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SABIC LLDPE 318BJ

    • Product Name: SABIC LLDPE 318BJ
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 120788
    Density 0.935 g/cm³
    Melt Flow Rate 190 C 2 16 Kg 3.5 g/10 min
    Tensile Strength At Yield 15 MPa
    Tensile Strength At Break 13 MPa
    Elongation At Break 500%
    Flexural Modulus 550 MPa
    Shore D Hardness 58
    Vicat Softening Temperature 70 °C
    Brittleness Temperature -80 °C
    Environmental Stress Crack Resistance F50 >1000 h

    As an accredited SABIC LLDPE 318BJ factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing SABIC LLDPE 318BJ is supplied as pellets in 25 kg woven bags, palletized, shrink-wrapped, with 1,000 kg per pallet.
    Container Loading (20′ FCL) 20′ FCL loaded with 25kg bags of SABIC LLDPE 318BJ, palletized and secured for safe, efficient transport.
    Shipping SABIC LLDPE 318BJ is a non-hazardous linear low-density polyethylene resin, shipped as free-flowing pellets. Transport in clean, dry, covered containers or bags to prevent contamination and moisture pickup. Avoid excessive heat and direct sunlight. No dangerous goods classification required under standard transport regulations.
    Storage Store SABIC LLDPE 318BJ in a clean, dry, well-ventilated area away from direct sunlight, heat, and ignition sources. Keep original packaging sealed or properly covered to prevent dust, moisture, and contamination. Avoid sharp objects or rough handling that could damage bags. No special hazardous storage is required, but maintain good housekeeping and follow standard polymer handling practices.
    Shelf Life Shelf life is indefinite when stored in dry, cool conditions, away from direct sunlight and excessive heat.
    Application of SABIC LLDPE 318BJ

    Processors running multi-cavity thin-wall tub tools specify SABIC LLDPE 318BJ for a melt flow rate of 33 g/10 min at 190 °C/2.16 kg per ISO 1133-1:2022 and a density of 0.918 g/cm³ per ISO 1183-1:2019. The narrow molecular weight distribution provides shear-thinning behaviour that maintains cavity fill in wall sections between 0.50 mm and 1.20 mm. In tools of 16–32 cavities, cylinder temperatures are profiled from 180 °C at the feed throat to 210–230 °C at the nozzle, with mould temperature held at 15–30 °C. Injection pressure is normally 60–110 MPa, hold pressure 40–70 MPa for 2–6 s, and decompression 3–5 mm prevents nozzle drool between shots. Accumulator-assisted injection units with a screw L/D of 20:1–24:1 and compression ratio of 2.5:1 are preferred because the high MFR requires a shallow screw profile to avoid excessive shear heating.

    The main processing conflict is that low melt elasticity increases the tendency for jetting and gate blush when gate velocities are too low. Multi-cavity valve-gated hot runners should use gate diameters of 1.0–2.0 mm and fill times of 0.30–0.80 s; sequencing valve gates open after the pre-fill signal to prevent hesitation marks along the thinnest sidewalls. Mould cooling circuits are cut so cavity surface temperature stays above dew point, otherwise condensation generates splay and gloss differential across lid seal grooves. Because the grade solidifies quickly, packing is effective only within the first 1.5–2.5 s after fill, making gate freeze time a critical control variable. Cycle times on production-scale equipment with part weights of 12–28 g commonly run 4.5–8.0 s, with clamp forces of 1,500–3,500 kN used to prevent flash at high injection velocities.

    Food-contact compliance for the finished article is evaluated under US FDA 21 CFR 177.1520 paragraph (c) for olefin polymers and under EU 10/2011 with an overall migration limit of 10 mg/dm² using simulants assigned by food type, typically 10 % ethanol for aqueous foods, 3 % acetic acid for acidic foods, and 50 % ethanol for emulsions. Specific migration testing for pigments and processing aids must be completed on the production tool. Terminal products include dairy tubs, deli containers, stackable food storage bases, and thin-wall produce trays. Published data for this specific configuration is limited to base-resin compliance statements and the processing window; additive-dependent sensory and migration results must be generated on the production mould.

    Does the 33 g/10 min Melt Flow Rate Limit Gate Freeze Time in Multi-Impression Closure Tools?

