| HS Code | 478935 |
| Melt Mass Flow Rate 230 C 2 16 Kg | 35 g/10 min |
| Density 23 C | 0.91 g/cm³ |
| Tensile Stress At Yield | 35 MPa |
| Tensile Strain At Yield | 12% |
| Flexural Modulus | 1700 MPa |
| Notched Izod Impact 23 C | 30 J/m |
| Heat Deflection Temperature 0 45 Mpa | 120 °C |
| Heat Deflection Temperature 1 82 Mpa | 70 °C |
| Vicat Softening Temperature | 150 °C |
| Melting Temperature | 165 °C |
| Rockwell Hardness | R105 |
| Melt Volume Flow Rate 230 C 2 16 Kg | 47 cm³/10 min |
As an accredited Profax PP Homopolymer PL835N factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Profax PP Homopolymer PL835N is supplied as pellets in 25 kg bags, packaged in multi-ply paper sacks for safe handling. |
| Container Loading (20′ FCL) | 20′ FCL container loading of Profax PP Homopolymer PL835N in palletized woven bags, ensuring safe, dry transport with proper segregation. |
| Shipping | Profax PP Homopolymer PL835N is a polypropylene resin supplied as solid pellets. It is non-hazardous under normal transport conditions and ships by truck, rail, or ocean container. Pack in sealed bags, supersacks, or bulk hoppers. Keep dry, away from excessive heat and ignition sources; handle with standard PPE. No special UN classification required. |
| Storage | Store Profax PP Homopolymer PL835N in a cool, dry, well-ventilated area, away from direct sunlight, heat, and ignition sources. Keep in original, sealed packaging to prevent moisture contamination. Avoid contact with strong oxidizers. Handle carefully to prevent bag damage. Under proper conditions, shelf life is stable for several years. |
| Shelf Life | Shelf life is typically 2 years from shipment if stored in original, unopened packaging under cool, dry conditions. |
With a manufacturer-published nominal melt flow rate of 35 g/10 min at 230 °C/2.16 kg under ASTM D1238-23, Profax PP Homopolymer PL835N is specified for thin-wall food packaging in which flow length-to-wall ratios exceed 200:1 and freezing during cavity fill is the dominant rejection mode. In a 32-cavity stack mold producing round delicatessen containers with a nominal sidewall of 0.45 mm, the mold is typically run with melt temperature between 210 °C and 250 °C and mold coolant at 20 °C to 35 °C; the lower coolant limit is set by condensation risk on the core when the production hall dew point is above 18 °C, and the upper limit is set by lip deformation during ejection. The homopolymer has no comonomer phase, so the crystallization rate is higher than impact copolymer grades and the hold-pressure window shortens: if switchover from velocity control to pressure control occurs too late, runner collapse or gate blush appears at the gate land, and if too early, sink marks develop on the rim. Packing pressure is commonly set at 60 % to 75 % of injection peak pressure, with a cushion held at 3 mm to 5 mm and decompression at 3 mm to 5 mm to prevent nozzle drool on a hot-runner bushing. On processing lines, shot-to-shot variation of cushion below 2 mm indicates check-ring wear and produces inconsistent filling of the stack mold’s far cavities. Food-contact compliance is not automatic: the converter must evaluate the finished article under FDA 21 CFR 177.1520 for olefin polymers and under Commission Regulation EU 10/2011, with overall migration testing at the intended condition of exposure; migration limits are applied to the entire formulation, including masterbatch and processing aids. Terminal articles include cold-fill delicatessen cups, dairy tubs, snap lids, and takeaway containers; hot-fill above 95 °C is outside the reliable shape-retention range of unfilled homopolymer thin walls and requires a different polymer or wall redesign.
The flash threshold in 96-cavity closure tooling shifts when PL835N is run at melt temperatures of 215 °C to 245 °C on hybrid machines with clamp force from 350 t to 500 t. The high MFR reduces fill pressure, but it also narrows the boundary between complete tamper-evident band filling and parting-line flash; in production, visible flash appears first on the band bridge where vent depth exceeds 0.02 mm and local pressure at the cavity end remains above 20 MPa. Reducing injection velocity to avoid flash can generate short shots in the far cavity or cold slugs at the nozzle if decompression is excessive; more stable practice is to audit platen parallelism and clean vent channels at intervals shorter than 20,000 cycles. The closure seal land wall below 0.6 mm requires hold pressure to pack the top sealing surface without overpacking the bridge; typical hold time is 1.0 s to 2.5 s for a 28 mm bore, but cavity-to-cavity variation above 0.05 mm in seal diameter is a tooling repeatability problem rather than a resin viscosity problem. Post-mold dimensional reversion occurs within 24 h to 48 h at ambient; closure ovality measured earlier can pass but may fail later, so dimensional release should be based on aged samples. For food-contact closures, compliance follows FDA 21 CFR 177.1520 and EU 10/2011; low-taste and odor requirements are evaluated under customer-specific organoleptic test protocols because published data for PL835N closures in aggressive fatty media are limited. Terminal products include linerless water closures, sports-drink caps, and dairy closure shells; carbonated beverage applications require continuous leakage testing because the homopolymer bottle cap body is not a gas barrier and seal performance is heavily design-dependent.
