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Sinopec Fujian HDPE FMA025

    • Product Name: Sinopec Fujian HDPE FMA025
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    VTB
    Specifications
    HS Code 119379
    Polymer Type High Density Polyethylene (HDPE)
    Density 0.954 g/cm³
    Melt Flow Rate 0.25 g/10 min (190°C, 2.16 kg)
    Melting Point 130-135°C
    Vicat Softening Temperature ≥124°C
    Tensile Strength At Yield ≥25 MPa
    Elongation At Break ≥500%
    Flexural Modulus ≥1000 MPa
    Brittleness Temperature ≤-70°C
    Environmental Stress Cracking Resistance ≥1000 h
    Hardness Shore D ≥60
    Water Absorption <0.01%
    Thermal Conductivity 0.40-0.50 W/m·K
    Volume Resistivity >10^16 Ω·cm

    As an accredited Sinopec Fujian HDPE FMA025 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Sinopec Fujian HDPE FMA025 is supplied in 25 kg woven bags, also available in 1000 kg jumbo bags.
    Container Loading (20′ FCL) 20′ FCL loads Sinopec Fujian HDPE FMA025 in 25 kg bags, typically 17–18 MT per container, loose or palletized.
    Shipping Sinopec Fujian HDPE FMA025 is typically shipped in 25 kg PP woven bags or jumbo bags, palletized and stretch-wrapped. Transport in clean, dry, covered containers or trucks. Store in a cool, ventilated warehouse, away from direct sunlight, heat, and ignition sources. Non-hazardous; avoid moisture and package damage.
    Storage Store Sinopec Fujian HDPE FMA025 in a cool, dry, well-ventilated warehouse, away from direct sunlight, heat, flames, sparks, and strong oxidizers. Keep original bags closed, dry, and palletized off the floor. Prevent moisture, dust, and contamination. Avoid excessive stacking and prolonged UV exposure. Use clean handling equipment and follow first-in-first-out stock rotation. Ensure adequate ventilation and inspect containers regularly.
    Shelf Life Store cool, dry, well-ventilated, away from direct sunlight; typical shelf life is 24 months in unopened sealed original packaging.
    Application of Sinopec Fujian HDPE FMA025

    For high-output thin-gauge carrier bag extrusion, Sinopec Fujian HDPE FMA025 is processed as a high-molecular-weight film-grade high-density polyethylene with a published melt mass-flow rate of 0.25 g/10 min when tested to ISO 1133-1:2022 at 190 °C/2.16 kg and a nominal density of 0.950 g/cm³ when tested to ISO 1183-1:2019. In retail carrier bag applications, the resin is typically run at 100 wt% for unpigmented film or at 85–95 wt% with 5–15 wt% linear low-density polyethylene when the conversion line requires improved dart impact; slip and antiblock masterbatch is metered at 2–4 wt% with synthetic silica active content of 20–30%, while addition above 5 wt% can reduce dart drop impact below merchant bag acceptance limits. The applicable compliance framework is EN 13590:2003 for carrier bag dimensions and strength classes, EU Packaging Directive 94/62/EC for heavy metal packaging limits, REACH 1907/2006 Annex XVII for substance restrictions, ASTM D882 for tensile properties, ASTM D1922 for Elmendorf tear, and ASTM D1709 for dart drop impact. Downstream production uses a single-screw blown film extruder with L/D 30:1, die gap 1.5–2.0 mm, blow-up ratio 3:1–4:1, and melt temperature 190–215 °C; the frost line height is held at 6–10 die diameters to balance machine-direction and transverse-direction tear. On the conversion line, bottom-seal bag machines with sealing temperature 135–150 °C are used, followed by handle punching and perforation. Terminal finished product types are T-shirt grocery sacks and retail carrier bags with film thickness of 8–20 μm, widths from 300–600 mm, and printed or unprinted surface finish. Processors should monitor extruder melt pressure; on a 50 mm grooved-feed extruder, melt pressure excursions above 380 bar typically indicate screen pack blockage or insufficient barrel temperature before the metering section.

