| HS Code | 260938 |
| Polymertype | Metallocene Linear Low Density Polyethylene |
| Catalyst | Metallocene |
| Comonomer | Hexene-1 |
| Density | 0.918 g/cm³ |
| Meltflowrate | 1.0 g/10 min (190°C, 2.16 kg) |
| Meltingpoint | 119 °C |
| Vicatsofteningpoint | 95 °C |
| Tensilestrengthatyield | 10 MPa |
| Tensilestrengthatbreak | 30 MPa |
| Elongationatbreak | ≥500% |
| Dartimpactstrength | ≥800 g |
| Elmendorftearstrength | ≥100 N/mm |
| Haze | ≤10% |
| Gloss | ≥70% |
| Molecularweightdistribution | Narrow |
| Additives | Antioxidant |
As an accredited PetroChina Dushanzi KunLun mLLDPE HPR1018HA factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | PetroChina Dushanzi KunLun mLLDPE HPR1018HA is supplied in 25 kg moisture-resistant woven bags, typically palletized for transport and storage. |
| Container Loading (20′ FCL) | 20′ FCL loaded with 25 kg bags of PetroChina Dushanzi KunLun mLLDPE HPR1018HA, palletized, shrink-wrapped, and securely stowed for export. |
| Shipping | PetroChina Dushanzi KunLun mLLDPE HPR1018HA is supplied as free-flowing plastic pellets in 25 kg PP bags or 500–1000 kg jumbo bags. It is a non-hazardous polymer shipped by standard truck/container in dry conditions, protected from moisture, direct sunlight, and excessive heat. |
| Storage | Store PetroChina Dushanzi KunLun mLLDPE HPR1018HA in a cool, dry, well-ventilated warehouse, away from direct sunlight, heat, moisture, and strong oxidizers. Keep original bags sealed and undamaged; stack on pallets off the floor. Avoid open flames and prolonged high temperatures. Follow the supplier SDS, local regulations, and first-in, first-out stock rotation. |
| Shelf Life | Typical shelf life is 24 months from production date when stored unopened in a dry, cool place away from direct sunlight. |
Coextruded blown film production for frozen food and form-fill-seal packaging positions HPR1018HA at 20–40 wt% of the sealant skin layer, the balance being an LDPE of 0.918–0.925 g/cm³ density or an EVA with 12–18% vinyl acetate. In this layer the metallocene short-chain branching distribution lowers seal initiation temperature compared with a Ziegler-Natta LLDPE at equivalent density, which is measured on the packaging line by heat-seal strength testing according to ASTM F2029. Published data specific to HPR1018HA under ASTM F2029 is limited; converter validation under actual sealing dwell and substrate structure is required. Direct food contact compliance in the United States is established under FDA 21 CFR 177.1520(c); European Union shipments require Regulation (EU) No 10/2011 Annex I with overall migration not exceeding 10 mg/dm² under the intended food simulant. For PRC domestic food packaging, GB 4806.7-2023 migration and sensory requirements apply, and the converter must validate the laminated structure under end-use time-temperature conditions. Production is typically a 3-layer blown film die of 250–400 mm diameter, die gap 1.6–2.2 mm, blow-up ratio 2.0–2.8, and frost-line height 600–900 mm. The extruder screw is a barrier design with an L/D of 30:1 and a Maddock mixing section; barrel temperatures range from 170 °C at the feed to 210–230 °C at the adapter, and the die is held at 220–230 °C. Terminal product types include stand-up pouches, quad-seal bags, and vertical form-fill-seal pillow packs for frozen vegetables, seafood, poultry, and ready-to-cook sauced meals.
Batch-to-batch viscosity drift of HPR1018HA at 190 °C and 2.16 kg is monitored by ISO 1133-1:2022 on an extrusion plastometer, with a permissible lot-to-lot drift of ±0.10 g/10 min from the certified value. Silo storage above 60% RH raises equilibrium moisture and can produce surface splay during extrusion; converters starting after weekend shutdown set desiccant-bed dryers to −30 °C dew point and hold the resin at 70–80 °C for 2–4 h. Melt fracture in the skin layer becomes observable when die gap is below 1.4 mm, while heat-seal transfer on the form-fill-seal machine loses repeatability when the sealing jaw temperature deviates by more than ±5 °C from the validated set point.
