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Shanghai SECCO LLDPE LL0209KJ

    • Product Name: Shanghai SECCO LLDPE LL0209KJ
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 626915
    Productname Shanghai SECCO LLDPE LL0209KJ
    Polymertype Linear Low Density Polyethylene (LLDPE)
    Comonomer Butene-1
    Density 0.920 g/cm³
    Meltflowrate 2.0 g/10min (190°C, 2.16kg)
    Meltingpoint 124 °C
    Vicatsofteningpoint 100 °C
    Tensileyieldstrength 12 MPa
    Elongationatbreak 800%
    Flexuralmodulus 320 MPa
    Dartdropimpactf50 120 g (50 µm film)
    Haze 14% (50 µm film)
    Gloss45 50 units
    Brittlenesstemperature -70 °C

    As an accredited Shanghai SECCO LLDPE LL0209KJ factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Supplied in 25 kg polyethylene bags, palletized with 20 bags per pallet, and shrink-wrapped for safe transport.
    Container Loading (20′ FCL) 20′ FCL: Shanghai SECCO LLDPE LL0209KJ resin pellets packed in woven bags, palletized, and securely loaded for safe transport.
    Shipping Shanghai SECCO LLDPE LL0209KJ is a non-hazardous linear low-density polyethylene resin, shipped as free-flowing pellets in moisture-proof bags or dry bulk containers. It must be kept clean, dry, and away from direct sunlight. Standard sea freight in ventilated, contamination-free containers, or rail/truck transport, ensures product integrity during transit.
    Storage Store Shanghai SECCO LLDPE LL0209KJ in a cool, dry, well-ventilated area, protected from direct sunlight, moisture, and heat. Keep containers/bags tightly sealed and avoid stacking excessively high. Store away from strong oxidizers and ignition sources. No special temperature control is required, but good warehouse hygiene prevents contamination and maintains resin quality.
    Shelf Life Shelf life: 2 years from manufacture if stored in a cool, dry area, protected from sunlight and moisture.
    Application of Shanghai SECCO LLDPE LL0209KJ

    On blown film towers producing 100–180 µm heavy-duty shipping sacks, SECCO LL0209KJ is typically introduced as the primary linear-low-density component at 75–90 wt% of the polyethylene fraction, with the balance being a low-density polyethylene grade selected for bubble stability and melt strength. The resin is a butene-based linear-low-density polyethylene film grade with a nominal density of 0.920 g/cm³ under ISO 1183-1:2019 and a melt flow index of 2.0 g/10 min under ISO 1133-1:2022; these values place the material in the intermediate-toughness film segment rather than the higher-dart hexene or octene copolymer segment. Compounding on a 65 mm single-screw extruder with a 30:1 L/D barrier screw and a Maddock mixer achieves acceptable melt homogeneity when the barrel profile is held at 180–210°C from feed zone to metering zone, while the adapter and die zones are maintained at 205–215°C. If the feed throat temperature exceeds 45°C, pellet bridging and irregular screw feeding have been documented on production lines, particularly when regrind content moves above 15 wt%.

    Die gap is normally set at 1.8–2.2 mm for 100–130 µm film and widened to 2.2–2.6 mm for 160–180 µm film because the thicker gauge requires a higher melt throughput and a more stable frost line. Blow-up ratio is maintained between 2.0:1 and 3.0:1, and internal bubble cooling is used to raise output by 20–35% compared with unassisted air rings on lines with a 250 mm die diameter. Anti-block masterbatch based on synthetic silica with 2–4 µm mean particle size is added at 0.2–0.5 phr, and erucamide slip is added at 0.05–0.1 phr; coefficient of friction values normally stabilize at 0.15–0.25 after 24–48 h under ISO 8295, but over-dosing above 0.15 phr erucamide can produce reverse blocking and creaminess on the film surface. End-user specifications are commonly referenced to ASTM D1709-16a and ASTM D882 with minimum values negotiated by sack fill mass and pallet stack height. Finished sacks are used for 25–50 kg fertilizer, polymer resin, and chemical powder packaging, where consistent film thickness and seal strength under automated filling heads are the critical conversion requirements.

