| HS Code | 751594 |
| Product Name | RTP 2099 X 126218 C Impact Modified Colorable Bio-Based Polylactic Acid |
| Base Polymer | Polylactic Acid (PLA) |
| Bio Based Content | Approximately 70% |
| Impact Modification | Impact Modified |
| Color | Colorable |
| Density | 1.24 g/cm³ |
| Tensile Strength | 31 MPa |
| Flexural Modulus | 2,400 MPa |
| Notched Izod Impact | 160 J/m |
| Heat Deflection Temperature | 49°C at 0.45 MPa |
| Vicat Softening Temperature | 60°C |
| Melt Flow Rate | 10 g/10 min at 190°C/2.16 kg |
| Processing Method | Injection Molding |
| Molding Shrinkage | 0.5-0.8% |
| Melting Temperature | 150-160°C |
As an accredited RTP 2099 X 126218 C Impact Modified Colorable Bio-Based Polylactic Acid factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | RTP 2099 X 126218 C Impact Modified Colorable Bio-Based Polylactic Acid supplied in 25 kg moisture-barrier foil-lined bags, palletized for shipping. |
| Container Loading (20′ FCL) | 20′ FCL: RTP 2099 X 126218 C Impact Modified Colorable Bio-Based Polylactic Acid in 25 kg bags, palletized, shrink-wrapped, braced. |
| Shipping | RTP 2099 X 126218 C Impact Modified Colorable Bio-Based Polylactic Acid is typically shipped as non-hazardous plastic resin pellets. Packaging: moisture-barrier bags, fiber drums, or supersacks. Not DOT/IMDG/IATA regulated. Store dry, away from heat. Labels include product name, grade, lot, net weight, and manufacturer. Handle per SDS. |
| Storage | Store in a cool, dry, well-ventilated area in sealed, labeled containers. Protect from moisture, direct sunlight, heat, and ignition sources. Keep away from strong acids, bases, and oxidizers. Maintain recommended temperature and low humidity to prevent hydrolytic degradation. Avoid dust generation and static discharge. Use original packaging, rotate stock, and follow local regulations and supplier SDS. |
| Shelf Life | Shelf life is typically 12 months when stored unopened in a cool, dry place, away from moisture and heat. |
Pre-drying is executed in a desiccant-wheel dryer with a dew point of −40°C and a setpoint of 80°C for 4 h, targeting residual moisture below 250 ppm before melt processing. Hydrolysis at moisture levels above 300 ppm depresses melt viscosity and creates silver streaking at the shearing zones of the injection screw. Barrel zones are profiled from 175°C at the rear to 195°C at the metering zone and 200°C at the nozzle; flat profiles above 210°C accelerate lactide reformation and brown streaking at hot-runner tips. Mold temperature is held at 25°C to 35°C with turbulent water circuits because polylactic acid remains above its glass transition at higher tool temperatures and can stick to sprue pullers. Injection velocity is set to fill a 2.0 mm wall in 1.5 s to 2.5 s, with pack pressure between 80 MPa and 100 MPa for 0.5 s to 1.5 s; excessive packing at thin ribs creates residual stress that promotes environmental stress cracking around ultrasonic weld joints. A 40:1 L/D barrier screw with low-shear mixing pins is preferred, while aggressive kneading blocks at the compression zone raise melt temperature by 8°C to 12°C and degrade the impact modifier at the barrel wall. Shrinkage recorded under ASTM D955-08 on a 3.2 mm plaque typically ranges from 0.4% to 0.7% after 24 h at 23°C and 50% RH. Terminal parts include router bottom covers, tablet rear frames, and PC-free monitor bezels where RoHS 2011/65/EU Annex II and REACH SVHC screening are specified.
