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Saint-Gobain CHR M746 Polyester Film Backing Silicone Adhesive Pressure Sensitive Tape

    • Product Name: Saint-Gobain CHR M746 Polyester Film Backing Silicone Adhesive Pressure Sensitive Tape
    • Factroy Site: Yinchuan, Ningxia, China
    • Price Inquiry: sales8@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 851089
    Product Name Saint-Gobain CHR M746 Polyester Film Backing Silicone Adhesive Pressure Sensitive Tape
    Manufacturer Saint-Gobain
    Brand CHR
    Model M746
    Tape Type Pressure Sensitive Tape
    Backing Material Polyester Film
    Adhesive Type Silicone
    Color Clear
    Total Thickness 2.0 mil (0.051 mm)
    Backing Thickness 1.0 mil (0.025 mm)
    Adhesive Thickness 1.0 mil (0.025 mm)
    Adhesion To Steel 25 oz/in (2.7 N/cm)
    Tensile Strength 25 lb/in (44 N/cm)
    Elongation At Break 100%
    Operating Temperature Range -100°F to 500°F (-73°C to 260°C)
    Dielectric Strength 5000 V
    Core Diameter 3 in
    Standard Length 36 yd (33 m)
    Available Width 1/4 in to 12 in

    As an accredited Saint-Gobain CHR M746 Polyester Film Backing Silicone Adhesive Pressure Sensitive Tape factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Saint-Gobain CHR M746 tape is packaged as 1 roll per carton, individually wrapped to protect the silicone adhesive from contamination.
    Container Loading (20′ FCL) 20′ FCL: Saint-Gobain CHR M746 polyester film silicone adhesive tape rolls, palletized, evenly loaded, braced, and secured for ocean shipment.
    Shipping Saint-Gobain CHR M746 Tape is a non-hazardous, pressure-sensitive polyester film tape with silicone adhesive. It is not classified as dangerous goods for shipping. Transport in original sealed packaging, protected from moisture, extreme heat, sunlight, and contamination. No UN number, hazard class, or packing group required.
    Storage Store Saint-Gobain CHR M746 Polyester Film Backing Silicone Adhesive Pressure Sensitive Tape in a cool, dry, well-ventilated area away from sunlight, heat, sparks, and moisture. Keep in original sealed packaging at controlled room temperature (15–27°C) and moderate humidity. Avoid incompatible chemicals, sharp objects, pressure, dust, and UV light. Rotate stock and follow manufacturer shelf-life recommendations. Do not stack heavy items.
    Shelf Life Typically 12 months from date of manufacture when stored unopened in original packaging at 21°C and 50% relative humidity.
    Application of Saint-Gobain CHR M746 Polyester Film Backing Silicone Adhesive Pressure Sensitive Tape

    Lead-free wave soldering of edge-card assemblies places pressure-sensitive masking tape in direct contact with molten Sn-Ag-Cu alloys and aggressive organic acid flux systems. In this operation, CHR M746 is applied over gold-finger contacts on printed wiring boards before conveyorized fluxing and dual-wave or selective wave soldering. The polyester backing at 0.002 in (0.051 mm) maintains sufficient stiffness for automated tape dispensing, while the silicone adhesive layer at 0.0015 in (0.038 mm) provides release after preheat exposure without tearing. Masking geometry requires the tape edge to extend 0.5 mm to 1.0 mm beyond the transition between plated gold and solder mask to prevent molten solder penetration into the contact zone. Production failure modes include edge lifting caused by fluxer spray impingement and adhesive ooze when applicator roll pressure exceeds the set point. When edge lifting occurs, solder wave turbulence elevates the polyester film and permits solder splash under the tape, producing solder balls and flux residues that are not acceptable for Class 3 assemblies. Board top-side preheat temperature should remain between 110 °C and 130 °C before wave contact; prolonged preheat above that band softens the silicone adhesive and increases lateral movement. Terminal assemblies include backplane edge connectors, PCIe riser cards, and industrial controller boards requiring inspection under IPC-A-610. Soldering acceptance criteria in J-STD-001 do not permit post-wave adhesive residue or masking-related contamination on gold fingers. Silicone adhesives, however, can deposit low-surface-energy species on adjacent solder mask; if conformal coating is applied after tape removal, wetting failure may occur within 1.0 mm of the masked edge unless plasma treatment or a qualifying solvent wipe is implemented. Peel adhesion data generated under ASTM D3330/D3330M is not sufficient to predict field performance because flux chemistry and board topography change the removal force and residue profile.

