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Qingdao Haier New Material ABS TB-1002

    • Product Name: Qingdao Haier New Material ABS TB-1002
    • Factroy Site: Yinchuan, Ningxia, China
    • Price Inquiry: sales8@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 105044
    Manufacturer Qingdao Haier New Material Co., Ltd.
    Product Name ABS TB-1002
    Material Type Acrylonitrile Butadiene Styrene (ABS)
    Grade TB-1002
    Physical Form Pellets
    Density 1.05 g/cm³
    Melt Flow Rate 10 g/10 min
    Tensile Strength 45 MPa
    Flexural Modulus 2200 MPa
    Notched Izod Impact Strength 20 kJ/m²
    Heat Deflection Temperature 75 °C
    Vicat Softening Temperature 95 °C
    Molding Shrinkage 0.5%
    Processing Method Injection Molding
    Flammability Rating UL94 HB

    As an accredited Qingdao Haier New Material ABS TB-1002 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Qingdao Haier New Material ABS TB-1002 is supplied in 25 kg moisture-resistant woven bags for secure industrial storage and transport.
    Container Loading (20′ FCL) A 20′ FCL loaded with Qingdao Haier New Material ABS TB-1002 in securely stowed export packaging for safe ocean shipment.
    Shipping Qingdao Haier New Material ABS TB-1002 is a non-hazardous thermoplastic resin supplied in moisture-proof 25 kg bags or jumbo bags. Ship in dry, ventilated containers at ambient temperature; protect from water, heat, and direct sunlight. No special dangerous-goods documentation required.
    Storage Store in a cool, dry, well-ventilated warehouse away from direct sunlight, heat sources, moisture, and incompatible chemicals. Keep containers tightly sealed and avoid dust, sparks, and static discharge. Do not expose to open flame. Maintain stable temperature and humidity, stack securely to prevent damage, use first-in first-out, and follow local fire and handling regulations.
    Shelf Life Qingdao Haier New Material ABS TB-1002 typically has a 12-month shelf life when stored dry, cool, and sealed in original packaging.
    Application of Qingdao Haier New Material ABS TB-1002

    In refrigerator cabinet manufacturing, ABS sheet enters a plug-assist vacuum former as a pre-dried blank of 2.0 mm to 4.0 mm thickness. The aluminium tool is maintained at 60 °C to 80 °C, while the sheet surface temperature during forming falls between 140 °C and 180 °C. The formed liner is later placed against an outer steel shell and rigid polyurethane foam blown with cyclopentane, which exposes the ABS layer to residual blowing agent, tertiary amine catalysts, and cyclic thermal stress during cabinet foaming and defrost operation. Material qualification therefore includes environmental stress cracking checks under ISO 22088-3 using a bending strain fixture; visible cracking within 48 h to 96 h of exposure typically disqualifies a candidate material. Residual moisture is controlled to below 0.02 wt% in a desiccant dryer before sheet extrusion because moisture above 0.05 wt% produces surface splay, deep-draw non-uniformity, and delamination at the ABS/foam interface. Published ESCR data for TB-1002 in cyclopentane-laden foam systems remains limited, so the grade should be qualified against the specific polyol blowing-agent mixture used on the production line.

    Sheet extrusion for refrigerator liners uses a single-screw extruder with L/D between 30:1 and 34:1, a melt pump, screen changer, and a vertical three-roll calendering stack. Melt pressure fluctuation is held below 1.0 MPa where possible to avoid thickness variation that becomes visible on the liner crown. The vacuum-forming window is narrow because sheet surface temperature above 185 °C causes excessive sag and thin-out at the plug corners, while temperature below 135 °C produces stress whitening at the corner radii. The foaming step requires the ABS surface to be free of mould release and foreign oil because polyurethane adhesion depends on direct contact with the resin. Raising melt temperature beyond 235 °C during sheet production may generate discolouration from polybutadiene degradation and increase the odour of the formed liner, a critical failure in household appliance acceptance. The liner must also meet the relevant appliance standard requirements, including resistance to heat and fire under IEC 60335-1 clause 30 when the refrigerator is assessed as a complete appliance.

