Products

TERRAMAC TE-7307 High Heat/High Rigidity Injection Molding Polylactic Acid

    • Product Name: TERRAMAC TE-7307 High Heat/High Rigidity Injection Molding Polylactic Acid
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
    • CONTACT NOW
    Specifications
    HS Code 610532
    Polymer Type Polylactic Acid (PLA)
    Processing Method Injection Molding
    Density 1.25 g/cm3
    Melt Flow Rate 15 g/10 min (190°C, 2.16 kg)
    Tensile Strength 70 MPa
    Tensile Elongation At Break 3%
    Tensile Modulus 4.0 GPa
    Flexural Modulus 4.5 GPa
    Flexural Strength 115 MPa
    Notched Izod Impact Strength 20 J/m
    Heat Deflection Temperature At 0 45 Mpa 150°C
    Heat Deflection Temperature At 1 82 Mpa 120°C
    Melting Point 210°C
    Glass Transition Temperature 60°C
    Mold Shrinkage 0.5%
    Rockwell Hardness R115

    As an accredited TERRAMAC TE-7307 High Heat/High Rigidity Injection Molding Polylactic Acid factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing TERRAMAC TE-7307 packaging: 25 kg moisture-barrier foil-lined bags, 40 bags per pallet, shrink-wrapped for safe transport and storage.
    Container Loading (20′ FCL) Loaded into 20′ FCL: TERRAMAC TE-7307 PLA resin, high heat/high rigidity injection molding grade, palletized, shrink-wrapped, and secured for export.
    Shipping TERRAMAC TE-7307 is supplied as polylactic acid resin pellets in moisture-barrier, heat-sealed bags, 25 kg sacks, or FIBCs. Ship in clean, dry, ventilated containers at moderate temperature, avoiding moisture, direct sunlight, and excessive heat. Not classified as dangerous goods; no UN number or special transport labels required.
    Storage Store TERRAMAC TE-7307 in a cool, dry, well-ventilated warehouse, away from direct sunlight, heat, and ignition sources. Keep sealed in original moisture-barrier packaging to prevent moisture absorption. Recommended conditions: below 30°C and 50% relative humidity. Rotate stock first-in, first-out. Avoid prolonged hot, humid storage and contamination from acids, bases, or oxidizing agents. Do not stack excessively; use clean handling equipment.
    Shelf Life Shelf life: typically 12 months from manufacture when stored unopened in a cool, dry place, away from moisture and heat.
    Application of TERRAMAC TE-7307 High Heat/High Rigidity Injection Molding Polylactic Acid

    TERRAMAC TE-7307 is processed as a high-crystallinity polylactic acid injection moulding grade. Its practical downstream value occurs where short-interval thermal loads and flexural rigidity must be maintained in thin-wall mouldings without secondary annealing. The following scenarios distinguish processable exposure classes by heat load, chemical contact, mechanical load, and regulatory framework. Nominal melt, mould, drying, and feedstock-ratio parameters are benchmarked against conventional high-crystallinity PLA injection moulding practice; machine-specific validation remains necessary.

    Exposure classMechanicalThermalContact/chemicalElectrical safety
    Food serviceISO 527-2ISO 75-2 Method BEU 10/2011; US FDA FCN
    ClosuresISO 527-2ISO 75-2 Method BEU 10/2011; US FDA FCN
    Consumer electronicsISO 527-2; ISO 178ISO 75-2 Method BRoHS; REACHIEC 62368-1
    Small appliancesISO 527-2IEC 60695-10-2 ball pressureIEC 60335-1IEC 60335-1
    Office automationISO 178ISO 75-2 Method BRoHS; REACH
    Cosmetic packagingISO 527-2ISO 75-2 Method BREACH; EC 1223/2009

