| HS Code | 147350 |
| Product Name | Techmer ES HiFill® ASA HiFill® ASA GF20 |
| Material Type | ASA (Acrylonitrile Styrene Acrylate) |
| Reinforcement | 20% glass fiber |
| Density | 1.13 g/cm³ |
| Mold Shrinkage | 0.3-0.5% |
| Tensile Strength | 75-80 MPa |
| Tensile Elongation At Break | 2% |
| Flexural Modulus | 6.0-6.5 GPa |
| Notched Izod Impact | 45-60 J/m |
| Heat Deflection Temperature | 100-105 °C at 1.82 MPa |
| Processing Method | Injection molding |
| Ul Flammability Rating | HB |
As an accredited Techmer ES HiFill® ASA HiFill® ASA GF20 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Packaged in 25 kg moisture-barrier, foil-lined paper bags on pallets for safe industrial storage and handling. |
| Container Loading (20′ FCL) | 20′ FCL: Techmer ES HiFill® ASA GF20 loaded palletized in moisture-protective packaging, dry ambient conditions, secured for transport, within container weight limits. |
| Shipping | Techmer ES HiFill® ASA GF20, glass-fiber reinforced ASA pellets, is non-hazardous and not regulated for transport (no UN number). Ship in sealed, moisture-barrier bags or containers; keep dry, away from heat, UV, and contamination. Maintain clean handling and stable storage conditions. |
| Storage | Store in a cool, dry, well-ventilated area away from direct sunlight, heat, and ignition sources. Keep containers tightly closed and palletized, protected from moisture and contamination. Avoid dust generation and static accumulation. Segregate from incompatible chemicals, and follow the manufacturer’s SDS and local regulations. Use first-in, first-out stock rotation. |
| Shelf Life | Shelf life is typically 12 months when stored unopened in a cool, dry place away from direct sunlight. |
Techmer ES HiFill® ASA HiFill® ASA GF20 is used in exterior automotive mirror shells, door handle bezels, and unpainted mounting brackets where long-term ultraviolet exposure and mechanical stiffness are required. The glass fiber content of 20 wt% raises the flexural modulus of the amorphous ASA matrix to the 5,800–6,800 MPa range when tested to ISO 178:2019, which limits deflection of the mirror head under highway-speed aerodynamic loading. The primary process conflict is anisotropic shrinkage. During filling, glass fibers align with the melt front, so post-mold shrinkage parallel to flow is typically 0.10–0.30% while shrinkage perpendicular to flow reaches 0.40–0.80% under ISO 294-4:2018. If the gate is positioned at the perimeter of a mirror shell, the differential shrinkage produces a bending couple that can exceed 0.5 mm of out-of-flatness across a 300 mm span. Mold temperature is held at 70–80°C to create a resin-rich surface and reduce exposed glass filaments. Mold temperatures below 60°C leave a matte surface with visible fibers, and paint adhesion measured by cross-cut tape testing under ASTM D3359 falls below the 4B rating. Two-component polyurethane topcoats are applied after cleaning, and chip resistance is evaluated to SAE J400. In dark colors, solar soak temperatures routinely exceed 90°C, but the material class retains stiffness because HDT/A is in the 100–110°C range under ISO 75-2:2013. Published datasheets for the exact grade should be used for tool design because fiber sizing and coupling chemistry shift these ranges.
Tool design values for a 20 wt% glass-fiber ASA material class, not exact product specifications.
| Property | Test method | Typical range |
|---|---|---|
| Parallel mold shrinkage | ISO 294-4:2018 | 0.10–0.30% |
| Perpendicular mold shrinkage | ISO 294-4:2018 | 0.40–0.80% |
| Tensile stress at break | ISO 527-2:2012 | 75–90 MPa |
| Flexural modulus | ISO 178:2019 | 5,800–6,800 MPa |
| HDT/A flatwise | ISO 75-2:2013 | 100–110°C |
Tool design for mirror brackets must also address glass fiber attrition and weld line placement. Abrasive glass filaments wear unhardened injection screws; bimetallic or powder-metal barrels with screw L/D ratios of 20:1 to 24:1 are used. Back pressure is held between 0.3 and 0.7 MPa; higher back pressure increases fiber fracture and lowers tensile strength. Weld lines on mounting bosses carry lower strength than the bulk, so bosses are spaced away from flow interruptions and reinforced with gusset plates. For parts later painted with two-component polyurethane systems, an isopropyl alcohol or alkaline degreaser is applied, and the substrate must be water-break-free under ASTM F22 before coating. Painted plaques are then exposed to 500 h xenon arc weathering under ISO 4892-2:2013 to detect delamination or gloss loss at fiber-rich areas.