Molding of PL835N into diagnostic pipette tips and microcentrifuge tubes is carried out at melt temperatures not exceeding 250 °C and with barrel residence time held below 10 min; prolonged thermal exposure shifts molecular weight distribution, which can be detected as a melt-flow increase under ASTM D1238-23 before it becomes visible as splay or yellowing. Cavity filling in a 0.3 mm tip orifice is dominated by flow-front acceleration in the shear field, and valve gates are preferred over open hot tips to prevent drool that could bridge tips in a high-cavitation mold. Mold temperature is kept between 20 °C and 30 °C; lower mold temperature may increase residual stress, which later contributes to cracking after packaging, while higher mold temperature increases cycle time without proportionally improving clarity. Cleanroom molding under ISO 14644-1 Class 7 requires that pellet handling and hopper loading be segregated from external regrind streams; the use of post-consumer recyclate is not appropriate for this segment. The resin does not itself confer medical-grade status; a finished pipette tip or tube must be evaluated under ISO 10993-5:2009 for cytotoxicity and ISO 10993-10:2010 for sensitization, with extractables/leachables profiling under ISO 10993-18:2020. Gamma irradiation at 25 kGy to 50 kGy is a known operational boundary for PP homopolymer because chain scission generates discoloration and loss of impact strength; if irradiation is specified, the device pack should be vacuum- or nitrogen-flushed to reduce oxidative embrittlement, and post-irradiation aging should be bracketed using ASTM F1980-21. Lot release after sterilization should include notched Izod impact under ASTM D256 and melt flow rate under ASTM D1238-23 to detect unacceptable molecular weight loss before shipment. Terminal articles include pipette tips, sample tubes, microcentrifuge tubes, and diagnostic reagent reservoirs; blood-contact or long-term implant use is not supported by this homopolymer grade.
| Regulatory/Technical Boundary | Standard or Method | Measured Parameter | Conformance Requirement |
|---|---|---|---|
| U.S. food contact | FDA 21 CFR 177.1520 | Olefin polymer extraction endpoints | Article-specific, based on conditions of use |
| EU food contact | EU 10/2011 | Overall migration | 10 mg/dm² |
| Cytotoxicity | ISO 10993-5:2009 | Cell viability | Pass on finished device |
| Sensitization | ISO 10993-10:2010 | Skin reaction | Pass on finished device |
| Sterile aging | ASTM F1980-21 | Accelerated aging interval | Sterility shelf life claim |
| Electrical ignition | UL 746A | HAI, CTI, D495 arc resistance | UL Product iQ card, color/thickness dependent |
Housewares and storage articles molded from PL835N typically use wall stock between 0.8 mm and 1.5 mm with rib-to-wall ratios near 0.6:1 to 0.8:1; heavier rib sections create sink marks on the opposite face because homopolymer PP shrinks more sharply than filled grades. Boxes and organizer bodies are molded at melt temperatures of 220 °C to 240 °C with mold temperature between 20 °C and 30 °C; when the mold is too cold, surface gloss decreases and internal stress increases, but when it is too warm, cycle time rises and rib crowns may hang onto the mold. The dominant field failure is not impact cracking at room temperature but creep under sustained top load at attic or container temperatures; a stack-load test at 50 °C for 48 h with the load set at rated gross container mass plus 25 % overload may produce deformation that prevents nested stacking and lid engagement. Increasing the top rim thickness and moving the latch undercut away from the flow front is more effective than increasing mold temperature; published data for long-term creep of PL835N in large storage crates is limited, so load-bearing designs should be prototyped and tested under ISO 899-1:2017 tensile creep or customer-specific stack tests. Low-temperature drop resistance is the second boundary: at 0 °C the unfilled homopolymer loses ductility, so corner radii should exceed 2 mm and drop tests should be run on filled boxes at 0 °C after 24 h conditioning. Terminal products include under-bed storage boxes, drawer organizers, file crates, and folded shelving bins, but not outdoor furniture or deep-freeze containers without impact modification.
