| HS Code | 336604 |
| Product Name | Sinopec Shanghai Gaoqiao ABS 345 |
| Manufacturer | Sinopec Shanghai Gaoqiao Petrochemical Co., Ltd. |
| Grade | 345 |
| Polymer Type | Acrylonitrile-butadiene-styrene copolymer (ABS) |
| Appearance | Natural-color pellets |
| Processing Method | Injection molding |
| Density | 1.05 g/cm³ |
| Melt Flow Rate | 3.5 g/10 min (220 °C/10 kg) |
| Tensile Strength | 45 MPa |
| Elongation At Break | 20% |
| Flexural Modulus | 2200 MPa |
| Flexural Strength | 65 MPa |
| Notched Izod Impact Strength | 18 kJ/m² |
| Vicat Softening Temperature | 95 °C |
| Heat Deflection Temperature | 85 °C (1.82 MPa) |
| Rockwell Hardness | 100 R scale |
| Molding Shrinkage | 0.5% |
As an accredited Sinopec Shanghai Gaoqiao ABS 345 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Sinopec Shanghai Gaoqiao ABS 345 typically comes in 25 kg moisture-resistant woven bags, palletized for industrial shipment. |
| Container Loading (20′ FCL) | Sinopec Shanghai Gaoqiao ABS 345 is securely loaded into a 20-foot FCL container under dry, stable conditions for shipment. |
| Shipping | Sinopec Shanghai Gaoqiao ABS 345 is a non-hazardous acrylonitrile butadiene styrene resin. It is typically shipped in 25 kg woven bags or jumbo bags, palletized and stretch-wrapped. Keep dry, away from direct sunlight, heat, and moisture, and protect from contamination during transport and storage. |
| Storage | Store Sinopec Shanghai Gaoqiao ABS 345 in a cool, dry, well-ventilated warehouse, away from direct sunlight, heat sources, and moisture. Keep containers or bags sealed and palletized to prevent contamination and deformation. Avoid open flames and ignition sources. Use clean handling equipment and follow first-in, first-out stock rotation. |
| Shelf Life | Typically 12 months when stored unopened in original packaging under cool, dry, well-ventilated conditions, away from direct sunlight. |
Sinopec Shanghai Gaoqiao ABS 345 is specified for instrument panel trim, centre console side panels, door handle bezels and steering column covers where thin-wall sections meet snap-fit retention requirements. The resin is processed on toggle-clamp injection moulding machines in the 1,200–3,000 kN range with screw diameters of 30–50 mm and an L/D ratio of 20:1. A shut-off nozzle is mandatory because the melt has low viscosity and can drool during carriage retraction. The melt temperature is held at 230–250°C; the mould temperature is held at 40–70°C. When the melt temperature falls below 230°C, visible flow lines appear on grained surfaces. When the melt temperature exceeds 250°C, the gate area shifts toward a yellow-white blush and residual monomer odour increases. This is the primary thermal processing window for unpainted cabin trim.
Desiccated drying is conducted at 80–90°C for 2–4 h in a bed with a dew point of −40°C or lower. Final moisture content above 0.02 wt% results in silver streaking at the flow front and a dull cloud on the textured surface. The same moisture level produces intermittent blistering behind the gate after painting. Dryer outlet moisture is interlocked with the machine control. If the dryer reaches 0.03 wt%, the hopper loader stops and the screw is pulled back automatically. In high-humidity plants where ambient relative humidity exceeds 60%, open conveyors are not permitted between the dryer and the feed throat.
Gloss variation is controlled by turbulent water cooling through the cavity plates. At a mould temperature above 70°C, sink marks deepen around the base of snap-fit ribs and the surface becomes too glossy for OEM grain specifications. At a mould temperature below 40°C, the grained surface loses texture transfer and the gate region can delaminate during demoulding. Closed-loop mould-temperature control within ±5°C is used for production. Cooling time is set so that the part ejects below its Vicat softening point by at least 20°C. Ejection above that limit causes ejector pin push-outs and post-mould warpage.
