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Sasol CMR348 PP Copolymer

    • Product Name: Sasol CMR348 PP Copolymer
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 336599
    Melt Flow Rate 8.0 g/10min (230°C, 2.16kg)
    Density 0.905 g/cm3
    Tensile Strength At Yield 27 MPa
    Elongation At Yield 12%
    Flexural Modulus 1200 MPa
    Izod Impact Notched 23c 5.0 kJ/m2
    Izod Impact Notched Minus20c 2.0 kJ/m2
    Rockwell Hardness R90
    Heat Deflection Temperature 0 45mpa 85 °C
    Vicat Softening Temperature 145 °C

    As an accredited Sasol CMR348 PP Copolymer factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Supplied in 25 kg moisture-protective bags on heat-shrink wrapped pallets, ensuring safe handling and product integrity.
    Container Loading (20′ FCL) Sasol CMR348 PP Copolymer is loaded for 20′ FCL in 25kg bags, palletized, and securely containerized for safe transport.
    Shipping Sasol CMR348 is a polypropylene copolymer supplied as free-flowing pellets. It ships in sealed multiwall bags, octabins, or bulk containers. Keep dry, away from heat, ignition sources, and direct sunlight. Not classified as dangerous goods for road, rail, or sea transport. Protect packaging from damage during handling.
    Storage Store Sasol CMR348 PP Copolymer in a cool, dry, well-ventilated area, away from direct sunlight, heat sources, and open flames. Keep containers tightly sealed to prevent contamination and moisture uptake. Avoid generating dust; use proper grounding to prevent static discharge. Maintain moderate temperatures and separate from oxidizing agents or incompatible materials.
    Shelf Life Sasol CMR348 PP Copolymer has a typical shelf life of two years when stored in original, unopened packaging under cool, dry conditions.
    Application of Sasol CMR348 PP Copolymer

    Sasol CMR348 PP copolymer is injection-moulded into thin-walled rigid food packaging at melt temperatures of 220–250 °C and mould temperatures of 10–40 °C; the grade is formulated at 96–100 wt% CMR348, with 2–4 wt% PP-based colour masterbatch and 0.5–2 wt% slip/antiblock masterbatch where denesting and lid-open force must be controlled. The compliance basis for this segment rests on EU Regulation (EU) No 10/2011, particularly Annex I and Annex V overall migration limits of 10 mg/dm², US FDA 21 CFR 177.1520(c)(1.1) for olefin polymers, and EN 1186-1:2002 migration test protocols. Processing on high-speed injection moulding machines with clamp forces from 1,500–4,500 kN, screw L/D ratios of 20:1–24:1, compression ratios of 2.5:1–3.0:1, and injection velocities of 120–250 mm/s is used to fill wall thicknesses of 0.4–0.8 mm before gate freeze occurs. In production-scale tools, a recurring failure mode is flow hesitation at sharp radius transitions below 1.0 mm, producing shear-induced visible flow lines and short shots even when the hot runner is mechanically balanced; reducing the gate land from 1.5 mm to 0.8 mm and raising nozzle temperature to 245 °C restores fill consistency. Terminal article types include 150–500 mL dairy cups, margarine tubs, dessert cups, round ready-meal containers, and rectangular food trays with rim and lid compatibility. CMR348 should be pre-dried at 80 °C for 2–4 h only when surface moisture exceeds 0.05 wt%; prolonged melt residence above 250 °C should be limited to under 5 min to avoid thermo-oxidative chain scission and loss of low-temperature impact.

    What processing limitations control low-fogging automotive interior substrates?

    In automotive interior injection moulding, CMR348 is typically specified for low-gloss, grained substrates that must survive cold-temperature airbag deployment and instrument panel structural loads without exhibiting brittle detachment. The formulation addition ratio commonly runs at 100 wt% CMR348 with 2–4 wt% colour masterbatch and 0.5–1.5 wt% of a low-fogging stabilizer masterbatch; external slip agents are avoided because stearyl erucamide at levels above 0.1 wt% is a documented fogging source in VDA 278:2011 thermodesorption analysis, and commercial formulations reported in automotive supply chains often require total VOC below 100 µgC/g and fogging condensate under 2 mg depending on specific OEM engineering specifications. Flammability is assessed by FMVSS 302 and ISO 3795 with a typical burn-rate ceiling of 100 mm/min. The process runs on injection moulding machines of 6,000–25,000 kN clamp force, with L/D ratios of 20:1–24:1, sequential valve gating on 2–6 drops, melt temperature between 230–260 °C, mould temperature between 25–50 °C, injection velocity between 80–180 mm/s, holding pressure between 40–70 MPa, and cooling time from 15–35 s. Production-scale experience indicates that batch-to-batch MFR drift of ±2 g/10 min under ISO 1133-1:2022, condition M, can shift fill time by 0.2–0.4 s in multi-cavity tools and displace knit lines by 20–40 mm; cavity-pressure sensors at end of fill are therefore maintained at 45–55 MPa to stabilise part dimensions. Terminal finished-product types are door trim panels, centre console carriers, B/C-pillar trim covers, glove box outer shells, and seat side shields, all of which require post-mould dimensional checking because differential shrinkage across thickness transitions of 1.5–2.5 mm can create visible read-through on the grain face.

