| HS Code | 658337 |
| Productname | Techmer ES HiFill® ASA HiFill® ASA GF15 |
| Polymertype | Acrylonitrile Styrene Acrylate (ASA) copolymer |
| Reinforcement | Glass fiber |
| Glassfibercontent | 15% |
| Density | 1.15 g/cm³ |
| Tensilestrength | 65 MPa |
| Tensilemodulus | 5000 MPa |
| Elongationatbreak | 2.0% |
| Flexuralmodulus | 5000 MPa |
| Flexuralstrength | 100 MPa |
| Notchedizodimpact | 5.0 kJ/m² |
| Heatdeflectiontemperatureat1 8mpa | 95 °C |
| Vicatsofteningpoint | 105 °C |
| Ul94flammability | HB |
| Moldingshrinkage | 0.2-0.4% |
As an accredited Techmer ES HiFill® ASA HiFill® ASA GF15 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Techmer ES HiFill® ASA GF15 supplied in sealed 25 kg moisture-barrier bags on pallets; store dry in original packaging. |
| Container Loading (20′ FCL) | 20′ FCL container loading of Techmer ES HiFill® ASA GF15: palletized moisture-proof bags, securely stowed for safe chemical transport. |
| Shipping | Techmer ES HiFill® ASA GF15 is normally supplied as dry, glass-fiber-reinforced ASA pellets. Ship in sealed moisture-barrier bags or containers, palletized and protected from moisture, direct sunlight, heat, and contamination. It is typically not regulated as dangerous goods; follow the SDS and local transport rules. |
| Storage | Store Techmer ES HiFill® ASA HiFill® ASA GF15 in a cool, dry, well-ventilated area away from direct sunlight, heat, sparks, flames, and strong oxidizing agents. Keep containers tightly closed to prevent moisture pickup and contamination. Avoid prolonged high humidity or elevated temperatures, follow first-in, first-out stock rotation, and keep packaging properly labeled and intact. |
| Shelf Life | Techmer ES HiFill® ASA GF15 typically has a 12-month shelf life when stored cool, dry, and in original sealed packaging. |
In exterior mirror housing production, the substitution of unfilled ASA with Techmer ES HiFill® ASA HiFill® ASA GF15 is normally driven by the need to eliminate creep-induced gapping between the housing shell and the aluminium mounting boss. The compound is dried in a desiccant hopper at 80°C for 4 h, a target that lowers residual moisture to 0.02% or less; skipping this step when relative humidity exceeds 60% produces hydrolysis, silver streaking, and a reduction in notched Charpy impact below typical 6–9 kJ/m² data measured to ISO 179-1/1eA. Melt temperature is held at 240–260°C, with barrel zones set from rear to nozzle at 235/240/245/250°C on a 1600 kN hydraulic machine using a 35 mm general-purpose screw with an L/D of 20:1 and compression ratio 2.5:1. The glass-fiber phase raises tensile modulus to a range of 5.0–6.5 GPa when tested to ISO 527-2, which allows the designer to reduce nominal wall from 3.5 mm to 2.8 mm and still meet the same deflection limit; this is the central structural advantage, not weathering retention alone. Fiber orientation creates anisotropic shrinkage: flow-direction shrinkage is 0.15–0.30%, while transverse shrinkage reaches 0.35–0.50% when measured to ISO 294-4 on a 60 mm × 60 mm × 2 mm plaque. The resulting warpage is controlled by setting cavity pressure at 35–45 MPa at gate freeze, maintaining a screw cushion of 3–5 mm, and avoiding overpacking beyond 0.5 s after the filling phase transitions to packing. Gate location directly governs weld-line visibility and mechanical integrity at the mounting boss. A single edge gate produces a cold weld line at the boss base, and the measured weld-line tensile strength after 23°C conditioning is commonly 35–50% lower than non-weld values when tested to ISO 527-2 coupon specimens. To reduce this loss, tool layouts rely on a valve-gated hot runner feeding the hub center, with the boss treated as a flow path rather than an obstruction. The gate land is held at 1.2–1.5 mm thickness and 1.5–2.0 mm length to supply enough shear heating to wet the glass bundles without excessive fiber breakage. At the tool surface, 70–80°C water temperature improves fiber cover and shortens the surface freeze layer, but a 10°C mold-temperature drop from 80°C to 70°C is sufficient to shift the glass bundles closer to the surface and produce a visible fibrous halo around the gate. This grade is considered for mirror housing support brackets, lower exterior mirror shells, and door handle bezels where the part is painted, film-embossed, or textured to hide fiber read-through. No standard high-gloss Class A body panel can be molded directly from this material without a paint layer because the 15 wt% glass loading disturbs the surface finish to a level that cannot pass ISO 2813 20° gloss values above 80 GU unless a two-component acrylic topcoat is applied. Weathering of the base resin is assessed by ISO 4892-2 cycle 1 or SAE J2527; the key acceptance criterion is less than 3.0 Δb after 2,000 kJ/m² at 340 nm, but published data for this specific Techmer compound in a mirror housing configuration is limited, so production validation should confirm delamination and color shift on painted plaques rather than relying on resin type alone. The total processing window is narrow: melt temperature above 260°C causes yellowing and fiber-matrix debonding, while below 235°C the glass phase cannot be encapsulated and the surface shows un-wetted strands. This processing constraint is the primary reason why molding trials start at 255°C and move downward only after confirming transverse tensile, not just flow-direction tensile, to ISO 527-2.