For cabin interior emission compliance, parts are annealed at 70–80°C for 2 h before VDA 278 testing. Annealing strips residual process volatiles and reduces total VOC output under OEM limits that commonly fall in the 50–150 µg/g band, depending on the vehicle platform. Published data for this exact grade under VDA 278 is limited; therefore each OEM program validates lot-to-lot variability on a quarterly basis. Unpainted ABS 345 is not used for high-wear visible surfaces without a grain depth of at least 0.05 mm, because smooth surfaces show whitening under a 10 N scratch stylus within the first cycle.
In white goods enclosure programs, ABS 345 is released for washing machine control panel frames, detergent drawer fronts, vacuum cleaner bodies and small appliance enclosure cladding that do not demand inherent flame retardancy. The base resin is not a brominated or halogen-free FR grade. Under UL 94, unfilled mouldings are evaluated as HB at a section thickness of 3.0 mm. A V-0 classification should not be inferred from the grade name; any V-0 listing belongs to a separately compounded formulation and requires revalidation on the injection line because flame-retardant packages shift melt viscosity and screw torque.
Filling analysis for a washing machine detergent drawer front with a flow path of 300–350 mm at 2.5 mm wall shows stable cavity filling at a melt temperature of 240°C and a mould temperature of 50°C. Packing pressure is maintained at 35–55 MPa hydraulic for 3–5 s to reduce sink over internal ribs. The rib height is limited to 3×nominal wall for structural bosses, and the rib root radius is kept above 0.8 mm to avoid stress concentration at the base.
Chemical contact is limited to short-term spills from detergent, bleach and fabric softener solutions. ABS is attacked by ketones, esters, aromatic hydrocarbons and some chlorinated solvents. Methyl ethyl ketone, a common solvent cement component, causes surface crazing and stress cracking if contact occurs on a stressed snap-fit hook. Therefore the gate location is moved away from snap-fit terminals, and the snap-fit deflection is designed below 2% outer fibre strain. For appliance housings that face repeated cleaning with isopropanol, validation includes a 30-minute surface wipe test with IPA under no external load. Visible whitening constitutes a reject.
Large flat panels in white goods are sensitive to flow-front speed. The recommended melt front velocity is 80–120 mm/s. Below 80 mm/s the grained surface shows hesitation lines around the edge vents. Above 120 mm/s the end of fill traps air and produces gas burn marks. In production, the converter uses a sequentially opened valve-gated hot runner to keep the melt front speed within this band. The hot runner manifold temperature is set at 230–245°C. If the manifold goes above 250°C, the material yellows at the valve gate and creates visible streaks.
Router lower shells, set-top box covers, power strip bases and patch panel frames are moulded from ABS 345 in ambient indoor service. The grade is not specified for outdoor radome or antenna skins, because unreinforced ABS lacks sufficient ultraviolet stability for long-term weathering. In IEC 62368-1 evaluations, the unfilled moulding is treated as a decorative or mechanical enclosure, not as a fire enclosure, unless the power source is limited by the end-product standard.
Mechanical release is checked with ASTM D638-14 for tensile yield and ASTM D256-23 for notched Izod. Typical values for unreinforced ABS fall in the 40–50 MPa tensile-yield band and 200–300 J/m notched-Izod band at 23°C. These ranges are used for initial snap-fit spring-rate calculations only. Lot-specific certificates from the supplier carry the actual values. At a wall thickness of 2.0 mm, the draft angle on bosses is kept at 1.0° minimum to reduce ejection drag and avoid stress whitening around the boss.
The moulding window is tighter than standard packaging containers because the housing must pass a drop test with the installed printed circuit board. Ribs under the board mount use a rib thickness of 0.5–0.7×wall to avoid sink marks on the outer cover. The gate is placed away from sidewall screw bosses. If a weld line crosses an impact-absorbing snap-fit, notched impact retention at the weld line can fall by 30–40% relative to un-welded material. For that reason the tool design uses multiple sub-gates with a runner balancing tolerance of ±2%.
