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REPOL PP Homopolymer H100EY

    • Product Name: REPOL PP Homopolymer H100EY
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 182936
    Polymer Type Polypropylene Homopolymer
    Melt Flow Rate 230 C 2 16 Kg 11 g/10 min
    Density 0.900 g/cm³
    Tensile Strength At Yield 35 MPa
    Elongation At Yield 11%
    Flexural Modulus 1400 MPa
    Notched Izod Impact Strength 23 C 3.5 kJ/m²
    Heat Deflection Temperature 0 45 Mpa 100 °C
    Vicat Softening Point 155 °C
    Rockwell Hardness R80
    Processing Method Injection Molding

    As an accredited REPOL PP Homopolymer H100EY factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing REPOL PP Homopolymer H100EY is packaged in 25 kg multi-wall paper bags with inner liner, palletized and shrink-wrapped for protection.
    Container Loading (20′ FCL) REPOL PP Homopolymer H100EY is packed in 25kg bags, loaded into a 20-foot full container load, palletized and secured.
    Shipping REPOL PP Homopolymer H100EY ships as a non-hazardous thermoplastic resin. It is supplied in moisture-protective woven bags or bulk containers, stored dry, and transported in clean vehicles. Avoid excessive heat, direct sunlight, and impact to preserve pellet integrity and prevent contamination during transit.
    Storage Store REPOL PP Homopolymer H100EY in a cool, dry, well-ventilated area away from direct sunlight, heat, and ignition sources. Keep in original sealed packaging or clean, covered containers to prevent moisture, dust, and contamination. Avoid prolonged UV exposure and static buildup. Maintain moderate temperatures and good airflow to preserve product quality.
    Shelf Life Shelf life is indefinite when stored in original packaging under cool, dry conditions away from direct sunlight.
    Application of REPOL PP Homopolymer H100EY

    At melt temperatures between 200 °C and 230 °C, the use of REPOL H100EY in thin-wall food-contact container production is governed primarily by the polymer’s melt flow rate of approximately 11 g/10 min under ISO 1133-1:2022 at 230 °C/2.16 kg. In high-speed multi-cavity moulding of wall sections down to 0.6 mm, this flow range supports fill times of 0.2–0.5 s on hydraulic machines fitted with accumulators and injection velocities of 120–180 mm/s. The compliance basis for food-contact articles includes FDA 21 CFR 177.1520 for olefin polymers, EU Regulation (EU) No 10/2011 with an overall migration limit of 10 mg/dm², and GB 4806.7-2016 for polypropylene food-contact materials. Formulation addition is normally limited to a polypropylene-carrier colour masterbatch at 1–3 wt%, a nucleating agent masterbatch at 0.1–0.3 wt% when cycle-time reduction outweighs haze development, and an antistatic masterbatch at 0.5–1.5 wt% for dry-goods packaging where dust attraction must be controlled.

    The injection moulding process uses a general-purpose screw with L/D ratio of 20:1–24:1 and a check-ring non-return valve, with a barrel temperature profile from 180 °C in the feed zone to 220 °C at the nozzle. Mould temperature is held at 15–35 °C; below 15 °C, short shots and flow marks occur in ribs below 0.8 mm, while above 35 °C cycle time rises without commensurate improvement in surface quality. Hold pressure is maintained at 50–70 MPa until gate freeze, typically 1.5–3.0 s for a 1.2 mm side wall. Because H100EY is a homopolymer, crystalline orientation in thin walls creates differential shrinkage; specimens moulded at 200 °C melt and 20 °C mould may show post-mould shrinkage of 1.2–1.8% over 24 h, requiring dimensional checks after 24 h and 48 h under ISO 294-4:2018 rather than immediate measurement. Finished article types include storage containers, lunch boxes, food trays, and container lids where repeated food contact is intended. An important operational boundary is low-temperature impact: unfilled H100EY becomes notch-sensitive below 0 °C, and freezing to -18 °C may cause brittle fracture on impact, so freezer-to-microwave claims should be excluded unless the finished design has been tested under ISO 180:2019 or ASTM D256-23 at the intended temperature.

