| HS Code | 238739 |
| Product | SIBUR PP Homopolymer PP H350 FF |
| Material Type | Polypropylene Homopolymer |
| Melt Flow Rate 230 C 2 16 Kg | 35 g/10 min |
| Density | 0.905 g/cm³ |
| Tensile Strength At Yield | 35 MPa |
| Elongation At Yield | 12% |
| Flexural Modulus | 1400 MPa |
| Izod Impact Strength Notched 23 C | 3 kJ/m² |
| Charpy Impact Strength Notched 23 C | 3 kJ/m² |
| Heat Deflection Temperature 0 45 Mpa | 100 °C |
| Vicat Softening Temperature 10 N | 155 °C |
| Rockwell Hardness | 105 R-scale |
| Melting Point | 170 °C |
As an accredited SIBUR PP Homopolymer PP H350 FF factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | SIBUR PP Homopolymer PP H350 FF is packaged in 25 kg woven polypropylene bags, palletized, and stretch-wrapped for protection. |
| Container Loading (20′ FCL) | 20′ FCL container loading of SIBUR PP Homopolymer PP H350 FF, packed in sturdy bags, secured for safe transport, protected from moisture and contamination. |
| Shipping | SIBUR PP Homopolymer PP H350 FF is shipped as free-flowing pellets in 25 kg bags, 500–1000 kg big bags, or bulk containers. Transport in covered trucks, railcars, or ISO containers. Keep dry, clean, and away from heat, ignition sources, and direct sunlight to preserve quality. |
| Storage | Store SIBUR PP Homopolymer PP H350 FF in a dry, clean, well-ventilated area away from direct sunlight, heat, and ignition sources. Keep pellets in sealed original packaging or closed silos to prevent moisture, dust contamination, and UV degradation. Avoid high stacking and extreme temperatures; use within recommended shelf life for optimal processing. |
| Shelf Life | Store in dry, cool conditions away from sunlight and heat. Shelf life is typically 12 months from date of delivery. |
Thin-wall injection moulding of food packaging with homopolymer polypropylene at a nominal melt flow rate of 35 g/10 min under ISO 1133-1:2022 (2.16 kg, 230 °C) positions SIBUR PP H350 FF in the high-fluidity segment used for dairy spread tubs, deli lids and stackable storage covers. The practical wall-thickness band lies between 0.45 mm and 1.20 mm; below 0.45 mm, the short-shot frequency rises sharply on direct-gated single-face tools unless the flow-length-to-wall-thickness ratio is kept below 150:1. In hot-runner moulds with valve-gate tip diameters of 0.8 mm to 1.2 mm, the injection speed is set from 150 mm/s to 300 mm/s, melt temperature from 230 °C to 250 °C, and mould-circuit coolant temperature from 10 °C to 30 °C. If the injection speed falls below 120 mm/s, flow hesitation can occur at ribs with thickness transitions below 0.8 mm, producing concentric ring defects near the gate. A gate land length of 0.5 mm to 1.0 mm and a land surface finish of Ra 0.4 µm or better reduce shear-induced gate blush in translucent parts. The holding pressure profile is critical: because high melt-flow resins transmit packing pressure less effectively over long flow paths, hold pressure should switch by screw position before the gate freezes, with start-up values of 400 bar to 700 bar at the hydraulic cylinder. Failure to do so produces sink marks around bosses and ribs, dimensional variation exceeding 0.15 mm on a 120 mm lid, and warpage caused by unbalanced post-fill shrinkage. Mould cooling time in this geometry is typically 4 s to 8 s; no external pre-drying is required when the resin is stored below 60 % relative humidity, but surface splay can appear if condensation has formed on granules. Food-contact compliance requires the finished article to meet overall migration limits under Regulation (EU) No 10/2011, including the 10 mg/dm² overall migration limit and simulant selection in Annex III and Annex V, while the base olefin polymer used in US applications falls under 21 CFR 177.1520. In compounding for food packaging, only substances listed in the relevant positive list should be added; natural talc or calcium carbonate fillers can alter the overall migration result and must be tested on the final article, not on the base polymer alone.