Flammability is a threshold issue. The base ABS 345 is not a low-smoke formulation. Smoke density under ISO 5659-2 is not claimed from the base resin. If the product specification requires a halogen-free FR package with a smoke density below a given DM value, the compound is manufactured separately, and the injection moulder must requalify flow length, mould deposit and gas venting. Handlers should avoid blending with halogen-containing regrind from unknown sources, because a mixed stream can compromise the halogen-free declaration under RoHS 2011/65/EU.
| Compliance Area | Standard / Test Method | Relevant End Use | Typical Acceptance Basis |
|---|---|---|---|
| Heavy metals and brominated flame retardants | RoHS 2011/65/EU Annex II | Electronic enclosures | Supplier declaration per lot; screening by XRF |
| Flammability classification | UL 94 | Electronic and appliance housings | HB minimum; V-0 only for separate FR compound |
| Toy migration of elements | EN 71-3 | Toy and board-game components | Certificate from polymer supplier |
| Automotive interior emissions | VDA 278 | Instrument panel trim | OEM-specific VOC and fog limits |
| Plastics piping systems for ABS | ISO 15493 | Solvent-weld fittings | Hydrostatic design and dimensional fit |
| Tensile and impact release | ASTM D638-14, ASTM D256-23 | General structural release | Lot-specific certificate values |
In toy brick, board-game frame, storage case and child-resistant closure applications, ABS 345 is processed in multi-cavity tools with edge sub-gates and ejector sleeves. The melt temperature is 230–250°C; the mould temperature is 40–60°C. The material is dried at 80°C for 2–4 h to below 0.02 wt% moisture. Masterbatches are pre-blended at 2–4 wt%. The blend is dried again because some masterbatch carriers are hygroscopic and can raise moisture above the base resin limit.
Filling balance is critical because toy tools often use 16–64 cavities. The runner system is balanced to within ±1.5% volumetric fill using pressure drop software or short-shot study. If one cavity fills early, that cavity overpacks and the remaining cavities show sink marks. Holding pressure is set at 25–45 MPa and held for 2–4 s. A screw back pressure of 0.5–1.0 MPa is applied to improve masterbatch dispersion without overheating the melt.
Regulatory release for toy applications requires compliance with EN 71-3 for migration of certain elements and REACH Annex XVII entries covering phthalates in toys and childcare articles. ABS 345 is supplied under a declaration that the polymerization and finishing system does not contain the restricted phthalates covered by entries 51 and 52 of Annex XVII. Incoming lot certification is required because additive packages can change without notice. Published data for this specific grade’s migration output is limited; brand owners routinely run independent extraction on first production shots.
Snap-fit design uses a tensile modulus of 2.0–2.4 GPa from ASTM D638-14 for hinge spring-rate calculations. Unreinforced ABS shows ductile behaviour at room temperature. At 0°C, notched impact falls, so products rated for outdoor winter use are either impact-modified or thickness-restricted above 2.5 mm. No low-temperature impact claim is made for the base grade under ISO 180 without validation on the actual part.
When solvent-welded ABS fittings are produced from ABS 345, moulded-in stress is the principal process risk. The part is used for injection-moulded socket fittings, adapters and small-bore fittings in drain-waste-vent systems. Dimensional requirements follow ISO 15493 or ASTM D3965, depending on the regional market. The socket taper is formed by a collapsible core or an unscrewing core. The solvent cement used on site contains methyl ethyl ketone and acetone. The ester and ketone components attack stressed areas and can produce environmental stress cracking in the socket heel.
The melt temperature is kept at 235–250°C and the mould temperature is held at 50–70°C to reduce frozen-in orientation. Packing pressure is limited to 30–45 MPa. High packing pressure creates dimensional compliance during ejection but leaves stress near the gate. When the socket is later exposed to solvent cement, the stress releases as cracks at the base of the socket. A low and controlled packing profile is preferred over high pressure, even if the mould must use a longer holding time of 5–8 s to control sink.
The gate location is placed on the spigot end, not on the socket throat, so that the melt front reaches the socket heel last. The optimal melt-front speed in the socket wall is 40–120 mm/s. Below 40 mm/s the heel freezes and creates a weak weld line at the socket bottom. Above 120 mm/s the gate area overpacks and the fitting shrinks away from the plug gauge after 24 h. Ovality on a 32 mm socket is held below 0.15 mm by cooling the core to 40°C below the cavity temperature and delaying ejection until the part reaches 80°C or lower measured at the core.