    Institutional Can Liners and Heavy-Gauge Refuse Sacks

    The conversion of FMA025 into institutional can liners and heavy-gauge refuse sacks uses the grade as the stiffness-bearing majority phase, with linear low-density polyethylene added to limit brittle puncture failure at low thickness. A typical formulation is 70–85 wt% FMA025, 15–30 wt% LLDPE, and 2–3 wt% carbon black masterbatch; post-industrial regrind may be introduced up to 15 wt% only if the converter verifies that dart impact resistance under ASTM D1709 and Elmendorf tear under ASTM D1922 remain within the liner specification. The applicable compliance set includes EN 13592:2017 for household refuse sacks, ASTM D882 for tensile properties, ISO 527-3 for film tensile behavior, REACH 1907/2006, and the EU Packaging Directive 94/62/EC. Downstream processing is commonly performed on high-output blown film lines with internal bubble cooling, a grooved-feed single-screw extruder at L/D 30:1, die gap 1.8–2.5 mm, blow-up ratio 2.5:1–3.5:1, and melt temperature 190–220 °C. Melt filtration through an 80/100/80 mesh screen pack is used to remove gel particles from recyclate-containing blends; pressure drop across the screen pack should be logged, and a rise above 80 bar over a stable baseline usually indicates gel accumulation. Terminal product types include institutional can liners of 10–25 μm and heavy-gauge refuse sacks of 50–100 μm, with widths from 500–1100 mm. A practical boundary condition is recycled-content variability: if the recycled HDPE fraction shifts melt index by more than 0.1 g/10 min between lots, dart impact can shift by 10–15%, requiring adjustment of the LLDPE fraction rather than barrel temperature alone.

    Where dry-food liners require low odor, low soluble content, and stable gauge at 20–40 μm, FMA025 is run on blown film lines configured with polished screws and low-shear metering sections to minimize polymer degradation and off-taste transfer. For direct food contact, the resin is used at 100 wt% natural, with no post-consumer recyclate; if an opaque white liner is specified, 2–4 wt% of a food-contact-grade white masterbatch is introduced, with the colorant listed under 21 CFR 178.3297. Slip and antiblock masterbatch is held at 1–2 wt% only when needed for high-speed bag conversion, because excessive slip can affect seal integrity on bottom-seal machines. The compliance framework includes FDA 21 CFR 177.1520(c) for olefin polymers, EU Regulation 10/2011/EC Annex I with an overall migration limit of 10 mg/dm², and China GB 9685 for food-contact additives and colorants; converters must verify that the specific lot certificate from Sinopec Fujian references the intended food-contact jurisdiction. Downstream production uses a blown film extruder with die gap 1.5–2.0 mm, blow-up ratio 3:1–4:1, and melt temperature 180–205 °C; lower melt temperature is preferred to limit oxidative degradation products, but too low a barrel setting produces shark skin and unstable bubble geometry. Terminal finished product types include cereal liners, bakery bag liners, dry powder sachet liners, and bulk dry-food box liners with surface treatment applied only when printed. The operational boundary is thermal: this application is not recommended for hot-fill above 80 °C or for long-term high-fat contact conditions, where a higher-viscosity HDPE or a functional barrier layer should be considered instead of a monolayer FMA025 film.

    Does FMA025 Function as a Viable Structural Layer in Coextruded Barrier Film?

    The grade is positioned as the stiff structural bulk layer in five-layer symmetrical barrier film where dry-food or non-food contents require oxygen or aroma barrier. In a five-layer construction, FMA025 is used at 20–35 wt% of total film weight as the outer or core layer; ethylene vinyl alcohol or polyamide barrier resin is introduced at 5–10 wt%; tie resin is held at 3–5 wt% per adhesive layer; and an LLDPE or plastomer seal layer occupies 25–40 wt%. The compliance framework for food-contact structures is FDA 21 CFR 177.1520 for the polyolefin layer and EU Regulation 10/2011/EC for overall migration; for non-food industrial film, REACH 1907/2006 and RoHS Directive 2011/65/EU are the relevant chemical restriction baselines. Downstream conversion is carried out on a multi-layer blown film line with separate extruders for each layer; the FMA025 extruder is run at 200–220 °C, while the barrier resin extruder is typically held at 195–210 °C, and the die gap is set at 1.8–2.5 mm with a blow-up ratio of 2.5:1–3.5:1. The main process conflict is interfacial instability: if the viscosity ratio between FMA025 and the barrier resin at the die-lip shear rate exceeds 3:1, haze bands or chevron-shaped optical defects appear across the bubble. This is controlled by maintaining the melt temperature differential between the HDPE layer and the barrier layer below 10 °C and by increasing the tie-layer thickness rather than increasing barrier-layer temperature. Terminal finished product types include printed barrier pouches for dry granular food, bag-in-box liners, and lamination web for non-food industrial packaging, with total film thickness commonly 45–90 μm.

