| HS Code | 220712 |
| Polymer Type | Metallocene linear low-density polyethylene |
| Density | 0.927 g/cm³ |
| Melt Flow Rate 190c 2 16kg | 2.0 g/10 min |
| Tensile Strength Md | 25 MPa |
| Tensile Strength Td | 22 MPa |
| Elongation At Break Md | 600 % |
| Elongation At Break Td | 700 % |
| Dart Impact Strength | 90 g |
| Tear Strength Md | 100 kN/m |
| Tear Strength Td | 120 kN/m |
| Haze | 8 % |
| Gloss 45 Degree | 85 % |
| Melting Point | 123 °C |
| Vicat Softening Point | 100 °C |
| Brittleness Temperature | -70 °C |
As an accredited Sinopec Qilu mLLDPE F271PU factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Sinopec Qilu mLLDPE F271PU is typically supplied in 25 kg moisture-resistant woven bags, 40 bags per pallet for 1,000 kg total. |
| Container Loading (20′ FCL) | 20′ FCL container loading for Sinopec Qilu mLLDPE F271PU: 25 kg bags palletized, securely stowed, moisture-protected, and evenly distributed. |
| Shipping | Sinopec Qilu mLLDPE F271PU is supplied in 25 kg moisture-resistant bags, palletized and stretch-wrapped, and shipped in standard 20'/40' containers. Use clean, covered transport; keep dry and ventilated, away from direct sunlight and heat, and prevent moisture ingress, bag punctures, or unstable stacking during handling. |
| Storage | Store Sinopec Qilu mLLDPE F271PU in a cool, dry, well-ventilated area, away from direct sunlight, heat, flames, and ignition sources. Keep original bags/containers closed and palletized to prevent moisture, dust, and contamination. Avoid physical damage and static buildup. Use first-in-first-out rotation and follow the supplier’s SDS and local regulations. |
| Shelf Life | Sinopec Qilu mLLDPE F271PU has a shelf life of 24 months in original unopened packaging under dry, ventilated storage. |
In coextruded food-packaging sealant webs, Sinopec Qilu mLLDPE F271PU functions as a heat-seal layer component where low seal initiation temperature and high hot-tack strength are required by high-speed vertical form-fill-seal lines. Published datasheet values for F271PU list a nominal density of 0.918 g/cm³ according to ISO 1183-1 and a melt mass-flow rate of 2.7 g/10 min at 190 °C/2.16 kg according to ISO 1133-1:2022. These values place the grade within the metallocene linear-low-density polyethylene range used for blown-film sealant layers, but final film performance depends on coextrusion structure, blend partners, and downstream sealing conditions. On production-scale coextrusion lines with 45 mm, 55 mm, and 75 mm grooved-feed extruders arranged in a 3-layer or 5-layer configuration, F271PU is typically introduced into the sealant skin at a starting-point addition level of 25 wt% to 35 wt% in a blend with LDPE having a melt flow rate of 0.7 g/10 min to 2.0 g/10 min. The die gap is commonly set between 1.8 mm and 2.2 mm, the blow-up ratio between 2.2:1 and 2.8:1, and the melt temperature between 204 °C and 232 °C. The resulting sealant layer is used in frozen vegetable pouches, snack-food bags, and dry-mix sachets, where seal integrity under powder or fat contamination is measured according to ASTM F88/F88M seal-strength testing and ASTM F1921 hot-tack evaluation. Because the grade has a narrow molecular weight distribution, blown-film lines may show higher melt pressure at low shear than an all-LDPE control; screw speeds should therefore be trimmed at the same barrel-temperature profile and die throughput to prevent bubble instability. Surface condensation on pellets stored at relative humidity above 85% can introduce moisture-related bubble defects, so silo drying is not normally required, but pellet surface water must be removed if external storage has created condensation cycles. Direct food-contact clearance is only complete when the converter verifies that the full formulation, including slip and antistatic additives, meets the applicable olefin polymer monograph and migration limits.