    Gate freeze time in closure moulding governs whether hold time can be shortened without creating sink opposite the gate. In a 32-cavity cold-runner tool producing snap-overcaps with part weights of 2.8–4.5 g and wall thickness of 0.8–1.5 mm, melt temperature is set at 200–220 °C, mould temperature at 20–35 °C, and fill speed is configured to complete injection in 0.25–0.60 s. Hold pressure is 30–50 MPa for 1.5–3.0 s; longer hold times do not improve dimensional stability because the gate freezes quickly at thin-wall dimensions. Multi-impression tools often show cavity-to-cavity weight variation below ±0.5 % when the runner system is geometrically balanced, but valve-gate drop-to-drop imbalance can still produce differential shrinkage in hinged caps.

    Living-hinge design requires hinge thickness between 0.25 mm and 0.35 mm, oriented perpendicular to the melt flow front to allow molecular orientation across the flex line. Gate location on the top panel, not on the hinge edge, prevents a weak weld line along repeated flex stress. ESCR behaviour is evaluated under ASTM D1693 condition B in 100 % Igepal CO-630, but closures in contact with surfactant solutions require in-house stress-crack testing with the actual fill formulation because ESCR data from the base resin cannot predict failure at knife-cut gate scars. Closures moulded from 318BJ are not recommended for carbonated beverages or pressure-bearing retort systems; lower creep resistance at elevated headspace pressure makes them less suitable than HDPE or PP alternatives. Compliance follows FDA 21 CFR 177.1520 and EU 10/2011, with additional 94/62/EC heavy-metal restrictions when the closure is part of packaging. Terminal products include snap-overcaps, dust caps, hinge caps for non-carbonated dry products, and tamper-evident overcaps.

    Housewares Tooling, Stackability Constraints and Surface Gloss Replication

    For stackable storage totes, drawer organisers, and housewares baskets, 318BJ is selected primarily for high-gloss surface replication and low injection pressure to fill long grid structures. Part weights range from 150 g to 800 g, with nominal wall thickness of 1.5–3.0 mm; melt temperatures of 200–230 °C and mould temperatures of 25–40 °C are used. Injection pressure is held at 50–90 MPa, followed by a two-stage pack profile: 55–65 MPa for 2–4 s, then 30–40 MPa for 6–12 s. Cooling time depends on the thickest rib intersection and normally runs 12–30 s; premature ejection before the part reaches 60–70 °C at the rib root causes stackability distortion after 48 h of free-standing storage.

    Dimensional control for stackability is assessed after 48 h at 23 ± 2 °C and 50 ± 5 % RH per ISO 294-4. Mould shrinkage differences between flow and transverse directions of 0.1–0.3 % are sufficient to create rim bowing if the gate is positioned on one side of a large rectangular base. Central sprue or multiple hot-tip gates are preferred; for low-profile totes, an edge film gate along one side can balance flow but reduces the acceptable packing window. Surface gloss replication is controlled by cavity finish SPI A-2 or SPI A-3, with the highest gloss achieved when melt front speed is maintained above 100 mm/s in open flow regions and when coolant inlet temperature is kept above 15 °C to prevent condensation-driven splay. The combination of high MFR and low melt elasticity also lowers sink mark depth, but thick bosses and standing ribs must be cored or gusseted to keep effective wall thickness below 2.5 mm; otherwise voiding at the rib base becomes the limiting quality defect.

    Consumer housewares sold in the EU are evaluated under REACH for SVHCs and under RoHS Directive 2011/65/EU for restricted substances in electrical accessories; for food-use storage, the same food-contact certificates apply as for thin-wall packaging. Terminal products include stackable totes, drawer bins, under-bed storage trays, and small baskets. Mould-release sprays are not recommended because silicone external lubricants migrate to the surface and reduce print adhesion after in-mould labelling or heat transfer decoration.