    For returnable logistics crates and interlocking pallets, CMR348 is direct-moulded at wall thicknesses from 2.5–4.0 mm, where cooling time becomes the cycle-dominant variable rather than injection speed. The formulation addition ratio is set at 80–100 wt% CMR348, 0–20 wt% recycled PP regrind, 2 wt% colour masterbatch, 1–2 wt% HALS-based UV stabilizer masterbatch for outdoor exposure, and 1–3 wt% antistatic masterbatch only for electronics transit crates; exceeding 2 wt% UV masterbatch can lower weld-line strength at latch and hinge features by 10–20% in ISO 179-1:2023 Charpy impact testing because the stabilizer package changes local crystallinity at the knit line. Compliance for pallets is anchored to ISO 8611-1:2021 test methods for plastic pallets, ASTM D4169-22 for distribution-cycle vibration and shock, and ISO 179-1:2023 notched Charpy impact at -20 °C for cold-room retrieval. The process operates on clamp forces from 8,000–30,000 kN, melt temperatures of 230–250 °C, mould temperatures of 20–50 °C, injection velocities of 50–120 mm/s, packing pressures of 40–60 MPa, hold times of 10–25 s, and total cycle times of 35–55 s. The most common production-scale defect is top-edge distortion of 1–2 mm caused by differential shrinkage between the thick base and thinner sidewall; a two-stage pack profile followed by post-mould cooling fixtures is required. Terminal product types include bottle crates, dairy crates, agricultural field crates, interlocking logistics pallets, and distribution totes.

    Application trackReference instrument or standardClause or test designationTypical acceptance condition
    Thin-wall food packagingEU Regulation (EU) No 10/2011Annex I, Annex VOverall migration ≤ 10 mg/dm²
    Thin-wall food packagingUS FDA21 CFR 177.1520(c)(1.1)Olefin copolymer compliance
    Automotive interior substratesVDA 278:2011VOC and fogging thermodesorptionOEM-specified ceilings, commonly ≤ 100 µgC/g
    Automotive interior substratesFMVSS 302 / ISO 3795Horizontal burn rateBurn rate ≤ 100 mm/min
    Returnable logistics cratesISO 8611-1:2021Plastics pallet test methodsRated load and stacking cycles
    Industrial pailsUN Model Regulations, 23rd rev.Chapter 6.1Drop height 1.2 m at -18 °C for Packaging Group II
    Appliance structural partsIEC 60335-1:2020 + A1:2021Clause 30, material testsGlow-wire 750 °C or 850 °C per appliance class
    Appliance structural partsUL 94:2023Vertical burn, 3.0 mmHB or V-2 depending part function

    Industrial pail moulding requires drop-impact and handle-weld coordination

    CMR348 is formulated for industrial pails and container lids at 100 wt% CMR348 with 2–4 wt% colour masterbatch and, only for powder or solvent-contact packagings, 0.5–1.5 wt% antistatic masterbatch; external mould-release additives are avoided because the pail surface must retain adhesive labelling integrity and interior coating compatibility. The controlling compliance route is the UN Model Regulations, 23rd revised edition, Chapter 6.1 for non-removable-head plastics packagings, with drop testing at 1.2 m for Packaging Group II after conditioning at -18 °C, supported by ISO 2248 for vertical drop and ISO 12048 for stacking creep performance. The downstream process uses injection moulding machines between 4,500–12,000 kN clamp force, melt temperatures of 230–250 °C, mould temperatures of 15–40 °C, injection velocities of 70–150 mm/s, holding pressures of 40–60 MPa, and wall thicknesses from 1.5–2.5 mm. The critical process conflict is at the handle hinge and bottom gate region: the hinge is a high-flow-length weld zone that must resist tensile tear during filled-pail drop cycles, while the bottom gate must be located to avoid jetting into the pail sidewall. Production-scale failure modes include stress whitening at the hinge weld line after low-temperature drop impact and sidewall sink marks at the gate boss; these are mitigated by placing the gate near the hinge dome, reducing injection speed to 70–90 mm/s during the first 20% of fill, and using a two-stage pack profile that decays from 55 MPa to 35 MPa over 6 s. Terminal product types are 5 L, 10 L, 15 L, 20 L, and 25 L open-head pails, tamper-evident container lids, and paint or lubricant pails.