Rooftop photovoltaic junction boxes and cable gland carriers are molded from glass-reinforced ASA where the part must satisfy IEC 62790 mechanical housing requirements and UL 746C f1 outdoor suitability. The lids and base carriers are exposed to continuous UV irradiance and temperature cycling from -40°C to 85°C, so dimensional stability of the sealing groove is evaluated by thermal cycling per IEC 60068-2-14 test Nb. The glass fibers reduce in-plane thermal expansion to 35–45 µm/m·K in the flow direction when measured to ISO 11359-2, which is up to 50% lower than unfilled ASA and thus prevents the lid from bowing away from the gasket after summer exposure. The process starts with desiccant drying to 0.02% moisture and uses a melt temperature of 245–255°C; lower melt temperatures are avoided because the thin-walled lid, often 1.8–2.2 mm nominal, freezes quickly and leaves exposed glass strands at the cable bump-off. Weld-line integrity is the limiting property in this application because the lid is gated at the center to produce a radially filled disc, and two opposing side bosses for cable entry create dead zones behind the core pins. In a four-cavity cold-runner mold, filling analysis shows the melt fronts rejoin at the boss edges at 180°, producing a knit line that retains only 30–45% of the unreinforced weld-line strength; this drive to avoid knit lines is why some tools use a second valve gate near the boss pack area or add a flow leader 1.5 mm thick. The clamping force is set at 1000–1200 kN for a 4-cavity tool, with injection speed profiled from 25 mm/s to 75 mm/s as the flow front passes the boss pins; faster injection reduces the time the glass bundles have to orient in the flowing melt, but it also raises injection pressure to 85–100 MPa and increases the risk of flash at the seal groove. The optimal holding pressure is 40–50 MPa, with a hold time of 6–8 s and cooling time of 18–22 s at 70°C tool temperature; this produces a consistently filled groove without overpacking the gate area. After molding, the lid is annealed at 80°C for 2 h to relax residual stress from the brass insert, but if the insert is not preheated to 80–100°C before placement, radial cracks form around the boss within the first thermal cycle to -40°C. Tightening torque for the M25 cable gland is typically limited to 1.5–2.0 N·m; higher torque ruptures the boss because the glass fiber aligns circumferentially around the insert and does not carry hoop stress across the weld line. The electrical tracking index of ASA is normally above 500 V when tested to IEC 60112; glass fiber does not eliminate this, but surface roughness from exposed fibers can reduce comparative tracking index if the mold texture is deeper than 25 µm because conductive contamination collects in the valleys. The application is therefore viable when the product is designed with a matte or pebble-textured exterior and generous root radii of 1.0 mm or above at every boss and rib junction. Published UL 746C f1 certification for the specific Techmer grade should be requested because f1 classification is formulation-specific, not resin-type based.