| Wall-thickness regime | Melt temperature | Mould coolant temperature | Injection speed | Holding pressure start-up | Cooling time |
|---|---|---|---|---|---|
| 0.45 mm–0.80 mm | 230 °C–250 °C | 10 °C–20 °C | 180 mm/s–300 mm/s | 500 bar–700 bar | 3 s–6 s |
| 0.80 mm–1.20 mm | 220 °C–240 °C | 15 °C–30 °C | 120 mm/s–200 mm/s | 400 bar–550 bar | 6 s–10 s |
| 1.20 mm–2.50 mm | 200 °C–230 °C | 20 °C–40 °C | 60 mm/s–120 mm/s | 300 bar–450 bar | 12 s–22 s |
On high-cavitation closure lines producing PCO 1881 or 29/25 neck finishes, the short flow path of a 2.5 g to 4.0 g cap does not allow a wide holding window; the gate freezes before the screw reaches its final cushion if the injection unit uses time-based switchover. SIBUR PP H350 FF enters the cavity with comparatively low melt viscosity, so filling is rapid, but holding pressure decays quickly along the sub-gate, which can produce sink in the hinge area and ovality in the tamper-evident band seat. Moulds with 48 to 96 cavities are usually run with injection speeds of 150 mm/s to 220 mm/s, melt temperature of 220 °C to 240 °C, and chiller temperature of 8 °C to 15 °C. Deceleration at the end of injection should be linear from 180 mm/s to 30 mm/s over the last 2 mm of screw travel to avoid jetting and gate smear. Cold-runner sub-gate diameter is generally 0.6 mm to 0.8 mm with a land length of 0.6 mm to 1.0 mm. The clamping force requirement is low for this part size; start-up clamp tonnage for a 48-cavity stack tool may be 1800 kN to 2500 kN. The tamper-evident band is slit by rotating knives immediately after ejection; if the melt temperature exceeds 260 °C, band fibrillation becomes irregular and stringing increases on the closure top surface. Mechanical evaluation of closures produced from unfilled homopolymer PP in this flow class typically shows tensile yield stress of 32 MPa to 36 MPa under ISO 527-2 and notched Charpy impact strength of 2.0 kJ/m² to 3.5 kJ/m² at 23 °C under ISO 179-1/1eA. Drop-impact resistance at -20 °C should not be assumed; child-resistant closures, hinge closures and designs with high snap-bridge elongation generally require an impact-modified PP copolymer or an ethylene-modified grade. For hot-filled closures, the part must be checked for post-sterilisation dimension change because homopolymer PP undergoes additional post-crystallisation shrinkage after first exposure to hot fill; a typical post-mould shrinkage of 1.0 % to 1.8 % should be added to tool sizing. Carbonated beverage closures require sustained pressure retention; the linerless PP design depends on the creep modulus and sealing lip geometry, so the converter should verify pressure retention according to customer specification after 24 h at 23 °C and after thermal cycling.
Storage boxes, kitchen drawer trays and refrigerator bins in the 1.2 mm to 3.0 mm wall-thickness segment receive the injection pressure reduction offered by PP H350 FF, but the grade also brings lower melt strength and a narrower pack window in thick rib intersections. Melt temperature for these parts is set from 200 °C to 230 °C, mould coolant temperature from 20 °C to 40 °C, and holding pressure from 300 bar to 450 bar at the injection unit. Rib-to-wall ratio should not exceed 50 % of nominal wall to prevent sink formation. When a living hinge is required in a box or tray lid, the hinge thickness should be 0.25 mm to 0.50 mm, the gate should be placed so that melt flow crosses the hinge perpendicularly, and flex endurance must be tested before production because high-flow homopolymer PP has lower hinge fatigue resistance than a low-MFR homopolymer of the same crystallinity. Sink-mark control in thick bosses requires a two-stage holding profile: initial pack at 400 bar to 450 bar for 1 s to 2 s, followed by a reduced stage at 200 bar to 250 bar for 3 s to 5 s. The homopolymer is not suitable for load-bearing freezer drawers at service temperatures below -20 °C; impact-copolymer PP should be evaluated unless the wall thickness is above 3.0 mm or the part is specified for ambient use only. Surface gloss in high-flow homopolymer is higher than filled PP, so visible sink and flow marks are more apparent; textured mould surfaces with a depth of 10 µm to 15 µm reduce visual defects. Drying is not required under normal storage, but granules left in open silos above 60 % relative humidity should be dried at 80 °C for 2 h to 4 h before processing. Long-term contact with strong oxidising acids or prolonged exposure to aromatic solvents at elevated temperature can cause surface crazing and should be excluded from the application specification.
