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SIBUR PP Homopolymer PP H250 GP

    • Product Name: SIBUR PP Homopolymer PP H250 GP
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 593580
    Density 0.905 g/cm³
    Melt Flow Rate 25 g/10 min (230°C, 2.16 kg)
    Tensile Strength At Yield 35 MPa
    Elongation At Yield 11%
    Flexural Modulus 1600 MPa
    Charpy Impact Strength Notched 23c 3 kJ/m²
    Charpy Impact Strength Notched Minus 20c 1.5 kJ/m²
    Rockwell Hardness R110
    Heat Deflection Temperature 0 45 Mpa 100°C
    Vicat Softening Temperature 155°C
    Melting Point 165°C
    Water Absorption 24h 0.02%

    As an accredited SIBUR PP Homopolymer PP H250 GP factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing SIBUR PP Homopolymer H250 GP is supplied in 25 kg polyethylene-lined paper bags, palletized and shrink-wrapped for safe transport.
    Container Loading (20′ FCL) 20′ FCL: SIBUR PP H250 GP polypropylene pellets packed in 25kg bags on pallets, securely stowed for transport.
    Shipping SIBUR PP Homopolymer H250 GP is shipped as free-flowing granules in moisture-proof bags or bulk containers. Ensure dry, ventilated conditions, avoiding direct sunlight and temperatures above 50°C. This non-hazardous material should be handled with standard PPE and protected from impact or contamination during transport.
    Storage Store SIBUR PP Homopolymer PP H250 GP in a dry, clean, well-ventilated area, protected from direct sunlight, heat, and ignition sources. Keep original packaging sealed to prevent contamination and moisture pickup. Maintain moderate ambient temperatures and avoid prolonged UV exposure. Handle carefully to avoid damaging bags; suitable storage preserves product quality and processing performance.
    Shelf Life Store in a cool, dry place away from direct sunlight. Shelf life is typically 12 months from date of manufacture.
    Application of SIBUR PP Homopolymer PP H250 GP

    Injection moulding of SIBUR PP H250 GP into thin-wall food-contact containers and lids on high-speed stack mould systems requires direct control over melt temperature, injection velocity, and holding pressure. The grade is specified with a nominal melt flow rate of 25 g/10 min determined under ISO 1133-1:2022 at 230 °C and 2.16 kg, which places it in the high-flow range for general-purpose homopolymers. In a stack mould with 16+16 or 24+24 cavities and a wall thickness of 0.6 mm to 1.1 mm, the flow length-to-wall thickness ratio can exceed 200:1 when gate design uses a hot runner with isolated manifold temperatures of 235 °C to 245 °C. Injection speed is typically set between 300 mm/s and 600 mm/s on electric or hybrid injection units; insufficient injection velocity produces premature freeze-off at the flow front and visible sink marks near the gate, while excessive velocity increases shear heating and may generate molecular orientation that distorts round lids after demoulding. Holding pressure is maintained at 35 MPa to 55 MPa hydraulic pressure for a duration of 0.8 s to 2.0 s per mm of nominal wall thickness, with gate seal verified by part weight stability within ±0.3%. Mould temperature is controlled between 10 °C and 30 °C using turbulent water circuits with a Reynolds number above 4000; higher mould temperatures reduce residual stress but increase cycle time because the homopolymer has a heat deflection temperature below 100 °C under ISO 75-2 method A. Food-contact compliance relies on the polymer matrix meeting EU Regulation 10/2011 Annex I and FDA 21 CFR 177.1520(c) for olefin polymers; however, each formulated compound or masterbatch must be evaluated separately under EN 1186-1 migration testing because additives and processing aids can shift overall migration. Colour concentrates used in thin-wall packaging should be based on the same PP carrier and must not introduce zinc stearate above 0.05 wt% where organoleptic testing is specified for dairy applications. The principal processing limitation is warpage from anisotropic shrinkage; PP H250 GP has an unfilled mould shrinkage range of 1.2% to 1.8% depending on flow direction and mould cooling uniformity, and parts with deep draw or large flat areas require careful balancing of cooling channels to avoid differential shrinkage above 0.3 percentage points between rim and base.

