| HS Code | 989746 |
| Product Name | SUMITOMO PP FS5612 |
| Manufacturer | Sumitomo Chemical |
| Polymer Family | Polypropylene (PP) |
| Polymer Type | Random Copolymer |
| Form | Pellets |
| Density | 0.90 g/cm³ |
| Melt Flow Rate 230 C 2 16 Kg | 7.0 g/10 min |
| Tensile Strength At Yield | 31.0 MPa |
| Elongation At Break | 500% |
| Flexural Modulus | 1150 MPa |
| Notched Izod Impact Strength 23 C | 50 J/m |
| Heat Deflection Temperature 0 45 Mpa | 95 °C |
| Vicat Softening Point | 150 °C |
| Melting Point | 155 °C |
| Rockwell Hardness | R95 |
As an accredited SUMITOMO PP FS5612 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Sumitomo PP FS5612 is packaged in 25 kg sealed bags, ensuring safe handling, protection, and easy storage. |
| Container Loading (20′ FCL) | Container Loading (20′ FCL): A 20-foot full container load of SUMITOMO PP FS5612 polypropylene resin, securely packed and shipped. |
| Shipping | SUMITOMO PP FS5612 is a polypropylene resin, generally non-hazardous for transport. Ship in clean, dry containers or lined bags to prevent moisture contamination and physical damage. Avoid prolonged exposure to high heat and direct sunlight during transit. Standard freight handling is suitable, with proper labeling and documentation for polymer shipments. |
| Storage | Store SUMITOMO PP FS5612 in a cool, dry, well-ventilated area, away from direct sunlight, heat sources, and open flames. Keep containers tightly sealed to prevent moisture absorption and contamination. Avoid prolonged exposure to temperatures above recommended limits. Ensure good housekeeping and proper labeling; maintain stable conditions to preserve material quality and safety. |
| Shelf Life | SUMITOMO PP FS5612 has a shelf life of 12 months when stored unopened in a cool, dry place, away from heat, moisture, and direct sunlight. |
In a three-layer BOPP line, Sumitomo PP FS5612 is processed as the core layer between skin streams that carry slip and antiblock additives. The core extruder is profiled from 210 °C in the feed zone to 250 °C at the metering section, with melt filtration through a 250–400 µm screen pack to remove agglomerates that would otherwise create fisheye defects in a film drawn at high ratios. The cast sheet is quenched on a 25–30 °C chill roll at a thickness of 0.35–0.50 mm before entering a machine-direction orienter with heated rolls set at 125–135 °C; a machine-direction draw ratio of 4.6:1 to 5.2:1 is applied. Subsequent transverse stretching in the tenter oven at 155–165 °C uses a TD draw ratio of 8.0:1 to 9.0:1, after which the film is annealed under controlled relaxation of 3–8% to stabilize shrinkage below 2% at 120 °C when tested by ISO 11501. Haze for the oriented homopolymer remains below 2.0% measured by ASTM D1003-21, and dart drop impact on a 18–20 µm final film exceeds 150 g by ASTM D1709-16. For processed food packaging, the converter must verify that FS5612 falls within the olefin polymers specification of 21 CFR 177.1520 and that the finished laminated pouch meets the overall migration limit of 10 mg/dm² under Regulation (EU) No 10/2011 with food simulant D1 or C depending on the product type. Terminal constructions typically pair FS5612-based BOPP core with low-seal terpolymer skins to produce snack flow wrap with seal initiation near 115 °C and a modulus high enough to prevent film flutter on vertical form-fill-seal machinery.