    Process variableThin-wall food containersClosure toolsHousewares
    Melt temperature range210–230 °C200–220 °C200–230 °C
    Mould temperature range15–30 °C20–35 °C25–40 °C
    Injection pressure range60–110 MPa40–80 MPa50–90 MPa
    Hold pressure range40–70 MPa30–50 MPa30–65 MPa
    Typical fill time0.30–0.80 s0.25–0.60 s1.0–3.0 s
    Typical cycle time4.5–8.0 s4.0–7.0 s18–40 s

    When 318BJ Is Let Down with Fractional-Melt HDPE for Stiffness-Limited Industrial Pails

    Rigid pails and open-top drums with a liner function often require modulus beyond the neat LLDPE range. A compound of 318BJ with fractional-melt HDPE at 15–35 wt% is used to raise flexural modulus while maintaining injection mouldability. The HDPE fraction generally has a melt flow rate of 0.3–1.2 g/10 min at 190 °C/2.16 kg and a density of 0.952–0.962 g/cm³; small pails of 3–5 L are blended at 10–20 wt% HDPE, while 10–25 L open-top drums use 25–35 wt% HDPE to control bulging under stacked load. Pre-compounding on a twin-screw extruder with L/D 36:1–44:1, barrel temperatures 170–210 °C, screw speed 300–450 rpm, and strand pelletizing is preferred over dry tinting because inconsistent pellet dispersion causes localised stiffness variation and visible flow lines in sidewalls.

    Pail injection moulding of this blend uses wall thickness of 1.8–3.5 mm, melt temperature 200–230 °C, mould temperature 20–35 °C, and clamp force 3,000–8,000 kN depending on cavity number and projected area. The high MFR of 318BJ reduces injection pressure, but the HDPE fraction increases shear heating, so cylinder temperature in the metering zone should be lowered by 5–15 °C relative to neat 318BJ to avoid odour and screw recovery inconsistency. Hold pressure is typically 35–55 MPa for 8–20 s, and handles and bail ears are gated with local valve drops to avoid weld lines at load-bearing points. Chemical compatibility and permeation testing for water-based coatings, detergents, and mild solvents are performed per ASTM D543; hydrocarbons, strong oxidisers, and solvent-based formulations are not suitable because the LLDPE/HDPE blend has limited barrier performance and may soften. Terminal products include round and square pails for water-based coatings, detergent powders, and food ingredient liners. Published data for this specific configuration is limited; end-use permeation and stacking tests must be generated on the production tool for each pail geometry.

    Toys and Childcare Articles Demand Buoyancy from 0.918 g/cm³ Density

    318BJ is suited to small toy and childcare components where low density, soft touch, and high flow into multi-cavity tools are controlling requirements. Because the base density of 0.918 g/cm³ is below water, closed-cell or hollow parts can be designed for bath toys that float without additional buoyant inserts. Part weights range from 5 g to 50 g for multi-cavity moulds; wall thickness is maintained between 0.8 mm and 2.5 mm to avoid sink over thick bosses. Melt temperature is 190–220 °C, mould temperature 15–30 °C, injection pressure 50–80 MPa, and hold pressure 25–40 MPa for 2–6 s. Flashing tendency increases with high MFR, so clamp force must exceed cavity pressure integrated over the projected area by at least 15 %; tools with worn parting lines produce flash in thin-walled toy lids. Colour masterbatch let-down is kept at 2–4 wt% to limit any effect on gate freeze and mould deposit formation.

    European toy safety compliance is assessed under EN 71-3 for migration of elements in accessible parts, with limits dependent on material category and extraction method. Phthalate and bisphenol A testing is not driven by the base polyolefin but may be required for overmoulded TPE grips, colour concentrates, or printing inks; the final article must comply with REACH Annex XVII entries applicable to toys. No post-mould crystallisation annealing is required because the part reaches dimensional stability within the same 48 h conditioning protocol used for housewares. Terminal products include bath toys, stackable blocks, soft-edge storage trains, and toy packaging windows; products with mouthing contact require additional extraction testing under the appropriate age band.

    Colour masterbatch producers use SABIC LLDPE 318BJ as a high-flow carrier resin when the let-down target is injection-moulded polyolefin ware, caps, closures, or thin-wall packaging. A typical formulation contains 50–65 wt% carrier, 25–40 wt% organic or inorganic pigment, and 5–12 wt% low-molecular-weight PE wax or polar dispersant. The carrier melt flow rate of 33 g/10 min allows pigment agglomerates to be wetted at lower shear stress than carriers with MFR below 10 g/10 min, but it also requires a screen pack of 100–150 µm across a melt pump to catch undispersed carbon black or phthalocyanine blue specks. Twin-screw compounding is run at L/D 36:1–44:1, barrel temperatures 180–220 °C, screw speed 300–500 rpm, and die head pressure 3–8 MPa.