| Application segment | F271PU addition level | Blend partners | Key test method | Typical film gauge or coat weight |
|---|---|---|---|---|
| Coextruded food-packaging sealant webs | 25–35 wt% | LDPE 0.7–2.0 MFR | ASTM F88/F88M, ASTM F1921 | 30–80 µm |
| Heavy-duty sack film and FFS packaging | 20–30 wt% | C4-LLDPE, LDPE, HDPE 5–10 wt% | ISO 7765-1, ISO 6383-2 | 120–180 µm |
| Agricultural silage wrap and greenhouse cover film | 20–35 wt% | LDPE, EVA, post-industrial recyclate | ISO 527-3, ISO 7765-1, ASTM D1003 | 25–200 µm |
| Cast stretch film and stretch hood skins | 20–30 wt% | LLDPE, LDPE, EVA | ASTM D5458, ASTM D5748, ASTM D882 | 12–30 µm |
| Extrusion lamination web and coating | 20–40 wt% | LDPE coating resin | ASTM F88/F88M, ISO 11339 | 12–20 g/m² |
| Breathable backsheet compound | 15–25 wt% | CaCO₃ 50–60 wt%, C4-LLDPE | ASTM E96/E96M, MVTR and pinhole count | 30–40 µm oriented film |
In heavy-duty sack film and form-fill-seal packaging for granular polymers, cement, and construction materials, F271PU is added to reduce film splitting during high-speed filling and stacked transport. A typical starting-point formulation uses 20 wt% to 30 wt% F271PU in a matrix of C4-LLDPE and LDPE, with 5 wt% to 10 wt% HDPE to increase machine-direction modulus and creep resistance. Film produced on a 70 mm extruder with a 30:1 L/D barrier screw, die gap 2.0 mm, and blow-up ratio 3.0:1 is drawn to a thickness of 120 µm to 180 µm for sacks carrying 25 kg to 50 kg. Dart impact resistance is assessed by ISO 7765-1 Method A or ASTM D1709 Method A, while Elmendorf tear resistance is measured according to ISO 6383-2. The metallocene grade supports higher dart impact at thinner wall sections, but tear propagation depends on film orientation; excessively high F271PU content without a high-melt-strength LDPE can reduce bubble stability and produce gauge bands in the bubble. Field observations on multi-layer sack lines indicate that the transition from an all-LLDPE formulation to an mLLDPE-containing blend often requires a frost line adjustment to restore bubble symmetry. The terminal sacks are used for petrochemical resin pellets, powdered minerals, and agricultural seed, where puncture from sharp granule edges is tested by ISO 7765-1 and tensile elongation by ISO 527-3. When sacks are intended for dangerous goods transport, certification is governed by the UN Model Regulations and the applicable packing group drop test, leakproofness test, and stacking test for plastics packaging. This application tests the interdependence of bubble stability and solid-state toughness; published data for F271PU in this specific sack configuration is limited, so pilot-scale frost line trials are necessary before full-line conversion.