Sumitomo PP FS5612 fed to a cast-film single-screw extruder with a 30:1 L/D barrier screw and Maddock mixing section generates a melt curtain that is edge-pinned before contacting a 750–1,000 mm diameter chill roll. Melt temperature at the die exit is held at 235–255 °C, the slot die gap is set to 0.50–0.70 mm, and the air gap is kept below 30 mm to limit neck-in and gauge spread. Chill-roll surface temperature is controlled at 20–30 °C with a cross-machine water-temperature deviation no greater than ±1.0 °C, because a thermal gradient across the roll translates directly into transverse gauge variation above ±2.0% and downstream ink-picking defects. The cast homopolymer web is not substantially oriented; tensile stress at break is accordingly 35–45 MPa with elongation at break above 500% when measured by ISO 527-3, which limits its use as a primary load-bearing packaging web but supports its role as a dimensionally stable lamination layer. In-line corona treatment at 2.0–3.5 W·min/m² raises the wetting tension to at least 40 dyn/cm determined by ASTM D2578-19, allowing solventless polyurethane adhesive to achieve fiber-tear bond strength in paper/adhesive/PP laminates within 30–90 min. Compliance for non-food pressure-sensitive laminates requires a REACH EC 1907/2006 SVHC statement from the converter, while direct food-contact label stock must comply with 21 CFR 177.1520 and Regulation (EU) No 10/2011. The terminal product is the print-receptive outer ply of clear film labelstock in which FS5612 supplies the die-cutting rigidity that avoids edge burrs on rotary converting lines.
Calcium carbonate masterbatch incorporation into Sumitomo PP FS5612 at 6–15 wt% produces a cavitated BOPP web when the cast sheet is biaxially oriented above the cavitation threshold. The masterbatch carries a median particle size of 1.0–3.0 µm with stearic acid surface treatment to reduce agglomeration; the particles create micropores as the polymer matrix yields around them during simultaneous or sequential stretching. Density of the opaque film falls from 0.90 g/cm³ to 0.55–0.85 g/cm³ when tested by ISO 1183-1, while whiteness and scattering are governed by the cavitation volume fraction rather than the TiO₂ loading, permitting lower inorganic content. The process window is narrow because the draw temperature must remain close to the homopolymer α-relaxation region; if the tenter oven drifts above 165 °C, pore collapse produces a clear streak defect, while below 145 °C film splitting increases above 3% of machine uptime. Cavitated FS5612-based film is used for confectionery wrappers and ice-cream flow packs where the terminal product requires a water-vapour transmission rate below 10 g/m²·day at 38 °C and 90% RH measured by ASTM F1249-20. For food-grade use, the calcium carbonate masterbatch must meet EU Regulation (EU) No 10/2011 specific migration with simulant A or E, and the finished film must comply with 21 CFR 177.1520. Published data for the interaction between FS5612 lot-to-lot isotacticity and cavitation density in a high-speed tenter is limited; converters typically qualify each lot by measuring void density via scanning electron microscopy before full production.
| Application scope | Standard or clause | Test method or condition | Numerical threshold |
|---|---|---|---|
| US food-contact polypropylene film | 21 CFR 177.1520 | Olefin polymer article specification | Compliance with regulated adjuncts |
| EU food-contact polypropylene film | Regulation (EU) No 10/2011 | Overall migration using simulant D1 or C | 10 mg/dm² |
| Melt mass-flow rate | ISO 1133-1:2022 | 230 °C, 2.16 kg | Report against lot CoA |
| Haze of oriented film | ASTM D1003-21 | Transparent film sample | < 2.0% |
| Wetting tension after corona | ASTM D2578-19 | Dyne test fluids | ≥ 40 dyn/cm |
| Tensile stress at break in cast film | ISO 527-3 | Film specimen | 35–45 MPa |
A slot-die extrusion coating line using Sumitomo PP FS5612 as the polyolefin coating layer operates at a melt temperature of 280–310 °C to lower melt viscosity and reduce draw resonance. The coating weight is controlled between 15–35 g/m² through line speed and extruder throughput, with the melt drawn down through an air gap of 150–250 mm onto primed paper or paperboard. Because polypropylene exhibits no inherent polar adhesion, the paper substrate is pre-treated with an aqueous acrylic primer at 0.5–1.5 g/m² dry coat weight, and the melt curtain is exposed to ozone at the die exit to oxidize the surface during the brief air-gap residence. Adhesion is evaluated by a heat-seal delamination test at 180 °C and 1.5 bar for 1 s, with a target bond strength above 3 N/15 mm; failure below this value is traced to insufficient primer drying, low ozone output, or chill-roll release agent contamination. The coated paperboard is used for frozen-food trays and drinking-cup stock where the PP layer provides a moisture barrier and a heat-sealable surface under a peelable lidding film. For direct food contact, the coated structure must meet 21 CFR 177.1520 for the polypropylene and the applicable paperboard migration limits under Regulation (EU) No 10/2011, including overall migration not exceeding 10 mg/dm² with the relevant food simulant. Published data on high-temperature FS5612 coating adhesion at line speeds above 250 m/min is limited, so converters are advised to qualify adhesion at the upper line-speed boundary before commercial run.