    Within appliance manufacturing lines, cavity-pressure measurement is used to control CMR348 parts where dimensional repeatability determines assembly fit to sheet-metal panels and sealing interfaces. The formulation addition ratio is 85–100 wt% CMR348, 0–15 wt% mineral masterbatch for stiffness adjustment, 2–4 wt% colour masterbatch, and 0–10 wt% flame-retardant masterbatch only when UL 94 V-2 at 3.0 mm is required; brominated flame-retardant masterbatches must be RoHS Directive 2011/65/EU compliant and free of polybrominated biphenyls and polybrominated diphenyl ethers. The compliance base includes IEC 60335-1:2020 with Amendment 1:2021 for household appliance material suitability, IEC 60695-2-11 glow-wire testing at 750 °C or 850 °C depending on unattended appliance class, and UL 94:2023 vertical burn classification. Process conditions on 4,500–12,000 kN machines use melt temperatures of 240–255 °C, mould temperatures of 30–60 °C, injection velocities of 60–140 mm/s, and holding pressures of 35–60 MPa; cavity-pressure setpoints are maintained between 35–50 MPa to avoid short-shot at rib intersections and overpacking at bosses. The main production-scale variance is top-surface gloss variation between 30–60 °C mould temperature zones, which becomes visible on large flat areas; conformal cooling or segregated mould temperature circuits are required. Terminal parts include washing machine control console carriers, top-cover inner frames, dishwasher door-liner supports, and dryer structural side panels.

    ParameterThin-wall food packagingAutomotive interiorLogistics crates/palletsIndustrial pails
    Wall thickness0.4–0.8 mm1.5–2.5 mm2.5–4.0 mm1.5–2.5 mm
    Melt temperature220–250 °C230–260 °C230–250 °C230–250 °C
    Mould temperature10–40 °C25–50 °C20–50 °C15–40 °C
    Injection velocity120–250 mm/s80–180 mm/s50–120 mm/s70–150 mm/s
    Holding pressure30–60 MPa40–70 MPa40–60 MPa40–60 MPa
    Clamp force requirement1,500–4,500 kN6,000–25,000 kN8,000–30,000 kN4,500–12,000 kN

    When CMR348 replaces heavier engineering resins in automotive under-bonnet and HVAC modules

    When CMR348 is selected to replace heavier engineering resins in HVAC module housings, battery covers, fuse box brackets, and fan shroud carriers, the formulation addition ratio is adjusted to 70–90 wt% CMR348, 1–2 wt% heat-stabiliser masterbatch, 2–4 wt% colour masterbatch, and 5–15 wt% mineral masterbatch where dimensional stability under moderate heat is required; copper-based stabiliser systems are avoided because copper ions can catalyse oxidative chain scission in PP at under-bonnet peak temperatures. The compliance framework includes ISO 16750-3:2023 for mechanical vibration and shock, ISO 179-1:2023 notched Charpy impact at -40 °C, ISO 188:2023 for long-term heat ageing, and UL 94:2023 HB classification. Processing uses injection moulding machines of 5,000–10,000 kN clamp force, melt temperatures of 230–250 °C, mould temperatures of 30–60 °C, injection velocities of 50–120 mm/s, holding pressures of 40–60 MPa, and post-mould annealing at 90–100 °C for 1–2 h when dimensional progression during subsequent heat exposure must be reduced. The process risk is a low-temperature impact cliff edge: heat ageing at 100 °C for 500 h can reduce notched Charpy impact by 20–40% depending on stabiliser concentration, and published data for this specific CMR348 heat-aged configuration is limited, so OEM validation under ISO 188:2023 is required before series release. Terminal product types are HVAC module housings, battery covers, fuse box brackets, fan shroud carriers, and air-filter housing bases.