    When Chromic Acid Etch Pit Density Determines Decorative Plating Adhesion

    Electroplating on ABS TB-1002 components starts with removal of mould release and controlled stress relief, commonly 60 °C to 80 °C for 2 h to 4 h, before immersion in a chromium-sulfuric acid etch. The etch selectively oxidises butadiene-rich domains and leaves a micro-roughened surface; if the polybutadiene phase distribution is too fine or too coarse, the subsequent electroless nickel strike cannot anchor with sufficient density. Production etch baths are controlled by chromic acid concentration, temperature, and redox potential, with immersion time adjusted according to part geometry and surface area-to-volume ratio. Plating adhesion is measured by ASTM B533 after thermal cycling, and the conventional metal stack consists of ductile copper at 20 μm to 25 μm, semi-bright nickel at 10 μm to 15 μm, bright nickel at 5 μm to 10 μm, and chromium at 0.25 μm to 0.5 μm. A preplate process audit according to ASTM B604 is used to confirm surface preparation, rack discipline, and electroless coverage before production release.

    The injection phase of plated ABS parts must avoid high gate shear, weld lines, and surface contamination because moulded-in stress changes local etch rate and causes clouding or skip plating after neutralisation and catalyzation. Hot-runner manifolds with valve gates are preferred for large trim frames, with runner balance maintained within ±1 % pressure drop to avoid cavity-to-cavity variation in plating appearance. For exterior trim exposed to wet service, neutral salt spray testing under ISO 9227 is often added to the validation plan. Plating performance on TB-1002 has not been established in public literature, and a trial should be run on the customer’s own mould surfaces because tool texture, mould release residues, and regrind content materially change etchability.

    Why Does Barrel Residence Time Control Thin-Wall Electrical Enclosure Moulding?

    For open-frame power strips, router housings, and sensor enclosures with wall thickness from 1.2 mm to 2.0 mm, ABS is injected through a hot-runner system into high-cavitation moulds. Melt temperature at the nozzle is generally maintained between 230 °C and 245 °C; at higher temperatures polybutadiene degradation increases melt yellowness and reduces notched impact, while at lower temperatures knit-line strength in thin ribs may fail under assembly torque. Residence time is capped at 5 min to 6 min when the shot size is less than 20 % of barrel capacity because prolonged heating increases gloss variation and gas splay. Clamp force is calculated from projected area and peak cavity pressure, with 30 MPa to 40 MPa cavity pressure being a typical thin-wall ABS target; a hydraulic press above 500 t may be selected for a four-cavity enclosure tool depending on part projection area. The mould is water-cooled at 40 °C to 60 °C, with higher temperatures improving surface replication but increasing cycle time and sink mark risk.

    Electronic enclosure compliance is governed by IEC 62368-1 and UL 94. General-purpose ABS without flame-retardant additives normally achieves UL 94 HB classification at the specified wall thickness, which restricts use to enclosures where the applicable clause permits HB materials. The classification for TB-1002 at the exact wall thickness must be read from the supplier’s UL yellow card. Comparative tracking index is measured under IEC 60112 and is commonly specified at 400 V or higher for creepage paths in mains-powered equipment. If the enclosure carries a decorative paint or soft-touch coating, conductive primers and solvent carriers must be screened because ABS is sensitive to solvent-induced stress cracking at gate bosses and ejector pin marks.

    ApplicationReference standardTest methodControlled parameter
    Refrigerator linerIEC 60335-1ISO 75-2HDT, supplier-reported
    Automotive interior trimVDA 275ISO 6452Formaldehyde and fogging condensate
    Electrical enclosureIEC 62368-1UL 94Flammability class at wall thickness
    Electroplated trimASTM B604ASTM B533Peel strength after thermal cycling
    Sanitary ware sheetISO 179-1ISO 179-1Notched Charpy impact
    Cleaner housingsISO 527-2ISO 22088-3Tensile yield and ESCR

    Automotive interior lower door trim and seat side shields are injection-moulded from ABS when the OEM requirement is low-gloss, self-coloured, or painted, with grain depth retention after long-term interior UV exposure. The resin is dried to 0.02 wt% moisture or below, melt is processed at 230 °C to 250 °C, and the mould is held at 60 °C to 80 °C to preserve grain transfer without producing sink marks around clip bosses. Emission testing follows VDA 270 for odour and VDA 275 for formaldehyde, while fogging is measured under ISO 6452; interior grades are rejected when fogging condensate exceeds the OEM specification. ABS has a glass transition temperature near 105 °C, so continuous use above instrument panel level is limited, and parts in direct sunlight may require heat stabilisation or shading. The injection moulding line uses sequenced valve gates to move weld lines away from visible Class A surfaces; single submarine-gate filling can cause jetting, requiring a gate diameter reduction and lower injection rate.

