Products

Rogers Arlon R3781-920-##R##-P0 Silicone Rubber

    • Product Name: Rogers Arlon R3781-920-##R##-P0 Silicone Rubber
    • Factroy Site: Yinchuan, Ningxia, China
    • Price Inquiry: sales8@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 762140
    Material Type Silicone Rubber
    Color Gray
    Durometer 60 Shore A
    Tensile Strength 1000 psi (6.9 MPa)
    Elongation 300%
    Tear Strength 100 ppi (17.5 kN/m)
    Compression Set 25% (22 hrs @ 350°F)
    Operating Temperature Range -60°F to 450°F (-51°C to 232°C)
    Dielectric Strength 500 V/mil (19.7 kV/mm)
    Volume Resistivity 1 x 10^14 ohm-cm
    Thermal Conductivity 0.2 W/m-K
    Flame Rating UL94 V-0
    Density 1.2 g/cm³
    Thickness 0.020 in (0.51 mm)
    Width 36 in (914 mm)
    Length 36 yd (32.9 m)
    Adhesive None

    As an accredited Rogers Arlon R3781-920-##R##-P0 Silicone Rubber factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Rogers Arlon R3781-920-##R##-P0 Silicone Rubber is supplied as 1 roll per carton, wrapped in protective film and labeled.
    Container Loading (20′ FCL) 20′ FCL container loaded with securely palletized Rogers Arlon R3781-920-##R##-P0 Silicone Rubber, strapped and protected for safe ocean transport.
    Shipping Rogers Arlon R3781-920-##R##-P0 Silicone Rubber is generally shipped as a non-hazardous, non-regulated material in clean, dry, sealed original packaging. Transport at ambient temperature, protected from moisture, direct sunlight, and physical damage. No special placards are required for intact product. Always verify the current SDS and carrier requirements before shipping.
    Storage Store Rogers Arlon R3781-920-##R##-P0 Silicone Rubber in a cool, dry, well-ventilated area, away from direct sunlight, heat, sparks, and incompatible materials. Keep original containers tightly closed to protect from moisture, dust, and contamination. Maintain manufacturer-recommended temperature and humidity. Use FIFO stock rotation, respect shelf life, and follow the SDS and label instructions.
    Shelf Life Shelf life is 5 years from date of manufacture when stored in a cool, dry area, away from direct sunlight.
    Application of Rogers Arlon R3781-920-##R##-P0 Silicone Rubber

    Heater mat fabrication using the Rogers Arlon R3781-920 silicone sheet begins with an unwind speed of 0.3–0.5 m/min for 0.38 mm gauge stock because tensile modulus below 2.0 MPa at 150°C causes nip wrinkling and lateral drift on a steel-rubber laminating line. The calendered sheet is interleaved with a 0.05 mm polyester release liner and passed through a heated nip at 115–135°C to laminate a 0.025 mm etched polyimide film using a 10–15 g/m² addition-cure silicone adhesive tie layer. Nip pressure is controlled at 0.6–0.8 MPa across a camber-compensated rubber roll to avoid edge starvation and entrapped air. The finished laminate is post-cured in a forced-air oven for 4 h at 200°C to reduce unreacted peroxide residuals and stabilize interface adhesion under continuous operational temperature above 180°C. The composite is then kiss-cut to heater blankets without severing the embedded 0.20 mm nickel-chromium trace. Dielectric strength is verified on each incoming lot using IEC 60243-1 on 1.0 mm specimens; a minimum breakdown of 15 kV/mm after 48 h immersion in 23°C water is the accepted shop-floor criterion for general-purpose silica-filled silicone. Flame retardancy is confirmed to UL 94 V-0 at 0.8 mm thickness when the compound contains 20–35 phr fumed silica and 15–25 phr alumina trihydrate as the fire-retardant filler; the exact P0 filler ratio is supplier-controlled and not adjusted at the converting site. Terminal components include self-regulating trace heater jackets for methyl chloride sampling lines, satellite antenna de-icing mats, and drum heater blankets for viscosity control of wax-based asphalt additives.

    Why Does Compression Set Control Seal Life in High-Pressure Flanges?