    The finished masterbatch is let down at 2–4 wt% in natural polyethylene or polypropylene; higher let-down ratios above 6 wt% may be used for black concentrates but are not recommended for thin-wall PP because the carrier viscosity mismatch can create gloss variation and cavity deposits. Quality control includes ISO 1133 MFR after compounding, pressure-rise testing on a 150 µm screen pack, and dispersion evaluation by injection plaque at 100× magnification. Storage below 40 °C prevents pigment reagglomeration and wax migration in pellet bags. Compliance is specific to colourant chemistry; the carrier resin must meet the same food-contact statements as above when the masterbatch is used for food-contact packaging. Terminal products include pelletised colour masterbatches and additive concentrates for polyolefin injection moulding.

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    Certification & Compliance
    More Introduction

    SABIC LLDPE 318BJ is a butene-copolymer linear low-density polyethylene granulate supplied for blown film conversion. The nominal melt mass-flow rate is 2.0 g/10 min when determined at 190 °C under a 2.16 kg load in accordance with ISO 1133-1, and the nominal density is 0.918 g/cm³ when measured according to ISO 1183-1. The comonomer is 1-butene, and the short-chain branch distribution is characteristic of a gas-phase polymerisation process. The grade is differentiated from high-pressure low-density polyethylene by its linear backbone and from high-density polyethylene by its lower density and differing short-chain branching architecture. It is not a metallocene resin; it is produced using a Ziegler-Natta catalyst and therefore has a broader comonomer distribution than a metallocene hexene LLDPE of equivalent density.

    Industrial use of 318BJ covers blown film structures from approximately 12 µm to 150 µm, including general-purpose liners, carrier bags, collation shrink film, agricultural film and lamination webs. Film properties must be established at the intended gauge because dart impact, Elmendorf tear and tensile values shift with blow-up ratio, frost-line height and die gap. Acceptance testing should follow ASTM D1709, ASTM D1922, ASTM D882 and ISO 527-3 as applicable. No single set of mechanical limits can be cited without specifying gauge, die diameter and tram position.

    On a typical single-screw blown film extruder, the grade is run with a die gap between 1.0 mm and 2.3 mm, a blow-up ratio of 2.0:1 to 3.5:1, and a melt temperature in the range of 195 °C to 215 °C. Barrel temperature profiles are usually set with feed zone at 170 °C, compression zone at 180 °C, metering zone at 190 °C, and die zones at 200 °C to 210 °C. These are representative ranges rather than fixed producer specifications; line trials must be used to optimise output and bubble stability for a given screw design and air ring.

    How Does a 2.0 g/10 min Melt Flow Rate Shift Extruder Loading?

    At constant die geometry and melt temperature, the 2.0 g/10 min melt flow rate of 318BJ generates lower extruder head pressure than a 1.0 g/10 min butene LLDPE of equivalent density. Because ISO 1133-1 is a low-shear index, it does not replace a capillary flow curve; a laboratory capillary rheometer operated per ISO 11443 is required for screw and motor sizing. On single-screw blown film extruders with screw diameter 50 mm to 75 mm and an L/D ratio of 25:1 to 30:1, the higher melt index typically permits either lower melt temperature or higher screw speed at equivalent backpressure. The magnitude of the pressure reduction is line-dependent and published lot-specific data for this configuration is limited.

    The corresponding trade-off is lower melt strength. In high-stalk film lines running at a blow-up ratio above 3.0:1, 318BJ may show reduced bubble stability compared with a 1.0 g/10 min butene LLDPE unless the formulation is modified. Blending with high-pressure LDPE at 20% to 30% by mass or with a fractional-melt HDPE at 10% to 20% by mass is used industrially to restore bubble rigidity. The optimum blend ratio depends on die diameter, frost-line height, ambient temperature and air-ring performance.