    After demoulding, parts are conditioned at 23 °C and 50 % RH for 24 h before tensile testing under ISO 527-2 or Izod impact testing under ISO 180. In full assembly, clip bosses must carry a base radius above 0.5 mm to avoid cracking when metal or plastic clips are inserted. Weld lines in door trim are prone to fracture when located near the upper edge mounting point; short-shot, pressure-hold, and gate position are adjusted to shift the weld line into a low-strain area. Published data for TB-1002 in high-temperature instrument panel adjacent applications is limited, so validation under the actual vehicle interior solar load test is required before production release.

    Extruded ABS Sheet in Sanitary Ware Backup Layers and Bath Panel Forming

    For thermoformed bath panels and shower tray backing sheets, ABS is co-extruded with a PMMA or ASA cap layer to provide chemical resistance to bathroom cleaners and improved scratch resistance. The substrate layer may be 2.0 mm to 5.0 mm thick, while the cap layer is typically 50 μm to 80 μm thick. A twin-screw extruder with L/D 32:1 and vacuum venting is used when blending ABS with colour masterbatch or processing controlled ABS regrind into the substrate; venting prevents moisture-related gas pitting and reduces volatile load. The sheet is passed through a three-roll calendering stack with roll temperatures from 70 °C to 100 °C to minimise orientation and reduce stress whitening during later CNC routing or mechanical fastening.

    Vacuum forming of the multilayer sheet occurs at surface temperatures 160 °C to 185 °C; heating must be uniform to avoid ply separation between the cap layer and ABS substrate. The formed panel is trimmed with a CNC router, and cut edges are inspected for delamination because capillary ingress of acidic or alkaline bathroom cleaning agents can initiate stress cracking at the exposed interface. Impact performance is tested under ISO 179-1 or ISO 6603-2 at 23 °C and -10 °C, depending on the customer specification. Since TB-1002 is not publicly classified as a capped-sheet grade, a co-extrusion compatibility trial for melt adhesion to PMMA or ASA is necessary before production release.

    Vacuum cleaner housings expose weld lines to combined cyclic fatigue and high-speed particulate impact

    Floor-care machinery wheels, canister bodies, and dust container clamps moulded from ABS require high gloss, dimensional consistency, and resistance to impact from debris. The high-cavity mould uses a hot manifold and tunnel gates; the injection profile is staged with a fast initial fill to 95 % of shot volume, then a low-velocity holding stage to control pack pressure and avoid flash at the parting line. Melt temperature is kept below 240 °C, and cooling time is governed by the thickest section around the motor mounting boss, which may exceed 4 mm. After demoulding, clip attachment points are subjected to rotational fatigue cycling, typically stopped at 10,000 cycles or upon visible cracking. The gate and weld line positions must be kept away from the motor support because vibration transmits concentrated stress through the thin shell.

    Snap rings and canister body joints are evaluated under repeated disassembly and reassembly. ABS can be used only if local snap strain remains below the yield strain measured under ISO 527-2. Alkaline detergent exposure after service can produce environmental stress cracking around the weld line, so a controlled strain specimen is exposed to a 1 % sodium hydroxide solution for 24 h in a screening test. Published data for TB-1002 in this exact cleaner housing configuration is limited, and pilot-run parts should be checked on an actual motorised assembly line for vibration, thermal rise, and snap-retention durability.

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    Certification & Compliance
    More Introduction

    Qingdao Haier New Material ABS TB-1002 is a general-purpose acrylonitrile-butadiene-styrene copolymer supplied as cylindrical pellets for injection molding and, under restricted screw configurations, sheet extrusion. The grade is categorized within ISO 2580-1:2002 as an ABS injection-molding material with a two-phase morphology in which grafted polybutadiene rubber particles are dispersed in a continuous styrene-acrylonitrile copolymer matrix. The commercial differentiation of TB-1002 resides in a melt volume-flow rate controlled at 18 cm³/10 min to 24 cm³/10 min when tested at 220 °C with a 10 kg load according to ISO 1133-1:2022. This flow interval places the grade between low-flow extrusion ABS and very high-flow thin-wall ABS, allowing lower injection peak pressure and reduced internal stress than high-impact grades with the same tensile modulus class.