If SIBUR PP H350 FF is considered for disposable non-implant medical or pharmaceutical consumables such as specimen cups, pipette tip racks and centrifuge tube bodies, the converter must first obtain grade-specific confirmation of the stabiliser package and production hygiene, because a homopolymer PP base resin is not automatically a medical grade. Processing under cleanroom conditions typically follows ISO Class 8 garment and air-handling protocols, with oil-free compressed air on the ejector circuit and a purging sequence using virgin PP after barrel residence. Melt temperature for these thin-wall parts is 220 °C to 240 °C; mould coolant temperature is 10 °C to 20 °C; and residence time above 260 °C should be kept below 5 min to avoid thermo-oxidative chain scission that increases yellowish discoloration in transparent or translucent parts. Sterilisation validation is the main technical boundary. Autoclave cycles at 121 °C for 30 min can produce additional post-crystallisation shrinkage; tooling should be sized for total post-mould shrinkage of 1.0 % to 1.8 %, and dimensional checks must be repeated after the first heat cycle. Gamma irradiation at 25 kGy to 40 kGy can cause embrittlement and yellowing of homopolymer PP unless the formulation contains a radiation-stabilising package; if gamma sterilisation is unavoidable, tensile impact and colour change should be measured under ISO 527-2 and ISO 11664-4. Ethylene oxide sterilisation is less aggressive but requires aeration to below the residue limits specified in ISO 10993-7. Biological evaluation of the finished device follows ISO 10993-1; extractables testing for plastic containers may reference USP <88> and USP <661> only when the grade-specific resin and finished device have been included in the test programme. The material is not suitable for implantation, prolonged mucosal contact, or blood-contacting components without an additional supplier qualification and regulatory dossier.
| Application route | Required evaluation | Reference standard | Key measurable |
|---|---|---|---|
| Food-contact packaging | Overall migration | Regulation (EU) No 10/2011 | 10 mg/dm² |
| Food-contact packaging | Olefin polymer compliance | 21 CFR 177.1520 | Commodity specification |
| Closures and housewares | Tensile yield stress | ISO 527-2 | 32 MPa–36 MPa |
| Closures and housewares | Notched Charpy impact | ISO 179-1/1eA | 2.0 kJ/m²–3.5 kJ/m² |
| Medical non-implant | Biological reactivity | USP <88> | Grade-specific test required |
| Automotive interior | Horizontal burning rate | ISO 3795 / FMVSS 302 | Below 100 mm/min |
Children’s toys, hobby kits and stationery cases moulded from high-flow PP homopolymer require the converter to pay attention to impact-test outcomes rather than filling behaviour, because the grade’s high MFR reduces notch sensitivity in thin sections but does not improve low-temperature ductility. Toy parts with wall thickness from 0.8 mm to 2.0 mm are usually processed at melt temperatures of 200 °C to 230 °C, with cold runners and submarine gates to avoid visible hot-runner vestiges. Compliance with toy safety requirements demands that the finished part meet EN 71-3 migration limits for specific elements and that heavy-metal stabiliser systems are absent from the formulation; no statement can be made about grade compliance unless the supplier’s regulatory certificate is available. In Europe, the product falls under Directive 2009/48/EC; in the United States, the applicable mechanical and chemical requirements are specified in ASTM F963. Painted or printed surfaces require pre-treatment because PP homopolymer has low surface polarity; corona discharge or plasma treatment should raise the surface energy to at least 40 mN/m before adhesion of water-based inks. Small parts and hinges should not contain sharp corners after ejection; the high-flow resin can fill deep ribs, but residual stress in thick-to-thin transitions may cause whitening if demoulding is too aggressive.