    Regulatory referenceRequirement or test methodApplication link
    FDA 21 CFR 177.1520Olefin polymers for food contact; extractive limits depending on food typeContainers, lids, trays
    EU Regulation (EU) No 10/2011Overall migration limit 10 mg/dm²Food-contact lids and boxes
    GB 4806.7-2016Polypropylene food-contact material specific migrationExport packaging for China
    ISO 1133-1:2022Melt mass-flow rate at 230 °C/2.16 kgProcess consistency control

    What Limits Torque Retention in Non-Carbonated Container Closures?

    The use of H100EY in screw closures for non-carbonated beverages, dry nutritionals, cosmetic packs, and household chemical closures places torque retention, dimensional stability, and migration control above impact toughness. The melt flow rate of approximately 11 g/10 min under ISO 1133-1:2022 is acceptable for multi-cavity closure moulds where the fill path is short but the flow-length-to-wall-thickness ratio can reach 120:1 in thin hinges and tamper-evident bands. The compliance basis includes FDA 21 CFR 177.1520 for food contact, EU Regulation (EU) No 10/2011 for overall migration, and USP <661.1> only where the closure is part of a pharmaceutical packaging system, in which case the entire finished packaging system, not the resin alone, must be tested. Formulation addition is typically 1.0–2.0 wt% of a slip/anti-block masterbatch based on erucamide or oleamide, with the active slip agent in the final compound at 500–1,000 ppm. Colour masterbatch addition is 1–3 wt%. Excess slip agent above 1,000 ppm can lead to plate-out on mould surfaces and to organoleptic taint in fatty food simulants.

    Slip agent migration in H100EY closures is diffusion-controlled: erucamide blooms to the surface over 24–72 h at 23 °C, and the coefficient of friction stabilises only after this conditioning period, so torque tests on freshly moulded caps understate the final removal force. High-cavitation closure moulding demands hot-runner valve gates, injection units with high injection-speed capability of 200–350 mm/s, and clamp forces between 1,500 kN and 4,500 kN. Melt temperature is set from 220 °C to 250 °C, while mould temperature ranges from 10 °C to 30 °C to achieve cycle times of 5–10 s. Injection-compression moulding is used when sealing surface flatness must be held within 0.1 mm. Terminal products include tamper-evident screw caps, snap-on lids, flip-top dispensing caps, and non-child-resistant pharmaceutical closures. This grade is not advisable for carbonated soft drink closures under sustained CO₂ pressure above 3 bar, because unfilled homopolymer lacks the environmental stress crack resistance and low-temperature ductility of impact copolymers; such applications require validation under ASTM D256-23 at 0 °C and closure retention testing on the finished package rather than on resin alone.

    Moulding utility crates, storage baskets, and domestic furniture components from unfilled H100EY places higher demand on wall-thickness distribution and hold-pressure control than on melt flow. The resin is typically injection moulded at 200–240 °C melt temperature and 20–40 °C mould temperature. Deep-rib designs require hold pressures of 40–70 MPa and gate freezing times up to 6 s, because sink marks over bosses can exceed 0.05 mm depth when hold pressure is released too early. Clamp force for crate and basket tools generally falls between 5,000 kN and 12,000 kN, depending on projected area and cavity count. The compliance basis includes REACH SVHC restrictions, RoHS Directive 2011/65/EU Annex II for electrical accessories if co-moulded, and EN 71-3:2019+A1:2021 when the article is marketed as a toy or childcare item. Food-contact houseware uses are regulated under EU Regulation (EU) No 10/2011 and FDA 21 CFR 177.1520.

    Formulation addition for these articles is often 2–4 wt% colour masterbatch, with outdoor service crates receiving 0.3–0.8 wt% UV stabilizer masterbatch and 10–20 wt% calcium carbonate when flexural modulus must be raised. The addition of calcium carbonate at the upper end reduces notched impact and weld-line strength; therefore impact tests per ISO 180:2019 at 23 °C and 0 °C are used to bound acceptable loadings. Processing problems observed on production lines include batch-to-batch MFI drift of ±1 g/10 min altering fill at rib thickness below 1.0 mm, so in-process melt flow checks by ISO 1133-1:2022 and fill-to-fill study at start-up are applied. Surface condensation on cold pellets stored below dew point can cause splay; the processor should store sealed and allow 2–4 h equilibration at moulding room temperature before hopper charging when ambient RH exceeds 60%. Finished article types include stackable storage crates, utility baskets, drawer organisers, hangers, furniture bases, and shell components. The resin should not be used for load-bearing outdoor furniture at temperatures below 5 °C without impact modification, and unpigmented outdoor weathering beyond short-term exposure leads to surface chalking and loss of gloss.

