| HS Code | 742059 |
| Productname | TERRAMAC HV-6250H |
| Polymertype | Polylactic Acid (PLA) |
| Grade | High Heat Extrusion/Blow Molding |
| Density | 1.25 g/cm³ |
| Meltflowrate | 5 g/10 min at 190°C and 2.16 kg |
| Meltingpoint | 220°C |
| Glasstransitiontemperature | 60°C |
| Heatdeflectiontemperatureat045mpa | 120°C |
| Heatdeflectiontemperatureat182mpa | 100°C |
| Tensilestrength | 50 MPa |
| Tensileelongationatbreak | 3% |
| Tensilemodulus | 3500 MPa |
| Flexuralmodulus | 3800 MPa |
| Flexuralstrength | 100 MPa |
| Notchedizodimpact | 3 kJ/m² |
| Rockwellhardness | R110 |
| Moldshrinkage | 0.5% |
| Waterabsorption | 0.2% |
| Biobasedcontent | 100% |
| Biodegradability | Industrial compostable |
As an accredited TERRAMAC HV-6250H High Heat Extrusion/Blow Molding Polylactic Acid factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | TERRAMAC HV-6250H is packaged in 25 kg moisture-barrier bags, palletized, and shrink-wrapped; 1,000 kg supersacks available for bulk. |
| Container Loading (20′ FCL) | Container Loading (20′ FCL): TERRAMAC HV-6250H High Heat Extrusion/Blow Molding Polylactic Acid, 25 kg bags, palletized, shrink-wrapped, secured for shipment. |
| Shipping | TERRAMAC HV-6250H High Heat Extrusion/Blow Molding Polylactic Acid ships as non-hazardous resin pellets. It is not DOT/IMDG/IATA regulated. Pack in moisture-barrier bags, lined cartons, or octabins. Keep dry, cool, and away from direct heat. Store covered, ventilated; avoid prolonged moisture exposure. Use FIFO rotation. Handle with standard industrial hygiene. |
| Storage | Store TERRAMAC HV-6250H in a cool, dry, well-ventilated warehouse away from direct sunlight, heat, ignition sources, and moisture. Keep original containers tightly sealed, labeled, and palletized. Protect from physical damage. Maintain first-in, first-out rotation. Avoid humid conditions and strong acids, bases, or oxidizers to prevent hydrolysis and degradation. Ensure spill containment and adequate ventilation. Follow supplier SDS. |
| Shelf Life | Typically 12 months when stored unopened in original packaging under cool, dry conditions, away from moisture, heat, and direct sunlight. |
In drying-limited sheet extrusion for hot-fill food-service ware, the critical control variable before any melt-phase operation is residual moisture: TERRAMAC HV-6250H pellets are brought to ≤250 ppm moisture in a desiccant dryer at 80 °C for 4–6 hours before entering a co-rotating twin-screw extruder with L/D 40:1 and vacuum devolatilization at −0.08 MPa. A barrel profile of 180 °C to 210 °C and a die zone of 200–220 °C are typical; the melt is fed through a gear pump into a calendering stack held at 30–50 °C to produce sheet of 0.25–1.50 mm thickness. In inline or roll-fed thermoforming, sheet surface temperature is brought to 150–180 °C before forming against molds maintained at 90–110 °C; parts intended for hot-fill duty above 85 °C are annealed in-mold for 20–60 s to achieve sufficient crystallinity. Without that annealing step, amorphous PLA heat deflection temperature remains near 55–60 °C under 0.45 MPa load, and hot-filled lids or trays lose dimensional stability. The terminal product class includes compartment trays, drink cups with lid recesses, and hinged takeaway containers used for short-contact hot-fill or reheated food service. Formulation for these products incorporates 0.5–1.5 wt% of a food-contact-approved nucleating agent to accelerate cold crystallization and 0.1–0.3 wt% of a slip/antiblock package; where impact strength must be raised for freezer-to-oven transitions, a food-contact-grade impact modifier at 2–5 wt% is compounded, but addition above 8 wt% should be tested for heat deflection and migration because published data for HV-6250H at this modifier loading is limited. Compliance is evaluated under EU Regulation (EU) No 10/2011 Annex I and II for plastic food-contact materials, with overall migration below 10 mg/dm²; in the United States, the exact Food Contact Notification for the grade must be confirmed with the supplier rather than assumed from generic PLA clearance. Industrial compostability claims are tested under EN 13432 and ASTM D6400 only when the entire formulation—including the nucleating package and impact modifier—meets the 90% biodegradation threshold within 180 days; a formulation that meets heat-deflection targets may fail compostability if non-biodegradable modifier content exceeds the standard’s limits.