Because outdoor electrical enclosures and photovoltaic combiner boxes must maintain mechanical integrity after prolonged UV and moisture cycling, ASA-GF20 is evaluated to UL 746C f1 for outdoor suitability and used for housing bodies, latches, and internal mounting rails. The glass fiber raises tensile stress at break to the 75–90 MPa range under ISO 527-2:2012, permitting thinner walls than unfilled ASA while maintaining cover stiffness. However, the non-flame-retardant version is generally rated UL 94 HB at 1.5 mm. Enclosures with printed circuit boards or terminal blocks requiring V-2 or V-0 cannot use this material alone; a flame-retardant ASA variant or a metal barrier plate is required. Drying is critical because residual moisture above 0.02% hydrolyzes the glass sizing during plastication and produces silver streaks. A desiccant dryer with a dew point below −30°C and a residence time of 4 h at 80°C is used. Melt temperature is held between 245°C and 265°C; melt temperatures above 270°C degrade the acrylic ester elastomer and cause yellowing. Mold temperature above 70°C is necessary to develop a resin-rich surface and prevent early gloss loss under xenon arc weathering to ISO 4892-2:2013. Accelerated weathering programs for outdoor electrical components typically run 1,000–2,000 h; published regression data for 20% glass-reinforced ASA show tensile strength retention above 80% after 1,000 h, but published data for this specific configuration is limited and must be confirmed per production lot. Sealing bosses and snap-fit lids are designed with radii above 1.5 mm because glass fiber lowers notched impact relative to unfilled ASA.
Qualification plan for outdoor enclosure applications.
| Property | Standard | Application relevance |
|---|---|---|
| Outdoor weatherability | UL 746C f1 | Polymer suitability for outdoor electrical enclosures |
| Empty enclosure performance | IEC 62208:2011 | Mechanical and environmental performance of enclosure |
| Ingress protection | IEC 60529 | IP54/IP65 sealing requirements |
| Flammability | UL 94 | Thickness-dependent rating; ASA-GF20 typically HB |
| Weatherometer exposure | ISO 4892-2:2013 | Xenon arc exposure for gloss and color retention |
Gate placement must avoid sealing surfaces and snap-fit retention features because glass fiber orientation around gates creates local shrinkage differences. Gates should be located away from gasket grooves, and mold-filling simulation is used to position weld lines behind support ribs rather than across the sealing plane. For photovoltaic combiner boxes, the material's water absorption is low, but silicone gaskets are still required because glass fiber can wick moisture from cut edges under repeated thermal cycling.
In marine deck hatches, antenna brackets, and instrument housings, the compound is exposed to simultaneous salt spray, moisture absorption, and ultraviolet radiation. The acrylic ester elastomer in ASA resists hydrolysis, unlike polyamide or polyester, while the 20 wt% glass fiber stiffens large flat covers and reduces creep under spring-loaded seals. Salt spray exposure to ISO 9227 for 720 h leaves natural 20% glass-reinforced ASA with minimal tensile strength loss, but surface microcracks from machining or cold-insertion of threaded brass inserts can wick salt solution into the glass sizing and initiate delamination. Threaded inserts should be installed by ultrasonic insertion rather than cold pressing, and the boss outer diameter should be at least 2.5× the insert diameter to keep hoop stress below the environmental stress-cracking threshold. The notched Charpy impact of glass-filled ASA is in the 7–12 kJ/m² range under ISO 179-1/1eA, significantly lower than unfilled ASA, so hatch corner radii and flange transition radii below 1.0 mm must be avoided. High-gloss black parts should contain carbon black at 2 wt% or more to prevent surface chalking during long-term exposure; lower loadings may produce visible chalking before 1,000 h of xenon arc testing under ISO 4892-2:2013. For pressure-tight enclosures, fiber orientation around gasket grooves must be modeled with mold-filling simulation to prevent uneven shrinkage from opening a leak path.