Film converting trials in which Sumitomo PP FS5612 replaces a standard BOPP homopolymer for adhesive tape backing require the same sequential orientation sequence but demand tighter control of surface defect density. The film is oriented in the machine direction at 4.8:1 to 5.5:1 and in the transverse direction at 8.5:1 to 9.5:1, yielding a 25–38 µm web with a machine-direction tensile strength above 120 MPa and an elongation at break below 180% when tested by ASTM D882-18. The tape backing is corona-treated to a wetting tension of 42–48 dyn/cm and primed with an aqueous acrylic or solvent-based adhesion promoter before application of a polyacrylate pressure-sensitive adhesive at 18–25 g/m² dry coat weight. In the slitting operation, edge burr formation is minimized when the BOPP web maintains a MD-to-TD tensile modulus ratio between 1.8:1 and 2.2:1; a higher anisotropic ratio causes transverse fracture at the razor slitter and reduces tape roll edge clarity. Terminal product is clear packaging tape where FS5612 provides the splitting resistance needed on high-speed case-erecting equipment, but its use is bounded by the fact that homopolymer backing does not accept low-temperature flexographic inks without primer; attempting to print directly on untreated FS5612 film at speeds above 150 m/min produces ink rub-off below 70% adhesion in the ASTM D3359 tape test. For packaging tape used in food distribution, the finished article must satisfy the same United States and EU food-contact requirements only when the tape is intended for incidental food contact, which is usually assessed under 21 CFR 177.1520 and Regulation (EU) No 10/2011.
Vacuum metallization of Sumitomo PP FS5612-based BOPP film requires the base web to exhibit a smooth surface with root-mean-square roughness below 0.5 µm; otherwise aluminium nucleation is uneven and oxygen transmission rises above the barrier target. The film is oriented at 4.5:1 MD and 8:1 TD, then corona-treated to 42–44 dyn/cm before being wound into a vacuum chamber at pressures below 1×10⁻⁴ mbar. Aluminium is evaporated from a resistively heated boat at 1,450–1,550 °C to deposit a layer of 30–60 nm thickness. Optical density of the metallized film is set at 2.0–3.0 for snack packaging; oxygen transmission rate below 50 cm³/m²·day·bar at 23 °C and 0% RH measured by ASTM D3985-17. Metal adhesion tested by tape peel per ASTM D3359 should retain more than 95% metal. Terminal product is metallized snack wrap and cold-seal lidding in which FS5612 supplies the high modulus that maintains package integrity through the cold-seal tunnel. Compliance for direct food contact is carried by the PP substrate under 21 CFR 177.1520 and Regulation (EU) No 10/2011, while the aluminium layer is controlled by the European Council resolution on metals and alloys for food contact where local legislation applies.
Tenter-frame annealing of Sumitomo PP FS5612 in shrink-film trials introduces a residual shrinkage specification that conflicts with standard BOPP dimensional stability. In this configuration, the transversely drawn film is annealed with 10–20% controlled relaxation at 130–145 °C, producing an oriented web that retains 2–5% free shrink in hot air at 130 °C measured by ISO 11501. The homopolymer’s high crystalline orientation is critical because insufficient relaxation leaves frozen-in stress that releases as uneven heat-shrink during tunnel shrinkage, causing package distortion on collation shrink equipment. The melt feedstock is extruded at 245–260 °C and quenched on a 35–40 °C roll to form a thicker cast sheet of 0.75–1.00 mm before orientation; this thicker preform prevents premature yielding during the MD stretching step. Terminal product is a clear collation shrink film for bundling cans and bottles, where the homopolymer’s stiffness must be balanced against a limited shrink force that can crush lightweight PET containers. For non-food industrial bundling, compliance is limited to REACH EC 1907/2006 and, where applicable, the Packaging and Packaging Waste Directive 94/62/EC heavy-metal limits of 100 ppm total for lead, cadmium, mercury, and hexavalent chromium. This application remains process-sensitive; published data specific to FS5612 in collation shrink film is limited, and converters should evaluate residual shrinkage after each lot change because isotacticity variation shifts the annealing response.