    Food-service mouldings such as institutional trays and bowl bases are exposed to alkaline detergents at pH 8.0–11.0, rinse-water temperatures of 75–85 °C, and intermittent contact with fats at pH 3.5–7.0. Compliance in this segment is evaluated under EU Regulation (EU) No 10/2011 overall migration limits of 10 mg/dm² and simulant-specific migration tests using acetic acid 3% w/v and ethanol 20% v/v; U.S. food-contact status must be confirmed against the issuer’s PLA food-contact notification, not by generic olefin sections. The moulding feedstock composition is set at 100 wt% TERRAMAC TE-7307, with closed-loop regrind of sprues and short-shot purge limited to 25 wt% so that melt mass-flow rate shift measured by ISO 1133-1 does not exceed 15% relative to virgin material. Colour masterbatch incorporation is held to 1–2 wt%, and only food-contact-approved carrier resins are permitted. Downstream processing employs a desiccant dryer with dew point below -40 °C to bring residual moisture to ≤250 ppm, followed by injection moulding at melt temperature 195–215 °C and mould temperature 100–120 °C. The mould must be held at the high end to complete in-mould crystallisation; otherwise parts fail dishwasher cycling through warpage after the first 300–500 cycles. A screw with L/D 20:1–24:1 and compression ratio 2.0–2.5 is typical; back pressure is maintained at 3–5 MPa. Finished product classes include reusable cafeteria trays, institutional bowl bases, and hotel buffet inserts. Published data for this specific configuration is limited when detergent pH exceeds 11, and alkaline soak beyond 30 min should be excluded.

    What Limits Thermal Distortion in Dairy and Beverage Closure Moulding?

    Dairy and beverage closures must withstand hot-fill temperatures between 60–75 °C while maintaining unscrewing torque and seal integrity. The limiting factor is not melt temperature but the degree of cold crystallisation developed in the cap sidewall during cooling; insufficient crystallinity produces post-fill shrinkage and liner compression loss. Compliance for food-contact closures is established under EU Regulation (EU) No 10/2011 with overall migration 10 mg/dm², specific migration testing in 3% w/v acetic acid and 50% v/v ethanol for water-based and fatty simulants, and US FDA FCN confirmation for the specific polylactic acid resin. Feed ratio for the closure feedstock is 100 wt% TERRAMAC TE-7307; slip/anti-block masterbatch addition is limited to 1–2 wt%, pigment masterbatch to ≤3 wt%, and no external plasticiser is used because plasticiser migration alters closure compression set. Regrind from sprues is limited to 20 wt%. Downstream production uses a hot-runner valve-gated cold mould at 100–110 °C, melt temperature 190–210 °C, and in-mould crystallisation hold time 10–15 s after fill. Injection velocity profile is set to avoid jetting in the cap skirt; hold pressure is 60–80 MPa. Residual moisture must be below 200 ppm using a desiccant dryer with dew point -50 °C. Finished product types include screw caps for pasteurised dairy bottles, caps for hot-filled juices, and overcaps for dairy-based drinks. Exposure above 80 °C in tunnel pasteurisation should be avoided unless the closure is annealed post-mould at 100 °C for 30 min and rechecked for roundness.

    Consumer Electronics Inner-Frame Dimensioning and IEC 62368-1 Compliance

    Dimensional stability of inner frames and light-pipe housings in personal electronics depends on constrained shrinkage control and creep resistance at local hot-spot temperatures of 60–80 °C. TERRAMAC TE-7307 is applied where the enclosure is not subject to open-flame or sustained high-energy electrical arcing; it is not a substitute for UL 94 V-0 polycarbonate or PC/ABS unless a tested flame-retardant PLA compound is qualified. Industry compliance for these non-ignition-exposed components is anchored to IEC 62368-1 mechanical enclosure requirements, RoHS Directive 2011/65/EU including Annex II restricted substances, and REACH SVHC screening. Blend ratio for this segment is 100 wt% TERRAMAC TE-7307 neat, or 90–95 wt% TERRAMAC TE-7307 with 5–10 wt% surface-treated mineral filler when mould shrinkage must be held below 0.4%; clean runner regrind is allowed to 20 wt%. Downstream production demands melt temperature 195–210 °C, mould temperature 110–120 °C, and sequential valve-gated filling for wall sections 0.8–1.5 mm. Holding pressure typically starts at 80–120 MPa and is dropped in two steps to avoid over-packing. Residual moisture must be controlled below 150 ppm to prevent hydrolysis-induced surface splay and a drop in weld-line strength. Finished product types include display bezel backing frames, internal spacer brackets, and decorative side keys. Published multivariant data for PLA inner frames under continuous 80 °C load is limited; end-product thermal cycling according to IEC 60068-2-14 is required before series release.