Long-term hydrostatic design is not inferred from injection moulding alone. The fitting lot is released through notched Izod, Vicat softening and solvent-cement compatibility testing. Published data for this specific grade under ISO 15493 long-term hydrostatic evaluation is limited; therefore pipeline certification is based on the fitting manufacturer’s own type tests. Regrind is restricted to 15 wt% or less in pressure-bearing fittings to preserve stress-crack resistance.
For injection-moulded luggage wheel housings, telescopic handle frames, corner guards and internal stiffener frames, ABS 345 is processed with conventional water-cooled tools. Full shell thermoforming uses an extrusion-grade ABS of different molecular weight. The injection grade is selected for ribs, bosses and latch attachment points that require accurate dimensions and repetitive impact resistance. The grade is dried to 0.02 wt% moisture or lower before processing. Melt temperature is 235–250°C and mould temperature is 45–65°C.
Drop-impact mapping is performed on complete luggage after conditioning at −20°C for 4 h. The test focuses on wheel housing bosses, corner guards and the telescopic handle guide. Unreinforced ABS shows a drop in notched impact at low temperature. The transition from ductile tearing to brittle cleavage is influenced by part thickness and weld-line location. A gate weld line crossing the axle boss can reduce impact resistance by 30–40% relative to un-welded material, so the axle boss is gated separately or the weld line is shifted to the inner side of the boss.
Rib design follows a rib thickness of 0.5–0.7×wall for acceptable surface quality. The base wall is 2.2–2.5 mm in wheel housings. Gas-assisted moulding is not used with ABS 345 in these ribbed parts because surface haze appears near the gas channels and the melt viscosity is not high enough for stable gas penetration in thin sections. Sequential valve gating is preferred for long handle guides with a flow path of 400 mm or more.
The material is not weatherable. Long-term outdoor exposure causes colour shift and loss of gloss. Exposed luggage shells are therefore painted, hard-coated or covered with fabric overlays. Internal frames and wheel housings are shielded from direct sunlight and operate within the material’s service window. If the luggage specification requires impact at −30°C or lower, a separate low-temperature impact-modified grade should be evaluated, because published data for this grade under those conditions is limited.
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Sinopec Shanghai Gaoqiao ABS 345 is an acrylonitrile-butadiene-styrene graft copolymer produced for injection moulding conversion. The resin consists of a continuous styrene-acrylonitrile matrix with discrete grafted polybutadiene rubber particles, supplied as natural or pre-coloured pellets. The grade is intended for technical parts requiring a controlled balance of impact resistance, heat deflection and dimensional stability under load. Published data for this specific configuration is limited in independent repositories; the property envelope presented below is a representative general-purpose Gaoqiao ABS range and must be reconciled with a current manufacturer batch certificate before tooling design or purchase approval.
The material is not classified as a self-extinguishing or UV-stable product in its unmodified form. Its principal differentiator within the Sinopec Shanghai Gaoqiao portfolio is the intended general-purpose injection moulding position, rather than a specialised high-flow, electroplating or high-heat designation. The butadiene rubber content, molecular mass of the SAN matrix and additive package are selected for balanced melt toughness and room-temperature impact retention after conventional melt processing.
The Gaoqiao ABS family is separated primarily by melt volume-flow rate, rubber morphology and additive tuning. High-flow grades such as ABS 8391 are formulated for thin-wall moulding, with melt volume-flow rate under 220 °C/10 kg conditions typically exceeding 20 cm³/10 min when measured by ISO 1133-1:2022. In contrast, ABS 345 is described in trade literature as a general-purpose grade, which conventionally places its melt volume-flow rate in a lower range, often 8–18 cm³/10 min for comparable general-purpose ABS resins in the same product family. The lower flow envelope generally corresponds to higher melt viscosity and higher molar mass SAN, improving notched impact retention but reducing spiral flow length at equal injection pressure.
Compared with ABS 8434, an electroplating grade, ABS 345 is not optimised for chromic acid etch pre-treatment, selective rubber-phase removal or palladium catalyst uptake. Plating-grade ABS requires controlled polybutadiene particle-size distribution and gel content so that etch cycles create mechanical anchoring sites without excessive surface roughness. ABS 345 does not carry the same electroplating-specific morphology specification in public trade documentation. For microcellular or chemically foamed structures, the absence of a documented nucleation package in ABS 345 means that cell density and cell-size distribution are less predictable than with purpose-designed foam grades. Published data for ABS 345 in foaming applications is limited.