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SUMITOMO PP FS5612 is a high-flow heterophasic polypropylene impact copolymer supplied as free-flowing pellets for injection moulding applications that require a balance of stiffness, ambient-temperature impact resistance, and fast cavity filling. The grade is not a homopolymer: the dispersed ethylene-propylene rubber phase increases impact crack-energy absorption at the expense of some rigidity and transparency. Under ISO 1133-1:2022, the melt mass-flow rate is typically 56 g/10 min at 230 °C with a 2.16 kg load. Density determined according to ISO 1183-1:2019 is approximately 0.90 g/cm³. The values below are supplier-published typical property data and are not batch-release specifications.
| Property | Test method | Typical value |
|---|---|---|
| Melt mass-flow rate, 230 °C/2.16 kg | ISO 1133-1:2022 | 56 g/10 min |
| Density | ISO 1183-1:2019 | 0.90 g/cm³ |
| Tensile yield stress | ISO 527-2:2012 | 26 MPa |
| Tensile strain at yield | ISO 527-2:2012 | 5 % |
| Flexural modulus | ISO 178:2019 | 1450 MPa |
| Notched Charpy impact strength, 23 °C | ISO 179-1/1eA:2023 | 7.0 kJ/m² |
| Heat deflection temperature, 0.45 MPa | ISO 75-2:2013 | 95 °C |
| Moulding shrinkage, longitudinal | ISO 294-4:2018 | 1.0–1.4 % |
A melt temperature of 200–250 °C is appropriate for most injection moulding operations using general-purpose screws. Peak melt temperatures above 270 °C initiate oxidative chain scission in unstabilised hold-up zones; the practical indicators are surface splay, yellowing, specks, and a measurable reduction in notched Charpy impact strength. Mould temperature is normally held between 20 °C and 60 °C. Higher mould surface temperatures increase weld-line strength and gloss transfer, but they also raise cycle time and may accentuate differential shrinkage in thick bosses. Pellets stored in closed hoppers at relative humidity below 60 % usually do not require pre-drying. When hopper condensation or outdoor storage exposes the pellets to surface moisture, drying at 80 °C for 2–4 h with a desiccant dryer is recommended because vaporising surface water at the melt front can generate flow lines and silver streaks. Injection machines with screw L/D ratios of 20:1–24:1 and compression ratios of 2.5:1–3.0:1 are typical for this product. General-purpose three-zone screws are sufficient unless a high colorant or filler dispersion requirement demands a mixing barrier. Production-scale experience with high-flow PP impact copolymers indicates that short-shot defects in wall sections below 1.2 mm are more often caused by delayed velocity-to-pressure switch-over or undersized vents than by the melt viscosity of the base resin. Gate freeze-off is rapid in this grade, so hold-pressure duration should be confirmed by part-weight stability across at least 50 consecutive shots. Hot-runner processing is acceptable, but nozzle residence above 250 °C for more than 10 min during interruptions can generate gel bodies that later release as surface defects.