    Low-heat exposure zones in small household appliances—knobs, vent rings, and non-steam internal brackets—require dimensional stability under intermittent surface temperatures of 70–85 °C and occasional contact with cleaning agents at pH 4.0–9.0. TERRAMAC TE-7307 is process-relevant only when the designed wall thickness exceeds 2.0 mm and the part is not located within 20 mm of exposed heating elements. Compliance is assessed under IEC 60335-1 clauses for thermal stability and resistance to heat, with ball-pressure testing to IEC 60695-10-2 at 75 °C for accessible thermoplastic surfaces. The compound ratio is 100 wt% TERRAMAC TE-7307 with appliance colour masterbatch at 1–3 wt%; regrind from hot-runner sprues is capped at 15–20 wt% because repetitive heat history raises the melt flow rate and can reduce HDT-B tested to ISO 75-2 by more than 4 °C. Downstream moulding uses a desiccated hopper at 80 °C for 4–6 h, melt temperature 195–215 °C, mould temperature 100–110 °C, and cooling time of 25–40 s for 2.0–2.5 mm wall sections. A post-mould annealing step at 100 °C for 30 min is applied only where sink marks or stress-whitening are detected; otherwise in-mould crystallisation is sufficient. Finished product types include drip-tray handles, control-panel knobs, and air-outlet vent rings for small kitchen appliances.

    When Office Automation Chassis Parts Require Sub-0.25 mm Warpage at 75 °C

    Mould filling of thin-wall chassis ribs and paper guide rails in printers and scanners becomes thermally limited when fuser-adjacent surfaces reach 70–80 °C during continuous operation. TERRAMAC TE-7307 is specified for internal structural parts where the alternative is glass-filled ABS and where the manufacturer needs reduced fossil-carbon content without sacrificing flexural modulus. Industry compliance for this segment relies on ISO 527-2 tensile modulus, ISO 178 flexural modulus, and ISO 75-2 Method B HDT-B to verify that the material retains stiffness after moisture conditioning at 50% RH and 23 °C. Feedstock formulation is 100 wt% TERRAMAC TE-7307 with carbon black masterbatch at 1–2 wt%, plus a nucleation masterbatch at 2–5 wt% only when cycle-time reduction below 50 s is required. Regrind is limited to 25 wt% and its feedstock moisture must be re-dried to ≤200 ppm. Downstream processing uses a reciprocating screw with L/D 20:1–24:1, melt temperature 195–210 °C, mould temperature 105–120 °C, and sequential valve gating for wall sections 0.8–1.2 mm. Injection pressure is set between 80–120 MPa with holding pressure stepped from 60–80 MPa to 30–40 MPa over 3–5 s to reduce warpage. Warpage is measured against a nominal flatness tolerance of ±0.25 mm after 24 h at 23 °C and 50% RH. Finished product types include scanner internal frames, printer paper guide rails, and fuser-side insulating brackets where surface temperature remains below 80 °C.