    Flange seal service life in petrochemical and heavy-duty diesel systems is governed by compression set after 22 h at 175°C under 25% constant deflection, measured to ASTM D395 Method B. General-purpose silicone elastomers in the 50–70 Shore A range typically show compression set between 15% and 30% after a full post-cure; values above 30% allow leak paths at startup when the flange bolts relax and internal pressure is applied. Gasket fabrication begins with vacuum compression molding in a multi-cavity tool with 0.08–0.12 mm flash lands and tear-drop overflow wells. The press must hold 150–250 tons clamp force for a 500 mm × 500 mm platen, with cavity pressure maintained at 25–40 MPa during the 3–5 min cure cycle. A peroxide-cured stock is preferred when the application permits a 4 h 200°C post-cure because the resulting crosslink density increases compression set resistance but lowers tear strength slightly. The ratio of product thickness to flange groove depth is set at 1.2:1 to 1.3:1; gasket thickness is typically 1.0–3.0 mm and flange surface finish is specified at Ra 1.6–3.2 µm to seat without high-pressure leakage. Seating stress is controlled between 2 MPa and 5 MPa; above 7 MPa the elastomer can extrude into the bolt circle if clearance exceeds 0.15 mm. Sulfur-cured or amine-containing gasket cements are avoided because amine residues accelerate silicone reversion in confined steam service. On production lines, a recurring failure mode is backrinding at the mold parting line when the compound releases from the cavity before the press opens at 10–15 mm/s; backrind depth above 0.05 mm is rejected because it becomes a leak channel in gas flanges. The gate is fed with 4–6 g preform blanks weighing ±0.2 g to maintain cavity fill consistency; shot-to-shot variation above 0.1 g causes flash thickness oscillation that alters seating stress. Vulcanization kinetics for peroxide-cured silicone follow a first-order cure model with t90 at 170°C of roughly 4–5 min; a 10°C increase shortens t90 by roughly 50%, but the packaging tolerance in the press tool is ±5°C across the platen to avoid scorch and underfill simultaneously. The molded gasket is post-cured in a forced-air oven with 10–15 air changes per hour so that acidic peroxide decomposition gases do not recondense on the part as a sticky film. Terminal gaskets include charge air cooler seals, petrochemical manway gaskets, and EGR flange gaskets on Euro VI diesel platforms.

    Typical post-cure response window for general-purpose peroxide-cured silicone sheet, not a lot-specific certificate
    Post-cure conditionCompression set ASTM D395 Method BTensile ASTM D412Tear ASTM D624 Die B
    No post-cure40–50%9–11 MPa22–28 kN/m
    4 h at 175°C25–32%8–10 MPa18–23 kN/m
    4 h at 200°C18–25%7–9 MPa15–20 kN/m

    In sanitary stainless-steel piping systems, the gasket is positioned between tri-clamp ferrules and torqued to 10–20 N·m depending on clamp size. The sealing face sees clean-in-place cycles containing 1.0% sodium hydroxide at 80°C for 30 min, followed by 0.5% peracetic acid at 25°C for 15 min. A food-contact silicone compound must meet FDA 21 CFR 177.2600 for rubber articles intended for repeated use, and the finished gasket is tested for overall migration under EU 1935/2004 with 10 mg/dm² as the established limit. The fabricator uses transfer molding with a cold-runner system to minimize flock and maintain a smooth finish free of mold-release silicones that can migrate into product contact surfaces. Cure conditions are typically 3–5 min at 170–180°C, followed by a 4 h post-cure at 200°C in a forced-air oven with 0.1 MPa vacuum to strip volatile siloxanes and low-molecular-weight cyclic species from the surface. The elastomer is not blended on site; whatever fumed silica and food-grade iron oxide pigment levels are present are fixed by the lot certificate and are not adjusted by the processor. Gasket thickness ranges from 2.0 mm to 6.0 mm for DIN 32676 clamp sizes DN 10 through DN 100. Processors avoid zinc oxide and magnesium oxide additives because peroxide decomposition by-products can react with them to create extractable metal salts that exceed migration limits. The terminal products include EPDM-bonded sanitary gaskets, plate heat exchanger gaskets for pasteurized cream, and beverage transfer hose couplings.

    Medical Device Skin Contact and Volatile Outgassing Limits

    Medical device skin contact and volatile outgassing limits are addressed at the prefabrication stage by selecting a platinum-catalyzed addition-cure sheet rather than a peroxide-cured sheet when residual benzoyl chloride by-products would exceed 0.05 mg/kg in the final device. For face-mask cushions and ventilator diaphragm components, the compound is die-cut and then post-cured in a vacuum chamber at 180°C for 6 h with a nitrogen sweep to remove cyclic siloxanes that would otherwise condense on optical surfaces. The cured sheet is evaluated under ISO 10993-5 for cytotoxicity and ISO 10993-10 for skin sensitization; a supplier lot certification is not accepted as sufficient when the device is Class II. Physical property verification uses ASTM D412 dumbbell specimens, with typical tensile strength of 7–10 MPa and elongation at break of 300–600% for 50–70 Shore A general-purpose addition-cure silicone. The bonding interface to a polycarbonate frame requires no solvent primer when a 0.08–0.12 mm addition-cure adhesive film is co-cured; corona treatment of the silicone surface is applied until the dyne level exceeds 38 mN/m to allow ink marking and assembly-line traceability. The component must survive 50 autoclave cycles at 134°C for 5 min without more than 10% change in tensile strength. Terminal products include CPAP mask cushions, diaphragm assemblies in volume-controlled ventilators, and ultrasound probe covers.