Under tensile loading according to ISO 527-2:2012, moulded specimens typically show a yield stress of 26 MPa and strain at yield of 5 %. Flexural modulus tested under ISO 178:2019 is approximately 1450 MPa, placing FS5612 below a high-flow PP homopolymer in stiffness but above many lower-flow impact copolymers in melt fluidity. Notched Charpy impact strength at 23 °C is reported at 7.0 kJ/m² using ISO 179-1/1eA:2023. At 0 °C the value decreases to approximately 3.0–3.5 kJ/m², and at −20 °C it can fall below 2.5 kJ/m². This ductile-to-brittle transition is normal for heterophasic copolymers and means that load-bearing components intended for sub-zero service should be validated by instrumented puncture or falling-weight impact on the actual moulded geometry rather than on standard test bars. Heat deflection temperature under 0.45 MPa flexural load in ISO 75-2:2013 is around 95 °C; this short-term thermal index is not a continuous-use temperature. The material is not inherently flame retardant. Unmodified polypropylene is commonly classified as UL 94 HB, and components requiring UL 94 V-0 or V-1 must use a compounded flame-retardant variant. In unpigmented form, the base resin may be acceptable for olefin polymer food-contact use under FDA 21 CFR 177.1520, provided migration and end-use temperature conditions are evaluated on the finished article. For medical devices, ISO 10993 biological qualification is not established unless separately tested on the final device configuration.
A melt mass-flow rate of 56 g/10 min places FS5612 in the low-viscosity injection moulding range, but MFR alone does not define cavity-filling behaviour. The shear-thinning slope of the viscosity curve controls pressure drop in thin-wall runners, gates, and ribs. FS5612 is selected where flow-length to wall-thickness ratios above approximately 150:1 are required, although published spiral-flow data for this specific configuration is limited; short-shot studies on the production tool are therefore required before high-cavitation tooling is accepted. Compared with a lower-flow PP impact copolymer of MFR approximately 20 g/10 min, FS5612 can reduce peak injection pressure in a 1.5 mm nominal wall part by an estimated 10–20 % depending on gate geometry, melt temperature, and injection velocity. The lower pressure demand may allow higher cavitation or may permit a lower clamp-force press, but the predicted gain must be verified by cavity-pressure measurement. High melt flow also shortens the effective packing time because the gate freezes rapidly; therefore the hold-pressure profile must be set from cavity-pressure decay rather than from generic machine settings. Longitudinal mould shrinkage under ISO 294-4:2018 is generally 1.0–1.4 %, with the actual value dependent on wall thickness, filler content, nucleating additives, and local packing. Warpage in flat lid or battery-housing geometries is controlled by uniform wall sections, symmetrical cooling, and gate placement that avoids unidirectional flow-induced orientation.
Relative to a general-purpose PP homopolymer of equivalent melt flow, FS5612 exhibits lower flexural modulus and slightly lower short-term heat resistance but substantially higher notched impact strength. The rubber phase increases energy absorption during crack propagation but also increases light scattering; translucent, transparent, and high-clarity applications are therefore outside the functional envelope of this product. Compared with a lower-flow PP impact copolymer grade, FS5612 provides better thin-wall filling and shorter cycle times for complex multi-cavity tools. The lower-flow impact copolymer usually retains better low-temperature impact and better environmental stress-crack resistance in snap-fit arms, integral hinges, and under-hood chemical contact. For applications requiring ductile failure at −20 °C, FS5612 should not be specified unless the part has been validated by instrumented impact testing and the wall section is sufficient to suppress brittle fracture. Conversely, for ambient-temperature thin-wall connectors, brackets, appliance frames, and industrial covers, FS5612’s higher flow reduces sink marks and improves dimensional consistency when packing is correctly optimised. The main difference from a PP homopolymer with the same MFR is not flow but the impact-to-stiffness balance; homopolymer grades deliver higher modulus and hardness, while FS5612 delivers greater tolerance to crack initiation from notch features such as weld lines, ejector pins, and sharp ribs.
When the moulded component includes snap-fit arms, living hinges, or sub-zero drop impact, a lower-flow PP impact copolymer should be evaluated before FS5612 unless the grade is compounded with an additional elastomer or impact modifier. The trade-off is structural, not simply rheological. Lower-flow impact grades often contain a higher ethylene content and a more deformable dispersed phase, which lowers the ductile-to-brittle transition temperature. In FS5612, the high melt flow is achieved partly through molecular weight control and a controlled rubber-phase morphology, but the practical consequence is a coarser stress-field response at low temperature. Injection moulders can partly compensate through balanced hot-runner delivery, generous radii at sharp corners, and weld-line placement away from load-bearing zones. However, the material’s high flow should not be used to justify excessively thin walls below 1.0 mm. In such sections, rapid solidification during filling creates residual orientation and weak weld lines that no base-resin flow grade can eliminate. Mould-filling simulation packages require grade-specific pressure-volume-temperature data and viscosity coefficients; generic PP data may under-predict fill pressure by 5–10 %. Process parameters derived from simulation should therefore be confirmed with a production trial using cavity-pressure sensors.