    What Limits Puncture Retention in Cast Stretch Wrap?

    In cast stretch wrap produced on high-speed chill roll lines, the limiting variable for SECCO LL0209KJ is not melt temperature but the equilibrium between cling additive migration, film blocking, and machine-direction orientation. The resin is dry-blended or compounded with 2–5 wt% polyisobutylene cling agent having a weight-average molecular weight of 800–1200 g/mol and, where higher pre-stretch is required, with 10–25 wt% of a higher-melt-strength LLDPE or LDPE to stabilize the web at draw ratios above 200%. Typical film gauge is 12–20 µm, with cast line speeds of 200–500 m/min and an air gap of 15–25 mm between die lip and chill roll. The chill roll temperature is held at 15–20°C, and a secondary cooling roll is run at 10–15°C to limit stretch-induced crystallinity and maintain cling force.

    Puncture retention is assessed under ASTM D5748-19; film from the 0.920 g/cm³ butene copolymer class tends to show progressive puncture force decay when the machine-direction extension exceeds 250% before wrapping, because the oriented tie chains in the butene copolymer do not redistribute stress as effectively as hexene or octene copolymers. This is the critical threshold that converters will observe on pre-stretch units set above 250%. Cling is evaluated by unrolling resistance and, where required, by ISO 8295 kinetic coefficient of friction; the target COF after 24 h migration is often 0.15–0.30 on the outside surface and 0.05–0.15 on the cling surface. Over-addition of polyisobutylene above 5 phr causes film blocking at the reel core and edge tack transfer, while under-addition below 2 phr produces tail release during wrapping. Published data for this specific configuration on SECCO LL0209KJ is limited, so converters should validate the exact puncture retention curve on their own pre-stretch equipment.

    Downstream sectorLL0209KJ loadingCo-resin/additive packageTypical gaugeCritical test anchor
    Heavy-duty shipping sacks75–90 wt%LDPE 10–25 wt%; silica anti-block 0.2–0.5 phr; erucamide slip 0.05–0.1 phr100–180 µmASTM D1709-16a; ASTM D882; ASTM D1922
    Cast stretch wrap70–90 wt%PIB cling 2–5 wt%; other LLDPE/LDPE 10–25 wt%12–20 µmASTM D5748-19; ISO 8295; ASTM D882
    Greenhouse film70–85 wt%LDPE 15–30 wt%; HALS 0.3–0.8 phr; UV absorber 0.2–0.4 phr150–200 µmISO 4892-3; ASTM D1003; ISO 527-3
    Extrusion lamination60–80 wt%LDPE 20–40 wt% for melt curtain stability15–40 g/m²ISO 11339; ASTM F88
    Frozen food packaging70–85 wt%LDPE 15–30 wt%; anti-fog masterbatch 1–2 wt%40–80 µmASTM D1709-16a; ISO 6383-2; ASTM F1249

    Greenhouse Film Ageing and the Role of Melt Stabilization

    Greenhouse film specifications for 150–200 µm covers require a stabilizer package that survives both extrusion heat history and multi-season UV exposure; SECCO LL0209KJ serves as the linear-low-density backbone at 70–85 wt%, with LDPE at 15–30 wt% and a UV stabilizer masterbatch containing hindered amine light stabilizers at 0.3–0.8 phr plus a UV absorber at 0.2–0.4 phr. The stabilizer addition is not a simple masterbatch letdown because the migration and surface bloom behaviour of HALS in a 0.920 g/cm³ butene copolymer differs from that in LDPE; surface whitening can occur when the masterbatch carrier is incompatible or when the letdown ratio drops below 2 wt%. On a 90 mm grooved-feed extruder with 30:1 L/D, the melt temperature is held at 195–210°C, die gap at 2.0–2.4 mm, and blow-up ratio at 2.0:1–3.0:1.