Recycled polypropylene compounds with 20 wt% to 40 wt% talc often exhibit insufficient spiral-flow length for complex injection moulding tools. A high-flow virgin homopolymer such as PP H350 FF is added at 10 wt% to 20 wt% to shift the apparent melt flow rate upward; the relationship is nonlinear and should be modelled with a log-additive mixing rule before plant trials. Compounding is performed on a co-rotating twin-screw extruder with an L/D ratio of 40:1 to 44:1 and a screw speed of 400 rpm to 600 rpm. Temperature zones are set from 180 °C to 210 °C, with the side feeder placed after the melt seal to minimise talc attrition. Vacuum devolatilisation at -0.08 MPa is used to remove residual moisture and degradation volatiles from recycled input. The addition of high-MFR PP reduces melt pressure at the die and improves filler wet-out, but it also reduces the notched Charpy impact strength of the final compound; if the compounded part is used outdoors or under cold impact, an ethylene–propylene impact modifier should be incorporated. Capillary rheometry per ISO 11443:2021 should be run at 230 °C and 250 °C to compare shear viscosity of the blend against standard unfilled H350 FF; the data are used to predict injection pressure and gate freeze time. A low-flow recycled stream with an initial MFR of 5 g/10 min can be raised into the 15 g/10 min to 25 g/10 min range with 15 wt% to 20 wt% addition, depending on filler level and peroxide history. If filler loading exceeds 40 wt%, feeding H350 FF through the main throat and talc through the side feeder can lead to agglomerate formation unless distributive mixing elements are placed before the side-feed port. Published data for this specific configuration is limited, so pilot-plant compounding is recommended before multi-tonne production.
For interior thin-wall trim parts such as door panel map pockets, speaker grilles and B-pillar lower covers, high-flow PP homopolymer is selected only when the component is not required to withstand cold impact or airbag deployment forces. The material fills long, thin ribs at melt temperatures between 220 °C and 250 °C and mould coolant between 15 °C and 30 °C; holding pressure is generally 300 bar to 500 bar at the injection cylinder. Because PP homopolymer has poor natural UV resistance, parts that receive direct sunlight through glazing must be stabilised with a UV package; outdoor weatherability is evaluated by xenon-arc exposure under ISO 4892-2 with the customer’s delta E limit. Automotive interior flammability is assessed under ISO 3795 or FMVSS 302, with a maximum burn rate of 100 mm/min for most interior components. Scratch and mar resistance is lower than talc-filled PP, so grained surfaces with a depth of 10 µm to 15 µm and low-gloss texturing are preferred to reduce visible damage in high-touch zones. The high-flow homopolymer is not recommended for airbag covers, load-bearing seat components, or parts requiring ductility below -30 °C; those applications require an impact-copolymer PP or a compounded TPO. If the grade is used as a thin-wall replacement for a lower-flow PP, the tool must be re-evaluated for gate size and venting because the faster fill rate can increase gas entrapment at the end of flow; parting-line vents of 0.02 mm to 0.03 mm depth are typical.
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Within the SIBUR polyolefin portfolio, the grade designated PP H350 FF is a high-fluidity polypropylene homopolymer supplied in pellet form for fiber, film, and injection-molding conversion. The product nomenclature identifies the polymer architecture and nominal flow: the “H” denotes a homopolymer backbone without ethylene comonomer, the “350” corresponds to a melt mass-flow rate of 35 g/10 min determined under ISO 1133-1:2022 at 230 °C and 2.16 kg, and the “FF” suffix indicates fiber and film processing capability. The polymer backbone consists of propylene repeat units with the formula [CH2–CH(CH3)]n and CAS registry number 9003-07-0. Because the main chain contains no ethylene interruptions, the homopolymer crystallizes more rapidly and develops higher ambient-temperature stiffness than propylene-ethylene random copolymer grades. The high melt-flow index places the material in the conventional continuous-filament spunbond, slit-tape, and thin-wall injection range, not in the meltblown range of 400–1800 g/10 min.
