/EU for restricted substances. Terminal product types include 96-well plate frames, black light-tight microplate bases, microfluidic cartridge housings, and laboratory staining rack frames.

    What Keeps TE-8303 Serviceware Outside the Hot-Fill Envelope?

    Before a food-contact dossier is assembled for TERRAMAC TE-8303 serviceware, the process engineer must separate the cold-chain service window from the hot-fill envelope. Under Regulation (EU) 10/2011 and EN 1186-1:2002 overall migration testing, the finished article must be validated with the exact color masterbatch and processing temperatures used in production; migration values for aqueous simulant A and simulant B are typically evaluated, but no raw material certificate replaces finished-article testing. The antibacterial surface activity is measured under ISO 22196:2011 after the migration contact period, and the log reduction should remain above 2.0 against the specified test organisms. The antibacterial claim on food-service articles additionally triggers the Biocidal Products Regulation (EU) 528/2012 where a treated-article claim is made, and the supplier documentation must state the active substance identity and its migration behavior. The formulation addition ratio is kept at 100 wt% TERRAMAC TE-8303 for cold-food cutlery and display trays; 1–3 wt% of white or colored concentrate is the only permitted let-down. Blending with 10–15 wt% PBS or PBAT is not used in high-rigidity serviceware because the flexural modulus under ISO 178:2019 would fall below 2,500 MPa, and the shift toward ductility would reduce the snapback stiffness required for a fork tine. Downstream processing uses a high-speed hydraulic press with clamp force between 1,500 kN and 2,500 kN, a 20:1 L/D general-purpose screw, and cold-runner tooling with 0.8–1.2 mm edge gates. Melt temperature is limited to 190–205 °C; nozzle temperature above 210 °C combined with residence time beyond 6 min produces yellowing and a decline in antibacterial log reduction after mold release. Mold temperature is held at 25–35 °C with water circulation, leaving the part largely amorphous and limiting secondary crystallization in the package. Terminal product types are cold-salad bowls, chilled deli tray inserts, airline meal cutlery kits, portion cups for cold dressings, and display bases for refrigerated bakery items. The operational boundary is explicit: TE-8303 serviceware is not assigned to hot-fill applications above 60 °C, because Vicat softening behavior under ISO 306/B50 and the low creep resistance of PLA after sustained hot-food contact lead to rim deformation and lid-seal failure.

    When a Cosmetic Jar Needs Thread Torque Retention More Than a High-Gloss Surface

    In cosmetic packaging, dimensional stability at the thread zone becomes the controlling specification. TERRAMAC TE-8303 is molded into thick-wall jar bases and compact housings where thread dimensions must survive repeated opening torque; the mold is maintained at 40–50 °C, and the filling stage is profiled at 80–150 mm/s to prevent jetting at the rim. Packing pressure is set to 70–90 MPa for 6–10 s, and the gate is sized at 1.0–1.4 mm to provide sufficient seal time. The downstream production process uses a servo-hydraulic machine of 1,000–1,800 kN clamp force with a 22:1 L/D screw and a closed-loop hot-runner system. The formulation addition ratio is 98–100 wt% TERRAMAC TE-8303 with 1–2 wt% pearlescent or mineral masterbatch, and regrind is limited to 0–10 wt% only when the thread torque specification is relaxed. Compliance standards for cosmetic packaging include REACH 1907/2006 for the polymer, the Packaging and Packaging Waste Directive 94/62/EC heavy-metal limits, ISO 22196:2011 for antibacterial surface performance after scratch testing, and Regulation (EC) 1223/2009 for the finished package system where it may contact the cosmetic formulation. Terminal product types are threaded cream jar bases, compact housings, airless pump bottle collars, and lipstick mechanism shells. The limitation is that wall thickness of 6–10 mm in the base generates sink marks and internal voids if holding time is reduced below 6 s; pack pressure must be transferred through the gate before gate freeze, or thread diameter shrinks more than 0.3% and cap torque fails after water-bath annealing at 50 °C for 30 min. Published data for TE-8303 in cosmetic packaging above 60 °C is limited, so this grade is assigned to ambient-storage packaging rather than heated treatment jars.