When a 0.8 mm snap-fit undercut is moulded into a lipstick sleeve, the gate is located away from the hinge to avoid knit-line embrittlement at the impact-modifier-rich skin. Cold-runner tools with polished SPC or H-13 cavities are run at a mold temperature of 30°C, and the filling stage uses a profiled injection speed of 120 mm/s to 180 mm/s at the screw front. Hot-runner valve-gate systems above 14 mm nozzle diameter tend to drool because of the low zero-shear viscosity of impact-modified PLA at 195°C; thermal gate temperature is capped at 190°C when needle shut-off nozzles are used. Color is introduced as a PLA-carrier masterbatch at 2 wt% to 4 wt% on a 25 mm twin-screw extruder with L/D 36:1 and an oil bath set to 180°C; pigment aggregates larger than 15 µm reduce Charpy impact from 18 kJ/m² to 9 kJ/m² in ISO 179-1/1eU tests. Drop resistance of threaded closures is evaluated by ASTM D2463-15 with a 1.2 m drop to a steel plate at 0°C; parts with a weld line at the thread root fail more often after moisture conditioning at 40°C and 90% RH for 48 h. Compliance for decorative packaging is assessed against EU 94/62/EC heavy metal limits and REACH candidate-list screening. Terminal formats include airless pump collars, compact lids, and mascara outer caps.
Impact modification of polylactic acid follows a ductile-to-brittle inversion driven by elastomer particle spacing. At additions below 5 wt%, the interparticle distance remains above the critical ligament thickness, and notched Izod values measured per ISO 180/A do not exceed 5 kJ/m². Between 8 wt% and 12 wt%, shear yielding initiates at the modifier-matrix interface, raising room-temperature notched Izod to 15 kJ/m² or 20 kJ/m². Beyond 12 wt% to 15 wt%, tensile modulus per ISO 527-2 falls below 2.0 GPa, and heat deflection temperature at 0.45 MPa per ISO 75-2 Method B declines below 55°C. This is the critical threshold for thin-wall electronic enclosures because the part may warp in a 60°C shipping container. Processing parameters also shift: melt viscosity decreases by roughly 30% when modifier content increases from 8 wt% to 15 wt% at 210°C, requiring shorter cushion and lower screw recovery. Colorable grades are more sensitive because low-molecular-weight pigment carriers can localize at the impact modifier interphase and reduce weld-line strength by 20% to 35%. The tabulated values below are not product specifications; they identify the cliff-edge trends that must be re-measured on each lot because bio-based monomer purity and modifier particle size shift the transition by ±2 wt%.
| Impact modifier content (wt%) | Notched Izod (kJ/m²) ISO 180/A | Tensile modulus (GPa) ISO 527-2 | HDT B (°C) ISO 75-2 | MFR (g/10 min) ISO 1133-1 |
|---|---|---|---|---|
| 4 wt% | 4 kJ/m² | 3.1 GPa | 58°C | 6 g/10 min |
| 8 wt% | 12 kJ/m² | 2.8 GPa | 55°C | 8 g/10 min |
| 12 wt% | 22 kJ/m² | 2.2 GPa | 52°C | 10 g/10 min |
| 15 wt% | 25 kJ/m² | 1.8 GPa | 48°C | 15 g/10 min |
Filament extrusion from RTP 2099 X 126218 C pellets begins with the same −40°C dew-point drying sequence as injection moulding; residual moisture must be below 200 ppm to prevent diameter flutter above ±0.05 mm. A 20 mm single-screw extruder with a 24:1 L/D and a melt pump is run at 180°C to 190°C, with melt pressure at the die held between 60 bar and 80 bar. Water bath temperature is set to 35°C to 45°C because quenching below 30°C produces excessive amorphous orientation that snaps at spooling radii under 0.10 N tension. Diameter is measured online by a dual-axis laser gauge at 1 kHz, and spooling uses a closed-loop dancer controlling tension to 0.20 N for 1.75 mm filament. Fused-filament-fabrication output from this feedstock runs with a nozzle setpoint of 195°C to 205°C and a heated glass bed at 50°C to 60°C; parts printed at 0.12 mm layer height exhibit interlayer bond strength of 18 MPa to 24 MPa when tested in the Z-axis per ISO 527-2. The impact-modified feedstock reduces part cracking during spool changes but lowers heat deflection; printed fixtures must not be exposed to sustained temperatures above 50°C. Terminal uses comprise jigs, automated test fixtures, and vacuum-forming templates.