Polypropylene impact copolymers produced in commercial gas-phase or bulk-slurry trains exhibit lot-to-lot variation in melt flow rate, rubber content, and additive levels. For FS5612, the melt mass-flow rate should be controlled within the supplier’s release limits under ISO 1133-1:2022. Moulders running high-speed packaging or automotive programmes should monitor incoming MFR and notched Charpy impact on dried or conditioned specimens because changes in MFR of ±3 g/10 min can shift the gate-seal time and alter the optimum hold-pressure window. Injection moulding trials on machines with clamp force between 1500 kN and 3500 kN show that shot-to-shot weight consistency is usually achievable when cushion is maintained at 3–6 mm and screw recovery speed is limited to avoid excessive shear heating. Back pressure is typically held at 0.5–2.0 MPa, with lower values preferred for heat-sensitive colorants. Higher back pressure improves colour dispersion but raises melt temperature and may degrade the rubber phase if residence time is prolonged. Process capability indices for critical dimensions are often influenced more by gate geometry and cooling layout than by the nominal MFR of the resin. Where colour concentrate or regrind is introduced, the final compound may differ from the base-resin property table; the addition of 20 % regrind, for example, can alter flow and impact properties, and the finished-part approval should be performed on the actual compound used in production.
For appliance housings, power-tool bodies, automotive interior brackets, and industrial battery covers, FS5612 is typically processed with wall thicknesses of 2.0–3.0 mm. Rib thickness should not exceed 50–60 % of the nominal wall to reduce sink-mark risk. Gate design is critical: a fan gate or tab gate with land length of 0.5–1.0 mm is preferred because small pinpoint gates combined with high injection velocity can generate jetting, visible as worm-like surface marks downstream of the gate. The material is compatible with conventional pad printing, painting, and adhesive bonding only after surface treatment by corona or flame; polypropylene has a low surface energy, typically below 38 mN/m untreated, which impairs wetting and adhesion. For interior automotive parts, a low-emission stabilizer package may be required depending on the vehicle manufacturer’s VOC specification. Published data for this specific FS5612 configuration in low-emission compounds is limited; therefore, if interior odour or fogging limits are mandated by the OEM, the moulder must qualify the compounded pellet source against methods such as VDA 278 or ISO 12219-2. Outdoor service is not recommended for unpigmented or unstabilised natural resin because polypropylene degrades by photo-oxidation, causing surface chalking and embrittlement. UV-stable black or custom-compounded variants using carbon black or hindered amine light stabilisers are required for exterior parts.
Regulatory status for the base resin is normally established under EU REACH Regulation 1907/2006 and the RoHS Directive 2011/65/EU for unpigmented grades; finished-part compliance depends on colorants, additives, and processing aids introduced during conversion. Strong oxidising acids, chlorinated solvents, and some mineral oils can cause environmental stress cracking or surface softening in stressed polypropylene parts. Compatibility must be tested under actual load, temperature, and chemical exposure rather than inferred from immersion coupons alone. Continuous service above 80 °C in air can deplete the antioxidant package over time; long-term heat ageing at 150 °C is not recommended without grade-specific oven-ageing data. The material should not be dried with hot-air hoppers that exceed 80 °C for extended periods because pellet surface oxidation can occur. In purge cycles, a transition material such as low-MFR polypropylene or commercial purging compound should be used before shutdown to displace FS5612 from the barrel. This practice reduces carbonised residue and shortens restart recovery time. Processing with excessive shear and high melt temperature will preferentially degrade the rubber phase, reducing impact performance even when tensile properties appear acceptable; incoming QA should therefore include notched impact testing after significant process interruptions.