In extrusion blow molding of cylindrical or rectangular dry-goods canisters, HV-6250H exposes a processing window materially narrower than that of HDPE or PETG. Melt temperature at the accumulator head is maintained at 190–210 °C; above 215 °C, melt strength declines steeply, and parison sag produces unacceptable wall thinning in the pinch-off and handle regions. A diverging die gap of 1.5–3.0 mm is used with a parison programmer that applies 20–40% radial wall-thickness profiling to compensate for die swell and sag, especially for containers with height-to-diameter ratios above 3:1. Mold temperature is set to 20–35 °C, and blow pressure of 0.5–0.8 MPa is applied for 2–4 s before exhaust and ejection. A head-temperature deviation of ±5 °C is often sufficient to alter parison sag to the point that wall-thickness programming must be reset; published data for this specific grade is limited, so start-up trials should include a parison sag study with high-speed video or infrared wall-thickness measurement. The formulation typically includes a polymeric chain extender at 0.1–0.3 wt% to increase melt strength and reduce melt flow rate under ISO 1133-1:2022; the selected chain extender must be evaluated for food-contact status because some epoxy-functionalized chain extenders may not be listed under EU Regulation (EU) No 10/2011. Terminal products include 250-mL to 2-L canisters for dry powders, granulated food ingredients, and moisture-barrier overwrapped dry goods; these containers are not suitable for hot-fill above 60 °C unless post-mold annealing is validated, because blow molding cools the part rapidly and freezes in low crystallinity. Compliance for dry-food contact is assessed under EN 1186-1 migration testing and EU Regulation (EU) No 10/2011, with additional requirements for manufacturing hygiene under Regulation (EC) No 2023/2006. Mechanical performance of the canister is characterized by ISO 527-2 tensile testing and ISO 178 flexural testing, while dimensional stability under load is reported using ISO 75-2 method B.
| Application segment | Standard / specification | Clause or test method | Verification purpose |
|---|---|---|---|
| Thermoformed food-service sheet | EU Regulation (EU) No 10/2011 | Annex I and II; overall migration 10 mg/dm² | Food-contact safety and migration control |
| Thermoformed food-service sheet | EN 13432 / ASTM D6400 | Disintegration, 90% biodegradation within 180 days, ecotoxicity | Industrial compostability claim |
| Extrusion blow molded dry-goods canisters | EN 1186-1 / EU Regulation (EU) No 10/2011 | Overall and specific migration testing | Dry-food packaging compliance |
| Cosmetic and personal-care bottles | Regulation (EC) No 1223/2009 / REACH Regulation (EC) No 1907/2006 Annex XVII | Safety assessment and restricted substances | Formula compatibility and EU market access |
| Industrial profiles | RoHS Directive 2011/65/EU as amended by Commission Delegated Directive (EU) 2015/863 | Annex II restricted substances | Electrical/electronic equipment component compliance |
| FFF filament feedstock | ISO 1133-1:2022 / ISO 75-2 method B | Melt flow rate and heat deflection temperature | Filament processability and printed-part thermal resistance |
For cosmetic and personal-care bottles blow molded from high-heat PLA, the required surface-finish and stress-cracking validation sequence differs from that of dry-goods canisters, largely because the closure neck finish and label panel are exposed to cyclic squeeze loading and surfactant-containing formulations. The resin is dried to ≤200 ppm moisture and processed through a continuous extrusion blow molding machine with L/D 24:1–30:1, barrel temperatures of 175–195 °C, and die head temperatures of 190–205 °C; mold temperature is raised to 30–40 °C to reduce surface haze and improve replication of embossed logo features. Formulation addition typically includes 2–4 wt% of a PLA-compatible color masterbatch and 0.2–0.5 wt% of a process aid; if the bottle must pass a drop test of 1.0–1.5 m at 4 °C, an impact modifier at 3–6 wt% is incorporated, but the same addition may lower hot-fill resistance and must be balanced against cap torque retention measured by the supplier’s closure test. Terminal product types include 200-mL to 500-mL lotion bottles, foaming hand-wash bottles, and refillable home-care bottles with standard 24/410 or 28/410 neck finishes. Stability against the filled medium is governed by Regulation (EC) No 1223/2009 through the responsible-person safety assessment; the packaging material itself is not a cosmetic ingredient, but its extractables profile must be compatible with the formula. REACH compliance is required for the EU market under Regulation (EC) No 1907/2006 Annex XVII, and any colorant must meet heavy metals limits under Directive 94/62/EC on packaging and packaging waste. In this application, published data for HV-6250H with fragrance-containing emulsions is limited, so storage stability testing at 40 °C and 75% RH for 4–12 weeks is necessary before commercial conversion. Particular attention is given to environmental stress cracking at the neck-shoulder transition, because PLA in contact with certain ethoxylated surfactants can exhibit localized stress whitening and loss of drop impact resistance below 5 °C; a validated production line should therefore include a cold-temperature drop test and a torque-rotation test on the filled closure.