Thermoforming-grade behavior diverges from injection moulding because sheet is drawn in a rubbery plateau above the glass transition. The compounded pellets are first extruded on a 35 mm single-screw sheet line with a 30:1 L/D, a gear pump, and a coat-hanger die at 180°C to 195°C. Chill rolls are held at 35°C to 45°C to limit crystallinity; sheet haze rises sharply when stock temperature exceeds 200°C due to lactide formation. A plug-assisted thermoformer running at 12 cycles/min is set to surface temperatures between 90°C and 110°C, with a draw ratio of 1.5:1 to 2.0:1; below 85°C the sheet tears at the clamp frame, while above 115°C the impact-modifier phase begins to agglomerate and creates visible flow lines. Mould temperature is kept at 30°C to 40°C; vacuum holes at 0.5 mm diameter are spaced at 25 mm to avoid freezing stress concentrators near the trim line. Food-contact compliance for cold-fill trays is assessed under EU 10/2011 with overall migration below 10 mg/dm², and US FDA 21 CFR 177.1520 for polymerized lactic acid conditions; however, the impact modifier must be verified for its own food-contact authorization if used above 5% in the formulation.
| Requirement | Method | Typical acceptance threshold |
|---|---|---|
| EU 10/2011 overall migration | EN 1186-1 | <10 mg/dm² |
| US FDA 21 CFR 177.1520 | extraction tests | modifier authorization verification |
| EU 94/62/EC heavy metals | packaging sum | <100 mg/kg |
| Biobased carbon | ASTM D6866-22 | 70% to 95% |
| Notched Izod | ISO 180/A | ≥10 kJ/m² |
For bench-top diagnostic enclosures, the material is first screened for extractables because the impact-modifier package may contain low-molecular-weight esters. Cytotoxicity is evaluated according to ISO 10993-5, and sensitisation or irritation per ISO 10993-10 is required when the housing is touched by operators for cumulative periods above 30 min. Moulding is performed on an electric injection press with a clamp force of 80 t to 120 t for tool projected areas around 350 cm²; barrel residence time is limited to 4 min at 195°C to avoid lactide reformation. Annealing at 55°C for 2 h in a forced-air oven reduces molded-in stress and stabilizes snap-fit retention by 15% when measured by pull-out force before and after thermal cycling from −20°C to 50°C. Sterilization by gamma radiation above 25 kGy is not recommended because polylactic acid chain scission embrittles the part; ethylene oxide exposure at 50°C and 60% RH for 6 h produces minimal dimensional change but requires outgassing to reduce residual ethylene oxide below ISO 10993-7 limits. Terminal parts include handheld reader shells, desktop diagnostic towers, and non-invasive sensor housings.
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RTP 2099 X 126218 C is a compounded bio-based poly(lactic acid) resin supplied in pellet form. The designation identifies a PLA carrier, an impact-modification package, and a colorable formulation variant; “colorable” indicates that color is introduced through a separate masterbatch at the converter rather than as a precolored pellet. The material is specified for injection molding, profile extrusion, and sheet extrusion where higher notched impact resistance and post-molding color control are required without switching to a petroleum-derived styrenic or polyolefin resin. Lot-specific certificates of analysis provide the melt mass-flow rate, moisture content, density, and bio-based carbon fraction; generic PLA datasheets should not be substituted for the lot-specific record.
No single technical description can serve as a processing guarantee. Specifications are defined by the supplier’s product datasheet and the agreed purchase specification. Values referenced in this document are comparative ranges drawn from publicly available technical literature for the 2099 series and comparable impact-modified PLA grades. Where published data for this specific configuration is limited, the text states the boundary instead of generating unsupported claims.
The primary functional difference between this compound and unmodified injection-grade PLA is the shift from brittle failure to ductile deformation. Unmodified PLA commonly exhibits notched Izod impact values in the 2–5 kJ/m² range and tensile elongation below 10%. The impact-modified system raises the notched Izod response into the 15–45 kJ/m² class at 23 °C, allowing parts to survive drop loading, snap-fit assembly, and localized impact. The trade-off is a reduction in stiffness: flexural modulus for impact-modified PLA typically falls between 1800 MPa and 2600 MPa, whereas unmodified PLA is commonly reported at 3000–3500 MPa. Ribbing, section thickness increases, or design changes may be required when the part must resist deflection under load.