Agricultural silage wrap and greenhouse cover films use F271PU as a puncture-resistance and optical-clarity modifier in coextruded structures that must survive repeated folding, UV exposure, and contact with ensiled plant material. A three-layer line with 50 mm, 60 mm, and 50 mm extruders typically runs a skin layer containing 20 wt% to 35 wt% F271PU blended with LDPE and EVA, while the core may include recycled greenhouse film flake at up to 30 wt% if the end-use specification allows post-industrial recyclate. The die gap is maintained between 1.6 mm and 2.0 mm, the blow-up ratio between 2.0:1 and 2.5:1, and the frost line height is lowered to improve tear resistance in the transverse direction. Light transmission and haze are measured by ASTM D1003, tensile strength by ISO 527-3 on film specimens, and dart impact by ISO 7765-1. UV performance is developed through hindered amine light stabilizers and benzophenone or triazine absorbers at total concentrations between 0.3 wt% and 0.8 wt%; F271PU itself is not a UV-stabilized resin, so outdoor lifetime depends on the additive package and film thickness. Silage wrap processed at 25 µm to 30 µm must retain puncture resistance after pre-stretching over a silage bale, while greenhouse covers at 150 µm to 200 µm are tested for tensile retention after accelerated weathering under ISO 4892-2 with irradiance and black-panel temperature specified by the converter. The narrow molecular weight distribution of the metallocene grade can increase shear heating in the die at high screw speed; converter records on agricultural film extruders show that a 5 °C to 10 °C melt temperature increase may occur when F271PU loading is increased from 10 wt% to 30 wt%, so barrel cooling capacity should be verified before raising output. Greenhouse and silage films are non-food-contact articles; heavy-metal limits from EU Directive 94/62/EC and REACH Annex XVII apply to pigments and stabilizers.
In cast stretch wrap and stretch hood film, F271PU is evaluated as a skin-layer modifier to improve puncture resistance and load retention at machine stretch rates approaching 200% to 250%. Cast film lines with a 90 mm extruder, 30:1 L/D screw, die gap 0.6 mm to 0.8 mm, and air gap 40 mm to 80 mm are used to produce machine film at 23 µm or less; the chill roll temperature is set between 16 °C and 22 °C. A common starting-point blend is 20 wt% to 30 wt% F271PU in an LLDPE-rich core or skin, with low-melt-index LDPE or EVA used to control cling, because F271PU does not produce inherent tack. Cling force is measured by ASTM D5458, stretch-film puncture by ASTM D5748, and film tensile by ASTM D882. The metallocene grade supports higher puncture extension on A-frame wrappers, but it can also reduce extruder output if the feed section is not kept filled; cast film extruders running mLLDPE-enriched formulations may display higher amperage at low screw speed, and feed-throat bridging must be controlled with pellet temperature below 35 °C. These films are converted into hand stretch wrap, machine wrap for palletized beverage containers, and stretch hoods for appliance distribution, where load containment is verified by a tilt-table test or by the shipper’s acceleration of 0.5 g to 0.8 g in transit. Stretch wrap is sold as non-food-contact industrial packaging unless specific migration testing is performed; EU packaging heavy-metal limits from Directive 94/62/EC apply to colored stretch film. Published data for F271PU in stretch hood formulations is limited, so a full-scale trial should evaluate cling force and stretch force retention over a 24 h period.
Extrusion lamination and extrusion coating convert F271PU into the polymer web that bonds BOPP, BOPET, aluminum foil, and paper into flexible packaging for soups, sauces, and personal care sachets. On tandem extrusion coating lines with 1200 mm to 1800 mm die width and 90 mm extruder barrels operating at 30:1 L/D, F271PU is blended with LDPE coating resin at 20 wt% to 40 wt%. The air gap is fixed between 100 mm and 180 mm, melt temperature between 290 °C and 315 °C, and coat weight between 12 g/m² and 20 g/m². Low neck-in and stable draw are critical because molecular orientation in the air gap controls gauge uniformity across the web; the narrow molecular weight distribution of F271PU reduces neck-in relative to conventional high-melt-index LDPE, but the extruder backpressure may increase. Adhesion to primed aluminum foil and to corona-treated BOPP is measured by peel testing under ASTM D1876 or ISO 11339, and the laminate is further converted into three-side-sealed pouches that are heat-sealed at 160 °C to 200 °C with 0.5 s to 1.0 s dwell time. The terminal pouches require seal integrity when filled with hot liquid or oily paste, so seal strength is verified by ASTM F88/F88M and hot-tack by ASTM F1921. No primer is required on corona-treated film at surface energy 38 mN/m to 42 mN/m, but foil substrates may require a water-based primer if line speed exceeds 200 m/min. Laminates intended for food contact must meet overall migration and specific migration limits under EU Regulation No 10/2011; the FDA status follows 21 CFR 177.1520 for olefin polymer components at the prescribed use temperatures.