    The critical processing constraint is gel formation: UV stabilizer agglomerates and oxidized LLDPE carryover from the feed system produce hard gels that are visible under ASTM D1003 haze testing and can initiate tear propagation under ISO 6383-2. Screen packs of 60/80/100 mesh are installed before the die, and the breaker plate is inspected after every 48 h of continuous operation to remove carbonized deposits. Accelerated weathering under ISO 4892-3 Cycle 1 is used for comparative retention of tensile elongation; greenhouse films typically must retain more than 50% of initial elongation after 6000 h of QUV exposure for multi-season use, but published data for LL0209KJ in this specific exposure window is limited, so validation on the exact masterbatch lot is required. Terminal applications include greenhouse covering, low-tunnel film, and silage clamp covers, where the film must withstand repeated mechanical contact with metal frame sections without splitting at staple points.

    Extrusion lamination with LL0209KJ is constrained by melt curtain stability rather than coating adhesion. The resin is used as a sealant or bulk layer in low-to-medium-speed extrusion lamination lines running 15–40 g/m² coating weights at melt temperatures of 290–320°C and line speeds of 80–250 m/min. At the low end of the melt temperature range, neck-in is wider and edge bead is more pronounced; at the high end, oxidative gel formation and odour rise. Adhesion to BOPP, PET, and aluminium foil is evaluated under ISO 11339, and heat-seal strength is measured under ASTM F88; corona treatment at 38–42 dyn/cm on the substrate immediately before the die station is required for consistent fibre tear on paper and metalized substrates. Published data for LL0209KJ in high-speed extrusion coating above 300 m/min is limited, and the grade is not recommended where a low-neck-in coating resin is required.

    When Layer Ratio in Frozen Food Packaging Shifts Below 80:20

    Frozen food packaging produced from LL0209KJ is normally a three-layer or five-layer coextrusion with the LL0209KJ-rich layer placed in the core and a lower-melting sealant resin in the skin. The film gauge range of 40–80 µm is selected according to fill temperature, product hardness, and distribution shock; a common structure is a skin layer of 10–15 wt%, a core of 70–80 wt% LL0209KJ, and a tie or second skin layer of 5–10 wt%. When the LL0209KJ fraction in the core drops below 80 wt% of the total polyethylene phase, low-temperature impact strength under ASTM D1709-16a at -20°C shows a measurable decline, and the seal-initiation temperature can rise when more LDPE is used to compensate for bubble instability. Blown film lines run with blow-up ratios of 2.2:1–3.0:1 and melt temperatures of 185–200°C; die gap is kept at 1.8–2.2 mm.

    Anti-fog masterbatch is added at 1–2 wt% when the package must maintain clarity for frozen vegetable or prepared-food display, but the anti-fog agent migrates to the surface within 24–48 h and can reduce seal strength if not permitted to fully bloom before slitting. Barrier performance is not a primary function of LL0209KJ; when a low water vapour transmission rate is required, the structure must include EVOH or a metallized layer, with WVTR assessed under ASTM F1249. Terminal products include frozen vegetable bags, poultry packaging, and industrial frozen food liners, where seal integrity after exposure to -30°C is the controlling conversion criterion.

    Regulatory areaStandard/regulationTypical test parameterLimit or status
    Food contact polyolefinFDA 21 CFR 177.1520(c)Olefin polymer clearanceCompliant when resin meets specified density and additive constraints
    Food contact plastics migrationEU 10/2011Overall migration< 10 mg/dm²
    Packaging heavy metalsEU 94/62/EC Article 11Sum of Pb, Cd, Hg, Cr(VI)≤ 100 mg/kg
    REACH screeningEC 1907/2006SVHC contentNo substance above 0.1% (w/w) without declaration
    Electrotechnical packaging residualRoHS 2011/65/EUPb, Cd limitsPb ≤ 1000 ppm; Cd ≤ 100 ppm
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    Certification & Compliance
    More Introduction

    Shanghai SECCO LLDPE LL0209KJ is an ethylene/1-butene linear low-density polyethylene produced at the Shanghai SECCO Petrochemical Co., Ltd. gas-phase polyethylene unit. It is supplied as a pelletized blown-film resin with a nominal melt mass-flow rate of 2.0 g/10 min determined at 190 °C under 2.16 kg load in accordance with ISO 1133-1:2022, and a nominal density of 0.920 g/cm³ measured at 23 °C in accordance with ISO 1183-1:2019. The 1-butene short-chain branching suppresses crystallinity relative to HDPE and MDPE, producing a tougher, puncture-resistant film with lower secant modulus than high-density polyethylene. The grade designation LL0209KJ encodes the linear low-density family, the nominal melt flow rate and density class, and a film-specific additive suffix. The exact additive package is proprietary and is disclosed in the lot-specific quality certificate.