| Property | Test method | Unit | Unmodified PLA reported range | Impact-modified PLA class reported range |
|---|---|---|---|---|
| Density | ISO 1183-1:2019 Method A | g/cm³ | 1.24–1.26 | 1.20–1.30 |
| Tensile stress at break | ISO 527-2:2012 Type 1A | MPa | 45–60 | 35–50 |
| Tensile elongation at break | ISO 527-2:2012 Type 1A | % | 3–10 | 15–100 |
| Flexural modulus | ISO 178:2019 | MPa | 3000–3500 | 1800–2600 |
| Notched Izod impact at 23 °C | ISO 180:2019 Method A | kJ/m² | 2–5 | 15–45 |
| Notched Izod impact at −20 °C | ISO 180:2019 Method A | kJ/m² | 2–4 | 6–20 |
| Heat deflection temperature at 0.45 MPa | ISO 75-2:2013 Method B | °C | 50–60 | 45–60 |
| Melt mass-flow rate at 210 °C/2.16 kg | ISO 1133-1:2022 | g/10 min | 6–15 | 5–25 |
The shift in notched Izod impact from below 5 kJ/m² to above 15 kJ/m² is the principal reason for selecting this compound over neat PLA in clips, closures, cosmetic housings, and durables that must survive drop loading at 23 °C. The lower flexural modulus means that a part designed for unmodified PLA cannot be directly substituted without stiffness review. Compared with a general-purpose ABS at approximately 20 kJ/m² notched Izod, the bio-based compound may occupy a similar toughness band, but heat deflection temperature remains close to 55 °C, and continuous service above 60 °C is not recommended unless the part is annealed or heat-resistant crystallinity is developed.
Morphology of the impact modifier is also a process-controlled variable. Over-dispersion from high shear and long residence time can reduce modifier particle size below 0.1 µm, lowering impact resistance. Under-dispersion leaves agglomerates above 1 µm that initiate cracks at modifier-matrix interfaces. On a co-rotating twin-screw compounding line, specific mechanical energy in the range of 0.15–0.25 kWh/kg is typical for comparable impact-modified PLA systems; specific mechanical energy should be monitored because it correlates with dispersion state, melt history, and lot-to-lot mechanical performance.
Moisture control is the limiting variable. The compound is hygroscopic and undergoes hydrolytic chain scission in the melt when pellet moisture exceeds 250 ppm (0.025 wt%). Sealed containers should remain closed until use. If the material has been exposed to ambient air with relative humidity above 60% for more than 1 h, it must be dried in a desiccant-bed dryer with a dew point of -30 °C or lower and an air temperature of 80 °C for 4 h. Hopper-mounted desiccant units on injection molding machines should be sized for the residence time at maximum shot weight and should not be bypassed during color changes.
On a 40:1 L/D co-rotating twin-screw extruder with vacuum venting at -0.08 MPa, processors have observed that moisture above the target produces gas splay, reduced melt strength, and a measurable drop in melt pressure. The same hydrolytic pathway reduces notched Izod impact at the same nominal barrel settings. This is not a specification; it is a field observation that reinforces drying discipline. On injection molding equipment, barrel profiles should rise from 170 °C at the feed throat to 200 °C at the nozzle. Melt temperature should not exceed 210 °C during normal cycles, and excursions above 220 °C accelerate lactide reformation, yellowing, and molecular weight loss. Screw recovery should be set so total residence time is below 8 min; if a machine cannot empty the barrel within that window, shot size should be moved to a smaller barrel capacity or melt hold time should be reduced. Hot-runner systems must avoid dead spots because stagnant melt degrades even at nominal set temperatures.
Back pressure of 0.3–0.7 MPa is typical. Screw speeds in injection molding are commonly 50–150 rpm, but the limiting parameter is shear heating. High-compression screws above 2.5:1 can overshoot the melt temperature by 10–15 °C at elevated screw speed and should be replaced with a medium-shear design. Mold temperatures are typically 15–40 °C for thin-wall parts and up to 60 °C when surface gloss or crystallinity development is required. Because PLA crystallizes slowly, cooling time is controlled by part thickness and mold steel rather than by the resin alone; ejection can be delayed by living hinges or deep texture. Mold shrinkage in flow direction is typically 0.3–0.6% at 2 mm nominal wall thickness, but transverse shrinkage may differ and prototype tools should allow for shrinkage correction after first-shot trials.