Outdoor power tool housings and portable generator enclosures are produced with ASA-GF20 where abrasive glass fiber dominates tool wear and fiber attrition. The glass fiber is abrasive; screws and barrels should use bimetallic or powder-metal construction, and injection units with 20:1 to 24:1 L/D low-compression screws are typical. Screw speeds above 150 rpm can break glass filaments and reduce tensile strength, so surface speed limits are set according to part volume and melt viscosity. The material is dried at 80°C for 4 h and molded at melt temperatures between 245°C and 265°C. Vibration from small gasoline engines is amplified by stiff glass-filled bosses; snap-fit designs should include isolation grommets and avoid cantilever lengths greater than 3× the wall thickness. The specific gravity near 1.22–1.28 under ISO 1183-1:2019 is lower than metal enclosures but higher than unfilled ASA, and the glass fiber lowers notched impact. Field failures generally occur at tooling splits, gate scars, and weld lines; mold-filling analysis should place weld lines away from screw bosses and handle load paths.
Exterior building louvers, solar shading fins, and cladding support profiles require long straight moldings with controlled thermal expansion. Glass fiber lowers CLTE relative to unfilled ASA, but flow-direction orientation produces different expansion and shrinkage in the length and width axes. A louver profile 1,200 mm long molded from a single end gate can exhibit bowing greater than 1.0 mm under a temperature swing from −20°C to 60°C if fiber orientation is unbalanced. Tooling should use dual hot-tip gates or a full-width film gate, and mold temperature should be kept within ±5°C across the cavity. For dark bronze or black profiles, solar heat build-up raises surface temperature to 70–80°C; the HDT/A of 100–110°C under ISO 75-2:2013 provides a thermal margin, but expansion gaps must be calculated using measured CLTE in both axes. Building code compliance may require a reaction-to-fire classification under EN 13501-1; ASA, both unfilled and glass-filled, is combustible and generally falls into Euroclass E or lower without flame-retardant additives. These applications are therefore limited to non-structural exterior components where fire propagation is controlled by facade geometry, cavity barriers, or metal sub-frames.
Fastener bosses in cladding profiles must withstand wind load creep at elevated temperature. Long-term creep under constant load is evaluated to ISO 899-1:2017; the glass fiber reduces creep strain compared with unfilled ASA, but boss countersinks and washers should distribute load over a minimum bearing area to avoid stress cracking. Pre-drilling is used before self-tapping screws in low-temperature installation because glass-filled ASA is more notch-sensitive than unfilled material below 0°C.
Cooling tower inlet louvers, agricultural sensor housings, and irrigation control boxes use ASA-GF20 because the amorphous matrix resists aqueous chemical attack and the glass fiber stiffens large louver arrays. The flexural modulus of 5,800–6,800 MPa under ISO 178:2019 allows thin blades to resist flutter under high air velocities, but weld lines must not fall on the leading edge because glass fiber orientation at the weld line reduces fatigue strength. Chemical resistance is evaluated to ISO 22088-1 or ASTM D543 under representative strain; glass-filled grades crack more readily than unfilled ASA due to notch sensitivity at the fiber-matrix interface. Strong oxidizers, concentrated sulfuric acid, and aromatic solvents can stress-crack the ASA phase. Urea solutions used in agriculture are generally compatible, but unsaturated esters and some amine-based cleaning agents can induce environmental stress cracking. For parts exposed to repeated high-pressure washdown, glass fiber can wick moisture from cut edges, so post-machining annealing at 85°C for 1 h is used to relax molded-in stress and close microchannels at the surface.
In large cooling tower louver arrays, filling must be balanced across multiple cavities because glass-filled ASA has higher viscosity than unfilled ASA and short shots occur at the last cavity if runners are not designed for equal pressure drop. Runner systems should use trapezoidal or full-round geometry, and cold slug wells are placed ahead of gates to capture solidified glass-rich material from the nozzle. Published data for this specific cooling tower configuration is limited; mold-filling simulation and multiple iterative trials are required to set gate freeze time and hold pressure for each cavity.
A simple flat cover plate or spacer ring in an indoor environment requires only standard drying at 80°C for 4 h and injection molding at the supplier's recommended melt-temperature range; no additional process development is usually necessary.
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