When a continuous length or complex cross-section makes injection molding uneconomical, high-heat PLA profiles—rods, square sections, U-channels, and edge-protection strips—are produced on single-screw extrusion lines configured for rigid profile manufacture. The process uses a single-screw extruder with L/D 30:1, a breaker plate and screen pack, a gear pump, and a vacuum calibration tank operated at −0.06 to −0.09 MPa. Melt temperature at the die is held between 185 °C and 205 °C; die land lengths are extended to 10–20 times the local wall thickness to reduce die swell and improve surface gloss. Calibration water temperature is controlled to 25–45 °C, and puller speed is synchronized to a melt-pressure signal upstream of the gear pump to maintain dimensional tolerance of ±0.05 mm on round profiles below 10 mm diameter. The formulation includes a mineral nucleant at 0.5–1.5 wt% to accelerate crystallization during calibration and an impact modifier at 5–10 wt% to prevent edge cracking during downstream cutting and installation; increasing the impact modifier above 10 wt% may reduce flexural modulus below the 2,500 MPa threshold commonly needed for rigid structural profiles, so validation under ISO 178 is mandatory. Terminal products are industrial edge guards, cable management channels, nonfood rigid tubes, protective profiles for furniture and logistics racks, and insertion strips used in secondary packaging. Compliance is primarily non-food: REACH Regulation (EC) No 1907/2006 Annex XVII, RoHS Directive 2011/65/EU as amended by Commission Delegated Directive (EU) 2015/863, and ISO 527-2 for tensile characterization. If the profile is marketed as industrially compostable, EN 13432 disintegrability and ecotoxicity criteria must be met, but high mineral loading may delay disintegration past the standard’s 12-week limit; this must be tested on the final profile, not on neat resin. In production-scale extrusion, melt-pressure variation across a 4-hour run can indicate screen-pack blinding from nucleant agglomerates; a continuous screen changer is therefore specified when mineral nucleant loadings exceed 1.0 wt%.
| Scenario | Additive class | Typical addition ratio | Function / validation |
|---|---|---|---|
| Thermoformed hot-fill sheet | Nucleating agent | 0.5–1.5 wt% | Accelerate crystallization; validate HDT per ISO 75-2 |
| Thermoformed hot-fill sheet | Slip / antiblock | 0.1–0.3 wt% | Sheet handling; validate coefficient of friction |
| Thermoformed hot-fill sheet | Impact modifier | 2–5 wt% | Frozen-impact resistance; migration testing under EU Regulation (EU) No 10/2011 |
| Extrusion blow molded dry-goods canisters | Chain extender | 0.1–0.3 wt% | Melt strength retention; verify MFR per ISO 1133-1:2022 |
| Cosmetic bottles | Color masterbatch / process aid | 2–4 wt% / 0.2–0.5 wt% | Color dispersion and surface finish; storage stability at 40 °C / 75% RH |
| Industrial profiles | Mineral nucleant / impact modifier | 0.5–1.5 wt% / 5–10 wt% | Dimensional stability and edge toughness; flexural modulus per ISO 178 |
| FFF filament feedstock | Nucleating package / chain extender | 0.5–2.0 wt% / 0.1–0.3 wt% | Printed-part heat resistance and layer adhesion; monitor diameter at 1.75 ± 0.05 mm or 2.85 ± 0.05 mm |
Because consistent melt strength and dimensional accuracy are the dominant constraints in fused-filament fabrication feedstock conversion, TERRAMAC HV-6250H is processed through a compounding and filament-forming sequence in which downstream blow-molding behavior is less relevant than diameter uniformity and thermal stability. The resin is dried to ≤250 ppm moisture and fed into a co-rotating twin-screw extruder with L/D 40:1, where a nucleating package at 0.5–2.0 wt% and a colorant masterbatch at 2–5 wt% are dispersed; melt temperature at the die is maintained at 190–215 °C. The filament line uses a melt pump after the extruder, a water bath at 30–40 °C, and a multi-axis laser micrometer with a closed-loop puller to hold diameter to 1.75 ± 0.05 mm or 2.85 ± 0.05 mm. Feedstock intended for high-temperature part use is characterized by ISO 75-2 method B heat deflection temperature after printing and annealing; amorphous printed parts may deflect at 55–60 °C, while annealed parts can exceed 100 °C only if the print geometry allows crystallization without distortion. The terminal product type is not the printed part itself but the filament spool for in-house and commercial FFF printing of heat-resistant tooling, jigs, and small-batch industrial fixtures. Compliance is governed by REACH Regulation (EC) No 1907/2006 and RoHS Directive 2011/65/EU; food-contact or medical claims are not assigned unless the specific formulation and printed part are evaluated under the relevant EU Regulation (EU) No 10/2011 or ISO 10993 series. Published data for HV-6250H in FFF filament production is limited; melt flow rate under ISO 1133-1:2022 should be monitored before and after chain-extender addition at 0.1–0.3 wt% to prevent layer-to-layer bonding failures associated with excessively low melt flow. During production-scale spooling, the main failure mode is ovality introduced by non-uniform cooling in the water bath; bath length must be sufficient to reduce the filament surface temperature to below 40 °C before laser measurement, otherwise the closed-loop puller may chase a moving diameter baseline and produce spools outside the ±0.05 mm tolerance band.