In blown film production for FIBC liners and heavy-duty shipping sacks, HPR1018HA is incorporated at 60–80 wt% of the core layer, with a Ziegler-Natta LLDPE at 20–40 wt% to maintain bubble stability. The controlling variables are low-speed dart impact and Elmendorf tear orientation balance rather than tensile yield alone. Dart impact is tested per ASTM D1709 Method A and tear per ASTM D1922; converter specifications commonly fall in the range of 600–900 g and 8–12 N/mm for 100 µm film, but these values are end-use-specific and are verified on each campaign. Compliance for FIBC outer packaging references ISO 21898:2019; liner films for food ingredients additionally require FDA 21 CFR 177.1520 and EU 1935/2004, while static dissipative liners must meet IEC 61340-5-1 surface resistance limits when specified. Production uses mono- or 3-layer blown film lines with a die diameter of 350–500 mm, die gap 1.8–2.4 mm, blow-up ratio 1.8–2.6, and internal bubble cooling to maintain frost-line height at 500–800 mm. On a 90 mm barrier screw with L/D 30:1, the narrow molecular weight distribution of HPR1018HA raises specific energy input relative to a broad-Mw LLDPE; a PPA processing aid is dosed at 300–600 ppm to suppress sharkskin and die-lip deposit. Terminal product types include circular woven FIBC liners, baffled container liners, valve sacks for resin pellets and mineral fillers, and heavy-duty shipping sacks for bulk food ingredients.
Regrind streams from washed liners introduce moisture when addition exceeds 15 wt%; blended formulations are pre-dried at 65–80 °C for 2–3 h before extrusion. PPA addition below 300 ppm may not suppress sharkskin on narrow-die-gap lines, while above 600 ppm can interfere with corona treatment and heat-seal adhesion. Corona discharge output is set at 2.0–3.0 kW for a 1,200 mm web width to achieve 38–42 mN/m surface energy before printing or lamination.
Pallet wrapping operations impose puncture, elongation, and load retention requirements that differ from food packaging. HPR1018HA is formulated into the skin layers of a 5-layer cast stretch film at 15–35 wt%, with the balance being cast-grade LLDPE and a cling additive in the outer skin; the core addition is lower, typically 5–15 wt%, to control machine-direction stretch. Industrial evaluation uses ASTM D5748 for stretch wrapper performance and ASTM D5458 for cling; film is normally pre-stretched to 200–300% on the wrapper. Puncture resistance is tested under ASTM D5748, and load retention is evaluated per ASTM D4649, with end-users specifying containment force after 24 h at 25 °C. Compliance for non-food pallet wrap is governed by REACH for EU shipments and by CONEG heavy-metal limits in North America; export to California requires California Proposition 65 screening when cling additives or colourants are present. Production is performed on a 5-layer cast coextrusion line with a die width of 1,800–3,000 mm, chill-roll temperature 18–24 °C, and line speeds of 450–600 m/min. Melt temperature at the die is held at 240–260 °C to manage high shear in the flat die and reduce draw resonance. Terminal products include machine-applied stretch hoods for building materials, transparent pallet wrap for logistics hubs, and agricultural bale clamp films requiring high puncture before clamping.
Linear low-density cast film develops edge bead and draw resonance when the die gap is below 0.8 mm or the draw ratio exceeds 25:1. On 5-layer lines the layer-to-layer viscosity ratio is managed by setting extruder temperature zones from 220 °C at the feed to 260 °C at the die; the outer cling layer receives an EVA-based cling masterbatch at 2–4 wt%. The primary failure mode under stretch is localized necking followed by sudden puncture when the film is stretched above 300% at low temperature.
Agricultural silage wrap produced from HPR1018HA-containing blown film operates under a combination of UV irradiation, silage acids, and mechanical abrasion that excludes formulations optimized only for clean indoor packaging. The resin is blended at 20–35 wt% into a 3-layer structure with a UV-stabilized LLDPE and a white or green masterbatch; total film thickness is typically 25–40 µm. European compliance is specified under EN 13206:2017, including Clause 4 durability and weathering requirements, while the food contact layer of the base polymer must also conform to Regulation (EU) No 10/2011 when fermentation acids contact the film. Production uses blown film lines with a die diameter of 300–450 mm, die gap 1.8–2.2 mm, blow-up ratio 2.0–3.0, and a dual-lip air ring. Melt temperature is normally set at 210–235 °C; temperatures above 245 °C can degrade the hindered amine light stabilizer package and lower the weathering performance of the finished wrap. Terminal products include round bale silage film, bale netting replacement stretch film, and single-season greenhouse cover film where wind-flap puncture is the primary failure mode.