| Region or use category | Reference basis | Test method or clause | Scope |
|---|---|---|---|
| US food contact | FDA 21 CFR 177.1520 | Olefin polymer monograph, conditions of use | Sealant webs and extrusion laminates |
| EU food contact | Regulation (EU) No 10/2011 | Overall migration OM2, Annex IV | Multilayer food films and laminates |
| Mechanical film | ISO 527-3 | Tensile properties of thin film | All film segments |
| Impact resistance | ISO 7765-1 / ASTM D1709 | Dart drop Method A | Sacks, agricultural film |
| Seal strength | ASTM F88/F88M, ASTM F1921 | Heat-seal strength and hot-tack | Packaging sealant webs |
| Stretch and cling | ASTM D5458, ASTM D5748 | Cling force and stretch-film puncture | Cast stretch wrap |
| REACH | Regulation (EC) No 1907/2006 | SVHC candidate list and Annex XVII | Monomers, stabilizers, pigments |
| Packaging heavy metals | Directive 94/62/EC | Sum of Pb, Cd, Hg, Cr(VI) ≤ 100 mg/kg | Packaging components |
Breathable film compounds for hygiene backsheet and medical barrier applications use F271PU as a metallocene-rich base resin in calcium carbonate-filled formulations that undergo machine-direction orientation. The filled compound typically contains 50 wt% to 60 wt% coated calcium carbonate with a median particle size of 1 µm to 2 µm, 15 wt% to 25 wt% F271PU, and the remainder a C4-LLDPE or LDPE carrier. Compounding is performed on a co-rotating twin-screw extruder with 44:1 L/D and a side feeder for mineral filler, followed by cast film extrusion and MDO stretching at draw ratios from 2:1 to 4:1. Moisture vapor transmission rate is measured by ASTM E96/E96M, and pinhole count is assessed by a water column test on 30 µm to 40 µm oriented film. The metallocene grade improves drawability and reduces gauge variation after stretching, but the filled system is more viscous than neat film, so die pressures above 200 bar are common on 1200 mm cast film dies. Terminal products include diaper backsheet, adult incontinence outer covers, and surgical gown barrier film, where the converter must verify skin-contact compliance according to EU Regulation No 10/2011 or ISO 10993-5 when medical claims are made. Because breathable film performance is strongly influenced by filler surface treatment and draw temperature, published data for F271PU in this specific configuration is limited; pilot trials should map MVTR and pinhole density against draw ratio and calendering temperature before committing to commercial output.
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Sinopec Qilu mLLDPE F271PU is introduced as a metallocene-catalysed ethylene-alpha-olefin copolymer resin developed for blown film and cast film applications where toughness, seal performance, and downgauging potential are assessed against conventional linear low density polyethylene. Manufacturer trade literature lists the nominal density at 0.918 g/cm³ and the nominal melt mass-flow rate at 1.0 g/10 min when measured under ISO 1133-1:2022 at 190 °C with 2.16 kg. The grade is differentiated from Ziegler-Natta C4-LLDPE by the narrower short-chain branching distribution produced by metallocene catalyst chemistry. Pellet and film specifications should be verified against the supplier’s certificate of analysis because additive loading and comonomer level can vary within the published tolerance band.
Film specimens produced from F271PU are routinely evaluated under ISO 527-3 for tensile properties, ISO 7765-1 for dart impact resistance, ISO 6383-2 for tear resistance, and ASTM F1921 for seal initiation and hot tack. The resin is not designed for injection moulding or rotational moulding; its rheological profile is oriented toward stable bubble formation and controlled melt draw in film processes.