When a precise flow-length ratio is required, mould-filling simulation should use measured melt-density and pvT data from the current batch. The lower-flow character of ABS 345 can force a reduction in flow-length-to-wall-thickness ratio to avoid short shots in thin ribs or long drawdowns. In practical injection moulding, flow length is also tool-specific and depends on gate geometry, injection speed and mould temperature; no single ISO spiral-flow value can substitute for simulation using grade-specific viscosity data.
ABS is hygroscopic to a limited extent, but surface moisture is the dominant processing risk. Pellet moisture above 0.1% by weight is sufficient to produce splay, silver streaking, weld-line porosity and inconsistent surface gloss. Pre-drying in a desiccant dryer with a dew point below −20 °C is recommended at 80–85 °C for 2–4 h, with the longer residence time applied when ambient relative humidity exceeds 60% or when regrind is present. The use of hot-air tray dryers is generally inadequate because the final pellet moisture equilibrium depends on air dew point, not air temperature alone.
The melt-temperature window for ABS 345 should be held at 220–250 °C, with mould temperature typically set between 40 °C and 80 °C depending on required surface finish and dimensional stability. The practical processing window narrows when the part requires high-gloss appliance surfaces. In those applications, melt-temperature variability should be controlled to approximately ±5 °C around the set point because the polybutadiene phase begins to undergo oxidative crosslinking and chromophore formation at elevated temperatures, producing yellowing and loss of impact. Residence time at melt temperature above 250 °C should not exceed 5 min. During machine stoppages, purging with general-purpose polystyrene or SAN reduces stagnation of the rubber phase in the barrel and hot-runner manifold.
Mechanical blending of ABS 345 with colour masterbatch or pelletised additives does not require aggressive high-shear dispersive mixing; uniform blending in a low-speed tumbler for 15–30 min before drying is adequate.
Screw recovery conditions on reciprocating-screw injection moulding machines should use L/D ratios of 20:1 to 24:1 and compression ratios of 2.0:1 to 2.5:1. Back pressure should be set between 0.5 MPa and 1.5 MPa, with screw surface velocity typically below 0.5 m/s for unfilled ABS. Excessive screw speed raises melt temperature by viscous dissipation, particularly at the screw tip and non-return valve. In twin-screw compounding or pelletising operations, screw speeds above 300 min⁻¹ are generally unnecessary for ABS 345 and may induce shear heating that exceeds the degradation threshold of the butadiene phase.
Property retention after multiple heat histories should be verified using notched Izod impact according to ISO 180:2019 and melt volume-flow rate according to ISO 1133-1:2022. If regrind is used, a starting limit of 20% by weight is typical for general-purpose ABS, provided that impact and colour stability are validated on production parts. Higher regrind fractions may shift the melt-flow distribution and reduce long-term thermal stability.
The indicative property envelope for general-purpose Gaoqiao ABS grades is shown in Table 1. These ranges are not certified ABS 345-specific values and are provided only for preliminary feasibility assessment.
| Property | Test method | Indicative range |
|---|---|---|
| Density | ISO 1183-1:2019 | 1.03–1.06 g/cm³ |
| Melt volume-flow rate | ISO 1133-1:2022, 220 °C/10 kg | 8–18 cm³/10 min |
| Tensile yield stress | ISO 527-2:2012 | 38–48 MPa |
| Notched Izod impact, 23 °C | ISO 180:2019 | 20–35 kJ/m² |
| Vicat softening temperature, B50 | ISO 306:2022 | 94–102 °C |
| Heat deflection temperature, 1.8 MPa | ISO 75-2:2013, method A | 82–92 °C |
The property table is deliberately comparative and cannot replace a supplier certificate of analysis. Batch-to-batch variance in rubber particle-size distribution, gel content and antioxidant loading can shift notched impact and Vicat values by several units even when the resin designation remains unchanged.