    What Controls Splice Survival During Roll-to-Roll Metallization and Coating?

    High-speed polyester film converting requires roll changes without line stops, and splice tapes must withstand web tension, heated nip rolls, and vacuum metallization conditions. When CHR M746 is used to join an expiring roll to a new roll, the overlap length is set in proportion to web gauge. For 12 µm polyethylene terephthalate film, splice overlap of 20 mm to 30 mm is common; for 50 µm film, overlap length is typically 30 mm to 50 mm. The single-coated silicone adhesive gives rapid tack to corona-treated PET at unwind tension between 15 N/m and 30 N/m, but tack falls sharply when relative humidity drops below 20%. In such conditions, pre-wetting of the film surface is not recommended because water interferes with silicone adhesive crosslink mobility. Longitudinal tensile strength of the polyester backing is measured under ASTM D3759/D3759M; a typical nominal value is 438 N/100 mm at 23 °C. During vacuum metallization, the backing must survive radiant heat from aluminum evaporation boats and contact with water-cooled drum surfaces at −15 °C to +5 °C. The resulting temperature gradient across the splice creates shear stress at the adhesive–polyester interface. If the splice passes through a corona treater after coating, silicone adhesive may oxidize and leave a visible haze on the finished roll; converters therefore record and remove spliced sections before final winding. Terminal products include barrier film for food packaging, capacitor-grade film, and holographic base film. Converters generally require splice traceability under ISO 9001, but the tape itself is not a food-contact material. Direct placement on food-contact surfaces is not appropriate unless the converter confirms migration compliance of the complete laminate under EU Regulation 10/2011. Failure of a splice in a metallizer can wrap the coating drum and contaminate the chamber with silicone adhesive, so splice survival testing at the maximum line speed is mandatory before release to production.

    When Batch Oven Powder Cure Demands Silicone Adhesive Masking Above 200 °C

    Powder coating lines mask threaded bosses, bearing seats, and grounding pads with pressure-sensitive tape before electrostatic spray. CHR M746 is applied after degreasing and phosphate or zirconium pretreatment because silicone adhesive will not bond reliably to oily stamping lubricant or wet conversion coatings. Typical powder cure schedules for TGIC polyester powder are 200 °C metal part temperature for 10 min to 15 min; epoxy-polyester hybrid powders cure at 180 °C for 10 min. The polyester backing maintains dimensional stability during cure, and the silicone adhesive strips cleanly after bake when the mask is designed correctly. Masking geometry requires overlap onto the metal surface of no less than 1.5 mm around circular bosses and 3.0 mm on rectangular pads to prevent powder intrusion from electrostatic wrap. Edge lifting emerges when oven temperature overshoot exceeds +5 °C because the polyester backing shrinks faster than the adhesive can flow. This failure mode appears first on thin-gauge brackets with low thermal mass placed near top oven racks. Silicone residue transfer has been documented on zinc-phosphated steel after 25 min at 215 °C; therefore cure cycles must not exceed the powder manufacturer’s upper time limit without testing removal cleanliness. After cure and cooling, the tape is pulled at an angle of 180° with a slow, steady peel. Peel force varies with substrate roughness but is typically lower than peel adhesion to steel measured under ASTM D3330/D3330M. Pulling the tape before the part cools below 60 °C increases adhesive residue on textured substrates. Terminal parts include automotive seat frames, electrical enclosure panels, and architectural aluminum extrusions. Powder coat adhesion after tape removal is verified by cross-cut testing according to ISO 2409:2013. Any silicone contamination outside the masked boundary can produce fisheyes in subsequent liquid topcoat operations, so masked areas must be solvent-wiped if a wet-on-powder topcoat is specified. The silicone adhesive is not suitable for use on substrates that will receive adhesive bonding without downstream plasma or fluorine-based surface treatment.