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    Certification & Compliance
    More Introduction

    Sasol CMR348 is an in-reactor impact-modified polypropylene copolymer supplied in pelletized form for injection moulding. The grade is classified under ISO 19069-2:2016 as a propylene impact copolymer; its multiphase architecture consists of a semicrystalline propylene homopolymer matrix and a dispersed ethylene-propylene rubber phase generated during the polymerization sequence. It should not be confused with a random propylene copolymer, which is optically clear and has lower stiffness but also lower notched impact at ambient temperature. Lot-release testing for CMR348 normally includes melt mass-flow rate by ISO 1133-1:2022 at 230 °C/2.16 kg, density by ISO 1183-1:2019, tensile properties by ISO 527-2:2012, notched Charpy impact by ISO 179-1/1eA:2010, and heat deflection temperature by ISO 75-2/B:2013. The specified melt flow interval is a production-control value; the certificate of analysis supersedes class-typical expectations. Impact copolymer grades of this flow class typically occupy a melt flow range of 30 g/10 min to 40 g/10 min; published data for this specific CMR348 configuration is limited to the supplier lot certificate.

    Production-control envelope for CMR348; values are class-typical for high-flow heterophasic copolymers and must be verified against the supplier lot certificate.
    ParameterTest designationUnitExpected production-control envelope
    Melt mass-flow rate, 230 °C/2.16 kgISO 1133-1:2022g/10 min30–40
    Density, 23 °CISO 1183-1:2019g/cm³0.900–0.910
    Tensile modulusISO 527-2:2012MPa1,000–1,300
    Tensile yield stressISO 527-2:2012MPa22–27
    Tensile yield strainISO 527-2:2012%5–7
    Charpy notched impact at 23 °CISO 179-1/1eA:2010kJ/m²8–15
    Charpy notched impact at -20 °CISO 179-1/1eA:2010kJ/m²3–6
    Heat deflection temperature, 0.45 MPaISO 75-2/B:2013°C70–85
    Vicat softening temperature, 50 NISO 306/A50:2013°C145–155

    These ranges are not specifications; they are reported here as a pre-award screening tool. Where an application is load-bearing, the purchaser should request a notarized certificate of analysis and a representative batch sample for verification by an ISO/IEC 17025:2017 laboratory.

    What Distinguishes an In-Reactor Impact Copolymer from a Dry-Blended Polypropylene/Elastomer Compound?

    The difference is morphological control and phase adhesion. In an in-reactor impact copolymer such as CMR348, the ethylene-propylene rubber domains are formed and dispersed during polymerization rather than by post-reactor melt compounding. This restricts rubber domain growth and produces a more stable stiffness-impact relationship than dry blending a 35 g/10 min polypropylene homopolymer with an ethylene-propylene or ethylene-octene elastomer. A dry-blended compound can be tailored to higher rubber content, but it generally requires a twin-screw extrusion step with high dispersive mixing and may exhibit larger batch-to-batch variation in rubber dispersion and interfacial bonding. By comparison, high-flow polypropylene homopolymers at equivalent melt flow often show tensile modulus values above 1,400 MPa but notched Charpy impact values below 3 kJ/m² at 23 °C. Random copolymers trade impact for transparency and lower seal initiation temperature. CMR348 therefore occupies a middle position: opaque, with higher room-temperature ductility than a homopolymer, higher stiffness than many random copolymers, and lower cold-temperature toughness than a purpose-compounded elastomer-modified grade.

    Within the Sasol polypropylene portfolio, lower-melt-flow impact copolymers near 12 g/10 min provide greater low-temperature impact but require higher injection pressures and longer filling times. Grades with melt flow rates above 50 g/10 min fill extremely thin walls but lose tensile yield strength and may exhibit reduced weld-line integrity. CMR348 is positioned for applications that demand a balance of flow length, short cycle time, and moderate impact resistance without the added cost of a compounded elastomer system.

    On a three-zone reciprocating-screw injection-moulding machine with a screw L/D ratio of 20:1 to 24:1 and compression ratio of 2.5:1 to 3.5:1, CMR348 reaches a stable melt cushion when the barrel profile is set from 190 °C at the feed throat to 230 °C at the nozzle. The material should not be held at melt temperatures above 280 °C for prolonged periods because oxidative chain scission shifts the melt flow rate upward and reduces notched impact strength. If the hopper has been exposed to humid air or cold storage, pre-drying at 80 °C for 2 h to 4 h is recommended, although polypropylene does not require hydrolytic drying. Back pressure should be limited to 0.5 MPa to 1.0 MPa to avoid excessive shear heating. Mould temperature from 20 °C to 50 °C is typical; lower temperatures reduce cycle time but increase residual stress and orientation, while higher temperatures improve surface transcription from the cavity but may increase post-demoulding shrinkage anisotropy.