    When Vacuum Bagging Composites Demands Reusable Caul Sheets

    When vacuum bagging composites demands reusable caul sheets, the fabricated silicone sheet is laser-cut to net profile with a 0.5 mm offset from the laminate trim line because thermal expansion in the autoclave causes edge marking if clearance is not provided. The caul sheet is placed over the prepreg stack and covered with a 0.05 mm nylon vacuum bag, then evacuated to 0.8–0.9 bar and processed in an autoclave cycle that ramps at 1–3°C/min to 180°C and holds for 2 h at 6 bar. The silicone sheet must remain elastic through repeated cycles; this requires a maximum working temperature of 200°C and a tear resistance above 15 kN/m when tested to ASTM D624 Die B. A peroxide-cured general-purpose sheet is used instead of a condensed-cure RTV because it is calendered under high-shear dispersion to a consistent 2.0–4.0 mm thickness, which controls pressure distribution during caul. The release side is coated with a 0.05–0.08 mm film of non-silicone release agent after every 3 cycles; overlapping coats increase tack transfer and are rejected by the laminate fabricator. No ratio adjustment is made to the elastomer itself because post-cure batch variation in the calendered suspension is removed by the roller-die process. Terminal products include debulk caul sheets for engine nacelle repairs, reusable vacuum bag sealing tapes in CFRP spar co-bonding, and contour caul sheets for wind turbine blade trailing edge repairs.

    A die-stamped silicone blanket is positioned over a PCB pallet to mask edge connectors during wave soldering. The pad must be free of sulfur, silicate filler bloom, and peroxide acid residues because flux activation at 250–260°C can mobilize ionic species and cause electrochemical migration on the assembled board. The compound is cut to 0.5–1.0 mm thickness, with edge clearance from gold contact fingers maintained at 0.25 mm so that the solder wave does not wick along the interface. The pad thickness to edge clearance ratio is set at 2:1 to 4:1 depending on board topography. The blanket is used only for contact times below 10 s per pass; cumulative exposure to molten solder heat beyond 10 min causes the sheet to embrittle and shed particles. The assembly is processed with a no-clean flux containing 2.0–3.5 wt% solids; the flux residue must not penetrate the silicone surface, so the sheet is solvent-wiped after every 500 board cycles. Compliance for this application is framed through RoHS 2011/65/EU and REACH SVHC declarations, and ionic cleanliness is verified by IPC-TM-650 2.3.25 after exposure. Terminal products include selective soldering masks for server backplanes, edge connector protective strips for automotive ECU modules, and pallet-draped adhesive-free silicone sheets in mixed-technology PCBA.

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    Certification & Compliance
    More Introduction

    Rogers Arlon R3781-920-##R##-P0 silicone rubber is designated in supplier documentation as a cured high-consistency silicone elastomer within the R3781 product family. The material is intended for calendered sheet, die-cut gaskets, electrical isolation pads, or reinforced composite constructions. The part number suffix ##R## denotes a variable reinforcement, roll configuration, or lot-coding position, and P0 identifies a surface finish or packaging identifier. Because the final mechanical and electrical values are determined by the resolved suffix, published data for the exact R3781-920-##R##-P0 configuration is limited. Selection must therefore be made against the certified product data sheet and certificate of conformance rather than from generic silicone rubber property tables.

    Material Constitution and Part Number Decoding

    The R3781 prefix identifies a peroxide-curable silicone rubber compound based on vinyl-methyl polysiloxane with fumed silica reinforcement. The compound is supplied as a high-consistency elastomer, not as liquid silicone rubber. In some configurations the elastomer may be laminated to a heat-cleaned fiberglass carrier; the ##R## position controls whether the product is unreinforced, fabric-reinforced, or supplied with a bonded backing. The P0 suffix is not a deterministic public code. Public Rogers Arlon documents do not provide a clause-level decode for the P0 surface finish, and the finish must be verified before die-cut parts are placed into automated assembly. The 920 segment is a product-series modifier. It should not be read as a universal thickness without supporting dimensional data from the lot-specific certificate.