| Application segment | Critical requirement | Test standard | Typical acceptance window |
|---|---|---|---|
| Automotive mirror bracket | Tensile modulus and weathering | ISO 527-2, ISO 4892-2 | ≥ 5.0 GPa; Δb ≤ 3.0 after 2,000 kJ/m² |
| PV junction box lid | Tracking index and outdoor suitability | IEC 60112, UL 746C f1 | ≥ 500 V; f1 listed |
| Telecom RRU housing | Thermal cycling and impact | IEC 60068-2-14, ISO 179-1 | -40°C to 85°C; ≥ 6 kJ/m² |
| Agricultural fender | Chemical exposure and low-temperature impact | ISO 22088-3, ISO 179-1/1eA | ≥ 6 kJ/m² at -20°C after diesel immersion |
| Outdoor HVAC louver frame | Flexural modulus and UV retention | ISO 178, ISO 4892-2 | ≥ 5.0 GPa; Δb ≤ 4.0 after 2,000 h |
| High-gloss exterior trim | 60° gloss and paint adhesion | ISO 2813, ISO 2409 | Direct molded <75 GU; painted ≥ 80 GU |
Outdoor telecom remote radio unit (RRU) housings and mounting brackets demand a combination of UV resistance, dimensional stability, low creep under clamp load, and resistance to salt fog. The 15 wt% glass loading in HiFill ASA GF15 reduces in-plane CLTE to 35–45 µm/m·K in the flow direction, which limits the clearance change around co-molded sealing grooves during solar heating; unfilled ASA grades with CLTE near 80–90 µm/m·K can generate sufficient thermal bowing to compromise the sealing lip after a single summer cycle. Compliance for salt fog resistance is evaluated by ISO 9227 with 720 h exposure, while outdoor operating life is assessed under Telcordia GR-487-CORE thermal cycling and solar radiation clauses. The housing walls are typically 2.5–3.0 mm, with rib bases at 1.2–1.5 mm and boss outer diameters at 2.0–2.5 times the screw diameter. Drying at 80°C for 4 h to 0.02% moisture is mandatory because the housings often use a hot-runner valve gate with extended residence time; any moisture hydrolyzes the ASA matrix and produces splay that weakens the seal groove weld line. The screw design should be a low-shear general-purpose screw with L/D 20:1 and compression ratio 2.3:1; higher compression above 2.8:1 breaks glass fiber and reduces retained length below 200 µm, which rapidly lowers notched impact and creates fine surface glass dust. On a 2200 kN hydraulic machine, injection pressure is typically 90–110 MPa with holding pressure 50–60 MPa and cooling time 25–30 s at 75°C mold temperature. The sealing groove flatness is inspected after 24 h at 23°C and 50% relative humidity; a flatness limit of 0.3 mm over 150 mm is typical, and parts molded with 10°C mold-temperature variation across the cavity fail this limit. Because radio housings are not high-impact consumer parts, the reduced notched impact of glass-filled ASA relative to unfilled ASA is acceptable if the boss design avoids sharp transitions. Creep under clamp load is evaluated by ASTM D2990 or a short 48 h stress-relaxation test at 60°C and 10 MPa on a rib section; published product-specific creep data for RRU configurations is limited, so generation of a compound-specific master curve is recommended. Flame retardance is the main limitation: a UL 94 5VA rating exceeds unfilled and GF15 ASA without additional halogen-free flame-retardant additives, and any flame-retardant package will shift mechanical properties and narrow the processing window. If 5VA is specified, the design should be validated on a full housing assembly because the glass fiber can create wicking paths that affect flame penetration at knit lines. The radio housing is therefore a suitable downstream segment only when the outdoor standard requires f1 weatherability and a lower flame classification such as HB, or when a metal chassis provides flame containment.
On agricultural tractor fender extensions and stationary pump cowlings, intermittent contact with diesel, hydraulic fluid, dilute fertilizers, and pesticide carriers is the primary performance boundary. ASA retains resistance to many dilute acids and aqueous salt solutions, but the glass-fiber phase does not improve chemical resistance because the styrene-acrylonitrile matrix governs sorption and craze initiation. Components in this segment are typically textured and pigmented black or dark gray, which hides the fiber read-through that prevents use in high-gloss panels. Impact toughness is evaluated by ISO 179-1/1eU at -20°C after 72 h immersion in the service fluid; diesel contact can reduce Charpy impact by 15–25% if the part is molded with high residual stress from the gate area. The injection mold is designed with large-radius transitions of 2.0 mm minimum and rib thickness below 50% of the nominal wall; nominal wall is 3.0 mm for large fender panels. Tool temperature is maintained at 70°C; once the tool surface falls below 60°C, the glass bundles become visible as surface striations oriented in the flow direction. Processing uses medium injection speed and a holding pressure of 45–55 MPa, with cavity pressure sensors in the last fill point to cut over at 40 MPa. The material is not suited for continuous immersion in ester-based solvents or strong ketones; these fluids stress-crack the acrylic phase, and the resulting surface microcracks can propagate along the fiber-matrix interface. Validation for agrochemical exposure is usually conducted per ISO 22088-3 bent-strip method or internal OEM standards; product-specific data for the Techmer grade is limited, so qualification requires exposure to the exact tank-mix formulation at 50°C for 7 days followed by notched Charpy to ISO 179-1/1eA. The UV resistance of ASA is sufficient to prevent significant chalking on black textured surfaces, but color shift is assessed by ISO 4892-2 with 800 h exposure and a ΔE limit of 3.0. The glass fiber causes CLTE to drop by roughly 40–50% relative to unfilled ASA, which is favorable for hoods that span 600 mm or more because thermal bowing is reduced. In production, a common failure mode is ejection pin push marks on the textured surface when the part is ejected too hot; keep the surface temperature below 75°C at ejection or use air poppets rather than pin heads to prevent gloss contrast around the pins.