    Melt rheology and filling-pressure limitations in thin-wall tooling

    Single-point melt flow rate is not sufficient for thin-wall filling simulation. For accurate injection-pressure prediction, the supplier should provide capillary viscosity data generated under ISO 11443:2021 or proprietary Cross-WLF coefficients validated for the specific grade and lot. Published CMR348-specific rheology is limited; therefore, simulation should be validated with spiral-flow and short-shot studies on the intended tool. In thin-wall sections below 1.2 mm, the filling-to-packing switchover point is controlled more by gate freeze than by melt temperature. Premature gate freeze produces underpacked parts with high mould shrinkage, sink marks, and reduced weld-line strength. Delayed gate freeze with excessive holding pressure can overpack the cavity and create warpage due to differential shrinkage between flow and transverse directions.

    Unfilled polypropylene impact copolymers of this family typically exhibit mould shrinkage from 1.2% to 1.8% in the flow direction and 1.0% to 1.5% perpendicular to flow. Tool design must account for this anisotropy, particularly around sharp corners, ribs, and bosses. Shrinkage variation across wall thickness is a common source of post-demoulding distortion in production-scale equipment. On a 120-ton clamp force machine, parts with rib root thickness above 60% of the nominal wall can generate sink marks that require periodic pack-pressure adjustments. Published data for this specific grade on production-scale tools is limited; successful setting transfer between machines requires mould-temperature mapping and pressure-transducer verification at the nozzle and cavity.

    If Post-Demoulding Distortion Falls Outside the Dimensional Tolerance, Adjust Packing Before Melt Temperature

    Dimensional stability is influenced more by packing pressure, gate geometry, and cooling time than by barrel setpoint changes within the recommended range. A first-stage correction on a production line should hold cavity pressure until gate freeze; a second-stage correction should reduce screw forward time in 0.1 s increments to avoid overpacking. Adjusting melt temperature alone rarely resolves warp because it changes both viscosity and crystallinity development. For semicrystalline polypropylene, rapid cooling at low mould temperature generates fine spherulites and lower total shrinkage but may increase internal stress. Slower cooling at higher mould temperature produces larger spherulites and a more relaxed morphology but also increases total shrinkage. Therefore, the mould-temperature setpoint must be held constant during dimensional-capability studies.

    When CMR348 is supplied as a natural pellet for food-contact or medical packaging, the converter must verify migration limits under EU Regulation 10/2011 and FDA 21 CFR 177.1520 rather than assume compliance. The olefin polymer positive list permits propylene homopolymers and copolymers, but additives, colorants, and processing aids introduced before melt conversion must be covered by their own migration or additive clearances. For automotive interior applications, the base resin should be combined with a stabilization package that passes VDA 277 VOC emission screening, VDA 270 odour testing, and ISO 6452:2021 fogging; the test result belongs to the finished part, not the unfilled resin. CMR348 should not be specified for continuous service above short-term HDT values without a creep-rupture evaluation, and it should not be used in contact with strong oxidizing acids, chlorinated solvents, or aromatic hydrocarbons at elevated temperatures without compatibility testing.

    Compliance verification matrix for natural CMR348 injection-moulding applications.
    RequirementCitation or test designationVerification focus
    European food-contact plasticsEU Regulation 10/2011Overall migration and specific migration limits for final article
    United States olefin polymer food-contactFDA 21 CFR 177.1520Natural polymer compliance; no non-approved colorants or processing aids
    REACH registration and restrictionRegulation (EC) No 1907/2006, Annex XVIINo restricted substance above applicable concentration limit
    EU RoHS directiveDirective 2011/65/EU as amended by (EU) 2015/863Lead, mercury, cadmium, hexavalent chromium, PBB, PBDE screening
    Automotive interior foggingISO 6452:2021Condensate formation from finished part
    Automotive interior VOC emissionVDA 277Total volatile organic compound release from finished part

    In luggage-shell and thin-wall appliance housings where wall sections fall below 1.2 mm, the high-flow character of CMR348 permits filling-to-packing switchover at lower hydraulic pressures than a 12 g/10 min impact copolymer, but the reduced molecular weight lowers the notched Charpy value at -20 °C; parts requiring cold-drop resistance below -20 °C should be evaluated under the OEM impact protocol before tool release.

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