In blown film conversion, F271PU exhibits higher melt viscosity and higher die pressure than a conventional C4-LLDPE of equal nominal melt index because the metallocene polymer has a narrower molecular weight distribution and a more uniform comonomer sequence distribution. On a single-screw extruder with 25:1–30:1 L/D and a die diameter between 150 mm and 250 mm, barrel set-point profiles are typically set from 170 °C in the feed zone to 210–230 °C at the adapter and die. Melt temperature at the die is normally held between 220 °C and 235 °C for neat F271PU. Die gap selection from 1.6 mm to 2.5 mm and blow-up ratio from 2.0:1 to 3.0:1 are used; at blow-up ratios above 3.0:1, bubble instability may occur unless the frost line height is controlled to 5–8 die diameters above the die face.
Field data from comparable metallocene LLDPE grades of 1.0 g/10 min MFR on a 65 mm grooved-feed extruder indicate melt pressure between 180 bar and 260 bar at the screen changer. When F271PU is run neat, pressure loss across a 100 mesh screen pack can be 20–35% higher than that of a C4-LLDPE of equal nominal melt index. Published data for this exact product configuration is limited; processors should derive alarm limits from line-specific data. Onset of sharkskin for neat F271PU may occur when wall shear stress exceeds 0.35–0.45 MPa depending on die temperature and polymer lot; the addition of 5–15 wt% LDPE can delay melt fracture and reduce die pressure.
Substitution of a conventional Ziegler-Natta C4-LLDPE with F271PU changes the film property balance because the metallocene catalyst produces a narrower distribution of short-chain branching across the molecular weight range. The reduced low-molecular-weight, highly branched fraction lowers extractable content and improves seal strength consistency. In form-fill-seal packaging, seal initiation temperature measured under ASTM F1921 is typically 5–12 °C lower for metallocene LLDPE than for equivalent-density C4-LLDPE, while hot tack strength can be 15–35% higher at jaw temperatures from 110 °C to 130 °C. These are resin-class trends; F271PU lot data should be obtained from supplier certification.
| Film property | Test method | Metallocene LLDPE class-typical band | Conventional C4-LLDPE class-typical band |
|---|---|---|---|
| Nominal density | ISO 1183-1:2019 | 0.917–0.919 g/cm³ | 0.916–0.920 g/cm³ |
| Melt mass-flow rate | ISO 1133-1:2022 | 0.9–1.1 g/10 min | 0.9–1.1 g/10 min |
| Dart impact on 25 µm film | ISO 7765-1 method A | 400–800 g | 200–500 g |
| Seal initiation temperature | ASTM F1921 | 5–12 °C below C4 baseline | baseline |
| Hexane extractables | FDA 21 CFR 177.1520 conditions | 2.0–4.0 wt% | 4.0–7.0 wt% |
Comparative film evaluation on a laboratory blown film line with 50 mm die diameter and 1.5 mm die gap positions F271PU as a higher-toughness alternative to C4-LLDPE in 25–40 µm film. The dart impact improvement is more pronounced at low gauge; at 25 µm, metallocene LLDPE films of this class withstand 40–60% higher dart drop energy than C4-LLDPE of equal density and melt index. Tear balance is orientation-dependent: at 2.5:1 blow-up ratio, machine-direction tear strength may remain 10–20% below that of a C4-LLDPE, while transverse-direction tear strength may exceed it by 30–50%. These shifts are process-related and not unique to F271PU.
Differential scanning calorimetry under ISO 11357-3 on F271PU typically records a peak melting temperature between 118 °C and 124 °C and a crystallisation exotherm from 102 °C to 108 °C at 10 °C/min cooling. The narrow melting endotherm supports a sharp seal initiation once jaw temperature exceeds the melting threshold, but it also narrows the heat-seal plateau between seal initiation and burn-through. In coextrusion, F271PU can serve as a sealing skin on HDPE, polypropylene, or EVOH-containing structures; the recommended melt temperature for the F271PU skin is 220–240 °C. The skin layer fraction is typically 15–25% of total thickness to balance seal performance against stiffness and barrier contribution.