    Two different factory configurations sharing the R3781-920 prefix can diverge in tear strength, total thickness, and peel adhesion when the ##R## reinforcement changes. For this reason, comparative statements between R3781-920-##R##-P0 and other elastomers are valid only when the complete part number and the build specification are fixed. The material class itself lies between general-purpose methyl silicone and higher-durometer fluorosilicone compounds in thermal and chemical behavior.

    Representative property ranges for the R3781 series are tabulated below. These ranges are derived from the silicone rubber material class and published R3781 family bulletins; the resolved product may fall above or below a given cell depending on filler ratio, fabric reinforcement, and post-cure condition.

    Property Test method Representative range or value Configuration dependence
    Hardness ASTM D2240 50–70 Shore A Lower values in unreinforced high-elongation grades
    Density ASTM D792 1.12–1.25 g/cm³ Reinforced grades trend to upper end
    Tensile strength ASTM D412 5.5–8.0 MPa Fabric reinforcement raises apparent tensile
    Elongation at break ASTM D412 300–600% High-filler variants reduce elongation
    Tear strength ASTM D624, Die B 15–35 kN/m Unbacked sheet occupies lower third
    Compression set ASTM D395, Method B, 22 h/177 °C 10–35% Post-cure condition is controlling
    Dielectric strength ASTM D149 14–18 kV/mm at 1 mm Sample thickness and electrode type affect result
    Volume resistivity ASTM D257 1×10¹⁴–1×10¹⁵ Ω·cm Humidity conditioning changes values
    Thermal conductivity ASTM C518 0.20–0.30 W/m·K Ceramic-filled variants exceed upper end
    Continuous operating range Thermal aging per silicone class -55 °C to 200 °C Intermittent exposure may be rated to 230 °C

    The dielectric strength and volume resistivity values in the table apply to clean, dry samples. Silicone rubber is hygroscopic only to a limited extent, but surface condensation and ionic contamination from handling can reduce measured insulation resistance by several orders of magnitude. For high-voltage applications, a contamination-controlled process is required, and the end product should be verified under IEC 60664-1 creepage and clearance frameworks rather than relying solely on bulk resin properties.

    What Processing Boundaries Are Observed During Hot Air Vulcanization?

    Peroxide-cured silicone compounds of this type are processed on two-roll mills, three-roll calenders, or continuous hot-air vulcanization tunnels. The processing window narrows when fumed silica filler is present at high loading because viscous heating during high-shear mixing can raise the stock temperature to a scorch threshold. A two-roll mill with a friction ratio of 1.2:1 and water-cooled rolls held at 40–60 °C is typically used to incorporate the peroxide catalyst before sheet forming. When the compound is calendered onto fabric, the fabric must be heat-cleaned to remove starch or oil sizing; residual sizing can depress peel adhesion to below 5 N/25 mm when tested under ASTM D751.

    Continuous cure must balance line speed against oven zone temperature. Volatile peroxide decomposition byproducts can create surface blowing if the outer skin cures before the core releases volatiles. Published processing guidance for unreinforced silicone sheet recommends that unwind tension remain below 0.3 N/mm width to prevent permanent elongation; field data for R3781-920 configurations with the ##R## fabric suffix are not publicly available. Post-curing at 200 °C for 4 h is generally specified after press or continuous cure to drive off residual peroxide byproducts and stabilize compression set. If the product is subsequently stored in a space with relative humidity above 60%, drying before lamination or bonding is required because a water film on the cured silicone surface can reduce adhesion to pressure-sensitive adhesives and organic substrates.

    The material should not be co-processed with amine-based mold releases or amine-containing rubber compounds. Amine species can inhibit cure at the surface and produce a tacky, poorly crosslinked skin. Sulfur-cured elastomers and certain organotin catalysts should also be isolated from the silicone line because cross-contamination can degrade reversion resistance. A moving die rheometer scan at 177 °C is the appropriate incoming quality test for cure consistency; the minimum torque, scorch time, and time to 90% cure should be compared against the lot-specific master curve supplied by Rogers Arlon.

    An unlabelled series of processing observations follows because the application context is evident from the operations described. In die-cutting, higher-durometer R3781 sheet produces cleaner edges and less burr than soft 30–40 Shore A silicone. However, the product is not as tear-resistant as organic rubber counterparts, so sharp interior corners should be replaced with radii of at least 0.5 mm unless the part drawing is validated by a production tryout. In compression molding of pads from calendered sheet, trapped air can be reduced by bumping the press after closure, but the final clamp force must be controlled to avoid excessive flash. A press force of 150–300 kN per 200 mm × 200 mm plaque is a reasonable starting envelope for this durometer class; the exact force depends on cavity depth and preform shape.

