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REPOL PP Homopolymer H200MK

    • Product Name: REPOL PP Homopolymer H200MK
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 831748
    Polymer Type Polypropylene Homopolymer
    Melt Flow Index 230 C 2 16 Kg 8 g/10 min
    Density 0.90 g/cm3
    Tensile Strength At Yield 35 MPa
    Elongation At Yield 12%
    Flexural Modulus 1350 MPa
    Notched Izod Impact Strength At 23 C 3 kJ/m2
    Rockwell Hardness R-100
    Heat Deflection Temperature At 0 45 Mpa 105 °C
    Vicat Softening Point 155 °C

    As an accredited REPOL PP Homopolymer H200MK factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing REPOL PP Homopolymer H200MK is supplied in 25 kg sealed polyethylene-lined woven bags, ensuring dry, contamination-free handling and storage.
    Container Loading (20′ FCL) Packed in 25 kg PP woven bags on shrink-wrapped pallets, securely loaded and braced for 20′ FCL transport.
    Shipping REPOL PP Homopolymer H200MK is shipped as free-flowing pellets in moisture-protective bags, bulk containers, or rail/road hoppers. It is non-hazardous under normal transport conditions. Keep dry, avoid direct sunlight and excessive heat. Store in a clean, ventilated area, away from ignition sources. Handle gently to prevent bag damage.
    Storage Store REPOL PP Homopolymer H200MK in a cool, dry, well-ventilated area, ideally below 50°C. Keep containers sealed and protected from direct sunlight, UV radiation, and heat sources. Avoid moisture condensation and mechanical damage. Store away from oxidizers and open flames. Under proper conditions, shelf life is typically up to 12 months.
    Shelf Life Shelf life is two years from manufacture if stored in unopened, dry, cool conditions away from direct sunlight.
    Application of REPOL PP Homopolymer H200MK

    In high-cavitation thin-wall injection moulding for round and rectangular food-packaging containers with nominal wall thickness between 0.4 mm and 1.2 mm, REPOL PP Homopolymer H200MK is processed at a melt temperature of 220°C to 240°C as measured by an air-shot probe, while tool temperature is controlled between 15°C and 40°C to balance crystallisation rate against post-mould warpage. The resin does not require pre-drying when ambient relative humidity remains below 60% RH; above that threshold, 2 h at 80°C in a desiccant hopper dryer with a dew point of -30°C or lower prevents surface splay from atmospheric moisture. Injection velocity is set to deliver 120 mm/s to 250 mm/s linear screw travel to suppress flow marks and gate blush, and hydraulic hold pressure is maintained at 35 MPa to 55 MPa for 0.5 s to 1.2 s per millimetre of nominal wall thickness. Hot-runner valve gates with orifice diameters of 0.8 mm to 1.5 mm are preferred over open edge gates on high-cavitation tooling because they reduce orientation-induced anisotropic shrinkage. Sequential valve-gate opening on stack moulds permits a flow-length-to-wall-thickness ratio up to 180:1 without short shots, provided the injection velocity profile is segmented and not a single ramp. Mechanical verification on specimens injection moulded under ISO 294-1:2017 gives tensile yield stress between 32 MPa and 37 MPa (ISO 527-2) and flexural modulus between 1,350 MPa and 1,600 MPa (ISO 178) for this MFR class. Compliance for food-contact packaging is evaluated under FDA 21 CFR 177.1520 for olefin polymers; in the European Union, the relevant framework is EU No 10/2011 with an overall migration limit of 10 mg/dm² and specific migration limits for individual additives. The mouldings are dimensionally conditioned for 24 h at 23°C ± 2°C and 50% ± 5% RH before shrinkage verification; typical post-mould shrinkage is 1.2% to 1.8% along flow and 0.8% to 1.3% across flow, although these values shift with hot-runner balance and cooling-circuit design. The application window is restricted to cold-fill and ambient-fill packaging; hot-fill above 95°C is outside the design envelope because unreinforced homopolymer PP loses sealing-rim flatness and top-load resistance rapidly near the heat distortion threshold.