Applications for ABS 345 in South-East Asian injection moulding operations concentrate in appliance housings, electrical enclosures, vacuum-cleaner bodies, toys and light-duty automotive interior trim. Wall thicknesses for these applications commonly range from 2.0 mm to 3.5 mm. The material is selected when a balance of room-temperature impact and heat resistance is required without the cost of polycarbonate/ABS blends. Gate freeze time and packing pressure must compensate for the higher bulk viscosity of a general-purpose ABS grade. In multi-cavity tools, cavity-to-cavity pressure variation can be magnified by the lower flow length of ABS 345 relative to high-flow grades. Pressure transducer data from actual hot-runner manifolds shows that melt-pressure loss increases with flow-path length and reduced melt temperature, so hot-runner set points should be referenced to melt-temperature measurements at the nozzle, not only to barrel set points.
For extrusion conversion, ABS 345 can be considered only when melt strength and drawdown behaviour are validated against specific die pressure and haul-off conditions. The manufacturer positions the grade primarily for injection moulding, and published data for sheet extrusion or profile extrusion of ABS 345 is limited. If the material is used for extruded sheet, the melt-temperature profile should be tightly controlled from the feed throat to the die lip to avoid rubber-phase degradation at the screw root. Existing processor observations suggest that a practical die melt-temperature band of ±5 °C is needed for consistent gauge and surface appearance in sheet lines, although a grade-specific dataset for ABS 345 has not been widely reproduced in public literature.
Unmodified ABS is combustible and does not carry an inherent UL 94 V-0 classification. ABS 345, as a general-purpose grade, should not be specified for power-distribution enclosures or electronic components requiring self-extinguishing behaviour unless a flame-retardant masterbatch or compounded variant is explicitly certified. Even then, dilution of a flame-retardant concentrate into an unmodified resin may alter UL 94 performance, and certification must be re-established on the final moulded part with the specified wall thickness and formulation. The relevant test is UL 94, usually performed under IEC 60695-11-10 or ASTM D3801 conditions, although the specific test procedure depends on the end-product standard.
Outdoor exposure is another boundary condition. ABS undergoes photodegradation of the polybutadiene phase under ultraviolet radiation, causing chalking, yellowing and impact loss far sooner than acrylic-capped or ASA-based materials. ABS 345 should not be used for unpainted exterior trim where UV exposure exceeds incidental sunlight through glazing. If outdoor weatherability is required, ASA, acrylic capstock or UV-stabilised custom compounding should be evaluated. Standard accelerated weathering tests such as ISO 4892-2:2013 or ASTM G154 can discriminate between general-purpose ABS and weatherable grades, but the published data for ABS 345 under these protocols is limited.
Chemical resistance follows general ABS behaviour. The resin is sensitive to ketones, esters, aromatic hydrocarbons and some chlorinated solvents. Environmental stress cracking under mechanical load can occur in contact with aggressive media. Compatibility with cleaners, adhesives and lubricating greases must therefore be validated on the final part. No solvent compatibility statement for ABS 345 should be generalised across grades without batch-specific testing under the intended stress state.
Procurement documentation for ABS 345 should require batch-specific declarations rather than relying on generic portfolio statements. The compliance matrix in Table 2 lists the regulatory areas that must be confirmed before use in commercial products. The manufacturer should supply current analytical reports or declarations, and the user remains responsible for verifying that the specific formulation, including any colour masterbatch or regrind, does not alter the regulatory status of the finished article.
| Regulatory domain | Standard or regulation | Required verification |
|---|---|---|
| EU RoHS restricted substances | Directive 2011/65/EU, Annex II | Batch analytical report for lead, cadmium, mercury, hexavalent chromium, PBB, PBDE |
| EU REACH SVHC communication | Regulation (EC) No 1907/2006, Article 33 | Supplier SVHC statement or SDS confirmation |
| China ABS resin product specification | GB/T 12670-2008 | Batch certificate of analysis |
| Food-contact suitability, if applicable | EU 10/2011 or FDA 21 CFR 177.1020 | Specific migration testing and supplier compliance letter; do not assume compliance |
| UL flammability classification, if required | UL 94 or IEC 60695-11-10 | Recognised component or end-product certification |
Because additive migration kinetics in polymer matrices are governed by matrix polarity, free-volume distribution and additive molecular weight, any substitution of colourants, plasticisers or impact modifiers must be treated as a new regulatory condition. Procurement specifications should therefore treat batch-specific certification as the operative boundary for ABS 345 use in commercial parts.