    Typical injection moulding parameter ranges for PP H250 GP in thin-wall container production
    ParameterThin-wall container ≤0.8 mmLid or shallow container 1.0 mm1.5 mm
    Melt temperature235 °C255 °C230 °C250 °C
    Mould temperature10 °C25 °C15 °C35 °C
    Injection velocity350 mm/s700 mm/s200 mm/s450 mm/s
    Holding pressure40 MPa60 MPa30 MPa50 MPa
    Back pressure2 MPa5 MPa2 MPa6 MPa

    What limits continuous operation time in closure moulding with PP H250 GP?

    Continuous production of injection-moulded caps and closures for still beverages and non-carbonated liquid products is constrained by build-up of low-molecular-weight fractions on venting surfaces and by closure dimensional stability after ejection. Closure designs with tamper-evident bands joined by frangible bridges have wall sections between 0.4 mm and 0.9 mm; bridge thickness is commonly 0.12 mm to 0.25 mm, and rupture behaviour is influenced by the notch produced at the parting line. Moulds are typically operated at melt temperatures of 220 °C to 250 °C and cooling water temperatures of 8 °C to 20 °C, achieving cycle times below 6 s on 48-cavity tools. In sustained production, the main failure modes are ejection pin push marks on the closure top face when melt temperature exceeds 255 °C, and ovality above 0.3 mm on the outer diameter when the cooling circuit is unbalanced. Removal torque testing is product-specific; no single ISO standard defines the passing limit, but dimensional acceptance sampling can follow ISO 2859-1. PP H250 GP is a homopolymer and therefore exhibits lower environmental stress crack resistance than random copolymers; closures for contents with higher surface-active ingredients or for hot-fill above 60 °C are outside the recommended operating envelope unless a post-moulding annealing step is introduced. Food-contact status is assessed under EU Regulation 10/2011 and FDA 21 CFR 177.1520, but specific migration limits apply to the finished closure when a liner is present.

    Spunbond nonwoven die pressure and draw resonance constraints

    Polypropylene homopolymer with a nominal 25 g/10 min melt flow rate can be processed on spunbond nonwoven lines to produce hygiene, filtration, and packaging fabrics. In this configuration, the polymer is melted in a single-screw extruder with a barrier screw and filtered through a melt screen pack of 40 μm to 60 μm before entering a metering pump. The melt is delivered to a spinneret with hole diameters between 0.25 mm and 0.40 mm at melt temperatures of 230 °C to 245 °C. The high-flow homopolymer reduces die pressure compared to 18 g/10 min grades, but it also reduces melt strength. Spin line stability is required at draw ratios above 150:1; if air quench temperature and velocity are not precisely controlled, filament breaks increase sharply. Draw resonance appears as periodic diameter fluctuations along the filament bundle and can be observed at high throughputs above 0.7 g/hole/min depending on spinneret hole density and quench air uniformity. Fabric produced from PP H250 GP has a filament diameter distribution typically between 15 μm and 22 μm; basis weight is set by collector speed and throughput. Tests are performed according to ISO 9073-1 for basis weight, ISO 9073-2 for thickness, and ISO 9073-18 for tensile properties. Because the grade is a homopolymer, the nonwoven fabric has a relatively narrow thermal calendering window; calender roll temperature must be kept between 145 °C and 155 °C, and a variation above 2 °C across the roll width can produce uneven bond points with reduced tensile strength. Published data for the exact die pressure profile of PP H250 GP on multi-beam spunbond systems is limited; line trials are required to map pressure versus throughput for a given spinneret geometry.

    When a talc-filled automotive compound is produced with a 25 g/10 min homopolymer base

    In a 40:1 L/D co-rotating twin-screw extruder with screw diameter of 65 mm to 92 mm, SIBUR PP H250 GP is fed into the main hopper, while surface-treated talc is introduced through a side feeder at the L/D 28 position to limit particle attrition and devolatilization losses. At talc loadings of 10 wt% to 40 wt%, the compound melt flow rate falls from the base value of 25 g/10 min to a range that may extend below 10 g/10 min at the higher filler level, particularly when fine talc with a median particle size below 2 μm is used. A maleic anhydride grafted polypropylene coupling agent is added at 1 wt% to 3 wt% to promote interfacial adhesion; without this coupling agent, tensile yield strength and flexural modulus are lower and the compound exhibits brittle failure at low deformation. The melt temperature along the barrel is controlled between 200 °C and 230 °C, with the final die temperature restricted to 220 °C to reduce thermal degradation of the coupling agent. Mechanical property requirements for automotive interior substrates are usually evaluated under ISO 527-2 for tensile properties, ISO 178 for flexural modulus, and ISO 179-1/1eA for Charpy notched impact strength. A talc-filled compound based on PP H250 GP can achieve a flexural modulus above 2500 MPa at 20 wt% talc and above 3500 MPa at 40 wt% talc, but notched Charpy impact strength at 23 °C typically remains below 5 kJ/m² and drops below 2 kJ/m² at -30 °C. The operational boundary is therefore at low-temperature impact; components requiring ductile failure below -10 °C should use an impact copolymer base rather than PP H250 GP. In production, the main processing conflict is the increase in melt pressure at the die plate when filler level exceeds 35 wt%, which may require screen pack changes and vacuum venting at -0.08 MPa to remove moisture introduced by the talc.