    Reusable Cosmetic Packaging Must Withstand 60–70 °C Filling Without Stress Whitening

    Hot-fill cosmetic containers and caps produced from PLA are limited by residual mould orientation that becomes visible as stress whitening when warm bulk material contacts the sidewall before crystallinity reaches a threshold value. The compliance framework for this downstream segment is REACH and Regulation (EC) No 1223/2009 for finished cosmetic product compatibility; packaging migration is screened by EU Regulation (EU) No 10/2011 migration test methods, although cosmetic contact is not a food-contact application. Addition ratio is 100 wt% TERRAMAC TE-7307 with pearlescent masterbatch at 1–2 wt%, processing aid at 0.5–1 wt%, and no plasticising additive. Regrind is restricted to 20 wt% and must be batch-separated to avoid gloss variation above 5% compared with virgin material. Downstream production uses a polished mould surface at 110–125 °C, melt temperature 190–210 °C, and a two-stage injection profile that limits peak shear rate below 50,000 s⁻¹ to avoid surface haze. In-mould cooling time is 30–45 s for wall thickness 2.0–3.0 mm; post-mould annealing at 100 °C for 20–30 min is used only for thin-wall caps that must survive hot-fill on a 60–70 °C filling line. Finished product types include reusable cosmetic jars, caps, compact bases, and brush-handle cores. Continuous immersion in high-alcohol formulas above 30% ethanol should be avoided because PLA absorbs polar solvents and may show environmental stress cracking.

    Free Quote

    Competitive TERRAMAC TE-7307 High Heat/High Rigidity Injection Molding Polylactic Acid prices that fit your budget—flexible terms and customized quotes for every order.

    For samples, pricing, or more information, please contact us at +8618136850665 or mail to admin@ascent-chem.com.

    We will respond to you as soon as possible.

    Tel: +8618136850665

    Email: admin@ascent-chem.com

    Inquiry

    Get Free Quote of Ascent Petrochem Holdings Co., Limited

    Flexible payment, competitive price, premium service - Inquire now!

    Certification & Compliance
    More Introduction

    TERRAMAC TE-7307 High Heat/High Rigidity Injection Molding Polylactic Acid is a nucleated polylactic acid compound supplied by Unitika Ltd. for injection molding applications requiring post-crystallization dimensional stability above the glass transition of commodity PLA. The grade is formulated to crystallize rapidly against tool surfaces maintained between 90 °C and 110 °C, producing parts with heat deflection temperature of 125 °C under 0.45 MPa load when measured according to ISO 75-1/-2 Method B. Representative injection-molded specimens conditioned at 23 °C and 50 % relative humidity exhibit tensile strength at break of 62 MPa when tested under ISO 527-1/-2, flexural modulus of 4.2 GPa under ISO 178, flexural strength of 96 MPa under ISO 178, Charpy notched impact strength of 2.0 kJ/m² under ISO 179-1/1eA, density of 1.26 g/cm³ under ISO 1183-1, and melt mass-flow rate of 7 g/10 min under ISO 1133-1 at 190 °C with 21.18 N load. These values are typical injection-molding data, not guaranteed specification limits; lot-specific certificates of analysis should be requested for production release.

    Data shown are representative values from injection-molded specimens. Production lot-specific certificates may differ, especially where crystallization is incomplete because of low mold temperature or short cooling time.

    Representative physical and thermomechanical property envelope for TERRAMAC TE-7307
    Property Test method Typical value
    Density ISO 1183-1 1.26 g/cm³
    Melt mass-flow rate ISO 1133-1, 190 °C, 21.18 N 7 g/10 min
    Tensile strength at break ISO 527-1/-2 62 MPa
    Tensile elongation at break ISO 527-1/-2 2 %
    Flexural strength ISO 178 96 MPa
    Flexural modulus ISO 178 4.2 GPa
    Charpy notched impact strength ISO 179-1/1eA 2.0 kJ/m²
    Heat deflection temperature ISO 75-1/-2 Method B, 0.45 MPa 125 °C

    What Drying and Feeding Parameters Prevent Hydrolytic Degradation During Molding?