    Under-slab vapor retarder conversion places a different demand on the resin because film thickness increases to 0.15–0.50 mm and water vapor permeance becomes the critical acceptance criterion. FMA025 is used at 100 wt% as the base resin, with 2–3 wt% carbon black masterbatch added for opacity and storage UV resistance; no post-consumer regrind is introduced unless the converter can document that tensile and puncture performance remain within the specification under ASTM E1745-17. The applicable compliance set includes ASTM E1745-17 Class A, which requires water vapor permeance not exceeding 0.1 perm (5.7 ng/(Pa·s·m²)) when tested to ASTM E96/E96M wet-cup or desiccant method, ASTM D882 for tensile properties, ASTM D1709 for impact resistance, and REACH 1907/2006 for chemical registration obligations. Downstream production uses blown film extrusion with die gap 2.0–2.5 mm, blow-up ratio 2.5:1–3.5:1, and melt temperature 195–215 °C; thickness control is maintained within ±10% of nominal because Class A vapor retarder performance depends on continuous film thickness rather than average thickness. Terminal finished product types include under-slab vapor barriers of 0.25–0.50 mm, crawl space liners, and temporary construction covers. Published data for FMA025-specific long-term UV aging at thicknesses above 0.50 mm is limited; qualification clauses in project specifications should therefore require site-specific exposure testing if the membrane is stored outdoors for more than 30 days before slab placement.

    When FMA025 Is Converted on Form-Fill-Seal Lines for Granular Dry Products

    On vertical or horizontal form-fill-seal equipment, the stiff HDPE backbone provides dead-fold and shelf stand-up, while controlled LLDPE addition compensates for the higher seal-initiation temperature of HDPE and reduces impact failure at seal corners. A typical formulation is 60–85 wt% FMA025 with 15–40 wt% LLDPE, 1–3 wt% slip and antiblock masterbatch, and 2–4 wt% color masterbatch if printed or brand-colored packaging is required. The compliance set includes FDA 21 CFR 177.1520 for dry food packaging in the United States, EU Regulation 10/2011/EC for food-contact plastic layers in the European Union, ASTM F88/F88M for seal strength, ASTM D1922 for tear resistance, and ASTM D1709 for dart impact. Downstream film production uses a blown film line with die gap 1.8–2.4 mm, blow-up ratio 2.5:1–3.5:1, and melt temperature 185–210 °C; the film is corona-treated to 38–42 mN/m before printing or lamination because untreated HDPE surfaces below 32 mN/m typically cause ink adhesion failure. Seal initiation for FMA025-rich blends is commonly 125–135 °C, while addition of 20–30 wt% LLDPE lowers initiation by 10–15 °C, which is necessary on high-speed FFS lines where seal dwell time is below 0.5 s. Terminal finished product types include 40–80 μm printed bags and pouches for granular detergents, dry pet food, and dry industrial chemicals. A documented line condition is coefficient-of-friction drift: if the kinetic coefficient of friction exceeds 0.4 on vertical FFS tracking belts, the film can wander and create misaligned seals; this is corrected by raising the slip masterbatch within the 1–3 wt% window, but addition above 3 wt% can reduce ink adhesion after corona treatment if the film is printed inline.

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    Certification & Compliance
    More Introduction
    Sinopec Fujian HDPE FMA025 is a high-density polyethylene blown film resin produced by Sinopec Fujian Refining & Chemical Co., Ltd. The grade designation FMA identifies the film extrusion series, and the numeric suffix corresponds to a nominal melt flow rate of 0.25 g/10 min at 190 °C under 2.16 kg load when tested per ISO 1133-1:2022. The base polymer is an ethylene homopolymer with a nominal density of 0.952 g/cm³ determined by ISO 1183-1:2019. The high-load melt index at 190 °C under 21.6 kg is 8.0 g/10 min, giving a melt flow ratio of 32. This ratio is characteristic of a broad molecular weight distribution and is used in film-grade HDPE to provide bubble stability, drawdown control, and balanced tensile properties. The CAS number for high-density polyethylene is 9002-88-4.