Compounding operations employ PL835N as a pelletized carrier for calcium carbonate, talc, and color concentrates because its melt flow rate of 35 g/10 min under ASTM D1238-23 enables wetting of filler at high loading without requiring an external plasticiser. In a co-rotating twin-screw extruder with 40:1 L/D and 70 mm screw diameter, a typical 75 wt% calcium carbonate masterbatch is run at a barrel profile from 190 °C in the feed zone to 220 °C at the die, with screw speed between 400 rpm and 600 rpm; the filler is introduced through a side feeder at zone 6 after the polymer is fully molten, and vacuum venting at -0.08 MPa removes volatile residuals. Strand cooling must avoid contact with hard water, which can leave mineral deposits that induce downstream die lip build-up; underwater pelletization with water temperature below 20 °C can chill the pellet surface too quickly and produce surface cavitation, while water above 45 °C may cause pellet agglomeration. The masterbatch is then let down into injection-grade PP at 2 wt% to 8 wt%, and the final compound MFR should be verified by ASTM D1238-23 because filler particle size distribution and moisture content can produce lot-to-lot variation. Batch records should include screw torque, die pressure, pellet bulk density, and colorimeter readings; published data for PL835N with submicron fillers is limited, so any formulation above 80 wt% filler must be confirmed on the production line rather than from laboratory mixing. Terminal articles are mineral-filled masterbatch for injection molded appliance parts, structural packaging, and consumer crates; the carrier is not intended for direct food-contact use unless the finished article is compliance tested.
In internal appliance connector housings, terminal covers, and fan shrouds, PL835N is used where thin-wall flow and dimensional repeatability are required, but the rating boundaries are controlled by colorant, wall thickness, and service temperature rather than by the base resin alone. The molder must consult the UL Product iQ card for PL835N at the exact color and minimum wall thickness; relative thermal index, hot-wire ignition, high-current arc ignition, and comparative tracking index are thickness-dependent, and a thin section below 1.5 mm may shift the thermal index because oxidative degradation increases with surface-to-volume ratio. Molding at melt temperatures above 250 °C or with regrind content above 20 % can decrease dielectric strength and produce black specks; a vented barrel is not a substitute for proper drying when high humidity exceeds 60 % RH, because surface moisture can create splay. The process window is narrow for connectors with 0.8 mm walls: melt temperature 220 °C to 235 °C, mold temperature 25 °C to 35 °C, injection time below 0.4 s, and hold pressure adjusted to eliminate sink at the screw bosses. Electrical tracking and ignition tests are run under IEC 60112:2020 for comparative tracking index and IEC 60695-2-11:2014 for glow-wire flammability; only the final part can be certified, and published data for PL835N in thin-wall electrical housings are limited. Terminal products include office appliance internal brackets, plug adapter bodies, terminal covers, and low-voltage fan housings; open-flame contact or continuous hot-surface temperatures above the UL-verified RTI are outside the grade’s reliable service boundary.
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Profax PP Homopolymer PL835N is a high-flow, nucleated polypropylene homopolymer supplied as pellets for injection moulding and thin-wall packaging applications. The grade is specified by a nominal melt mass-flow rate of 35 g/10 min when measured in accordance with ISO 1133-1:2022 at 230 °C and 2.16 kg. The homopolymer backbone yields higher stiffness and heat deflection temperature than random copolymer grades at equivalent melt flow, while the nucleating system accelerates crystallisation and produces a finer, more uniform spherulitic morphology than non-nucleated homopolymers.
Because high melt flow is commonly achieved by controlled rheology, the molecular weight distribution of PL835N is typically narrower than a reactor-grade homopolymer with the same nominal melt flow. A narrow distribution reduces die swell and improves dimensional repeatability in injection moulding but also reduces melt strength. This trade-off is intentional for thin-wall filling. The grade is not intended for extrusion blow moulding or thick sheet where sag resistance is required.
| Property | Test method | Nominal value |
|---|---|---|
| Melt mass-flow rate | ISO 1133-1:2022 (230 °C, 2.16 kg) | 35 g/10 min |
| Density | ISO 1183-1:2019 | 0.90 g/cm³ |
| Tensile stress at yield | ISO 527-2:2012 | 35 MPa |
| Flexural modulus | ISO 178:2019 | 1500 MPa |
| Notched Izod impact at 23 °C | ISO 180:2019 | 2.0 kJ/m² |
| Heat deflection temperature at 0.45 MPa | ISO 75-2:2013 | 100 °C |
| Melting temperature by DSC | ISO 11357-3:2018 | 165 °C |
The values in the accompanying table are representative of unfilled high-flow nucleated PP homopolymers and are provided for initial tooling calculations. The PL835N certificate of analysis is the controlling document for lot-specific specifications; variations in additive package, pellet geometry, and stabiliser loading can shift these values by several percent.