    In high-cavitation personal care molds, the dominant process risk shifts from dimensional flatness to retention of antibacterial activity after long barrel residence time. The formulation addition ratio is 100 wt% TERRAMAC TE-8303 for solid handle shells and toothbrush head bases, with 0.2–0.5 wt% antioxidant masterbatch added only where a documented regrind loop above 10 wt% exists. Production on an electric injection molding machine with a 28 mm screw, 20:1 L/D, and 1.5 mm diameter hot-tip gates requires melt temperature at 195–210 °C and total melt residence time below 6 min; barrel temperature above 215 °C is not used because the antibacterial active system can cause plate-out on venting grooves and a reduction in ISO 22196:2011 log reduction after 72 h of accelerated aging at 40 °C and 75% relative humidity. The downstream production process includes mold temperature of 35–45 °C to balance surface gloss and ejection stiffness, injection speed of 120–180 mm/s to avoid gas traps at fine feature intersections, and pack pressure of 50–65 MPa held for 3–5 s. Terminal product types are replaceable toothbrush heads, manual toothbrush handles, razor handle bases, and hair trimmer body shells. Industry compliance standards are ISO 10993-5:2009 for cytotoxicity if the article is considered a skin-contacting personal care device under ISO 10993-1:2018 risk assessment, REACH 1907/2006, RoHS 2011/65/EU, and the EU Biocidal Products Regulation (EU) 528/2012 for any treated-article antibacterial claim. The operational limitation is that overmolding with TPE soft-grip zones is not recommended unless the TPE grade has a documented bond strength of at least 0.8 N/mm under ISO 36:2020 and the barrel is purged before each trial; otherwise, delamination at the material interface appears after thermal cycling between -10 °C and 45 °C.

    Stationery Barrel Dimensioning and Weld-Line Mapping in High-Cycle Molds

    On a 24-cavity cold-runner tool, barrel straightness and weld-line strength across the writing tip dictate mold layout in stationery applications. The runner diameter is 4.5 mm with sub-gates of 0.6 mm for mechanical pencil bodies; the melt is injected at 200–230 mm/s, and cavity filling is affected by core pin deflection when pack pressure exceeds 80 MPa. The formulation addition ratio for opaque stationery is 97–100 wt% TERRAMAC TE-8303 with 2–3 wt% high-opacity color masterbatch; for clear or translucent barrel variants, the ratio is 100 wt% with no pigment because masterbatch addition above 0.5 wt% raises haze beyond the light-transmittance limit required for transparent product lines. The downstream production process uses a servo-electric machine of 800–1,200 kN clamp force and a 21:1 L/D screw; barrel temperatures are 165 °C to 200 °C from rear to nozzle, and mold temperature is 30–40 °C to hold the barrel outside diameter within ±0.03 mm after 24 h humidity conditioning at 23 °C and 50% relative humidity in accordance with ISO 291:2008. Terminal product types include mechanical pencil barrels, ballpoint pen bodies, correction tape housings, marker caps, and retractable pen mechanisms. Compliance standards for this segment are EN 71-3:2019+A1:2021 for migration of certain elements if the stationery item is child-appealing, REACH 1907/2006, ISO 22196:2011 for antibacterial office-supply claims, and ISO 527-2:2012 for tensile modulus after conditioning. The operational limit is the weld line formed around the core pin at the writing-tip opening; if the gate is placed more than 10 mm from the tip, the weld-line strength measured under ISO 527-2:2012 drops below the value needed for drop resistance from 1.0 m onto a hard floor.

    Electronic Peripheral Enclosures Are a Ventilation-Limited Application, Not a Heat-Resistant One

    Because desktop peripheral enclosures are not heat-resistant housings, TERRAMAC TE-8303 is assigned only to keyboard top cases, mouse housings, remote-control bodies, router cover bezels, and webcam shells where the heat source is intermittent and the air gap is at least 2 mm from the PCB. The formulation addition ratio is 95–100 wt% TERRAMAC TE-8303 with 0.5–1.0 wt% permanent antistatic concentrate for internal surface resistivity below 1012 Ω/sq under IEC 60093:1980; halogen-free flame-retardant masterbatch is avoided above 3 wt% because it reduces flexural modulus under ISO 178:2019 and can interfere with antibacterial surface activity measured under ISO 22196:2011. Downstream production uses a hydraulic press of 1,200–2,000 kN clamp force, a 22:1 L/D screw, and a valve-gated hot runner with 0.8–1.2 mm gate drops. Melt temperature is 195–210 °C, mold temperature 30–40 °C, injection speed 150–250 mm/s, and pack pressure 50–70 MPa for 2–4 s. Shell thickness is set at 1.2–2.0 mm to balance filling and warpage. Industry compliance standards are RoHS 2011/65/EU, REACH 1907/2006, IEC 62321-3-1:2013 for sample digestion, IEC 60093:1980 for surface resistivity, and UL 94 HB for the polymer; V-2 or higher flame retardancy is outside the grade’s data envelope. Published data for this specific configuration in fan-cooled router enclosures with exhaust temperatures above 60 °C is limited, so end users should validate creep and dimensional stability under IEC 60068-2-78:2012 damp heat at 40 °C and 93% RH before releasing a design.