    Wound stator and field-coil production interposes polyester film tape between winding layers to reduce turn-to-turn movement and maintain creepage distance in low-voltage electric motors. In half-lap application, CHR M746 is wound with 50% overlap, producing two backing layers across every point on the coil lamination stack. The silicone adhesive is specified over acrylic alternatives because it does not soften during varnish cure cycles at 150 °C to 165 °C and because it holds the backing in place during vacuum pressure impregnation of epoxy or unsaturated polyester varnish. Winding tension is controlled below the tape yield point; field data from coil winders show that excessive tension above 30 N/25 mm can thin the polyester backing and reduce dielectric strength before varnish encapsulation. Dielectric strength of fresh tape is tested under ASTM D149; typical nominal value for the total thickness is 5 kV, but the useful rating after varnish cure depends on air entrapment between tape layers. Air trapped at the overlap edge can initiate partial discharge in motors operated above 600 V; operators therefore roll-press each layer with a silicone-faced roller at 0.2 MPa to 0.4 MPa nip pressure. Terminal wound products include Class F motors rated at 155 °C and intermittent Class H windings rated at 180 °C. Insulating tape requirements for use in electrical equipment are covered by UL 510, which includes tests for dielectric strength, tensile strength, and heat-aged adhesion. The polyester backing is hygroscopic to a small degree; coils should be dried at 105 °C before varnish impregnation if storage relative humidity exceeds 60%. Silicone adhesive is not recommended for oil-filled transformer winding tapes unless compatibility with mineral oil is verified under IEC 60422 or the transformer manufacturer’s own aging protocol.

    Downstream applicationGoverned test or standardCritical parameterTypical value or acceptance criterion
    Wave solder maskingIPC J-STD-001, IPC-A-610Solder splash residue after 260 °C wave contactNo residue on gold fingers; Class 3 acceptable
    Roll-to-roll splicingASTM D3759/D3759MTensile strength at 23 °CTypical nominal 438 N/100 mm
    Powder coat maskingISO 2409:2013Cross-cut adhesion after 200 °C cureNo coating lifting at taped boundary
    Coil interlayer insulationUL 510, ASTM D149Dielectric strength, heat-aged adhesionInitial typical 5 kV; no relift after 165 °C
    Autoclave tool maskingASTM D3759/D3759M, ASTM E595Tensile after 177 °C; outgassingNo backing shrinkage; TML report for critical use
    Flexible heater positioningISO 10993-1Finished device biocompatibilityRequires device-level verification

    Autoclave Tool Masking and Thermocouple Hold-Down in Composite Cure

    Aerospace composite layup often uses polyester-backed silicone tape to hold thermocouple wires and vacuum bag seals against aluminum or invar tool surfaces during autoclave cure. CHR M746 is applied to the tool, not to uncured prepreg, because silicone adhesive can inhibit resin wetting if transferred to the laminate. Cure cycles for 180 °C-cure epoxy prepregs typically ramp at 1 °C/min to 3 °C/min to a final cure of 177 °C for 120 min with autoclave pressure at 6 bar to 7 bar. Under these conditions, polyester backing remains dimensionally stable, but shrinkage can occur if localized tool surface temperatures exceed 200 °C near heat-up ramps. Tape application over thermocouple junctions requires a bond width of 10 mm to 15 mm on either side of the wire; narrower widths allow the wire to debond under vacuum bag compaction, producing temperature measurement lag. On production autoclave tools, residue from silicone adhesive can accumulate after repeated cures. Cleaning with methyl ethyl ketone or isopropyl alcohol does not fully remove silicone films, and periodic abrasive cleaning or plasma treatment is required to maintain tool surface energy above 38 mN/m for subsequent bag sealant adhesion. Terminal composite parts include carbon-fiber-reinforced epoxy spoilers, radomes, and leading-edge ribs. The tape is not used as a release film or peel ply because polyester backing does not provide the porosity or release chemistry required for those functions. Aerospace tape qualification generally references ASTM D3759/D3759M for tensile strength after thermal aging and may require outgassing data under ASTM E595 for spacecraft interiors. Published data for this specific configuration is limited, so qualification programs should run a tool residue coupon trial before production implementation.