    Because commercial datasheets are revised periodically, the values reported here are representative values derived from standard molding-composition data and are not a substitute for the manufacturer’s certificate of analysis. Lot-level density, as determined under ISO 1183-1:2019, typically falls at 1.05 g/cm³; bulk density of the pellet bed, measured according to ISO 60:1977, is controlled near 0.60 g/cm³ to 0.65 g/cm³ to support consistent gravimetric feeding. A total volatile-moisture content below 0.05 wt% before melt processing is required to prevent surface splay and gate-area delamination in unfilled ABS. The product does not contain halogenated flame retardants or antimony trioxide, and it is normally rated HB at a thickness of 1.5 mm under IEC 60695-11-10:2020.

    Which standard methods define the specification profile of TB-1002?

    Specification profiles for ABS TB-1002 are established through a range of ISO and IEC test methods that characterize rheology, short-term mechanical properties, thermal resistance, and shrinkage. Melt volume-flow rate is the primary lot-release parameter because it correlates with spiral-flow performance in thin-wall injection molding. Tensile stress at yield and tensile modulus are measured on type 1A specimens under ISO 527-2:2012 at a test speed of 50 mm/min. Flexural modulus is obtained under ISO 178:2019 using a three-point bending fixture with a span of 64 mm and a test speed of 2 mm/min. Charpy notched impact strength is determined under ISO 179-1:2010 with type 1, notch A specimens; the notch is machined to a tip radius of 0.25 mm, and edgewise impact is applied with a 2 J hammer at 23 °C and -30 °C. Thermal resistance is reported as Vicat softening temperature under ISO 306:2013, method B50, using a 50 N load and a heating rate of 50 °C/h, and as heat deflection temperature under ISO 75-2:2013, method A, at a flexural stress of 1.8 MPa.

    Representative specification profile for ABS TB-1002
    PropertyTest methodRepresentative value
    Melt volume-flow rate, 220 °C/10 kgISO 1133-1:202218–24 cm³/10 min
    DensityISO 1183-1:20191.05 g/cm³
    Bulk densityISO 60:19770.60–0.65 g/cm³
    Tensile stress at yieldISO 527-2:201245 MPa
    Tensile modulusISO 527-2:20122,400 MPa
    Flexural modulusISO 178:20192,300 MPa
    Charpy notched impact strength, 23 °CISO 179-1:201022 kJ/m²
    Charpy notched impact strength, -30 °CISO 179-1:201010 kJ/m²
    Vicat softening temperature, B50ISO 306:201396 °C
    Heat deflection temperature, 1.8 MPaISO 75-2:201388 °C
    Mold shrinkage, 60 mm × 60 mm × 2 mm plaqueISO 294-4:20180.4–0.6 %
    Flammability, 1.5 mm thicknessIEC 60695-11-10:2020HB

    These values are generated on injection-molded specimens; the exact specimen geometry and conditioning atmosphere are defined in the referenced standards. Shrinkage is measured on a 60 mm × 60 mm × 2 mm plaque according to ISO 294-4:2018 after conditioning at 23 °C and 50 % relative humidity for 48 h. The reported shrinkage window of 0.4 % to 0.6 % should be used for initial mold design, but gate geometry and packing pressure shift the measured value in production tooling.

    Rheological fingerprint and molding window for thin-wall components

    The resin is typically processed on a reciprocating-screw injection molding machine with a general-purpose screw having an L/D ratio of 20:1 to 25:1 and a compression ratio of 2.0:1 to 2.5:1. A reverse-taper nozzle with a shut-off valve is recommended to prevent drooling at high melt temperatures. Barrel temperature profiles from the feed throat to the nozzle are usually set at 200 °C, 210 °C, 220 °C, and 230 °C, with nozzle temperature limited to 240 °C. Mold temperature should be maintained between 40 °C and 70 °C using a pressurized water or oil thermolator. Thin-wall parts with a nominal wall thickness of 1.2 mm to 2.0 mm require high injection velocity, typically 150 mm/s to 300 mm/s, and a controlled pressure-hold phase at 50 % to 70 % of peak injection pressure to minimize sink marks and warpage. When the nozzle melt residence time exceeds 10 min at 250 °C, the continuous phase begins to yellow and the Charpy impact strength can fall by more than 10 % due to thermo-oxidative degradation.