    Effect of talc loading on selected compound properties for a PP H250 GP base
    Talc loadingFlexural modulus ISO 178Charpy notched impact at 23 °C ISO 179-1/1eAMFR after compounding ISO 1133-1
    0 wt%1200 MPa1500 MPa2 kJ/m²4 kJ/m²25 g/10 min nominal
    20 wt%2400 MPa2800 MPa3 kJ/m²5 kJ/m²15 g/10 min20 g/10 min depending on talc grade
    40 wt%3300 MPa3800 MPa2 kJ/m²4 kJ/m²8 g/10 min15 g/10 min depending on talc grade and coupling agent

    Household appliance trim components with limited load-bearing requirements are moulded from PP H250 GP at melt temperatures of 210 °C to 250 °C and mould temperatures of 15 °C to 40 °C; parts are limited to continuous service temperatures below 90 °C under ISO 75-2 method A, and warpage is controlled by cooling channel uniformity rather than by formulation changes.

    Masterbatch carrier resin and pigment dispersion thresholds

    PP H250 GP is used as a carrier resin in polyolefin masterbatches because its 25 g/10 min melt flow rate permits high pigment and additive loadings while maintaining adequate let-down into injection moulding or extrusion base resins. In a co-rotating twin-screw extruder or a high-shear internal mixer, the carrier is premixed with pigment, processing aid, and wax dispersant before melt compounding. For organic pigments, typical loadings are 40 wt% to 60 wt%, while for inorganic pigments such as titanium dioxide or carbon black, loadings can reach 60 wt% to 75 wt%. The critical dispersion threshold is reached when filter pressure rise exceeds 0.5 MPa/h on a 14 μm screen pack after 30 min of continuous extrusion; at that point, agglomerates larger than 5 μm are likely to survive let-down and produce visible specks in thin-wall parts. Processing temperatures for masterbatch production are maintained between 170 °C and 210 °C to protect heat-sensitive organic pigments, although the homopolymer itself can tolerate higher temperatures. The carrier resin must satisfy REACH registration and, for food-contact masterbatches, the finished article must comply with EU Regulation 10/2011 and FDA 21 CFR 177.1520. In let-down, a dilution ratio of 2% to 5% is common for single-pigment concentrates, but carrier-induced changes in the base resin melt flow should be checked by ISO 1133-1; the high-flow carrier can increase the final compound MFR by 0.5 g/10 min to 2 g/10 min depending on dilution ratio. Dispersion quality is assessed by film gauge test under EN 13900-5 or by pressure-rise test in the production extruder; particle count is reported as the number of undispersed particles per unit area according to the masterbatch specification. The main incompatibility is with amine-based hindered amine light stabilizers in certain packaging applications where reaction with pigment surface treatments may cause colour shift; screening under ISO 4892-2 accelerated weathering is required before final selection.

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    Certification & Compliance
    More Introduction
    SIBUR PP Homopolymer PP H250 GP is an injection-moulding grade of isotactic polypropylene supplied as reactor granulate. Its nominal melt flow rate is 25 g/10 min at 230 °C with a 2.16 kg load when tested to ISO 1133-1:2022. Density at 23 °C falls within 0.90–0.91 g/cm³ per ISO 1183-1. The melt-flow position of this grade places it between extrusion-oriented homopolymers with low melt flow and very high-flow thin-wall grades. That position translates into a balance of injection pressure demand, solidification rate, and melt strength. The material is intended for short-cycle injection moulding of rigid articles such as caps, closures, housewares, thin-wall food packaging, and general-purpose technical components where the absence of an ethylene copolymer phase is acceptable. Field data from 1000 kN toggle-clamp machines with 30 mm reciprocating screws show that H250 GP can fill rectangular containers with nominal wall thickness of 0.6 mm when injection velocity is kept above 180 mm/s. On the same equipment, gate freeze is observed in less than 0.5 s when mould temperature drops below 10 °C. This solidification front limits the use of oversized cold runners and favours direct sprue gating or hot-runner systems with short thermal paths.