    Bonding to metal inserts is possible with silicone-compatible primers. The metal surface must be degreased and lightly abrasive-blasted to a profile of 1.5–3.0 µm Ra before primer application. Adhesive bond strength is configuration-specific; published data for the exact R3781-920-##R##-P0 adhesion to passivated steel is limited.

    If Fuel Swell and Thermal Class Are Evaluated, What Product-Specific Differences Emerge?

    R3781-920-##R##-P0 differs from fluoroether and fluorosilicone elastomers in solvent exposure. Fluorosilicone compounds are specified when the application requires low volume swell after immersion in hydrocarbon fuels, hydraulic fluids, or aromatic solvents. A fluorosilicone grade will typically exhibit volume swell below 10% after 70 h immersion in ASTM Reference Fuel B at 23 °C, whereas a dimethyl silicone compound may swell substantially under the same conditions. R3781-920 is therefore not the first-line material for fuel cell or engine compartment liquid seals unless the fluid exposure is validated by testing the finished part under ASTM D471 or ISO 1817.

    The thermal comparison between general-purpose methyl silicone and R3781-920 is less severe than the chemical comparison. The material is capable of continuous operation at 200 °C when properly post-cured, but high-consistency silicone rubbers should not be pressed into continuous service above 230 °C without evaluating reversion, hardness increase, and loss of elongation. Phenyl-modified silicone grades can operate above 250 °C for limited intervals, but they often carry higher cost and lower tear strength. Published data for the specific R3781-920 thermal aging response is limited; a user-specific heat aging test at 200 °C for 1,000 h is recommended before qualification.

    Compared with liquid silicone rubber injection-molding grades, the peroxide-curable high-consistency product is better suited to calendered sheet and die-cut part geometries. LSR requires closed-loop metering, static mixing, and injection molding equipment with cooled runner systems. R3781-920 can be run on conventional rubber calenders and compression presses, but it lacks the very low viscosity and rapid flash-free cavity filling associated with LSR. The high-consistency material also offers higher green strength for sheet handling and die-cutting, while LSR is typically preferred for high-cavity-count automated molding.

    Differences from general-purpose VMQ compounds appear in compression set, volatile content, and surface consistency. A lightly post-cured general-purpose VMQ may have compression set above 40% after 22 h at 177 °C; the R3781 series is controlled to lower values for sealing applications. The P0 surface finish, once resolved, is intended to reduce variation in coefficient of friction during automated die-cut part placement. The user should request the coefficient of friction test data from the manufacturer rather than assuming a value from uncoated silicone sheet literature.

    Compliance status is configuration-dependent. The checklist below identifies the standards applicable to silicone rubber materials of this class; actual certifications depend on the resolved ##R## reinforcement and the final fabricated part.

    Requirement Standard or reference Relevant condition for R3781-920
    Food contact rubber articles FDA 21 CFR 177.2600 Applies only if cure and extraction limits are met by the final article
    EU drinking water contact Regulation (EU) 10/2011 Not assumed without specific article testing
    RoHS restricted substances RoHS 2011/65/EU Declaration required from Rogers Arlon for the exact product code
    REACH SVHC Regulation (EC) No 1907/2006 Supplier statement required for P0 surface finish and fabric suffix
    Flame resistance UL 94, thickness-dependent Classification depends on backing and gauge
    Electrical insulation coordination IEC 60664-1 Used with ASTM D149 and ASTM D257 data

    For motor terminal gaskets, busbar isolation sheets, and outdoor enclosure seals, R3781-920-##R##-P0 is fabricated into die-cut pads or slit rolls. The silicone base provides the necessary thermal endurance for terminals that experience repeated thermal spikes to 180 °C, while the controlled compression set assists in maintaining bolt load over service life. In high-voltage assemblies, the part must be kept free of silicone oil bloom and release-agent residues; an isopropanol wipe followed by a drying period of 10–15 min at 60 °C is a common pre-installation conditioning step. For outdoor gasketing, the material should be compressed to a defined percentage within the recommended range for the specific thickness, and no claim of weather-sealing should be extended beyond validation under ASTM D395 compression set and ASTM D412 tensile retention after environmental aging.

    In thinly reinforced configurations, continuous flexing can create delamination at the elastomer-to-fabric interface. The product should not be used in dynamic bellows applications unless cyclic flex testing has been conducted on the exact reinforced construction. If the required flex cycles exceed 100,000 at 25 °C, material-class substitution based solely on thickness and durometer is insufficient; a prototype endurance test is required.

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