    Because 318BJ is a linear resin, surface melt fracture can appear at high throughput through narrow die gaps. A fluoroelastomer-based polymer processing additive is introduced at 200 mg/kg to 500 mg/kg by mass to delay shark-skin melt fracture. No additional pre-drying is required unless the granulate has been stored at sustained relative humidity above 60%; in that case, drying at 80 °C for 2 h in a dehumidified air dryer removes surface moisture. Additive concentrates should be checked for carrier resin compatibility.

    When Film Gauge Falls Below 25 µm

    Processing below 25 µm narrows the operating window because the film is more sensitive to bubble instability and gauge variation. Production set-ups in this range commonly use a die gap of 1.0 mm to 1.6 mm, a blow-up ratio of 2.0:1 to 2.8:1, and a melt temperature of 195 °C to 215 °C. Keeping the melt temperature below 230 °C reduces gel formation and off-odour risk from long residence time. Screw speed should be selected so that melt pressure remains within the extruder manufacturer’s maximum rating; exact pressure limits are machine-specific.

    In this thickness range, dart impact under ASTM D1709 and tensile strength under ASTM D882 are strongly influenced by frost-line height. A higher frost-line height generally improves impact strength but may reduce throughput and increase haze. The 318BJ grade can be used in thin-gauge applications, but the converter should establish lower control limits for impact and tear through a design of experiments that includes die gap, blow-up ratio, output rate and winding tension. Published data for this specific configuration is limited.

    Gel formation in LLDPE film lines is more often a function of stagnant zones in the die and screw than of resin lot defects. The converter should inspect the die lip gap, screen packs and breaker plate for degradation after each product change. A screen-pack configuration of 60/100/60 mesh is typical for LLDPE blown film; finer screens increase melt temperature and backpressure. The 2.0 g/10 min melt flow rate of 318BJ assists in reducing residence time in the adapter, but it does not eliminate the need for periodic purging after running high-temperature resins.

    Dart Impact and Tear Property Sensitivity to Gauge

    For butene-copolymer LLDPE with a density of 0.918 g/cm³, dart impact per ASTM D1709 and Elmendorf tear per ASTM D1922 are not intrinsic constants; they vary with gauge and orientation. In a typical blown film line, machine-direction and transverse-direction tear values diverge as the film is drawn down because orientation increases along the take-off direction. The producer’s certificate of analysis may report values for a 25 µm or 30 µm reference film, but those values cannot be applied directly to other tram positions or die sizes. Lot acceptance should compare measured values against an internal control film produced on the same line.

    Impact and tear data used for specification purposes should be generated at the same blow-up ratio and frost-line height as production. A film produced at a 2.0:1 blow-up ratio and a short frost line will not have the same transverse-direction tear balance as a film produced at a 3.0:1 blow-up ratio and a high frost line. The converter should therefore treat published mechanical values as comparative rather than predictive.

    In three-layer coextruded film, 318BJ is placed in the skin or core depending on the required heat-seal performance and coefficient of friction. The grade is typically combined with a lower-MFR LLDPE or an HDPE layer to increase stiffness and dart resistance. Interlayer adhesion in coextruded structures is usually adequate without tie resins because the layers are polyolefinic, but the converter should test heat-seal strength per ASTM F88. Seal initiation temperature should be established on the specific film and fin-sealer because hot-tack and seal strength are functions of contact time and pressure. Published data for this specific configuration is limited.

    Table 1 summarises the resin properties most commonly specified for incoming inspection and processing selection.

    PropertyNominal value or specificationTest methodRemark
    Polymer familyButene-copolymer LLDPEZiegler-Natta gas-phase
    Melt mass-flow rate2.0 g/10 minISO 1133-1190 °C, 2.16 kg
    Density0.918 g/cm³ISO 1183-1Nominal
    Melting peak region121 °C to 125 °CISO 11357-3DSC, 10 °C/min
    Comonomer1-buteneProducer specificationShort-chain branch type
    Processing methodBlown film extrusionSingle-screw, L/D 24:1 to 30:1

    The values in Table 1 are nominal producer data and are not upper or lower specification limits. A certificate of analysis for each batch should be obtained because melt flow rate and density may show lot-to-lot variation around the nominal. For performance-critical applications, the converter should set internal targets and reject criteria based on ISO 1133-1 and ISO 1183-1 results from retained samples. The melting peak should not be used as a lot-consistency parameter unless the heating rate and sample preparation are strictly controlled.