Outdoor HVAC condensing unit louver frames and fan shrouds are molded from glass-reinforced ASA where the component must hold a screw boss and maintain louver spacing across a large flat panel. The main defect in this application is post-mold thermal creep at the screw boss; the GF15 grade reduces time-dependent strain to a level that accepts low-torque self-tapping screws at 1.0–1.5 N·m without cracking after thermal aging. Creep is assessed by a 24 h clamped boss stress-relaxation test at 70°C or by ASTM D2990; published product-specific creep data should be generated because louver plates are flat and glass orientation can vary. The glass fiber loading improves flexural modulus to 5.0–5.5 GPa when tested to ISO 178, which permits thinner louvers with 2.5 mm wall instead of 3.2 mm in unfilled ASA. The mold is typically a single-cavity tool with a fan gate along the long edge or a valve-gate hot runner to avoid weld lines across the louver span. During filling, fibers orient in the flow direction, so the short transverse direction shows lower tensile strength and higher shrinkage; this is compensated by adding 0.5–1.0 mm of extra stock to the outermost louvers. The tool temperature of 65–75°C is selected to keep the resin-rich skin consistent; temperature variation across the cavity should be held below 5°C or the part warps. Drying at 80°C for 4 h to 0.02% moisture is mandatory; moisture above 0.05% causes surface splay at the fan-gate land. Painting is generally not used; instead the material is pigmented in dark gray or beige and textured lightly. UV performance is defined by UL 746C f1 and accelerated weathering per ISO 4892-2 for 2,000 h; the critical failure is a Δb shift above 4.0 or a loss of flexural strength above 15% after exposure. Because the application is not flame-retardant and not impact-critical at sub-zero temperatures, GF15 is a suitable engineering replacement for painted steel in coastal installations where chloride corrosion is high. The screw boss design should use an outer diameter of 2.0–2.5 times the core hole and a minimum boss wall of 2.0 mm; thinner boss walls crack during self-tapping screw insertion due to the low transverse elongation of glass-filled ASA, which is typically below 2.0% when tested to ISO 527-2.
High-gloss exterior trim remains a boundary condition for HiFill ASA GF15 rather than a primary downstream market. Directly molded components display a visible fiber pattern and a 60° gloss reading substantially below the 80–90 GU threshold required for automotive black trim; typical unfilled ASA can reach 85–95 GU on a polished tool, while 15 wt% glass-filled ASA usually falls below 75 GU when measured to ISO 2813 at 60°. This limitation is an inherent consequence of the fiber bundles aligning near the surface during filling; the resulting heterogeneity appears as a matte, grainy halo around gates and knit lines. Applications that require Class A painted surfaces therefore use GF15 as a structural substrate only when the mold texture depth is at least 30–40 µm, hiding fiber read-through before a two-component acrylic or waterborne basecoat/clearcoat system is applied. Paint adhesion is evaluated by cross-cut per ISO 2409 after 90°C water immersion for 24 h; any release is normally at the fiber-matrix interface, which demands flame or plasma surface activation to raise polar surface energy above 42 mN/m. In applications where an unpainted black textured finish is acceptable, such as cowl covers and wiper motor covers, the glass fiber provides enough stiffness to reduce part mass while the grained surface masks surface imperfections. The operational boundary is narrow: mold temperature must be maintained within ±5°C to keep the thickness of the resin-rich skin stable, because the skin thickness controls both gloss and fiber visibility. At a mold temperature of 60°C, the skin freezes before fiber bundles have moved away from the surface, producing a white-grey surface bloom; at 80°C, the skin is thicker and the surface is smoother, but cycle time increases by 8–12 s. The use of GF15 is therefore deliberately avoided in large unpainted black exterior trim with a flat Class A surface; unfilled ASA or ASA/PC blends are used there. When GF15 is selected for a painted component, the recommended practice is to mold the part with a gate diameter at least 2.0 mm on a 3.0 mm wall and to place the gate in an area that will be covered by an assembly gap or hidden after installation, because the gate frost line cannot be removed by sanding without cutting glass fibers. A final limitation is that high shear in thin walls below 1.5 mm breaks glass fibers and increases fiber-matrix separation, so the compound is not recommended for long-flow, thin-wall decorative trim. This boundary filters many consumer appliance front panels, which require gloss and tight demold tolerances, and routes them to unfilled ASA or ASA/PC rather than GF15.
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