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TERRAMAC HV-6250H is a high-heat polylactic acid extrusion and blow molding grade supplied by Unitika Ltd. under the TERRAMAC trademark. The model designation HV-6250H identifies a high-viscosity, high-heat variant formulated for continuous single-screw extrusion and intermittent extrusion blow molding where conventional PLA grades exhibit insufficient melt strength, excessive parison sag, or heat deflection temperatures below 60°C in amorphous finished parts. The resin combines a controlled D-lactic acid fraction, a high-molecular-weight backbone, and a nucleating additive package. Its pellet moisture specification and narrow processing window require closed-loop drying and barrel temperature management; when those conditions are met, the material yields blow molded containers and extruded sheet with elevated crystallinity and a heat deflection temperature above the amorphous glass transition of PLA.
`The primary difference is thermal service range. General-purpose PLA remains largely amorphous after melt processing and softens near its glass transition temperature of approximately 55–60°C. HV-6250H is designed to crystallize during mold residence or post-extrusion annealing, shifting the heat deflection temperature under 0.45 MPa to 110–125°C when tested according to ISO 75-2 Method B. Melt strength is also differentiated. Standard extrusion PLA grades show rapid parison drawdown on vertical accumulator-head machines; HV-6250H is rheologically modified for extensional viscosity retention at low strain rates, which reduces longitudinal thinning at die gaps between 1.0 mm and 3.0 mm. The D-lactic acid content is lower than in commodity PLA, a condition that raises the melting point and increases the maximum attainable crystalline fraction.
`Typical comparative data are summarized in Table 1. These values are not specification limits and must be confirmed against the supplier certificate of analysis for a given production lot.
`| Property | Standard | Typical value |
|---|---|---|
| Melt mass-flow rate | ISO 1133-1:2022 | 3.5–5.5 g/10 min at 190°C, 2.16 kg |
| Density | ISO 1183-1:2019 | 1.24–1.25 g/cm³ |
| Tensile yield stress | ISO 527-2:2012 | 60–65 MPa |
| Tensile elongation at break | ISO 527-2:2012 | 4–8% |
| Flexural modulus | ISO 178:2019 | 3.2–3.6 GPa |
| Flexural strength | ISO 178:2019 | 95–105 MPa |
| Notched Izod impact | ISO 180:2019 | 2.5–4.0 kJ/m² |
| Heat deflection temperature, annealed | ISO 75-2:2013, 0.45 MPa | 110–125°C |
| Vicat softening temperature | ISO 306:2013 A50 | 115–125°C |
| Residual moisture as supplied | — | ≤ 400 ppm |
At the feed throat, moisture becomes the first process boundary. PLA hydrolyzes in the melt state through ester bond scission; the reaction rate increases sharply when residual pellet moisture exceeds 0.025 wt% (250 ppm). Drying therefore must be performed in a desiccant dryer with a dew point below -40°C, air temperature 80°C ± 5°C, and residence time 4–6 h. The dried pellets should be conveyed by dry air and introduced to a sealed feed throat; open hoppers in high-humidity plants can raise surface moisture by 0.01 wt% within 30 min. Failure to maintain dryness produces viscosity loss at the die, irregular parison length on blow molding flights, and weld-line splitting.