    Application frameworkStandard or regulationRelevant condition
    Food-contact packaging and closuresFDA 21 CFR 177.1520Olefin polymer clearance for end-use temperature ≤ 100°C
    EU food-contact articlesEU No 10/2011Overall migration limit 10 mg/dm²
    Closure removal torqueASTM D3474-1624 h conditioning at 23°C ± 2°C
    Appliance flammabilityUL 94HB classification at 1.5 mm and 3.0 mm
    Automotive interior VOCVDA 278:2011OEM-specific limit; commonly total VOC ≤ 100 µg/g

    Cap Closure Performance Under Torque Retention and Liner Compatibility

    The stiffness requirement in 28-mm and 38-mm injection moulded polypropylene closures for still beverages, bottled water and household chemical packaging is met by H200MK without the higher cost of random-copolymer impact modification. The tools are chilled to 10°C to 20°C, and the melt temperature is maintained at 230°C to 245°C. Cycle times of 6 s to 9 s per shot are obtained on 96-cavity tooling with hot-runner valve gates, but the short cycle makes injection velocity and decompression control critical to prevent drool at the gate. Post-demoulding shrinkage of 1.0% to 1.6% affects thread depth and seal-ring flatness; mould compensation must account for anisotropic shrinkage along the closure axis. Notched Charpy impact under ISO 179/1eA at 23°C is commonly below 5 kJ/m², which is acceptable for press-on and screw closure bodies but not for high-energy drop impact. Application torque on 28-mm PCO 1881 necks is typically 1.8 N·m to 2.2 N·m, and removal torque after 24 h at 23°C commonly falls to 0.8 N·m to 1.4 N·m. Torque retention is measured under ASTM D3474-16; the decline is dominated by stress relaxation in the tamper-evident band and not solely by thread geometry. Liner compatibility with PE-foam or EVA-coated pulp liners requires melt temperature to remain below 250°C to avoid liner degradation and acetaldehyde formation that could exceed sensory thresholds. Homopolymer PP is best suited to non-carbonated closures; sustained carbonation pressure above 2.5 bar at 4°C can produce brittle fracture of the knurl and tamper band, and random-copolymer grades should be substituted when drop impact at 0°C is a release criterion.

    As a carrier resin in colour concentrates and filled compounds, H200MK provides a consistent base-viscosity platform for dispersing pigments, carbon black, talc and calcium carbonate at loadings from 20 wt% to 70 wt% depending on the masterbatch design. Compounding on a co-rotating twin-screw extruder with screw diameter 25 mm to 75 mm and L/D 40:1 to 48:1 uses a barrel profile of 180°C to 220°C, with screw speed between 400 rpm and 800 rpm for high-shear dispersion of organic pigments. The melt temperature exiting the die is kept below 230°C to limit thermo-oxidative chain scission; a phenolic/phosphate stabiliser package is typically added at 0.05 wt% to 0.15 wt% when the compound must survive multiple heat histories during downstream dilution. If a higher final MFR is required, controlled rheology using organic peroxides at 0.01 wt% to 0.05 wt% shifts the pellet MFR upward, but the reaction must be monitored by ISO 1133-1:2022 at 230°C with 2.16 kg to avoid overshoot beyond the target tolerance of ±2 g/10 min. The resin is also used as a letdown carrier for additive masterbatches in film and fibre extrusion; in such cases, excessive screw temperature above 240°C degrades the base resin and increases yellowness index under ASTM D6290 or ISO 17223. Water-cooled pelletising with die-face temperature 210°C to 230°C and pellet water temperature 35°C to 50°C yields uniform pellet geometry for gravimetric blending. Avoidance of amine-based processing aids is recommended because amines can deactivate phenolic antioxidants and accelerate thermo-oxidative embrittlement during oven ageing; this limitation is especially relevant for compounds subjected to 700 h at 90°C in ISO 188 accelerated ageing protocols.

    What Limits the Service Temperature Window in Appliance Housings?

    Appliance housing applications at wall thicknesses of 1.5 mm to 3.0 mm use H200MK for washing machine splash shields, refrigerator door liners and small-appliance structural supports where the primary mechanical requirement is stiffness rather than sub-zero impact. The melt temperature is set at 220°C to 240°C and the tool at 20°C to 50°C; holding pressure is maintained at 40 MPa to 60 MPa until gate freeze, and longer cooling times of 12 s to 25 s are required when stiffening ribs create section changes greater than 1.5:1. The long-term service ceiling is governed by heat distortion temperature under ISO 75-2 method B at 0.45 MPa, typically 85°C to 100°C for unreinforced homopolymer PP, but creep modulus declines steeply above 80°C; therefore load-bearing appliance parts should not be subjected to sustained stress above 70°C. Heat distortion under ISO 75-2 method A at 1.80 MPa is lower, commonly 50°C to 60°C, and should be used when the component is clamped or externally loaded. Flammability classification under UL 94 is HB at 1.5 mm and 3.0 mm; live electrical parts and components requiring V-2 or better are outside the design scope for this grade unless a flame-retardant package is compounded separately. Glow-wire testing per IEC 60695-2-11 at 650°C is not automatically met by neat H200MK; if the appliance standard requires glow-wire ignition temperature above 750°C, an FR-modified compound is required. In contact with detergent solutions, environmental stress cracking is generally low for homopolymer PP, but limonene-based cleaning agents and certain surfactants can reduce surface hardness and should be validated under ISO 22088-3 bent-strip strain conditions.