    Moisture control is the critical prerequisite for melt processing. PLA degrades via random chain scission through ester hydrolysis, and residual moisture above 250 ppm produces viscosity loss, splay, and lower Charpy impact. TE-7307 should be dried in a desiccant dryer at 80 °C for 4–6 h with a supply-air dew point of -40 °C or lower. In plants with ambient relative humidity above 60 %, the drying dwell time should be extended to 8 h and the dried material conveyed to the hopper in sealed, dry-air-purged lines. Validation of residual moisture should follow Karl Fischer coulometric titration per ISO 15512:2019 or an equivalent loss-on-drying method calibrated to the same standard. Conveying lines should be stainless steel or flexible dry-air-purged piping to avoid moisture regain between dryer outlet and feed throat.

    On a hydromechanical toggle press, the barrel profile from feed throat to nozzle is typically 180 °C, 195 °C, 200 °C, and 195 °C with a general-purpose screw of 20:1 L/D and 2.0:1–2.5:1 compression ratio. The feed throat should be maintained at 30–40 °C to prevent premature bridging. Nozzle melt temperature should not exceed 210 °C; higher temperatures accelerate lactide generation and molecular weight loss. Shot size should occupy 40–70 % of the barrel capacity to avoid excessively long residence time. Plasticating conditions should maintain screw rotation at 80–120 rpm and back pressure at 0.5–1.0 MPa. For a 3 mm wall section, injection speed of 30–60 mm/s and holding pressure of 60–80 MPa are used; holding time should be set by gate freeze measured on the specific tool. Mold surface temperature must be held at 90–110 °C. If mold surface temperature drops below 80 °C, the resulting crystallinity is insufficient and heat deflection temperature can remain below 70 °C at 0.45 MPa, even if drying and melt conditions are correct.

    Recommended start-up processing window for TERRAMAC TE-7307
    Parameter Recommended range Control method
    Drying temperature 80 °C Desiccant dryer
    Drying time 4–6 h; 8 h if ambient RH > 60 % ISO 15512 sample check
    Residual moisture 250 ppm maximum Karl Fischer titration
    Feed throat temperature 30–40 °C Thermocouple
    Barrel zone 1 180 °C PID zone
    Barrel zone 2 195 °C PID zone
    Barrel zone 3 200 °C PID zone
    Nozzle temperature 195–210 °C Thermocouple
    Mold surface temperature 90–110 °C Surface probe
    Melt residence time 10 min maximum Screw recovery calculation
    Back pressure 0.5–1.0 MPa Hydraulic pressure
    Injection speed 30–60 mm/s for 3 mm wall Linear transducer
    Holding pressure 60–80 MPa Hydraulic pressure
    Screw rotation 80–120 rpm Tachometer
    Cooling time 25–35 s for 3 mm wall Cycle timer

    Under differential scanning calorimetry at 10 °C/min, non-isothermal crystallization of TE-7307 typically shows a cold crystallization exotherm beginning near 100 °C, which explains the elevated mold temperature requirement. Isothermal crystallization on hot tooling is designed to bring the part to a semicrystalline state before ejection. The crystallization temperature window is narrow; mold cavity surface temperatures should be uniform within ±5 °C. Poor temperature uniformity leads to differential shrinkage between crystallized skins and amorphous core regions, producing warp or sink marks. For thick sections above 4 mm, the cooling time is extended and the core may remain amorphous if the mold cycle is too short; this condition is detectable by low part density and lower HDT. The use of hot oil or pressurized water up to 120 °C in conformal cooling channels is preferred over standard tower water at 20 °C.