Bale wrap film production is more sensitive to ambient relative humidity than cast film; converters operating in coastal areas pre-dry the UV masterbatch rather than the base resin because hindered amine light stabilizer hydrolysis at 70–80 °C can reduce additive efficiency. Thickness control on a 25 µm film requires a capacitive or beta gauge feedback loop with a tolerance of ±2 µm; beyond that band, bale puncture failures increase. The film is slit to 500 mm and 750 mm rolls for round balers, with a winding tension of 12–18 N per 100 mm width to prevent telescoping.
Within liquid paperboard and aseptic brick packaging lines, HPR1018HA is applied as the sealant web at 15–30 wt% in a blend with LDPE or as the primary polymer in the heat-seal layer. The addition ratio is constrained by the need to maintain neck-in stability at the slot die and adhesion to the aluminium foil or paperboard substrate. The process is a tandem extrusion coating line with a slot die of 1,200–2,800 mm width, an air gap of 150–250 mm, and line speeds of 150–300 m/min. Melt temperature at the die is 280–300 °C for LDPE-based blends; HPR1018HA-rich formulations are processed at 260–280 °C to limit oxidative chain scission and odour formation. FDA compliance for the food-contact surface is under 21 CFR 177.1520; indirect contact with aqueous and acidic liquids requires migration testing under 21 CFR 176.170(c) for paper and paperboard components, and European compliance is under Regulation (EU) No 10/2011 with specific migration limits for residual metals from the PE matrix. Seal performance is validated using heat-seal strength per ASTM F88 and peel failure mode per ASTM D1876, with end-users requiring clean peel or fibre-tear failure on the board. Terminal product types include gable-top cartons, brick packs for UHT milk, portion cups for juice, and paperboard lids with peelable seals.
Adhesion failure at the foil or board interface is monitored by peel testing per ASTM D1876; fibre-tear failure is acceptable, while adhesive delamination at the foil-polymer interface indicates inadequate corona treatment or an air gap below 150 mm. The extruder is equipped with a gear pump to reduce output variation to ±2%; barrel zones are set from 180 °C at the feed to 280 °C at the adapter, and the die is maintained at 280 °C. Oxidative gel contamination in the sealant web is managed by limiting residence time at melt temperature to ≤15 min and purging with LDPE between production campaigns.
Converted into inflatable packaging, the HPR1018HA-containing film is required to maintain internal pressure after inflation, limit creep under sustained load, and resist flex fatigue during distribution. HPR1018HA is used as the sealant layer at 20–35 wt% of a multilayer film, or at 100 wt% in monolayer constructions where converters accept lower modulus. The production process is blown film extrusion with a die diameter of 200–350 mm, die gap 1.4–1.8 mm, blow-up ratio 2.2–3.0, and subsequent conversion on an air cushion machine with inflation pressure between 0.02–0.06 MPa. Because creep resistance is the dominant parameter, the film is evaluated using ASTM D2990 tensile creep at 23 °C and 50% RH, and the finished package is qualified under ASTM D4169 distribution cycle 1 or 2, often with ISTA 3A for e-commerce parcels. Compliance for non-food protective packaging includes REACH and RoHS Directive 2011/65/EU for electrical goods packaging in direct product contact; CONEG heavy-metal limits are applied in North America. Terminal product types include inflatable void-fill pillows, air tube cushioning for glass bottles and cosmetic containers, and pre-inflated bubble mailers with a puncture-resistant outer layer.
Air cushion converters frequently run the film through a nip at 0.2–0.4 MPa pressure and then inflate through a heated sealing jaw at 120–140 °C. The heat-seal layer must not lose tack under inflation delay; seal strength is checked per ASTM F88 on a 25 mm specimen. Creep failure in e-commerce transit is influenced by ambient temperature excursions above 40 °C inside trailers; film qualified only at 23 °C per ASTM D2990 may not predict summer field performance.