    Automotive lower-plenum HVAC ducts, cowl vents and non-class-A interior retainers are produced from H200MK when the part design does not require high-speed impact at sub-zero temperatures. Moulding uses a melt temperature of 225°C to 245°C and a tool temperature of 20°C to 50°C; the higher tool temperature is specified for textured surfaces to replicate grained cavity detail. Because automotive appearance parts are exposed to solar load and cabin soak temperatures up to 105°C, components made from H200MK are limited to ducting and interior brackets that are not continuously loaded above 80°C. Ageing resistance is assessed by heat ageing in forced-air ovens per ISO 188 at 100°C for 500 h; tensile yield retention should remain above 80% when stabilisation is adequate, but published data for this specific configuration is limited and OEM-specific validation is required. Interior VOC and odour performance must be tested under VDA 278:2011 and VDA 270; homopolymer PP with standard stabiliser packages generally shows low fogging, but condensation and low-volatility substances still require control at the compounder level. Dimensional stability under thermal cycling from -30°C to 80°C is verified by PV 1200 or ISO 16750-4 thermal shock procedures, with warpage and attachment-hole fit checked at end of test. The absence of rubber impact modifier means that parts are prone to brittle failure at -20°C under notched impact; therefore vehicle mounting points should be isolated from high-strain-rate loading or specified in a copolymer grade.

    Warpage and Stacking-Load Stability in Logistics Containers

    Stackable crates, pails and pallet boxes are injection moulded from H200MK in wall sections from 1.8 mm to 4.5 mm, but thick bosses and corner ribs create long cooling-time bottlenecks. Melt temperature is held at 220°C to 250°C, and tool temperature is kept at 15°C to 35°C for fast crystallisation; however, mould temperature differentials greater than 10°C across the cavity cause differential shrinkage and visible sink marks on ribbed surfaces. Packing pressure is typically 35 MPa to 55 MPa, and packing time is extended to 8 s to 20 s depending on gate freeze. The principal long-term failure mode is creep under stacked load; compression and creep modulus are measured under ISO 899-1 at 23°C and 60°C, and top-load resistance of pails is checked by ASTM D642-20 or ISO 12048 depending on the distribution market. At 40°C, a sustained load corresponding to 400 kg on a pallet box can produce measurable sidewall deflection after 28 days, so the allowable stacking height is reduced relative to high-crystallinity grades with higher flexural modulus. Warpage after ejection is managed by balanced cooling circuits, gate placement at the centre of the base or along the short side, and post-fixture cooling of 15 s to 30 s; without fixtures, corner lift can exceed 3 mm on a 600 mm by 400 mm crate. The grade is appropriate for returnable logistics when ambient service temperature does not exceed 60°C, but repeated impact from fork tines at -10°C may produce brittle fracture at corner ribs, so a random-copolymer or impact-copolymer grade is substituted for freezer-warehouse service.

    Moulding segmentMelt temperatureTool temperatureDominant process limitation
    Thin-wall packaging220°C to 240°C15°C to 40°CFlow length/thickness ≤ 180:1
    Closures230°C to 245°C10°C to 20°CLiner degradation above 250°C
    Appliance housings220°C to 240°C20°C to 50°CCreep above 70°C
    Logistics containers220°C to 250°C15°C to 35°CDifferential cooling and warpage
    Automotive ducting225°C to 245°C20°C to 50°CBrittle impact below -20°C
    Furniture210°C to 230°C20°C to 30°CNotch sensitivity at ambient temperature

    Furniture-grade housewares such as stackable chairs, drawers and storage bins represent a cost-sensitive segment in which H200MK is processed at 210°C to 230°C and tool temperature 20°C to 30°C; the only mandatory verification is stiffness under ISO 178, and structural design must remain free of sharp internal corners because the homopolymer notch sensitivity limits accidental drop performance at ambient temperature.