    Appliance Housings and Internal Structural Parts Without Flame-Retardant Modification

    The use of H100EY in small appliance housings and internal structural parts is confined to components that are not directly exposed to glowing contacts or to continuous service above 80 °C under load. The compliance basis is end-product driven: components for household electrical appliances are assessed against IEC 60335-1 clauses on resistance to heat and fire, IEC 60695-2-11 glow-wire test only where required by the end-product standard, and RoHS Directive 2011/65/EU Annex II for restricted substances. Unfilled H100EY does not carry an inherent UL 94 V rating, and no flame-retardant claim should be made unless a specific flame-retardant formulation is tested. Formulation addition includes 10–20 wt% talc or 15–25 wt% calcium carbonate for dimensional stability, 1–3 wt% PP-g-MAH where filler-matrix adhesion must be improved, and 2–4 wt% colour masterbatch. The compound is prepared on a co-rotating twin-screw extruder with L/D ratio 40:1 and a side feeder at 12D–16D from the feed throat, at screw speeds of 250–500 rpm and melt temperatures 180–230 °C.

    For appliance parts, the injection moulding stage uses melt temperatures of 200–240 °C, mould temperatures of 30–60 °C, and injection pressures of 80–140 MPa; higher mould temperature is necessary to reduce warpage in thin-walled front panels. The production bottleneck is usually the balance between crystalline orientation and part flatness, because uncontrolled shrinkage anisotropy results in dimensional variation of ±0.2 mm or greater across a 300 mm span. Terminal products include air baffles, structural brackets, fan shrouds for non-flame-retardant appliances, bases, and internal service covers. Continuous load-bearing applications above 60 °C or stress levels above 10 MPa require creep-rupture data by ISO 899-1:2017 because homopolymer PP may exhibit excessive creep. Avoid halogenated flame-retardant masterbatches unless the end-product standard requires them; these can corrode mould surfaces and alter melt viscosity.

    Compounding H100EY with talc for automotive interior trim substrates and non-impact-critical underbonnet service covers starts with the virgin pellet feed in a co-rotating twin-screw extruder, with melt temperature maintained between 200 °C and 230 °C at the die. The filler is introduced through a side feeder positioned at 12D–16D downstream to minimise barrel abrasion and to disperse talc without extensive matrix degradation. Typical addition ratios are 10–25 wt% talc, 1–3 wt% PP-g-MAH coupling agent, 2–4 wt% colour masterbatch, and 0.2–0.6 wt% heat-stabilizer masterbatch. Compliance standards for the resulting components include FMVSS 302 (49 CFR 571.302) for flammability with a burn rate not exceeding 100 mm/min, ISO 3795:1989, SAE J369:2019 for interior trim, and REACH SVHC restrictions. This is not a grade for exterior painted body panels or for components requiring low-temperature impact below -20 °C, because unfilled and talc-filled homopolymer PP shows a sharp ductile-to-brittle transition.

    For these compounds, injection moulding uses melt temperatures 220–250 °C, mould temperatures 30–60 °C, injection pressures 90–150 MPa, and clamp forces from 3,000 kN to 12,000 kN depending on part size. The production-scale failure mode observed on similar homopolymer compounds is delamination at weld lines when the melt front temperature drops below 200 °C before the flow fronts merge; this is controlled by increasing injection velocity or relocating the gate rather than by raising barrel temperature above 250 °C, which accelerates molecular weight degradation. Terminal products in this scenario include interior trim carriers, HVAC duct housings, service lids, ventilation components, and non-structural underbonnet covers. Published data for long-term coolant, oil, and zinc chloride exposure on this specific H100EY/talc combination is limited; compatibility testing should be performed according to end-product specifications if such contact is intended.