Compared with an impact-modified PLA/PBAT blend used in blown film, this injection-molding grade has a narrower processing window and higher shear sensitivity because the impact-modifier package is designed for injection molding rather than film stretching. The colorable carrier is not intended for blown film at high blow-up ratios. Dry indoor storage below 30 °C is sufficient for unopened containers.
The colorable formulation is intended for letdown with a masterbatch. The carrier resin in the masterbatch must be a PLA or bio-based polyester with a melt viscosity within approximately ±15% of the base resin at the processing melt temperature. A carrier based on polyethylene or ethylene copolymer creates a lower-viscosity domain that can cause streaking, delamination, and loss of impact. Masterbatch pellets must be dried to the same moisture target as the base resin, typically 250 ppm maximum, before blending.
Color letdown ratios of 2–4 wt% are common for opaque concentrates; translucent, pearlescent, or laser-marking additives may require different ratios and should be qualified by CIELAB measurement. A low-shear tumble blender operating for 10–15 min provides adequate dispersion before the feed hopper. Static charge separation can occur with fine particle colorants; grounded equipment and avoidance of long pneumatic conveying lines reduce color variation.
On a 32:1 L/D compounding line, additive dispersion depends on the location of the masterbatch addition. If masterbatch is added at the feed throat, the initial melting zone must be long enough to disperse the concentrate before the vacuum port; otherwise volatiles pull colorant from the melt. Pre-melt side feeding after the plastication zone can improve color consistency but requires a side feeder that can feed low-bulk-density masterbatch without bridging.
Process-induced color drift is commonly caused by residence time and shear. When melt temperature exceeds 210 °C or residence time exceeds 8 min, the base resin yellows and darkens the final part. This shift is measurable with ISO 7724-1:2019 and ISO 7724-2:2019; a change in b* of 1.0–2.0 is visible in opaque whites and pastels. For a stabilized production cell, a CIELAB ΔE*ab target of 1.0 for opaque colors and 1.5 for translucent colors is a reasonable process capability target, but customer-specific standards may be tighter.
Purge between color changes should use a PLA-based or acrylic purge compound. PVC, acetal, and polycarbonate residues are incompatible and can release acid or gas at PLA processing temperatures. Residual acetal in the barrel reacts to generate formaldehyde and should be avoided. Amine-based additives should also be avoided unless explicitly qualified because they can accelerate PLA degradation and shift color.
Bio-based carbon content is not a self-declared property. The accepted evidentiary method is ASTM D6866-22 Method B or ISO 16620-2:2019; results are reported as a fraction of total organic carbon and must be paired with the lot number, sampling date, and laboratory accreditation. A claim under EN 16785-1 or the USDA BioPreferred program requires additional chain-of-custody documentation and cannot be transferred from the base resin to the finished part without mass-balance records.
Food-contact status must be established for the finished article. The base resin may have a regulatory status, but the addition of impact modifier and colorant changes the migration profile. Users must obtain a written compliance statement from the supplier and, where applicable, conduct migration testing under Regulation (EU) No 10/2011 or FDA 21 CFR 177 as appropriate for the intended food type, temperature, and contact time. RoHS compliance under Directive 2011/65/EU Annex II must be evaluated with the specific colorant package; certain pigments contain metals that influence the certificate. REACH SVHC screening should be repeated when masterbatch or processing aids change.
Service boundaries include continuous exposure to temperatures above 60 °C, alkaline cleaning solutions with pH above 9, or high-humidity steam; these conditions are not recommended without part-specific validation. Bio-based polylactic acid hydrolyzes under prolonged moisture and heat, and mechanical properties decline in wet service environments even below the heat deflection temperature. For applications requiring dishwasher resistance, autoclaving, or under-hood heat, the product is not a direct substitute for polypropylene or polycarbonate. Keep sealed, dry, and below 30 °C; shelf life after opening depends on ambient humidity and is not indefinite.