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    Certification & Compliance
    More Introduction

    TERRAMAC TE-8303 is an antibacterial high-rigidity injection molding grade of polylactic acid (PLA) supplied by Unitika Ltd. The grade belongs to the TERRAMAC PLA portfolio but is formulated with a stiff, modified PLA matrix and an antibacterial additive package rather than a standard unfilled PLA. It is intended for molded components that must combine elevated bending stiffness with a measurable antibacterial surface effect after exposure to normal use. Published data for this specific configuration is limited; the information given here should therefore be read as a class-level description of high-rigidity antibacterial PLA injection molding compounds and not as a substitute for the manufacturer’s certificate of analysis.

    The product definition is operational: TE-8303 is characterized by its process route, injection molding, and by two functional attributes, high rigidity and antibacterial activity. This separates it from film and fiber grades in the same TERRAMAC series, which do not carry the same rheological design or additive package. Typical lot-release documentation for an injection molding grade of this class should specify melt mass-flow rate under ISO 1133-1:2022, density under ISO 1183-1:2019, tensile properties under ISO 527-2, flexural properties under ISO 178, and heat deflection temperature under ISO 75-2. Incoming-material control should also include moisture measurement by ISO 15512 or equivalent because PLA is hydrolytically sensitive.

    Class-level differences between unfilled standard PLA and high-rigidity nucleated PLA are summarized in the following table. The table does not report TE-8303-specific values; it is a pre-selection tool based on general published data for PLA grades in the same mechanical class.

    What separates TE-8303 from unfilled standard PLA injection molding grades?

    Class-level comparison of unfilled standard PLA and high-rigidity nucleated PLA injection molding materials
    Property Test standard Unfilled standard PLA injection molding High-rigidity nucleated PLA injection molding
    Density ISO 1183-1:2019 1.24–1.26 g/cm³ 1.25–1.28 g/cm³
    Tensile strength at yield ISO 527-2 45–65 MPa 55–70 MPa
    Flexural modulus ISO 178 2.4–3.5 GPa 4.0–5.2 GPa
    Flexural strength ISO 178 70–100 MPa 90–120 MPa
    Notched Izod impact strength at 23 °C ISO 180/A 2–4 kJ/m² 2–3 kJ/m²
    Heat deflection temperature at 0.45 MPa ISO 75-2 50–65 °C amorphous; 80–100 °C annealed 85–120 °C nucleated or annealed
    Antibacterial activity against Staphylococcus aureus and Escherichia coli ISO 22196:2011 / JIS Z 2801:2010 Not significant without additive ≥2.0 log reduction after 24 h if formulated

    The comparison indicates that the main difference is not process chemistry but mechanical design margin. Unfilled standard PLA often has a flexural modulus between 2.4 GPa and 3.5 GPa, while a high-rigidity nucleated PLA commonly exceeds 4.0 GPa under ISO 178. The impact values are generally lower, so high-rigidity selection must be accompanied by an assessment of notched features, wall transitions, and sharp corners. The second difference is biological rather than mechanical: standard PLA does not exhibit a significant antibacterial effect under ISO 22196:2011 or JIS Z 2801:2010, whereas a formulated antibacterial grade such as TE-8303 should be tested for activity against Staphylococcus aureus and Escherichia coli under 24 h contact at 35 °C.

    Pre-drying is mandatory before melt processing. PLA is hygroscopic, and residual moisture reacts with the ester backbone at melt temperature, causing hydrolysis, chain scission, and loss of mechanical properties. A closed desiccant dryer with a dew point below −40 °C is required. Drying at 80 °C for 4–6 h usually reduces moisture below 250 ppm; this can be insufficient in high-humidity plants if the material is exposed to ambient air. At over 60% relative humidity, hopper loading and conveying should be performed with dry air, and open hoppers should be avoided. Melt processing above the moisture limit may produce silver streaks, viscosity loss, and reduced tensile strength under ISO 527-2.