The producer’s lot-release specification for PP H350 FF is structured around ISO 19069-1:2015 and ISO 1873-2:2007 test conditions for polypropylene. Because the grade is a controlled-rheology homopolymer, melt mass-flow rate is the primary viscosity-control parameter and is usually reported as a range rather than a single point. Typical values obtained under producer quality-control protocols are shown in the table below. The data are indicative; binding lot limits are defined in the commercial specification and may include gel count, ash content, additive content, and pellet bulk density.
| Property | Test method | Indicative value or range | Unit |
|---|---|---|---|
| Melt mass-flow rate at 230 °C, 2.16 kg | ISO 1133-1:2022 | 32–38 | g/10 min |
| Density | ISO 1183-1:2019 | 0.90–0.91 | g/cm³ |
| Tensile stress at yield, 50 mm/min | ISO 527-2 | 34–37 | MPa |
| Tensile strain at yield | ISO 527-2 | 8–10 | % |
| Flexural modulus | ISO 178:2019 | 1450–1650 | MPa |
| Charpy notched impact strength at 23 °C | ISO 179-1/1eA | 2.0–3.5 | kJ/m² |
| Heat deflection temperature at 0.45 MPa | ISO 75-2/B | 88–100 | °C |
| Vicat softening temperature A50 | ISO 306 | 150–155 | °C |
| Melting temperature by differential scanning calorimetry | ISO 3146 | 160–166 | °C |
| Mold shrinkage after 48 h | ISO 294-4 | 1.2–1.6 | % |
Specimen preparation for these tests follows ISO 294-1 for injection-molded plaques or ISO 1873-2 for compression-molded sheet. The notched Charpy value is strongly affected by cooling rate and skin-core morphology; slow-cooled compression specimens can show lower values than fast-cooled injection specimens. Published data for this specific configuration is limited for sub-zero impact and dynamic rheology. These properties should be measured before final design of thin-wall medical, packaging, or technical nonwoven applications.
Compared with SIBUR homopolymer extrusion grades carrying nominal MFR values below 10 g/10 min, PP H350 FF exhibits lower melt viscosity and lower melt elasticity. This difference reduces pressure drop in a 30:1 L/D single-screw extruder and allows longer spiral flow in injection molds. The trade-off is a measurable reduction in melt strength, which is critical in cast-film neck-in, blow-film bubble stability, and foamed structures. In comparison with a 12 g/10 min homopolymer, the high-flow grade typically processes at melt temperatures 10–20 °C lower for equivalent die pressure. The oriented skin layer can be thinner, altering surface hardness and tensile stress at yield measured under ISO 527-2. Against propylene-ethylene random copolymers, PP H350 FF offers higher stiffness and higher heat deflection temperature under ISO 75-2/B; against heterophasic impact copolymers, the homopolymer has lower notched impact strength below 0 °C. The absence of ethylene-derived rubber domains also reduces light scattering, but homopolymer polypropylene remains translucent in thick sections unless clarified with nucleating agents. In nonwoven webs, the homopolymer chemistry improves resistance to organic solvents and may maintain tensile strength after gamma irradiation better than some random copolymers, provided that the stabilizer package contains a suitable hindered-amine light stabilizer at the required loading.
Class-level differences are summarized in the second table. The comparisons are directional and do not replace grade-specific datasheets or converter validation.
| Polymer class | Nominal MFR range | Relative stiffness | Low-temperature impact | Optical clarity | Typical conversion |
|---|---|---|---|---|---|
| PP H350 FF high-flow homopolymer | 32–38 g/10 min | high | low | translucent | spunbond, slit tape, thin-wall injection |
| Lower-flow homopolymer | 1–12 g/10 min | high | low to moderate | translucent | sheet, pipe, thick-wall injection |
| Random copolymer | 2–30 g/10 min | moderate | good | high | clear film, blow molding, medical packaging |
| Impact copolymer | 0.2–30 g/10 min | low to moderate | high | low | automotive parts, crates, caps |
In cast-film and extrusion-lamination lines, the high MFR permits thin-gauge coating at lower melt temperature. A typical configuration uses a 65–90 mm single-screw extruder, a coat-hanger die with adjustable restrictor bar, and a chill-roll stack maintained at 15–30 °C. The lower melt strength of PP H350 FF increases neck-in relative to a 3 g/10 min homopolymer; die-gap adjustment and air-knife positioning are therefore set to minimize draw resonance. For slit-tape production, the extruded cast film is quenched at 25–35 °C, slit, and then oriented in a hot-air oven at 100–130 °C using draw ratios between 5:1 and 8:1. The homopolymer’s higher crystallinity contributes to tape tenacity but requires stable draw ratios. Excessive draw above 8:1 causes fibrillation and lowers transverse tear strength.