    For 318BJ, a general-purpose polyolefin screw with a compression ratio of 2.5:1 to 3.5:1 and a Maddock-type barrier section is common on single-screw blown film lines. A high-pressure, high-shear screw is not required; excessive shear can increase melt temperature and reduce bubble stability. A grooved-feed section is possible, but it must be matched to the pellet geometry and throughput target. Published data for this specific configuration is limited.

    Comparing 318BJ with Metallocene Hexene LLDPE

    318BJ is a butene-copolymer produced by Ziegler-Natta catalysis; metallocene hexene LLDPE grades typically deliver a more homogeneous comonomer distribution and higher dart impact at equivalent density and melt index. Under ASTM D1709, laboratory comparisons frequently show metallocene hexene grades outperforming butene grades at 25 µm gauge, but published data for this specific configuration is limited. Those differences are most pronounced in thin films and demanding frozen-food or heavy-duty packaging. For less demanding liners and carrier films, 318BJ is used because its melt index supports high throughput and its density provides a balance of stiffness and toughness.

    The choice between 318BJ and a metallocene hexene LLDPE should be made on the basis of a full film property matrix: dart impact per ASTM D1709, Elmendorf tear per ASTM D1922, puncture per ASTM D5748, tensile properties per ISO 527-3 or ASTM D882, and haze per ASTM D1003. Processing conditions, not resin identity alone, determine the final balance of properties. No single grade can be pre-selected without a design-of-experiments study on the target blown film line.

    Against a high-pressure LDPE of comparable melt index and density, 318BJ typically exhibits higher dart impact per ASTM D1709 and improved environmental stress-crack resistance per ASTM D1693 because of its linear butene-copolymer structure. However, it exhibits lower bubble stability in air-ring-controlled films because it lacks long-chain branching. Against an HDPE film grade of 0.952 g/cm³ density, 318BJ has lower tensile modulus but higher tear and softer conformability. The density difference is the main design variable; stiffness can also be increased by blending with HDPE at 10% to 30% by mass.

    Table 2 lists the compliance frameworks most often referenced for polyethylene film grades.

    Regulatory frameworkRelevant designationVerification methodStatus/limitation
    US food-contact olefin polymersFDA 21 CFR 177.1520Producer letter; extraction testingRequires end-use suitability assessment
    EU plastic food-contact materialsEU Regulation 10/2011EN 1186 overall migrationConformity depends on final film composition
    REACH SVHCREACH 1907/2006Producer declarationNo intentionally added SVHC above 0.1%
    RoHS heavy metalsRoHS 2011/65/EUXRF screening; producer dataPackaging generally outside scope; verify if product is an electrical/electronic part

    Compliance determinations require the final film composition, not the base resin alone. Surface coatings, printing inks, slip/antiblock masterbatches and recycled content can alter the regulatory status. The converter is responsible for migration testing under the intended conditions of use, including time, temperature and food simulant defined in the applicable regulation.

    Edge trim and start-up film from 318BJ can be re-extruded if the material is clean and dry. Recycled content alters bubble stability and gel level; most converters limit in-house regranulate to 20% to 30% by mass in high-clarity film and higher proportions in opaque industrial liners. Extraction and migration status may change with recycled content; food-contact applications should not incorporate post-industrial scrap without producer approval.

    The granulate should be stored in a dry, enclosed silo or hopper and protected from direct sunlight. Resin temperature during silo transport should remain below 60 °C to prevent pellet blocking. If outdoor storage is unavoidable, the container should not be opened until the granulate has equilibrated to plant ambient temperature.

    Food-contact use of 318BJ is possible only after evaluating the complete film composition and the applicable regional migration limits. The resin should not be used in applications requiring prolonged exposure to strong oxidising agents or aliphatic solvents without compatibility testing. For outdoor films, ultraviolet stabilisation must be supplied by masterbatch addition because the base grade does not include a long-term weathering package. The producer’s technical literature should be consulted for specific antioxidant and stabiliser details.

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