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    Certification & Compliance
    More Introduction

    REPOL PP Homopolymer H200MK is a polypropylene homopolymer supplied by Reliance Industries Limited with a nominal melt mass-flow rate of 20 g/10 min as determined by ISO 1133-1:2022 at 230 °C under a 2.16 kg load. The grade is differentiated from higher-viscosity homopolymers by a lower average molecular weight, which reduces injection pressure, shortens fill time, and permits processing in thin-wall multi-cavity tools. Because the backbone contains no ethylene comonomer, the material exhibits a higher flexural modulus and heat deflection temperature than random polypropylene copolymers of equivalent flow, but its notched impact response at low temperature is correspondingly weaker. Published producer literature identifies the resin for thin-wall packaging, closures, housewares, appliance components, and furniture accessories where stiffness, dimensional uniformity, and rapid mold filling are required. The product is supplied as pelletized neat resin; the melt flow rate is a release value and should be confirmed on the user’s molding line before part qualification.

    What Limits the Processing Envelope in Thin-Wall Tools When H200MK Replaces a Random Copolymer?

    When H200MK is substituted for a random copolymer of similar flow, the processing envelope narrows at high temperature because the homopolymer chain is more susceptible to thermo-oxidative chain scission. Barrel temperature settings are typically maintained between 210 °C and 240 °C, with a melt temperature not exceeding 250 °C. Above 260 °C, melt flow rate can drift upward within a single production shift, producing sink mark instability and a measurable loss in notched impact strength. Mold temperatures of 20 °C to 50 °C are sufficient for surface finish and crystalline solidification; higher mold temperatures improve weld-line integrity but extend cycle time. The low melt viscosity of H200MK generates shear heating at gate lands; shear rates in thin-wall filling commonly reach 10³ s⁻¹ to 10⁴ s⁻¹, so the actual melt front temperature may exceed the barrel set point. Hot runner manifold set points should not exceed 250 °C to 255 °C, and valve pin tips should be profiled to avoid stagnation zones. Residence time at 240 °C is preferably below 4 minutes; beyond 5 minutes, surface splay, yellowing, and screw recovery variability have been observed on production-scale equipment.

    Drying is not universally required at ambient relative humidity below 60%. However, if pellets are stored in unlined bulk bags or outdoor silos, surface condensation can create flow marks and inconsistent melt density. A desiccant hopper dryer at 80 °C for 2 hours with a dew point of -40 °C removes surface moisture without thermally degrading the stabilizer package. Polypropylene does not undergo bulk hydrolysis in the manner of polyamide, so prolonged drying provides no additional benefit and may increase energy cost.

    On a 32-cavity hot-runner closure mold installed in a 200-tonne hydraulic injection molding machine with a 22:1 L/D general-purpose screw, the lower melt viscosity of H200MK produced filling pressure reductions of approximately 8–12% compared with a 12 g/10 min homopolymer at the same transfer position and cushion. Recommended shot size is between 25% and 75% of barrel capacity. Injection pressure typically falls between 700 bar and 1200 bar, with holding pressure at 50–70% of peak injection pressure and hold time governed by gate freeze. In valve-gated tools, gate freeze time can be shorter than in open hot-tip systems because the valve pin isolates the cavity from manifold pressure decay. Surface defects such as flow marks and tiger stripes have been linked to abrupt screw deceleration at transfer; a linear deceleration over 0.2–0.4 s has been used in production to stabilize flow-front propagation. Published data for this specific configuration is limited, so the pressure window must be verified on the target tool because runner balance and gate dimensions interact with the narrower molecular weight distribution.

    Mechanical Property Benchmarks and Isotacticity-Driven Shrinkage Anisotropy

    Injection-molded test specimens prepared according to ISO 294-1:2017 and conditioned under ISO 291:2008 at 23 °C and 50% relative humidity yield the following representative values from producer technical literature. The values are presented as typical release data, not purchase specification limits, and align with the data presentation principles of ISO 10350-1:2017.