    Flexible printed heater and sensor assembly uses polyester film tape as a temporary positioning aid during screen printing of conductive ink, lamination of foil elements, and termination of stranded lead wires. In heater manufacturing, CHR M746 is applied across the transition between the foil trace and the insulated lead wire before the stack is pressed at 150 °C to 170 °C and 0.5 MPa for 20 min to 30 min. The silicone adhesive does not flow into screen-printed silver-palladium traces under those pressures because flow is limited by the crosslinked silicone network, not by backing stiffness alone. A bond width of 5 mm across the lead wire is sufficient for positioning during lamination, but it is not a permanent electrical insulation layer in the finished device. After lamination, the tape is removed and the termination is encapsulated with a screen-printed dielectric overcoat. Terminal products include patient warming pads, battery preheater foils, and microfluidic diagnostic cartridges. Compliance for medical device assemblies is not automatically satisfied by the tape; manufacturers must evaluate biocompatibility of the finished device under ISO 10993-1 because silicone adhesive components can migrate during final assembly. In battery preheater foils, the tape must not be used as the sole layer between resistive traces and aluminum backing because polyester backing lacks the thermal aging margins required for continuous operation above 105 °C. Long-term aging at 85 °C and 85% relative humidity on copper circuits has shown that silicone adhesive can corrode exposed copper if humidity penetrates the adhesive edge; terminals should be sealed with an overcoat to prevent this failure mode.

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    Certification & Compliance
    More Introduction

    Saint-Gobain CHR M746 is a single-coated pressure-sensitive tape comprising a biaxially oriented polyester film backing and a silicone pressure-sensitive adhesive layer. The product is supplied in slit rolls and log rolls. Manufacturer-published nominal construction data list total thickness as 0.076 mm, backing thickness as 0.025 mm, and adhesive thickness as 0.051 mm. The continuous service temperature range is specified from -73 °C to 204 °C. The silicone adhesive is selected where high-temperature masking, electrical insulation, splicing of low-energy release liners, or coil wrapping is required and where acrylic adhesives soften by cohesive failure above 120–150 °C. The product is not a direct substitute for polyimide-backed silicone tapes in applications exceeding 204 °C. Use of the tape as a primary insulation barrier is not recommended; end-use creepage and clearance requirements remain governed by the final equipment standard.

    What thermal and electrical boundaries govern M746 use?

    The thermal limit is set by the polyester backing rather than by the silicone adhesive. At 204 °C, the backing withstands short cure cycles, but oxidative embrittlement begins with cumulative exposure. In forced-air powder-coating ovens with air velocities above 2 m/s, edge lift is observed when the cure dwell exceeds 20 min; process validation is required beyond this window. The manufacturer-published breakdown voltage is 7.5 kV under ASTM D149 using a 500 V/s rise in air, but the value applies only to dry, unstressed film. Creases, solvent wiping, puncture, and dust contamination reduce breakdown voltage. UL 510 flame-retardant recognition should be confirmed for the specific slit width and lot; the manufacturer’s file number applies only to the listed construction. In coil-winding operations, a single half-lap layer of the product serves as supplementary insulation rather than as reinforced insulation.

    Moisture absorption in the polyester film is below 0.8% by weight at 23 °C and 50% RH; at higher humidity, the tape should be conditioned in a dry area before dielectric testing. In tropical environments with relative humidity above 60%, pre-drying at 50–60 °C for 24 h is used before varnish potting or encapsulation. Silicone adhesive does not develop sufficient edge-sealing capacity under ambient conditions to prevent liquid varnish wicking; a varnish-compatible edge seal may be required.