    ParameterTarget or limitTest method / equipment
    Talc content10–25 wt%Ash content by ISO 3451-1:2019
    Melt temperature at compounding die200–230 °CMelt thermocouple
    Injection moulding melt temperature220–250 °CNozzle pyrometer
    Flammability≤ 100 mm/min burn rateFMVSS 302

    When H100EY Appears in Laboratory and Diagnostic Consumable Moulding

    Laboratory consumables such as pipette tip racks, centrifuge-tube racks, specimen transport trays, and diagnostic waste boxes are injection moulded from H100EY only after the processor confirms that the relevant finished-article standards have been met, because the resin alone is not marketed as a certified medical-grade material. The compliance basis for these articles includes ISO 10993-5:2009 for cytotoxicity and ISO 10993-10:2021 for irritation when the consumable contacts biological specimens or skin, while repeat autoclave compatibility is verified by visual inspection, dimensional checks, and ISO 527-2:2012 tensile testing after the specified number of cycles. USP <88> Class VI testing is performed on the finished device or article rather than on the pellet where regulatory claims are made. REACH and RoHS Directive 2011/65/EU apply for import and disposal.

    Formulation addition is minimal: colour-coding masterbatch at 0.5–1.5 wt% and, where needed, an acid-neutralising additive masterbatch at 0.1–0.3 wt%; slip additives are excluded because they may interfere with surface assays. Moulding is performed in an ISO Class 7 or ISO Class 8 cleanroom using a hydraulic or electric injection moulding machine with a general purpose screw L/D 20:1–24:1, melt temperature 200–230 °C, mould temperature 15–30 °C, and injection pressure 70–120 MPa. Mould release sprays are avoided, and tool surfaces are passivated or chrome-plated to minimise contamination. Terminal products include non-sterile racks, trays, storage boxes, and disposable diagnostic holders. Operational boundaries include distortion during autoclaving at 121 °C; if the part must survive repeated steam cycles without dimensional shift, a restrained cooling fixture and post-mould annealing are required. Gamma irradiation above 25 kGy may discolour and embrittle the homopolymer, so irradiation dose mapping and post-irradiation ISO 180:2019 impact tests are necessary.

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    Certification & Compliance
    More Introduction

    REPOL PP Homopolymer H100EY is a polypropylene homopolymer injection-moulding grade supplied by Reliance Industries Limited. The grade is classified according to ISO 19069-2 as a PP-H material with a nominal melt mass-flow rate of 10 g/10 min at 230 °C/2.16 kg determined under ISO 1133-1:2022. The polymer chain contains propylene repeat units without intentional ethylene incorporation, which produces a density of approximately 0.90 g/cm³ under ISO 1183-1:2019. The homopolymer architecture distinguishes H100EY from random copolymer and impact copolymer grades in the REPOL PP range.

    Published supplier technical data for H100EY list the following typical values; they are not lot-specific specification minima or maxima. Final conformity is determined by the certificate of analysis for each production lot and by the application-specific performance requirements of the moulded article.

    PropertyStandardTypical value
    Melt mass-flow rate at 230 °C / 2.16 kgISO 1133-1:202210 g/10 min
    DensityISO 1183-1:20190.90 g/cm³
    Tensile stress at yieldISO 527-2:201236 MPa
    Tensile strain at yieldISO 527-2:20129 %
    Flexural modulusISO 178:20191,600 MPa
    Notched Izod impact at 23 °CISO 180/A2.5 kJ/m²
    Heat deflection temperature at 0.45 MPaISO 75-2/B105 °C
    Vicat softening temperatureISO 306/A50155 °C
    Rockwell hardness, R scaleISO 2039-2103
    Mould shrinkage, flow directionISO 294-4:20181.2–1.8 %

    Thermal Degradation Pathways During Extended Barrel Residence

    Because H100EY is a homopolymer, its processing window is governed by oxidative chain scission at elevated temperature. At barrel temperatures above 240 °C, hydroperoxide formation and β-scission reduce molecular weight and melt viscosity; the resulting degradation products include volatile aldehydes and ketones that are detected as odour and splay at the part surface. Processing audits on conventional reciprocating-screw machines report that melt residence times exceeding 5 min at 240 °C produce measurable yellowing, while nozzle temperatures above 260 °C can initiate localised gel formation in stagnant zones. The stabiliser package in H100EY is formulated for short to moderate thermal exposure; sustained hot-runner temperatures above 250 °C are not recommended unless the hot-runner system is sized for minimum residence volume. Process settings that combine high back pressure, high screw speed, and long hold time can generate shear heating above the set-point; therefore, melt temperature should be verified by pyrometer rather than barrel heater display. The upper melt temperature limit for H100EY in long-cycle operations is 250 °C; shutdowns should be purged with a purge compound before barrel idle.