In spunbond nonwoven production, the melt temperature set point is the key variable because PP H350 FF operates close to the onset of thermo-oxidative chain scission. Extruder barrel profiles typically begin at 190–200 °C in the feed zone and rise to 230–240 °C at the metering section; the transfer line and spin beam are held at 235–250 °C. Above 260 °C, antioxidant consumption is accelerated, and the melt mass-flow rate can drift upward by 5–10 g/10 min during a single hour of residence time. The resulting viscosity drop lowers spinline stress, producing under-drawn filaments with lower tensile strength, higher elongation, and increased web fuzz. Equipment configuration matters: lines with 30:1 L/D single-screw extruders and gear melt pumps can hold die-pressure fluctuation within a narrow band if the feeding system supplies uniform pellet size and bulk density. Screen-pack integrity is also critical; a torn or misaligned screen can introduce unmelted particles and gel-like defects into the spinneret, increasing filament break frequency.
Quench air temperature and velocity set the final filament diameter and crystalline orientation. At quench-air temperatures below 12 °C, surface cooling is too rapid, producing a thick skin and a brittle core. Above 20 °C, filament draw-down becomes unstable and web uniformity deteriorates. Spinneret capillary diameter is generally 0.3–0.6 mm for spunbond deniers in the 0.8–2.2 dpf range; hole cleanliness and melt filtration at 200–400 μm are required to maintain denier uniformity. The material is not classified as hygroscopic, but surface condensation from silo storage can be removed by predrying at 80 °C for 2 hours before the hopper.
Stabilization practice for PP H350 FF in fiber and film applications relies on a synergistic package of a hindered phenolic antioxidant, a phosphite or phosphonite processing stabilizer, and an acid scavenger such as calcium stearate. The acid scavenger content is typically kept below 0.10 wt% to avoid die-lip build-up. The controlled-rheology nature of the grade means that peroxide addition for in-line vis-breaking is not required and should be avoided. Uncontrolled peroxide residuals can shift MFR beyond the specified 32–38 g/10 min window, affecting nonwoven fabric tensile strength and film seal strength. Color and additive masterbatches should be metered with a gravimetric feeder; carrier resins with low melt viscosity can reduce melt strength and should be tested under ISO 527-2 or ISO 527-3 before production. For applications requiring UV resistance, a hindered-amine light stabilizer is added at concentrations guided by accelerated weathering tests under ISO 4892-2 or ISO 4892-3; final loading depends on exposure class and fabric basis weight.
Regulatory compliance is not automatically transferred from pellet to final article; it depends on downstream processing and food-contact use. Polypropylene homopolymer based on propylene may fall within the scope of 21 CFR 177.1520 in the United States and Regulation (EU) No 10/2011 in the European Union when the final article meets applicable migration limits. The producer’s documentation for REACH registration and RoHS hazard-substance restrictions should be requested for the specific production site and lot. Because PP H350 FF contains only polypropylene and authorized additives, heavy-metal and phthalate content are expected to be below the usual RoHS reporting thresholds, but analytical verification by the converter remains required for electrical and electronic equipment applications.
Thin-wall injection molding of packaging and medical disposables benefits from the high MFR when hot-runner tooling is used. Melt temperature is held at 220–250 °C, mold temperature at 20–50 °C, and clamp force is selected based on projected area and wall thickness. In mold-filling simulation, the high-flow homopolymer gives lower injection pressure than a 12 g/10 min grade at identical gate and runner geometry; however, the low molecular weight reduces notched impact strength, so the grade should be used only where impact loads are moderate or where part design compensates with ribs and radii. Post-mold shrinkage under ISO 294-4 is typically 1.2–1.6%. For load-bearing medical or technical parts requiring sterilizable performance at 121 °C, a heat-stabilized homopolymer or a higher-molecular-weight grade should be selected instead of PP H350 FF. Final validation must include tensile testing after aging and sterilization, because the high-flow homopolymer can lose embrittlement resistance under repeated autoclave cycles.