    Typical application sectors include heavy-duty sacks, carrier bags, agricultural film, freezer film, industrial liners, and coextruded film structures where processability on conventional blown-film lines is a primary requirement. These sectors require a balance of bubble stability, melt strength, and thin-gauge toughness without excessive gel levels.

    What Does the Published Technical Datasheet Specify for LL0209KJ?

    Representative physical and film properties from the producer technical datasheet are listed in Table 1. These values are not mutual specification limits; lot-specific certificates govern. Film properties are thickness-dependent and are generated on 50 µm blown film at a 2.5:1 blow-up ratio, 200 °C melt temperature, and 2.0–2.2 mm die gap unless otherwise indicated.

    Table 1 — Representative physical and blown-film properties
    PropertyTest methodTypical value
    Melt mass-flow rateISO 1133-1:20222.0 g/10 min
    DensityISO 1183-1:20190.920 g/cm³
    Tensile stress at yield, MD/TDISO 527-3:201811 MPa / 11 MPa
    Tensile stress at break, MD/TDISO 527-3:201822 MPa / 20 MPa
    Elongation at break, MD/TDISO 527-3:2018500% / 700%
    Dart impact resistance, method AISO 7765-1:1988≥110 g
    Elmendorf tear resistance, MD/TDISO 6383-2:1983100 g / 300 g
    HazeISO 14782:199912%
    Gloss at 60°ASTM D2457-1340
    Melting temperature, DSC second heatISO 11357-3:2018122 °C
    Vicat softening temperature, A50ISO 306:202298 °C

    Because the grade is a butene-copolymer LLDPE, the mechanical values reflect a different crystalline structure from high-pressure LDPE or HDPE. Tensile yield stress and tear resistance are influenced by film gauge, frost-line height, and orientation. The dart impact and Elmendorf tear values are strongly gauge-dependent and should be confirmed on the targeted line before setting incoming quality-control limits.

    Film extrusion on conventional single-screw blown-film lines requires close attention to melt rheology. A 0.920 g/cm³ butene-LLDPE shows less shear thinning than high-pressure LDPE, so extruder head pressure and motor load increase at equivalent screw speed. A barrier screw with 25:1–30:1 L/D and a Maddock or barrier mixing section is recommended. Melt temperature is maintained within 190–220 °C. Die gap is widened to 1.8–2.2 mm to reduce melt fracture and sharkskin. The blow-up ratio is held between 2.0:1 and 3.0:1, and frost-line height is set at 2–3 die diameters. These settings are start-up values rather than universal limits; they are adjusted based on die diameter, output rate, and ambient conditions. The resin’s 2.0 g/10 min MFR limits head pressure while maintaining bubble stability in medium-molecular-weight packaging films.

    The lower long-chain branching of LL0209KJ also reduces melt strength relative to high-pressure LDPE. Bubble support through internal bubble cooling, a higher frost-line, or a stabilizing cage may be required if gauge uniformity is insufficient. At high take-off rates, the onset of melt fracture is managed by increasing die gap and lowering die shear stress rather than by reducing output alone.

    When Replacing LDPE with LL0209KJ in Heavy-Duty Sack Structures

    At equivalent film thickness, a butene-LLDPE with density 0.920 g/cm³ and MFR 2.0 g/10 min exhibits higher tensile strength at break and puncture resistance than high-pressure LDPE of comparable melt index. The improvement is associated with the linear backbone and short-chain branches rather than long-chain branching. Under ISO 527-3:2018, tensile energy to break is typically higher, permitting gauge reduction of heavy-duty sacks by 20–30% in validated structures. However, the same structural difference increases shear viscosity and modifies bubble stability. Melt pressure may rise by 10–30% relative to LDPE at the same output, and die gap widening is required to avoid melt fracture.