    Comparative Position of TE-7307 Against Unmodified PLA and Medium-Impact Styrenics

    General-purpose PLA molded with cold tooling at 25–40 °C typically shows heat deflection temperature near 55 °C at 0.45 MPa and flexural modulus near 3.5 GPa under ISO 178. Medium-impact ABS, by comparison, has flexural modulus near 2.4 GPa, notched Izod impact strength above 15 kJ/m² under ISO 180/A, and heat deflection temperature near 95 °C at 0.45 MPa. TE-7307 occupies a differentiated position: its 4.2 GPa flexural modulus exceeds both general-purpose PLA and medium-impact ABS, while its notched impact strength of 2.0 kJ/m² is lower than that of medium-impact ABS and must be considered in snap-fit or impact-loaded designs. The heat deflection temperature of 125 °C at 0.45 MPa exceeds both general-purpose PLA and amorphous ABS, but this value is reached only after the part has completed crystallization in the heated tool. If the part is ejected before crystallization is complete, post-mold annealing at 100 °C for 30–60 min in a circulating air oven can improve HDT but may also cause dimensional change. Compared to unfilled PBT or polypropylene, TE-7307 does not require glass fiber to reach 4.2 GPa flexural modulus, but impact strength is lower and moisture uptake is higher than PBT. The material is therefore specified for stiff, dimensionally stable parts with limited impact requirements, not for ductile thin-wall packaging or high-impact housings.

    Because the grade relies on tool-mediated crystallization, hot-runner and cooling-line design differs from amorphous PLA processing. Valve-gate hot runners should use internally heated tips at 190–200 °C and avoid dead-end melt channels where residence time exceeds 3 min. Gate locations should minimize flow length beyond 120 mm for 3 mm wall stock because PLA has low melt strength and weld-line strength decreases when melt front temperature at the meeting plane drops below 180 °C. Draft angles of 0.5–1.0° are typical for smooth surfaces to overcome ejection forces caused by mold adhesion. Tooling cost is higher than for cold-mold PLA because of thermal expansion allowances and heater capacity. Published data for specific thermal expansion compensation factors in TE-7307 is limited; tooling trials on the target hot-runner system are required to confirm shrinkage and warpage.

    When Ambient Relative Humidity Exceeds 60% Prior to Hopper Loading

    Unopened TERRAMAC TE-7307 containers should be stored below 40 °C and below 50 % relative humidity. Once opened, the material is best consumed within 8 h if the molding bay is not humidity-controlled. In plants where relative humidity exceeds 60 %, hopper blankets or desiccant beds must be used because PLA reabsorbs moisture rapidly. Re-drying wet material at 80 °C for 4–6 h may recover processability if the material has not been exposed to visible condensation or degraded by hydrolysis; severely hydrolyzed material cannot be reclaimed by drying. Blending with non-PLA regrind should be limited to 30 wt% unless the regrind has been rheologically characterized and dried to 250 ppm moisture or less. The product is incompatible with purging compounds that generate acidic volatiles, such as PVC or acetal-based purges; low-MFR polyethylene or polypropylene purges are recommended.

    On production-scale equipment, batch-to-batch variance in melt flow rate of ±1 g/10 min can alter injection pressure by 5–10 %. Dies with hot-runner pressure transducers should record peak melt pressure at the nozzle; if it exceeds 100 MPa, the melt temperature or injection speed should be reduced because excessive shear can lower molecular weight. If short shots occur at the recommended barrel profile, the nozzle should be checked for solidification at 190 °C; a higher nozzle setpoint up to 210 °C may be needed only for long flow lengths. Splay or silver streaks usually indicate moisture above 250 ppm, not insufficient melt temperature. Burn marks or acrid odor indicate dead zones in the hot runner or screw; the cause should be removed because PLA degradation is autocatalytic once lactic acid forms.

    Applications requiring short-term thermal exposure up to 120 °C include internal appliance brackets, office automation chassis, and stationary equipment housings. These applications exploit the high flexural modulus under ISO 178 and the ability to maintain geometry during hot-shipping or enclosed operation. Long-term UV exposure and food-contact compliance require separate validation; published data for TE-7307 under extended UV aging is limited. For regulators, the manufacturer’s compliance statement should be requested for EU Regulation (EC) No 1935/2004, FDA 21 CFR 177.1520, and REACH SVHC content. The grade should not be specified for components requiring notched impact strength above 5 kJ/m² or long-term hot-wet load-bearing above 60 °C, because PLA hydrolytic embrittlement can occur.

    Top