The nucleating package in PL835N creates a high density of crystallisation sites during cooling. Under differential scanning calorimetry performed to ISO 11357-3:2018, a nucleated grade of this class typically shows a crystallisation peak temperature 10–15 K higher than a non-nucleated homopolymer of equivalent melt flow. This shift allows the frozen skin to form earlier in the mould, which shortens the required holding time and can reduce total cycle time by 5–12% in high-cavitation packaging tools. However, early skin formation also reduces the effective flow channel during filling; in thin-wall parts of 0.4–0.8 mm nominal wall thickness, injection speed must be sufficient to fill before the advancing flow front freezes. Mould shrinkage for the class is typically 1.0–1.5% with less difference between flow and cross-flow directions than in non-nucleated homopolymers.
On a 250-tonne hydraulic injection moulding machine running a 24-cavity thin-wall container tool, the high flow of PL835N permits filling at lower injection pressure than a 12 g/10 min homopolymer. The hydraulic pressure drop through a cold runner is lower, but the same low viscosity can cause flash on tools with clamp force margins below 20%. A fill-to-pack switchover should occur before the flow front velocity decays below 200 mm/s; delayed transfer can produce sink marks at gate-adjacent regions because the nucleated melt has already begun to solidify. Published data for PL835N-specific cavity pressure traces is limited; processors should confirm the switchover point with short-shot studies and cavity pressure sensors.
The melt exhibits non-Newtonian shear thinning. Capillary rheometry performed to ISO 11443:2021 shows apparent viscosity decreasing as apparent shear rate increases from 100 s⁻¹ to 10,000 s⁻¹. Mould-filling simulation should use Cross-WLF parameters fitted from capillary data at 220 °C, 240 °C, and 260 °C. Because the grade is nucleated, crystallisation data from ISO 11357-3:2018 should be included in the simulation to predict gate freeze. In hot-runner systems, residence time above 260 °C should be limited to avoid molecular weight reduction. Shut-off nozzles and thermal gating are preferred when the resin is used in high-speed packaging tools.
Substitution of an impact copolymer with PL835N raises stiffness and heat resistance but reduces impact toughness. Notched Izod impact at 23 °C for the homopolymer class is approximately 2.0 kJ/m² measured to ISO 180:2019, whereas many impact copolymer polypropylenes fall between 8 kJ/m² and 15 kJ/m² at the same temperature. At low temperatures the difference becomes larger; a homopolymer is not suitable for applications with frozen impact or drop-load requirements without instrumented puncture testing to ISO 6603-2. The higher flexural modulus, near 1500 MPa in ISO 178:2019, can allow down-gauging in rigid containers only if impact loads are limited. Gate design should avoid sharp notches because nucleation increases local brittleness at weld lines.
| Parameter | PL835N high-flow nucleated homopolymer | Random copolymer | Impact copolymer |
|---|---|---|---|
| Flexural modulus | High, ≈1500 MPa | Moderate | Lower |
| Notched Izod at 23 °C | Low, ≈2.0 kJ/m² | Moderate | High, 8–15 kJ/m² |
| Clarity | Translucent | Transparent-to-clear | Opaque |
| Heat deflection temperature | Higher | Moderate | Lower |
| Shrinkage isotropy | More uniform due to nucleation | Isotropic due to comonomer | Less uniform with rubber phase |
| Low-temperature impact | Low | Moderate | High |
Random copolymers are preferred when contact clarity and softness are required; PL835N is translucent and stiffer. The haze of PL835N is higher than a random copolymer, and gloss may be lower if mould temperature is low. In caps and closures, the homopolymer provides good dimensional stability and low creep under sustained top-load; in clear storage containers, the random copolymer provides the required see-through appearance. This distinction is a principal reason PL835N appears in rigid packaging rather than transparent thin-wall containers.