    On single-screw reciprocating machines with screw L/D ratios between 20:1 and 24:1, the barrel thermal profile is typically set at 30–50 °C in the feed throat, 210–230 °C in the compression zone, and 220–240 °C in the metering zone and nozzle. Injection pressure at the screw face commonly falls between 70–120 MPa depending on flow length and wall section; hold pressure is staged at 50–70 % of injection pressure and held for 1–2 s/mm of nominal wall thickness. Back pressure is limited to 0.5–1.0 MPa, and screw speed is maintained at 80–120 rpm. Mould temperature is controlled from 20–50 °C; lower settings shorten cycle time but increase moulded-in stress and produce duller surfaces, while higher settings improve surface reproduction and raise post-mould shrinkage. Mould shrinkage in the flow direction is typically 1.2–1.8 % under ISO 294-4:2018, with transverse shrinkage generally lower by 0.1–0.3 percentage points. Published data for this specific configuration is limited for hot-runner systems; in such systems, gate freeze-off should be confirmed by pressure decay rather than timer alone.

    Rheologically, a 10 g/10 min homopolymer melt is shear-thinning. Capillary rheometry under ISO 11443:2021 shows a decrease in apparent viscosity from roughly 1,200 Pa·s at 100 s⁻¹ to 300 Pa·s at 1,000 s⁻¹ at 230 °C for unfilled PP homopolymers of this flow class. These values are representative literature data for unfilled PP-H, not lot-specific values for H100EY. This non-Newtonian response allows thin-wall filling at moderate injection speeds, but it also makes the material sensitive to gate shear rate; gate shear rates above 100,000 s⁻¹ can initiate melt fracture and surface haze. Consequently, gate diameters should be selected to keep shear rate within the manufacturer’s design curve, and published data for this specific additive-stabilised grade should be obtained from the supplier before final tooling release.

    The stiff behaviour of H100EY is a function of spherulitic crystallisation during cooling. Fast cooling at mould temperatures below 20 °C reduces spherulite size and yields lower crystallinity, which can decrease flexural modulus by 5–10 % compared with slow cooling at 50 °C. Differential scanning calorimetry under ISO 11357-3:2018 typically places the peak melting temperature for PP homopolymer between 160–165 °C; the crystallisation half-time is strongly cooling-rate dependent. In thick sections above 3 mm, slow core cooling can produce non-uniform shrinkage and sink marks; tooling should therefore use uniform wall thickness and adequate packing pressure rather than high mould temperature alone.

    What Distinguished H100EY from Ethylene-Modified Polypropylene Grades?

    The primary difference between H100EY and a random copolymer of comparable melt flow is the absence of ethylene co-monomer. Random copolymers contain typically 1–7 wt% ethylene, which disrupts crystallinity and lowers flexural modulus by approximately 20–30 % relative to homopolymer PP under ISO 178:2019. H100EY therefore provides higher stiffness and a higher heat deflection temperature under 0.45 MPa load. However, the same structural regularity reduces notched impact toughness at sub-ambient temperature; H100EY should not be specified for parts exposed to impact below 0 °C unless impact modification is added at the converter’s own risk. Impact copolymer grades contain a dispersed ethylene-propylene rubber phase and are preferred when toughness is the controlling requirement, but their flexural modulus is usually 15–30 % lower than homopolymer grades of similar melt flow. Compared with high-flow PP homopolymers such as 35 g/10 min grades, H100EY retains longer molecular chains and therefore offers higher tensile stress at yield but requires higher injection pressure for thin-wall parts with long flow paths. These differences are measurable under ISO 527-2:2012 and ISO 180/A, but exact values vary by supplier and additive package; published data for this specific comparative configuration is limited beyond the supplier datasheet.