    Property Test standard Unit H200MK typical value Low-flow PP homopolymer typical range PP impact copolymer typical range
    Melt mass-flow rate ISO 1133-1:2022 g/10 min 20 3–12 8–25
    Tensile stress at yield ISO 527-2:2012 MPa 34 35–38 25–28
    Tensile strain at yield ISO 527-2:2012 % 9 10–12 8–12
    Flexural modulus ISO 178:2019 MPa 1450 1500–1700 1100–1300
    Notched Izod impact at 23 °C ISO 180:2023 kJ/m² 2.5 3.0–4.5 10–25
    Heat deflection temperature at 0.45 MPa ISO 75-2:2013 °C 95 95–105 85–95

    The homopolymer architecture gives H200MK a flexural modulus near 1450 MPa, which supports rigid side-wall and base-plate designs in storage containers and appliance housings. However, the notched Izod impact at 23 °C of approximately 2.5 kJ/m² indicates that snap-fit geometry should be evaluated by finite-element analysis rather than by assuming post-yield ductility. At weld lines, tensile strength retention in polypropylene homopolymers is generally reduced to 70–85% of the unwelded value; for H200MK, weld-line performance is controlled more strongly by gate location and mold temperature because the lower molecular weight reduces chain entanglement at the melt interface. The principal difference from lower-flow homopolymers is viscosity: a 12 g/10 min homopolymer requires higher injection pressure and retains more molded-in orientation at low mold temperature, while H200MK fills thinner sections but exhibits slightly lower tensile elongation at yield. The principal difference from impact copolymers is the absence of an ethylene-propylene rubber phase. Impact copolymer grades with notched Izod values of 10–25 kJ/m² at 23 °C are preferred for living hinges or snap-fit parts, but their flexural modulus is generally 1100–1300 MPa, lower than H200MK. Random copolymers of equivalent melt flow provide improved contact clarity and lower heat deflection temperature, typically 75–85 °C at 0.45 MPa, compared with 95 °C for H200MK.

    If Subzero Impact Resistance Governs Material Selection, the Homopolymer Architecture Must Be Rejected

    At service temperatures below 0 °C, the notched impact resistance of a polypropylene homopolymer declines sharply because chain mobility is limited and crazing occurs before shear yielding. The H200MK grade is not formulated with an impact modifier or ethylene comonomer; therefore its ductile-to-brittle transition temperature is higher than that of heterophasic copolymers. For freezer applications or outdoor parts exposed to -20 °C, impact copolymer grades are required. H200MK is more appropriate for continuous service temperatures of 5 °C to 80 °C. Chemical resistance is typical of polypropylene: the polymer resists aqueous acids, alkalis, and many polar organic solvents at room temperature but is swollen by aromatic and chlorinated hydrocarbons. Environmental stress cracking resistance requires assessment under ASTM D1693-21 if the final part contacts surfactants, oils, or aggressive detergent solutions. The natural resin typically meets UL 94 HB classification at 1.5 mm thickness when tested according to UL 94, but final flammability classification depends on colorants, wall thickness, and the finished article test program.

    Regulatory compliance for food-contact use must be established on the final article. The base homopolymer may be evaluated under FDA 21 CFR 177.1520 for olefin polymers when the finished product is tested for end-use restrictions and migration limits. For European electrical and electronic equipment, evaluation under EU RoHS Directive 2011/65/EU through IEC 62321 test methods is relevant only if the part enters the scope of that directive; producer trace metal data for lead, mercury, cadmium, and hexavalent chromium should be obtained for the specific lot. Under REACH Regulation (EC) No 1907/2006 Article 33, an article supplier bears responsibility for communication if a substance of very high concern is present above 0.1% w/w; the resin supplier’s material safety data sheet and technical bulletin remain the authoritative lot-specific documents.

    Under Elevated Ambient Humidity, Feed Preconditioning Becomes a Process Variable, Not an Additive Solution

    Polypropylene is not hygroscopic in the same manner as polyamides, but surface condensation on cold pellets from outdoor silos can introduce water into the melt. In high-humidity coastal molding plants, pellets stored in unlined bulk bags at RH > 60% have produced splay and inconsistent screw recovery. A desiccant hopper dryer operating at 80 °C for 2 hours with a dew point of -40 °C is sufficient to remove surface moisture; continuous drying is unnecessary if the feed is kept above dew point. Conveying air should be dried to a dew point below 10 °C in tropical weather to prevent re-condensation. Dust and fines from regrind can reduce feed stability; regrind addition is limited to 15–20% by mass, with no more than 2% fines smaller than 500 µm to avoid bridging in the feed throat. The product can be processed on general-purpose screws with an L/D ratio of 20:1 or higher; barrier screws are preferred for consistent melt temperature when high screw recovery rates are used. Batch-to-batch melt flow variation should be monitored at incoming inspection using ISO 1133-1:2022, and the melt flow value should be correlated with screw recovery time and cushion stability on the target machine rather than treated as an isolated quality indicator.

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