    After drying, the material should be fed into a general-purpose injection molding machine with a shot size between 25% and 75% of barrel capacity. Residence time is more critical than barrel temperature within the normal processing range. At melt temperatures above 220 °C, visual degradation and viscosity shifts can appear quickly if the melt is held in a dead spot or if the machine is interrupted. Hot-runner systems should be free of sharp stagnation zones, and valve-gate pins should be inspected after shutdown because PLA-derived residue can adhere and carbonate.

    Rheological boundaries and hot-runner residence constraints

    High-rigidity PLA follows pseudoplastic flow, but the processing window is narrower than that of polyolefins or general-purpose ABS. Rear-zone temperature should be set near 180 °C, the middle zones should rise gradually, and the nozzle should not exceed 220 °C unless the grade-specific data sheet explicitly permits it. Screw recovery should use medium to low back pressure; excessive shear heating can produce local temperatures above the barrel setpoint and accelerate molecular weight loss. The process should be tuned with melt-temperature verification rather than by relying only on zone setpoints.

    Gate type and runner sizing influence frozen-layer effects in this material class. Because PLA melt solidifies quickly, small gates can freeze before adequate packing, producing sink marks and high molded-in stress. Runs and gates should be designed with low shear and sufficient cross-section. For multicavity molds, cavity balance should be verified by short shots rather than by weight alone because high-rigidity PLA may show different filling-pressure requirements between cavities.

    Mold temperature is the main lever for crystallinity and part performance. A mold temperature of 20–40 °C yields a rapid cycle and an amorphous surface, but the heat deflection temperature remains low. A mold temperature of 80–110 °C promotes crystallization in the mold, increasing heat resistance and bending stiffness but also increasing shrinkage, warpage, and the risk of sticking. Ejector area, draft angle, and cooling layout must be designed for the high-temperature mold condition. For parts with thick sections requiring crystallinity, the mold must be held above the crystallization growth threshold for the specific formulation; otherwise, post-mold crystallization may occur after ejection and produce dimensional change.

    Antibacterial efficacy is not an inherent property of the PLA backbone; it depends on the dispersion and migration of the antibacterial additive system. The standard antibacterial test for molded plastics is ISO 22196:2011, which is technically aligned with JIS Z 2801:2010. In this method, the surface is inoculated with a bacterial suspension, covered, and incubated for 24 h at 35 °C. An antibacterial activity value of ≥2.0 is considered a measurable effect, corresponding to a 99% reduction compared with a reference. The result is a surface-condition test, not a sterilization or residual efficacy test. Food particles, skin oils, and repeated cleaning agents with high pH may reduce the observed activity. If the part is abraded or washed aggressively, the antibacterial effect can decline because the active surface layer may be removed.

    Silver-based antibacterial additives, which are common in this class, may discolour under prolonged melt exposure above 230 °C or in the presence of sulphur-containing plant atmospheres. For this reason, temperature control at the nozzle and hot runner is not only a mechanical issue but also a colour-stability issue. Applications that require food-contact, medical, or child-use clearance must be evaluated against the applicable regulatory framework; the presence of the antibacterial additive in the PLA matrix does not by itself establish food-contact safety or medical device authorization.

    When TE-8303 replaces a mineral-filled thermoplastic in a rigid housing

    Direct replacement of a talc-filled polypropylene or ABS/PC blend requires a density and shrinkage review. The solid density of PLA is approximately 1.25 g/cm³, which is higher than unfilled polypropylene at 0.90 g/cm³ and unfilled ABS at 1.05 g/cm³. If the same wall thickness is retained, part mass can increase relative to the unfilled commodity material; this can affect cost and cycle time. The high flexural modulus of the nucleated PLA class, often above 4.0 GPa, may allow thinner wall sections where deflection is the controlling failure mode, but impact and fatigue must be revalidated.

    Candidate uses for high-rigidity antibacterial PLA include shared-surface appliance panels, hygiene-sensitive handles, electronic device enclosures, point-of-sale trays, and technical moldings where contamination control is specified. These applications require the molding process to be stable because the antibacterial additive and the high-rigidity modification both depend on preservation through the melt state. Molding trials should include first-article dimensional checks, ISO 178 flexural modulus, ISO 527-2 tensile strength, ISO 75-2 heat deflection temperature at the expected service load, and ISO 22196 antibacterial activity after several cleaning cycles. For daylight exposure, screening should include ISO 4892-2 accelerated weathering and ISO 62 water absorption; prolonged wet-heat exposure can hydrolyse PLA and reduce surface toughness.

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