    The application envelope for H100EY includes rigid packaging containers, pails, crates, houseware products, furniture components, caps and closures, and appliance interior parts. In caps and closures, the 10 g/10 min melt flow supports filling of multi-cavity closure tools with short cycle times, while the homopolymer backbone provides restrained creep under repeated opening torque. Closures moulded from H100EY are typically evaluated for environmental stress-cracking resistance under ASTM D1693 and for oxygen permeability under ASTM D3985 when barrier requirements apply; published data for this specific grade is limited. Furniture and crate applications use the grade’s flexural modulus of 1,600 MPa under ISO 178:2019 to resist stacking loads, but outdoor weathering requires carbon black or UV stabiliser masterbatch because unpigmented homopolymer PP undergoes rapid photo-oxidation. For food-contact articles, converter-specific migration testing is required because processing conditions may alter organoleptic performance.

    Chemical resistance of H100EY follows general PP-H behaviour: it resists most dilute acids, alkalis, and aqueous detergent solutions at temperatures below 60 °C; it is swollen by aliphatic and aromatic hydrocarbons, and oxidising agents such as bleaching powder or concentrated hydrogen peroxide attack the polymer chain. Stress-cracking resistance under ASTM D1693 should be evaluated for closures in contact with aggressive surfactants. These statements are based on PP-H reference data; supplier testing is required for critical applications.

    When H100EY Replaces Random Copolymer in Rigid Packaging

    When H100EY is substituted for a random copolymer in a rigid packaging tool, the main process change is an increase in melt pressure due to the higher crystallinity of the homopolymer; injection pressure may rise by 10–20 % for identical wall thickness and flow length. The mould shrinkage of the homopolymer is also higher, and the absence of ethylene reduces warpage tolerance in shallow rectangular parts. The replacement is most suitable when the package requires higher stacking strength or higher heat deflection; it is not suitable when contact clarity is a specification, because homopolymer PP produces haze in thick sections unless nucleating agents are added. Retraction settings should be adjusted to prevent stringing, and mould temperature should be kept at the high end of the 20–50 °C range to reduce flow marks. Gate size must be checked against the unfilled homopolymer melt; for thin-wall packaging below 1.0 mm, shot-to-shot repeatability is best when the gate diameter is at least 0.8 mm and land length is 1.0 mm or less, although published data for this specific tool configuration is limited.

    Industrial re-grind of H100EY sprues and runners can be reintroduced up to 20 wt% in non-appearance parts if the regrind is dry and free from degraded material. Higher re-grind levels increase black speck formation and reduce notched impact; therefore closed-loop granulation should be equipped with magnetic separation and a screen pack. Published data for this specific configuration is limited.

    Regulatory Compliance Checklist for Food-Contact and Electrical End-Uses

    Regulation / StandardScopeStatus for H100EY
    21 CFR 177.1520(c)Olefin polymers for food contactSupplier should confirm lot-based compliance; specific migration not included
    Regulation (EU) 10/2011EU plastics food-contact migrationFinished article testing required; overall migration limit 10 mg/dm² for generic containers
    EC 1907/2006 REACHRegistration and SVHC declarationCertifiable via supplier SDS; no SVHC above threshold declared for standard PP grade
    2011/65/EU RoHSRestricted heavy metalsCompliance applies to homopolymer matrix; additives must be reviewed for Pb, Hg, Cd, Cr(VI)
    UL 94Flammability classificationPublished data for this specific configuration is limited; flammability class must be tested on final part thickness

    Storage conditions for H100EY should maintain pellet temperature below 50 °C and protect from direct sunlight. Polypropylene homopolymer has low equilibrium moisture uptake, but surface condensation can occur when sacks are moved from cold storage to warm production areas at relative humidity above 60 %. Under these conditions, pellets should be conditioned in the production area until surface condensation evaporates or dried with dehumidified air at 80 °C for 2 h. Do not use hot-air recirculation dryers above 90 °C, because pellet softening and agglomeration can occur. Avoid contamination with polyethylene at levels above 2 wt% if consistent stiffness is required, because phase separation reduces flexural modulus and visual homogeneity. The product should not be blended with PVC or PET scrap; processing temperatures for PVC would cause corrosive HCl evolution, and PET melt incompatibility creates delamination.

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