    Compared with HDPE film of 0.945 g/cm³ density, LL0209KJ has lower tensile yield stress and lower stiffness, but higher dart impact resistance under ISO 7765-1 and greater tear propagation resistance under ISO 6383-2. The lower crystallinity reduces water-vapour barrier relative to HDPE; therefore, LL0209KJ is not selected where moisture barrier is the primary function unless laminated with a barrier layer.

    Across the butene-copolymer LLDPE range, property changes are driven by density and MFR. A grade with density 0.922 g/cm³ at the same MFR provides higher secant modulus and higher tensile yield stress under ISO 527-3:2018, but lower dart impact strength and lower Elmendorf tear resistance. A fractional-melt film grade with MFR 0.9 g/10 min may provide marginally higher toughness but will increase extruder pressure and may reduce output. The selection of LL0209KJ over such grades is therefore based on a balance of processability on older lines, gauge reduction, and package toughness.

    Differentiation from metallocene-catalyzed LLDPE is also required. Metallocene grades of equivalent density and MFR generally have narrower comonomer and molecular weight distributions. This gives lower haze and higher dart impact, but lower process stability and higher melt pressure. LL0209KJ, as a conventional Ziegler-Natta butene-copolymer, trades some optical and toughness performance for easier processing, lower gel sensitivity, and lower melt pressure on legacy blown-film lines. Published data for the direct comparison of LL0209KJ against specific metallocene film grades is limited; the user should compare film properties on the same line.

    Regulatory Status in Food-Contact and Industrial Film Applications

    Food-contact evaluation begins with the base-olefin polymer designation. In U.S. jurisdictions, LLDPE may be evaluated under FDA 21 CFR 177.1520(c) for olefin polymers. The final article must meet the specific conditions of use and food-type classification; the resin’s antioxidant, slip, and antiblock additives require independent clearance. In the European Union, compliance is assessed under Commission Regulation (EU) No 10/2011 with an overall migration limit of 10 mg/dm² for plastic materials and specific migration limits for authorized additives. For industrial film sectors, the resin is commonly evaluated under REACH Regulation (EC) No 1907/2006 and Directive 2011/65/EU for restricted substances.

    Table 2 — Compliance evaluation frameworks
    FrameworkRelevant designation/clauseEvaluation focus
    U.S. food contactFDA 21 CFR 177.1520(c)Olefin polymer specification; end-use temperatures and food simulants
    EU food contactCommission Regulation (EU) No 10/2011Overall migration limit 10 mg/dm²; authorized additives
    China food contactGB 4806.7-2016Migration limits, sensory properties, total migration
    REACHRegulation (EC) No 1907/2006SVHC content 0.1% w/w
    RoHSDirective 2011/65/EUPb, Cd, Hg, Cr(VI), PBB, PBDE

    The table identifies evaluation frameworks, not a compliance declaration. Because the product is sold as a pelletized resin and downstream processing may introduce additional additives or contaminants, the producer’s certificate of conformity and a completed article migration test are required for final applications. The as-supplied pellet does not contain long-term UV protection unless specified in the lot certificate; agricultural film converters must add suitable stabilizer masterbatches during extrusion.

    In silo storage and pneumatic conveying, pellet surface moisture must be controlled if the resin has been exposed to high-humidity warehousing. Polyethylene is non-hygroscopic; pre-drying is generally unnecessary unless surface condensation is present. If surface moisture is observed, a dehumidified-air hopper dryer at 60–70 °C for 2–4 h may be used. The resin should not be over-dried or exposed to temperatures above 90 °C for extended periods because antioxidant depletion may occur. Purging is performed with a lower-viscosity LDPE or a commercial purging compound; polystyrene and PVC purges are to be avoided. The hopper, loader, and die lip should be inspected for carbonized residue if line shutdown exceeds 30 min at processing temperature.

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