    Machine-direction tensile strength is published at 438 N/100 mm with elongation at break near 100% under ASTM D3759. Transverse-direction properties are lower and are influenced by slit-edge microcracking from tungsten carbide shear blades. On rotary shear slitters, web tension below 1.5 N/mm of web width and blade overlap between 0.02 mm and 0.05 mm reduce edge fracture. Wound roll hardness between 75 and 90 Shore A edge durometer readings prevents telescoping and blocking during storage and shipping. The polyester backing is not intended for repeated flexural stress beyond 10,000 cycles; cyclic bending can initiate delamination at the adhesive interface.

    Slitting-induced edge fracture is a known failure mode on narrow widths below 12 mm. A blade lateral runout below 0.5 mm and a sharpened blade angle between 20° and 30° reduce defects. If the edge shows visible white stress crazing, the roll is rejected because dielectric breakdown can initiate at those microcracks.

    Adhesion build, release, and roll-converting constraints

    Peel adhesion to stainless steel is approximately 6.0 N/25 mm at 180° peel and 300 mm/min under ASTM D3330. On low-energy surfaces, adhesion is dwell- and pressure-dependent. A lamination nip at 0.2–0.4 MPa and a rubber roll hardness of 60–80 durometer improves initial bond; ultimate peel on silicone-coated liners may not stabilize until 24 h of dwell at 23 °C. The silicone PSA does not separate cleanly from itself at elevated temperature; hot stripping above 100 °C can produce cohesive splitting. After powder-coating cure, the tape is removed after cooling below 65 °C to avoid residue and backing fracture. Stamping oils and release agents lower room-temperature peel, so the substrate is cleaned with isopropanol or methyl ethyl ketone before placement. Published data for adhesion to plasma-treated polypropylene and polytetrafluoroethylene are limited; line trials are required because peel strength on these surfaces depends on surface energy, roughness, and dwell.

    In powder-coating masking, M746 is applied to clean, dry metal or primed surfaces before electrostatic spray. The backing resists strike-through from powder overspray under booth voltages of 60–100 kV. Cure cycles up to 204 °C for 15–20 min are tolerated; above this window, polyester shrinkage can exceed 2% and produce lifted edges. Where a sharper paint line is required, a thinner polyimide-backed silicone tape is substituted because the 0.076 mm total caliper of M746 creates a thicker edge profile. Masking removal is performed at part temperatures below 65 °C. On textured powder-coated surfaces, adhesion may be lower than on smooth steel; a pre-production trial with actual cure conditions is necessary because powder chemistry, gloss level, and cure time change the tape release.

    For clean removal from powder-coated surfaces, the adhesive’s low surface energy leaves minimal residue, but residue inspection should be performed with white lint-free wipes and isopropanol under 45× magnification for high-reliability parts. If residue is observed, a solvent wipe is applied after cooling.

    When a silicone adhesive replaces an acrylic system, processing validation changes

    Silicone pressure-sensitive adhesives have lower room-temperature initial tack than solvent-borne or emulsion acrylic PSAs, but they retain cohesive strength at temperatures where acrylic systems soften. In lamination, this means M746 may require a higher nip pressure or a dwell time before heat exposure. Acrylic tapes bond rapidly to high-energy metal surfaces; M746 reaches final adhesion on low-energy substrates after sufficient wetting and dwell. In roll-to-roll splicing, a minimum overlap length of 25 mm and web tension below 0.8 N/mm are used to compensate for the lower initial shear of the silicone PSA. If immediate room-temperature tack is the controlling variable, a silicone adhesive is not the first choice. If the process includes a subsequent powder-coat or varnish cure above 150 °C, the silicone system is retained because acrylic adhesives may soften, ooze, and leave residue.

    In coating lines, acrylic PSA tapes are often processed at 15–25 °C; M746 handles the same slitting and laminating equipment, but unwind tension may need to be reduced because the silicone adhesive’s lower room-temperature shear modulus can allow adhesive flow at the roll edges. Unwind tension above 1.0 N/mm of web width can cause edge ooze and roll blocking during storage.