Food-contact and medical-facing evaluations require grade-specific documentation. Polypropylene homopolymers of this type are typically assessed under FDA 21 CFR 177.1520(c) 1.1 for olefin polymers and Commission Regulation (EU) No 10/2011 as amended, with overall migration limits determined under simulant conditions selected by food type. The processor must request a product stewardship bulletin for PL835N before converting the resin for food packaging; the presence of a nucleating package and any release additives may affect compliance. REACH Regulation (EC) No 1907/2006 and the RoHS Directive 2011/65/EU are generally addressed in the safety data sheet for the supplied pellets. No statement of compliance for a finished article should be inferred from resin-level documentation alone.
Pre-drying is not normally required for PL835N when pellets are stored in sealed, undamaged packaging at ambient conditions below 60% relative humidity. If sacks or silos are exposed to condensation, surface moisture can be removed by a desiccant dryer at 80 °C for 2–4 h with a dew point below -20 °C. The melt temperature must not exceed 260 °C because oxidative chain scission increases melt flow erratically and may generate odour. Avoid combining the resin with copper-based pigments or incompatible peroxide masterbatches unless the formulation has been stabilised for high-temperature processing. When drying is omitted at high humidity, surface bubbles or streaks can appear in thin-wall parts because moisture volatilises in the hot runner.
The melt should not be held above 260 °C in hot-runner manifolds for extended periods. Polypropylene undergoes thermo-oxidative chain scission at high temperature, which increases melt flow and lowers melt strength; in severe cases, the resin can develop yellowing, acetaldehyde-like odour, or surface splay. Residence time at 250 °C should be limited to the shortest interval consistent with colour change and cavity filling. Capillary rheometry according to ISO 11443:2021 can be used to detect viscosity loss after repeated heating cycles. When hot-runner nozzle tips run hotter than the melt by more than 20 °C, local degradation may occur even if the barrel temperature is within the nominal range.
Venting is critical for high-flow nucleated PP. In thin-wall packaging tools, inadequate vents can produce burn marks at flow-front meeting points. Vent depth below 0.02 mm is typical for PP to prevent flash while allowing air escape. In multicavity tools, cavity-to-cavity melt temperature differences of more than 5 °C can generate inconsistent shrinkage and dimensional variation. The tool should be designed with conformal cooling when cycle times fall below 8 s.
PL835N possesses an isotactic homopolymer backbone. The regular stereochemical sequence permits high crystallinity and results in flexural modulus values near 1500 MPa, measured according to ISO 178:2019. Impact copolymers, by contrast, sacrifice stiffness to gain low-temperature impact through an ethylene-propylene rubber phase. The selection decision should be driven by the loading mode. For a rigid container that is primarily loaded in compression or bending, the homopolymer allows wall thickness reduction; for a component that may be dropped at 0 °C or below, the homopolymer may fail by brittle fracture unless part geometry and impact testing demonstrate sufficient margin. Weld lines in PL835N are a particular concern because the high orientation and fast crystallisation reduce molecular entanglement across weld interfaces.
Back pressure of 0.5–1.5 MPa and screw speeds in the range of 80–150 rpm are typical for the class; excessive shear can raise melt temperature above setpoint and accelerate degradation. Decompression after screw recovery should be limited to 3–5 mm to avoid air entrapment. For hot-runner systems, sequential valve gating is preferable to open nozzles to prevent drool from the low-viscosity melt. Gate location should be selected to avoid long flow paths since the fast crystallisation of the nucleated grade makes the flow front freeze sooner than in non-nucleated resin. For parts with flow-length-to-wall-thickness ratios above 150:1, multiple gates or hot-runner valve gates are typically required.
Typical applications for PL835N include thin-wall rigid food packaging, caps and closures, housewares, and appliance components where high flow and stiffness are required. The resin is not intended for clear containers, film, fibre, or extrusion blow moulding. In caps and closures, the material provides sufficient top-load rigidity and dimensional stability; however, tamper-evident band hinge performance must be evaluated because the nucleated homopolymer may exhibit lower hinge flex life than an impact copolymer.
Incoming inspection of PL835N often focuses on melt flow stability and additive dispersion. A rapid melt-mass-flow rate check using ISO 1133-1:2022 at 230 °C and 2.16 kg can detect lot-to-lot drift before the material enters silos. Ash content determined by ISO 3451-1:2019 may be used to verify stabiliser and nucleator loading. When the resin is transferred from rail cars or bulk trucks to silos, pellet fracture and angel hair can affect feed consistency; the use of dense-phase conveying with low air speed reduces fines. Injection moulding trials for thin-wall closures should evaluate dimensional stability after 24 h because post-mould crystallisation in nucleated homopolymers reaches a stable plateau earlier than in non-nucleated grades.