    Primary applications are thin-gauge blown film for vest carrier bags, refuse sacks, industrial liners, and multi-wall bag liners. The grade is specified where film thickness reduction, stiffness retention, and melt strength are process-limiting variables. Typical lot properties reported in manufacturer technical bulletins are shown in Table 1.

    PropertyTest methodNominal value
    Melt flow rate, 190 °C/2.16 kgISO 1133-1:20220.25 g/10 min
    High-load melt index, 190 °C/21.6 kgISO 1133-1:20228.0 g/10 min
    DensityISO 1183-1:20190.952 g/cm³
    Tensile yield strength, machine directionISO 527-3:201828 MPa
    Elongation at break, machine directionISO 527-3:2018>600 %
    Vicat softening temperature, A50ISO 306:2022124 °C
    Environmental stress-crack resistance, F50ASTM D1693-21>300 h

    The values in Table 1 are lot-to-lot typical data and may shift with catalyst, comonomer control, and additive package. They are not specification limits; the supplier’s certificate of analysis is the controlling document. In film thicknesses between 8 µm and 40 µm, FMA025 is used where higher modulus and downgauging capability are required. Compared with lower-density HDPE film grades at approximately 0.948 g/cm³, FMA025 provides higher secant modulus and lower permeability, but lower dart impact than LLDPE-rich structures. The density must be controlled within approximately ±0.002 g/cm³ on production lots to maintain consistent bubble width and final film gauge.

    What Limits the Use of FMA025 in High-Shear Injection Molding?

    FMA025 is not recommended for injection molding. The melt flow rate of 0.25 g/10 min at 190 °C under 2.16 kg indicates high zero-shear viscosity. In injection molding, shear rates at the gate typically reach 10,000 s-1 to 100,000 s-1. The resulting pressure drop for FMA025 exceeds values generated by injection grades with MFR of 8–20 g/10 min. On a general-purpose 20:1 L/D screw and a 1,000 kN clamp mold, filling thin-wall tooling would require melt temperatures above 230 °C, which approaches the upper thermal stability limit and increases oxidation risk. Published data for FMA025 in injection molding is limited; the manufacturer does not list injection molding as a recommended conversion process.

    Small-part blow molding grades typically flow at 0.30–0.60 g/10 min; they are optimized for parison hang strength, surface finish, and top-load development. FMA025 has similar density but is formulated for biaxial blown film extension from an annular die. Its molecular architecture favors melt strain hardening in film blowing rather than controlled sag in parison formation. Cast film HDPE grades are lower-viscosity and are processed through flat dies with chill roll quenching; FMA025 is specific to air-cooled blown film, where the melt must support the bubble before crystallization at the frost line.

    Food-contact status is not automatically conferred by the base resin. The converter must verify that the antioxidant package and final film structure comply with 21 CFR 177.1520 for polyethylene contact with food, or with EU Regulation 10/2011 for overall migration and specific migration limits. Restricted substance compliance for the final article must be assessed under REACH Annex XVII and, where relevant, RoHS Directive 2011/65/EU; the HDPE base resin alone does not automatically satisfy all article-level requirements.

    On a 55 mm grooved-feed extruder with 30:1 L/D and barrier screw, FMA025 is processed through a 1.2–1.8 mm die gap. Barrel temperatures follow a rising profile from 180 °C in the feed zone to 210 °C in the metering zone; die temperatures are maintained at 205–220 °C. Melt pressure before the screen pack is typically 25–35 MPa, depending on screw speed and mesh configuration. If pellets are stored at relative humidity above 60 %, surface moisture should be removed with a desiccant dryer at 70 °C for 1–2 h; drying above 90 °C may cause pellet agglomeration and feed starvation. Table 2 summarizes the processing window reported in converter production logs.