    The polyester backing is hydrolyzed by hot aqueous alkaline solutions above 60 °C and swollen by strong acids and chlorinated solvents. The silicone adhesive is resistant to moisture and oxidation, but prolonged immersion in ketones or aromatic hydrocarbons reduces peel strength. When the tape is used in electrical potting or varnish systems, compatibility with solvent-borne varnishes is tested per IEC 60464-2 or the relevant end-use standard. Published data for solvent immersion of M746 at elevated temperature are limited. A trial under actual concentration, temperature, and dwell is required for chemical exposure applications.

    Thermal Degradation Pathways Separate M746 from PTFE and Polyimide Backings

    Above 204 °C, the polyester backing undergoes thermal shrinkage and oxidative embrittlement. Polyimide-backed silicone tapes are specified to 260–315 °C and are selected for high-temperature electrical insulation and aggressive masking. Polytetrafluoroethylene/fiberglass tapes provide a lower-energy release surface and higher continuous temperature, but the woven backing is thicker and less uniform at the masked edge. General-purpose polyester/acrylic tapes are lower in cost but are limited to roughly 120–150 °C continuous exposure and are not used where high-temperature cohesive failure would contaminate a coated surface. The selection of M746 is therefore made when the process ceiling is 204 °C and the backing must provide a smooth, nonwoven masking edge with dielectric strength above 5 kV.

    The following comparative values are typical and are not to be interpreted as specification limits. Test methods are identified for each measurement.

    PropertyCHR M746PET/acrylicPolyimide/siliconePTFE/fiberglass/silicone
    Continuous service-73 °C to 204 °C-40 °C to 130 °C-73 °C to 260 °C-73 °C to 260 °C+
    Nominal total thickness0.076 mm0.050–0.080 mm0.060–0.080 mm0.13–0.18 mm
    Breakdown voltage7.5 kV (ASTM D149)5.0–6.0 kV (ASTM D149)6.0–7.5 kV (ASTM D149)4.0–8.0 kV (ASTM D149)
    Machine-direction tensile strength438 N/100 mm (ASTM D3759)350–450 N/100 mm (ASTM D3759)530–620 N/100 mm (ASTM D3759)300–600 N/100 mm (ASTM D3759)
    Adhesion to low-energy release surfacesModerate–highLowHighHigh
    Cost classIntermediateLowHighHigh

    Compliance status applies to the standard construction and must be confirmed against the current manufacturer certificate for the specific width and lot.

    Standard or regulationRelevance
    UL 510Flame-retardant adhesive tape component recognition; recognition is construction-specific.
    ASTM D1000General test methods for pressure-sensitive electrical tapes.
    ASTM D149Dielectric breakdown voltage and dielectric strength of solid electrical insulating materials.
    ASTM D3330Peel adhesion of pressure-sensitive tape.
    ASTM D3759Breaking strength and elongation of pressure-sensitive tapes.
    RoHS 2011/65/EURestriction of hazardous substances; manufacturer certification should be requested for each lot.
    REACH 1907/2006SVHC content in the standard construction; the candidate list changes and must be rechecked.

    The product is not recommended for continuous immersion in hot aqueous alkaline solutions above 60 °C, for primary insulation creepage and clearance in mains-supply circuits without overvoltage classification, or for service above 204 °C where polyimide or PTFE backings are specified. Silicone PSA residues can interfere with subsequent bonding or coating steps that require polar or silane-primed surfaces; residue removal is required before those operations. In vacuum applications, the silicone adhesive may release low-molecular-weight cyclic siloxanes under low-pressure and elevated-temperature conditions. Published outgassing data for this specific construction are limited. Cleanroom compatibility is not implied by the standard product; if the tape is used in ISO 14644-1 Class 7 or lower, packaging and particle counts must be specified separately. The tape should be evaluated in the installed configuration under the end-use thermal, mechanical, and electrical load profile.

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