Capillary rheometry under ISO 11443 at 190 °C shows shear-thinning behaviour. For class-typical metallocene LLDPE with 0.918 g/cm³ density and 1.0 g/10 min MFR, apparent viscosity at 100 s⁻¹ falls between 2,000 Pa·s and 3,000 Pa·s, while at 1,000 s⁻¹ apparent viscosity falls between 400 Pa·s and 600 Pa·s. F271PU lot-specific capillary data should be used for die design and pressure drop calculations. Melt strength is lower than LDPE; in extrusion lamination, line speeds above 150 m/min may induce draw resonance unless 10–20 wt% LDPE is added or the draw ratio is reduced.
When pellets are stored above 60% relative humidity, the principal moisture source is surface condensation rather than bulk moisture absorption. Condensation on cold pellets produces bubble instability and pinhole defects. Pre-drying at 70–80 °C for 1–2 h in a desiccant dryer is applied when pellets have been exposed to rapid temperature shifts. Masterbatch dilution should avoid acid-releasing carrier systems; residual acidic species can promote chain scission at processing temperatures above 230 °C. Fluoropolymer processing aids at high additive levels can reduce coefficient of friction under ISO 8295 below 0.20, but migration to the sealing surface may reduce hot tack if the additive is concentrated in the seal layer.
Slip and antiblock performance is not inherent to F271PU. Films require an erucamide or oleamide slip additive to achieve coefficients of friction below 0.20 under ISO 8295 at 23 °C and 50% relative humidity. Without additive migration, COF may remain above 0.50. The coefficient of friction stabilises within 24–72 h after film production as the additive migrates to the film surface.
On vertical form-fill-seal equipment running 45–60 packages/min, the heat-seal jaw dwell time is commonly 0.2–0.5 s at 120–140 °C. F271PU is evaluated for hot tack under ASTM F1921 to confirm seal integrity against product loading forces before crystallisation. The narrow comonomer distribution provides rapid crystallisation onset after cooling; this can shorten tack time and reduce cycle time. However, if sealing temperatures exceed 150 °C, burn-through and seal thinning may occur because the narrow melting distribution leaves less plateau. The operating window should be established with sealing force and dwell time fixed under ASTM F88/F88M seal strength testing.
Compliance decisions for food contact should be based on supplier confirmation of FDA 21 CFR 177.1520 and EU No 10/2011. Overall migration under EU No 10/2011 is assessed with food simulants appropriate to the end use; the limit is 10 mg/dm². Specific migration limits for the antioxidant package are governed by Annex II of EU No 10/2011. The resin is not supplied for medical implant use; it is not autoclave-stable above 121 °C under saturated steam because the crystalline morphology softens and film dimensional stability is lost. For pharmaceutical packaging, extractables testing under USP <661.1> is required on the finished film rather than the pellet.
| Regulatory reference | Applicability | Key condition or limit |
|---|---|---|
| FDA 21 CFR 177.1520 | Olefin polymer food-contact articles | Specification by density, melting point, extractables end-test |
| EU No 10/2011 | Plastic materials and articles in food contact | Overall migration 10 mg/dm²; specific migration limits in Annex II |
| REACH | Substance registration and SVHC screening | Polymer registration exempt; monomer and additive obligations apply |
| ISO 11357-3 | Differential scanning calorimetry | 10 °C/min under nitrogen; second heating cycle |
The difference between F271PU and a higher-MFR metallocene grade such as a 2.0 g/10 min mLLDPE is most visible in melt pressure and bubble stability. The 1.0 g/10 min MFR of F271PU increases melt strength and improves bubble stability in high blow-up ratio film, but it raises extruder amperage and die pressure. Consequently, F271PU is selected when film toughness and seal integrity are prioritised over pure output rate. A lower-MFR grade may require a wider die gap to prevent melt fracture; a higher-MFR grade can be processed at lower melt temperature, but it may show reduced dart impact and lower hot tack at equivalent thickness.