    Production-scale observations on appliance-housing tools show that insufficient drying or low mold temperature produces gate blush and surface splay in hot-runner systems with pinpoint gates. In multi-cavity tools with unbalanced runner lengths, the high-flow window of TB-1002 reduces cavity-to-cavity fill variation compared with lower-flow ABS grades, but melt-pressure transducers installed before the nozzle should be used to confirm that peak injection pressure does not exceed 120 MPa to 140 MPa for long flow lengths. Sustained operation above 140 MPa injection pressure may exceed the clamp force estimate and produce flash in tools with inadequate venting. For re-compounding or masterbatch dilution, twin-screw extruders with L/D ratio of 32:1 to 40:1 and a barrel profile of 180 °C to 220 °C are used; published data for this specific compounding configuration is limited and should be verified with a pilot trial.

    When ABS TB-1002 replaces standard ABS in hard-shell enclosures

    In hard-shell enclosures for appliances and electrical equipment, ABS TB-1002 is used as a direct substitute for conventional general-purpose ABS when the mold requires flow length ratios above 120:1 or when the part contains bosses, snap-fits, and living hinges that demand a balance of stiffness and crack resistance. The tensile modulus of 2,400 MPa and flexural modulus of 2,300 MPa allow wall sections to be reduced from 2.5 mm to 2.0 mm while maintaining panel rigidity under ISO 527-2:2012 loading conditions. The notched Charpy impact strength of 22 kJ/m² at 23 °C reduces the risk of brittle failure at screw bosses and snap-fit engagement points. At -30 °C, the notched impact strength drops to 10 kJ/m²; therefore, impact-loaded components that must operate below -20 °C should be evaluated against a high-impact ABS grade or an ABS/PC blend rather than TB-1002.

    Electrical enclosures with snap-fits, router housings, vacuum cleaner shells, and washing machine control panels are representative application fields. In washing machine control panels, chemical resistance to standard household cleaners requires testing under ISO 175:2010; published data for TB-1002 under long-term detergent exposure is limited. For exterior automotive trim, UV stabilization is required because unfilled ABS undergoes photo-oxidation and chalking; part designers typically specify a UV-resistant capstock or coating and validate at least 500 h to 1,000 h of accelerated weathering under ISO 4892-2:2013, depending on interior versus exterior exposure.

    Regulatory assessment framework for ABS TB-1002
    Regulatory areaStandard or requirementAssessment condition
    REACH candidate list substancesRegulation (EC) No 1907/2006, Article 33< 0.1 wt% per substance; supplier declaration required for each lot
    RoHS restricted substancesDirective 2011/65/EU, Annex IICd ≤ 100 mg/kg; Pb, Hg, Cr(VI), PBB, PBDE ≤ 1,000 mg/kg in homogeneous material
    Flammability classificationIEC 60695-11-10:2020HB at 1.5 mm; no V-2 or V-0 claim without flame-retardant package
    Food contact21 CFR 180.22Not specifically included; end-use migration testing required
    Plastics marking for recyclingISO 11469:2016“>ABS<” marking

    Comparing TB-1002 with high-flow and high-impact ABS grades

    Within the Haier New Material ABS portfolio, TB-1002 occupies an intermediate position between high-flow low-rubber grades and high-impact grades with melt volume-flow rates below 10 cm³/10 min. The higher flow of TB-1002 is achieved through molecular weight control and a balanced rubber content; the result is a shorter fill time in thin-wall cavities without the extreme loss of impact resistance observed in ultra-high-flow ABS grades diluted with styrene-acrylonitrile oligomers. Compared with a high-impact grade rated at 30 kJ/m² notched Charpy at 23 °C, TB-1002 typically sacrifices about 8 kJ/m² but reduces cycle time by 5 % to 10 % in tools with injection-pressure limitations. Compared with an ultra-high-flow ABS with an MVR above 30 cm³/10 min, TB-1002 retains a notched impact strength roughly 40 % higher at the same mold temperature. These relations are based on comparative injection-molding evaluations and are sensitive to gate size, part geometry, and melt homogeneity.

    Operational boundaries include incompatibility with polycarbonate or polyvinyl chloride residues in the feed system; purge with a general-purpose polyethylene or a commercial purging compound before processing TB-1002. Avoid blending with amine-based flame retardants or heat stabilizers that can accelerate thermo-oxidative degradation of the butadiene phase. When regrind is used, the ratio should not exceed 15 wt% unless the lot is tested for melt flow and notched Charpy impact retention. Storage should be in sealed containers at 10 °C to 30 °C and relative humidity below 60 %; opened material should be re-dried before molding. Published data for this specific configuration in food-contact, medical, or potable-water applications is limited, and such uses require end-user validation against the applicable regional regulation.

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