    Which Barrel, Screw, and Hot-Runner Settings Are Required for This Melt-Flow Class?

    On reciprocating screw injection-moulding machines, a general-purpose polyolefin screw with length-to-diameter ratio of 20:1 and compression ratio of 2.5:1 is suitable. Barrel-zone settings are commonly profiled from 180–200 °C in the feed zone, 210–230 °C in the compression zone, 220–240 °C in the metering zone, and 220–245 °C at the nozzle. Melt temperature measured at the nozzle should be maintained between 220 °C and 250 °C. Back pressure is held between 5 bar and 15 bar hydraulic, while screw surface speed for this melt-flow class is typically 0.15–0.30 m/s. Higher screw speeds increase shear heating and may produce local melt temperatures above 260 °C even when barrel setpoints remain lower. The processing window is governed by two competing failure modes. At melt temperatures below 200 °C, apparent viscosity increases and the frozen skin thickens before the cavity fills, producing short shots and high residual orientation. At nozzle temperatures above 260 °C, thermo-oxidative chain scission accelerates, and surface splay or brown discolouration can appear after 5–10 min of static residence. Therefore hold-up time in the shot reservoir should be minimised, and shutdown of a hot runner with stagnant melt should not exceed 10 min without purging. For hot-runner systems, manifold and drop temperatures are held between 230 °C and 245 °C. If the hot runner exceeds 250 °C at the gate area, low-molar-mass species may deposit on cavity surfaces. In cold-runner systems, the sprue bush included angle should be 2–3° to allow clean sprue pull. Tunnel-gate and submarine-gate diameters below 0.8 mm can cause excessive shear heating and gate-vestige breakage. Published data for this specific configuration is limited when vented barrels or high-shear mixing screws are used. In such cases, the converter should first run a rheological window study using capillary rheometry or a mould-filling simulation validated against short-shot trials.

    Mechanical benchmark data for the H250 GP melt-flow class are reported under ISO 527-2 and ISO 178

    Mechanical property values for unreinforced homopolymer polypropylene are sensitive to specimen preparation, cooling rate, nucleating additives, and test speed. The following table reports representative ranges for homopolymer PP grades with MFR near 25 g/10 min, not lot-specific release limits for SIBUR H250 GP.
    PropertyTest methodUnitCharacteristic range for MFR 25 homopolymer PP
    Melt flow rateISO 1133-1:2022g/10 min25 nominal
    DensityISO 1183-1g/cm³0.90–0.91
    Tensile stress at yieldISO 527-2MPa33–37
    Tensile elongation at yieldISO 527-2%10–12
    Tensile modulusISO 527-2MPa1400–1800
    Flexural modulusISO 178MPa1500–1800
    Notched Charpy impact at 23 °CISO 179-1/1eAkJ/m²1.5–2.5
    Heat deflection temperature at 0.45 MPaISO 75-2/B°C90–100
    The crystalline melting peak of homopolymer PP in this class is usually recorded between 160 °C and 170 °C by differential scanning calorimetry per ISO 11357-3. This peak position is higher than that of propylene-ethylene random copolymers, which typically melt between 130 °C and 145 °C depending on ethylene content. The higher melting point supports short demoulding times, but it also reduces the melt-strength window for thermoforming and blow moulding. Consequently H250 GP is not the preferred choice for extrusion blow moulding, pipe, or sheet. Injection-moulded specimens prepared according to ISO 294-1 may show anisotropic shrinkage. On unfilled homopolymer PP of this flow class, mould shrinkage commonly falls between 1.0% and 1.6% in the flow direction and between 1.2% and 1.8% transverse to flow when measured per ISO 294-4. Weld-line tensile strength is lower than bulk tensile strength. If melt-front temperature falls below 180 °C before the fronts merge, weld-line strength can be reduced by 20–40% relative to the homogeneous section. This threshold is particularly relevant in moulds with multiple gates or flow interruptions.