    Operating parameterRecommended range
    Extruder barrel feed zone180–200 °C
    Extruder barrel metering zone200–220 °C
    Die temperature205–220 °C
    Die gap1.2–1.8 mm
    Blow-up ratio3.0–5.0
    Frost line height8–12 × die diameter
    Pre-drying, if surface moisture is present70 °C for 1–2 h

    Batch-to-batch MFR variation of approximately ±0.02 g/10 min can change melt pressure by 2–4 % on a 55 mm line; operators typically adjust screw speed to maintain constant bubble width. Screen pack changes from 40/60/100 mesh to 60/100/200 mesh raise melt pressure by 5–10 MPa, which may exceed the die pressure limit at high output. Melt temperature measured at the adapter should not exceed 230 °C to avoid gel formation and bubble defects.

    High-Stalk Bubble Geometry, Die Gap Adjustment, and Frost Line Thermal Gradients

    The high-stalk bubble configuration is typically used with FMA025. A stalk height of 6–10 die diameters promotes extension-induced crystallization and improves machine-direction tear and tensile balance. Blow-up ratios of 3.0–5.0 are common. At blow-up ratios below 3.0, transverse orientation is reduced and TD tear may fall below converter specifications for vest bag handles. Above 5.0, bubble geometry becomes unstable and gauge variation increases above ±5 %, particularly on unilayer lines without internal bubble cooling.

    Die gap selection interacts with melt strength. At 1.2 mm, the shear rate is higher and the melt may exhibit surface melt fracture. Increasing gap to 1.8 mm reduces shear and lowers melt pressure, but may increase machine-direction orientation. For 8 µm film, converters often start at 1.8 mm and reduce only if gauge uniformity improves. Continuous capacitance gauge measurement should remain below ±4 %; variation above ±5 % indicates an unstable bubble, uneven air ring, or die temperature imbalance.

    Frost line thermal gradients control quench rate. Cooling air temperature below 10 °C lowers the frost line and may increase film clarity, but excessive quench can promote brittle failure if the film is further oriented. Above 30 °C, cooling becomes insufficient and the bubble may contact the collapsing frame at high output; output must then be reduced. The frost line height is maintained at 8–12 die diameters for balanced MD/TD tear. On unilayer lines without internal bubble cooling, maximum output for 10 µm film may be limited to 80–120 kg/h on a 65 mm extruder; with internal bubble cooling, output can reach 150 kg/h depending on air ring and die diameter. Published data for FMA025 under this exact configuration is limited.

    When FMA025 Is Downgauged Below 8 µm for T-Shirt Bags, Tear and Dart Impact Requirements Change

    Film at 8 µm and below is used for vest carrier bags to reduce mass per bag. At this thickness, the stiffness contribution of FMA025 is retained because density is 0.952 g/cm³; however, dart drop impact and Elmendorf tear resistance become the limiting properties. Neat FMA025 film at 12 µm may show different tear balance than film containing 10–20 wt% LLDPE. Blending with a metallocene LLDPE with a melt index of 1.0–2.0 g/10 min is used to increase dart impact without eliminating bubble stability. The addition of 20 wt% LLDPE can raise dart impact by 20–40 % relative to the neat HDPE film when measured per ISO 7765-1:2004, but melt pressure increases and the bubble may become more sensitive to frost line movement.

    LDPE is added in some refuse bag structures to improve processability, but LDPE content above 30 wt% reduces film stiffness and increases bag opening effort. In food-contact applications, the final coextruded or blended structure must be tested for overall migration according to EU Regulation 10/2011; the migration behavior of slip and antiblock additives may differ from the neat HDPE base. Heat seal initiation temperature for monolayer FMA025 film is typically 125–135 °C; seal jaw temperatures are therefore set at 150–180 °C depending on line speed and film thickness.

    Mechanical acceptance tests are specified as dart drop impact per ISO 7765-1:2004 or ASTM D1709-16a; Elmendorf tear per ASTM D1922-23; and tensile yield and elongation per ISO 527-3:2018. These tests should be run at 23 °C and 50 % relative humidity after conditioning per ISO 291:2008. Post-industrial regrind up to 20 wt% is common in non-food bag structures; above that level, gel counts and film defects may increase. Avoid combining FMA025 with amine-based antifog or antistatic additives in food-contact structures without migration and organoleptic testing because such additives can alter surface seal initiation and overall migration.

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