In medical device packaging, seal integrity after ethylene oxide or electron-beam sterilization is the governing requirement when HPR1018HA is employed in peelable pouches and lidding webs. The resin is incorporated at 30–60 wt% of the sealant layer, blended with an EVA or a lower-density polyethylene to produce a cohesive failure mode at 145–165 °C seal bar temperature. Compliance is defined by ISO 11607-1:2019 for sterile barrier systems, EN 868-5:2019 for paper/plastic pouches, FDA 21 CFR 177.1520 for the polymer, and USP <87> or ISO 10993-5 when cytotoxicity evaluation is required by the device manufacturer. Production is conducted on cleanroom-compatible blown film or cast film lines with a die gap of 1.3–1.7 mm, a blow-up ratio of 2.0–2.5, and a positive-pressure HEPA-filtered cooling-air system; the film is converted on pouch-making machines with a sealing pressure of 0.3–0.5 MPa and dwell times of 0.5–1.0 s. Terminal product types include peel-open pouches for syringes and catheters, lidding webs for thermoformed trays, and header bags for surgical kits.
Validation of seal integrity after ethylene oxide sterilization involves visual inspection for channel defects, dye penetration, and seal strength per ASTM F88; electron-beam irradiation above 25 kGy can increase polyethylene crystallinity and lower peel strength, so converters must audit the irradiation dose against sealant layer thickness. Batch-to-batch variance in HPR1018HA comonomer distribution is monitored by ISO 1133-1:2022 melt flow rate and ISO 1183-1:2019 density, with a retention sample from each lot tested for film appearance and seal response before release.
Competitive PetroChina Dushanzi KunLun mLLDPE HPR1018HA prices that fit your budget—flexible terms and customized quotes for every order.
For samples, pricing, or more information, please contact us at +8618005193850 or mail to sales8@ascent-chem.com.
We will respond to you as soon as possible.
Tel: +8618005193850
Email: sales8@ascent-chem.com
Flexible payment, competitive price, premium service - Inquire now!
PetroChina Dushanzi Petrochemical Company provides the KunLun mLLDPE HPR1018HA as a metallocene-catalyzed linear low-density polyethylene film resin. The designation places it within the Dushanzi mLLDPE product group; it is supplied in pellet form for cast film, blown film, and thin-gauge coextrusion lines. The nominal density of 0.918 g/cm³ and the nominal melt mass-flow rate of 1.0 g/10 min at 190 °C and 2.16 kg are used for grade differentiation and incoming material verification. Product literature for the KunLun mLLDPE group identifies the primary comonomer as 1-hexene, and the metallocene active-site distribution produces a narrower short-chain branching profile than conventional Ziegler-Natta linear low-density polyethylene. This comonomer choice influences dart impact and tear strength without requiring an increase in film thickness.
Table 1 summarizes the release property envelope and associated test methods. Properties such as tensile yield stress and dart impact are strongly dependent on film fabrication parameters, including die gap, blow-up ratio, frost line height, and draw ratio. The producer’s certificate of analysis is therefore the controlling document for lot-specific mechanical data. Published data for this specific configuration is limited in open databases, and film mechanical values should be normalized to 25 µm film thickness for comparison.
| Property | Test reference | Nominal release basis |
|---|---|---|
| Density | ISO 1183-1:2019 | 0.918 ± 0.002 g/cm³ |
| Melt mass-flow rate | ISO 1133-1:2022, 190 °C/2.16 kg | 1.0 ± 0.15 g/10 min |
| Melting peak temperature | ISO 11357-3:2018 | 120–124 °C |
| Vicat softening temperature | ISO 306:2022, method A50 | 104–108 °C |
| Ash content | ISO 3451-1:2021 | ≤0.05 wt% |
Relative to conventional butene-1 Ziegler-Natta LLDPE, the metallocene architecture in HPR1018HA yields lower compositional heterogeneity. Butene-copolymer resins often contain dispersed high-branched fractions that crystallize later and form weak tie-chain populations at interfacial boundaries. The metallocene-active site distribution inserts comonomer more uniformly along the chain, which alters the lamellar thickness distribution and shifts the tear-dart relationship toward higher puncture resistance at equivalent thickness. In processing terms, the resin exhibits a narrower molecular weight distribution, with Mw/Mn values for metallocene LLDPE film grades commonly in the 2.0–2.5 range, compared with 3.5–5.0 for many Ziegler-Natta LLDPE products. This narrower distribution reduces gel formation and smoke at equivalent melt temperatures but raises screw back-pressure and may require higher extruder torque. Compared with high-pressure low-density polyethylene, HPR1018HA lacks meaningful long-chain branching. Melt tension is therefore lower, and bubble stability in blown film is reduced. Converters using 5–15 wt% of high-melt-strength LDPE can restore neck-in control and bubble quiver resistance.