`On a 24:1 to 30:1 L/D single-screw extruder with a compression ratio of 2.5:1–3.0:1, typical set points are feed 170–180°C, compression 180–190°C, metering 190–200°C, and die 195–205°C. Melt temperature measured at the exit should remain below 220°C; excursions above 230°C accelerate lactide reformation, reduce melt strength, and produce yellowing or acrid decomposition products. At the lower boundary, die temperature below 190°C creates high melt viscosity, sharkskin surface defects, and uneven parison wall thickness. The practical die-temperature window is therefore approximately 195–205°C, a range of 10°C that is narrower than for polyolefin blow molding grades.
`| Process parameter | Suggested operating range |
|---|---|
| Desiccant dryer set point | 80°C ± 5°C |
| Dry air dew point | ≤ -40°C |
| Drying time | 4–6 h |
| Residual pellet moisture | ≤ 250 ppm |
| Feed zone | 170–180°C |
| Compression zone | 180–190°C |
| Metering zone | 190–200°C |
| Die set point | 195–205°C |
| Melt temperature | 200–220°C |
| Mold surface temperature | 30–70°C |
| Blow-up ratio | ≤ 2.5:1 typical |
| Screw L/D | 24:1–30:1 |
| Compression ratio | 2.5:1–3.0:1 |
Mold temperature controls the crystalline skin layer. If the mold surface remains below 25°C, the parison quenches into a largely amorphous state; the part may pass visual inspection but exhibits heat deflection temperature near 55–60°C, which is unsuitable for hot-fill or short-term thermal exposure. If the mold surface exceeds 70°C, cooling time lengthens, parts may warp, and release becomes inconsistent. The usable mold-surface band for HV-6250H on extrusion blow molding trials is 30–70°C, with 50–60°C preferred for wall thicknesses from 1.5 mm to 3.0 mm. At that mold temperature, the nucleated formulation crystallizes sufficiently during the cooling portion of the cycle to raise the heat deflection temperature after demolding; post-mold annealing at 80–100°C for 30–60 min can further shift dimensional stability for parts that will see elevated temperatures in service.
`Blow-up ratios above 2.5:1 reduce wall uniformity because the parison must travel farther before contact with the mold wall; cooling is asymmetric and the part may show amorphous regions in the thinnest walls. Tooling should therefore use a diverging die land, minimal changes in parison wall thickness, and adequate venting to avoid gas entrapment. Published data for large accumulator heads above 5 kg shot capacity with this specific grade is limited.
`In sheet extrusion and thermoforming, the same melt-temperature limits apply, and the chill-roll temperature should be held between 30°C and 60°C to allow nucleation without blocking. The high heat deflection after crystallization makes the material suitable for containers used for dry food, cosmetics, household products, and industrial intermediates when service temperatures do not exceed approximately 80°C under short-term exposure. Published data for specific packaged product shelf life is limited and must be established by end-use migration and thermal testing.
`Residence time is a critical operating boundary. At melt temperatures between 200°C and 220°C, total barrel and head residence should not exceed 8 min; longer residence produces progressive viscosity reduction and parison sag despite stable set points. On accumulator-head machines, shot size should be matched to extruder output so that the accumulator does not hold a full charge for more than 5 min. Start-up and shutdown must be managed with an inert purge or a low-MFR polyolefin; purging with PET or PVC is incompatible because residual acetal, ester, or chlorine species accelerate PLA degradation. When shutting down for more than 2 h, the barrel should be purged and temperature reduced below 150°C to avoid thermal decomposition in the head.
`During isothermal crystallization, differential scanning calorimetry of nucleated high-heat PLA typically shows faster crystal growth than unmodified PLA. For nucleated PLA grades in general, published crystallization half-times at 100–110°C are reported in the 1–3 min range, whereas unmodified PLA may exceed 10 min under the same conditions. The actual HV-6250H value should be confirmed by DSC under the intended mold thermal cycle. This crystallization response explains why mold residence time, rather than simple cooling rate, is the controlling variable for high-heat performance.
`Compared with PET blow molding resin, HV-6250H has lower density (1.24–1.25 g/cm³ versus approximately 1.34 g/cm³) and lower processing temperatures, but also lower drop-impact toughness and higher moisture sensitivity. The material is not a direct drop-in replacement for PET in carbonated beverage containers because of carbon dioxide permeation and heat-set limitations. Bio-based carbon content can be verified by ASTM D6866; typical PLA grades report more than 95% biobased carbon.
`Food-contact suitability must be verified by end-use migration testing under EU 10/2011 or equivalent national regulation. The grade should not be dry-blended with amine-based processing aids or certain metal stearates without prior evaluation; residual alkalinity can hydrolyze the ester backbone. For long-term service in humid conditions, hydrolytic stability must be assessed by end-use testing at the intended temperature and relative humidity.
`