    When H250 GP Replaces a Random Copolymer or Impact Copolymer in Rigid Articles

    Substitution of H250 GP for a random copolymer or heterophasic impact copolymer changes stiffness, impact resistance, optical clarity, and low-temperature behaviour. The table below compares property classes at equivalent melt flow.
    PropertyH250 GP homopolymer classRandom copolymer classImpact copolymer class
    Flexural modulus1500–1800 MPa900–1200 MPa800–1200 MPa
    Notched Charpy at 23 °C1.5–2.5 kJ/m²4–8 kJ/m²10–25 kJ/m²
    Heat deflection temperature at 0.45 MPa90–100 °C75–90 °C70–90 °C
    Haze on 1 mm plaque15–40%5–15%opaque
    Ductile-to-brittle transition regionnear or above 0 °C in notched geometrybelow 0 °C depending on ethylenecommonly below −20 °C
    The homopolymer grade provides higher flexural modulus and higher heat deflection temperature than random copolymer at equivalent MFR. This can support wall-thickness reduction in rigid packaging when top-load and panel-buckling requirements are verified by ISO 12048 or equivalent compression methods. The trade-off is lower notched impact strength. H250 GP should not be specified for frozen-food packaging, automotive interior parts requiring airbag deployment safety, or any application with service temperature below 0 °C and impact loading unless the part geometry is validated by instrumented puncture tests such as ISO 6603-2. Optical performance is also different. Homopolymer polypropylene has larger spherulitic structures than ethylene-containing random copolymer, increasing haze and reducing contact clarity. If transparent thin-wall containers are required, a random copolymer or a nucleated clarified grade is preferred. Nucleating agents can reduce spherulite size and improve stiffness, but they also alter shrinkage and may shift the crystallisation onset.

    When replacing a block copolymer in a non-impact application, the converter should first measure notched Charpy or instrumented puncture on the actual part geometry. Homopolymer PP can exhibit brittle failure at stress concentrations such as gate vestiges, weld lines, and sharp corners even at 23 °C. The absence of an elastomer phase also reduces tolerance to contamination by incompatible polymers such as polyethylene terephthalate or polyamide. Such contamination can produce delamination and weld-line separation.

    Regulatory Boundary Conditions and Resin Handling Limits for Converter Verification

    Unfilled polypropylene homopolymers are generally referenced in food-contact compliance under FDA 21 CFR 177.1520(c) when the final article meets extractive limits. In the European Union, compliance with Regulation (EU) 10/2011 requires overall migration below 10 mg/dm² for food-contact articles. However, published migration data for SIBUR H250 GP in aggressive food simulants such as 95% ethanol or isooctane are limited; converter-specific migration testing remains required for the finished article. Under REACH, the polymer itself is exempt from registration under Article 2(9), but monomers and additives must be registered. RoHS 2011/65/EU restrictions on lead, mercury, cadmium, hexavalent chromium, PBB, and PBDE apply only if the final product falls within the electrical and electronic equipment categories. Drying of unfilled PP homopolymer is generally unnecessary. Equilibrium moisture uptake at 23 °C and 50% RH is below 0.05 wt%. If surface condensation occurs during transfer from cold storage to a warm processing hall, or if pellet moisture exceeds 0.10 wt%, pre-drying at 80 °C for 2–4 h in a desiccant dryer with a dew point below −20 °C is sufficient. Drying above 100 °C should be avoided because pellet surface softening and additive migration can occur. Thermal stabilisation is required for prolonged service above 80 °C. This grade is intended for normal converter processing, not for long-term hot-water or automotive under-bonnet use. Outdoor exposure without ultraviolet stabilisation leads to surface chalking, embrittlement, and loss of tensile elongation. If outdoor use is required, the compound should contain a suitable hindered amine light stabiliser package or sufficient carbon black loading, and the weathering programme should be validated by ISO 4892-2 or ASTM G154. Copper-containing pigments and certain transition-metal salts can accelerate thermo-oxidative degradation and should be evaluated before use. Material handling should exclude contact with strong oxidising agents, chlorinated solvents at elevated temperature, and aromatic hydrocarbons that can swell or dissolve polypropylene. In silo or octabin storage, lot-to-lot variance in melt flow rate is normally controlled within the supplier specification; nevertheless, converters should monitor melt flow rate per ISO 1133-1:2022 on incoming lots and after drying to detect contamination or degradation.
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