Within the mLLDPE group, the 1.0 g/10 min melt flow rate is intermediate. Lower-MFR products can offer higher dart impact but reduced output, while higher-MFR products are more suitable for cast lines with limited torque. HPR1018HA is positioned for downgauged film where puncture and tear must not be sacrificed for melt temperature reduction.
In blown-film conversion on a 65 mm single-screw extruder with L/D 30 and a barrier screw, the melt temperature is typically maintained at 190–220 °C through the metering zone. At output rates of 120–180 kg/h, the use of a double-lip air ring and internal bubble cooling stabilizes the bubble at a blow-up ratio of 2.0:1 to 3.0:1. Frost line height is held at 6–10 die diameters to balance transverse direction tear and longitudinal direction tear. A die gap of 1.8–2.4 mm is used for monolayer and coextruded film structures; narrower die gaps increase shear heating and can shift the melt temperature toward the upper processing limit without reducing external barrel setpoints.
Downgauging trials from 150 µm to 25 µm in a five-layer coextrusion line with a 300 mm die and internal bubble cooling require rebalancing frost line and haul-off speed. The grade supports nominal thickness reductions of 20–30% relative to a butene-LLDPE reference at equivalent dart impact, but this is line-specific and must be verified on the target film structure. For food overwrap and hygiene film, tensile yield stress determined by ISO 527-3:2018 or ASTM D882-18 is used as the lower-bound specification. Freeze-fracture optical microscopy is used to detect fish-eye gels above 200 µm in 40 µm film. The base grade is supplied without intentionally added slip or antiblock packages. Processors must control coefficient of friction by dosing masterbatch into the hopper or by post-extrusion corona treatment, with an upper limit of 38 mN/m wetting tension for solvent-free lamination.
For heavy-duty shipping sacks, the resin is commonly selected in a three-layer blown film formulation where the outer layers use a higher-density LLDPE for stiffness and the core uses HPR1018HA for puncture. The final sack is qualified by drop testing according to ISO 7965-2 or ASTM D5276, and Gelbo flex pinhole resistance is often measured under ASTM F392 after 500 cycles. The film structure, sealant layer, and adhesive thickness affect these results, so the pellet alone cannot define final laminate performance.
If the melt temperature is allowed to exceed 240 °C on a 65 mm single-screw extruder with L/D 30, the risk of oxidative chain scission increases depending on antioxidant concentration and residence-time distribution. Operators typically maintain a flat-to-reverse temperature profile from feed throat to die, with compounding zones at 180–220 °C and adapters at 220–230 °C. Screw speeds above 70 rpm on a 65 mm extruder may raise melt temperature through viscous dissipation. A melt-pressure transducer calibrated to ≤350 bar at the die prevents over-shear. If the film edge exhibits draw resonance, haul-off speed variations should be reduced before changing the resin. The grade should not be compounded with amine-based additive packages that can generate oxidative degradation products; standard phosphite and hindered phenolic antioxidant combinations are acceptable. Pre-drying is not required for sealed pellet deliveries, but open storage at relative humidity above 60% may require a 75 °C desiccant-hopper drying step for 2 h to avoid surface moisture defects in cast film.
On cast film lines, melt temperature is maintained at 220–230 °C, and chill roll temperature is held at 24–38 °C. In cast stretch film, the resin is usually blended with 5–10 wt% high-pressure LDPE and a tackifier masterbatch. On a 1000 mm cast die, lower melt strength without LDPE can produce neck-in and edge bead instability. The selection of HPR1018HA in the core layer of a cast film reduces puncture propagation under ASTM D5748 while maintaining machine-direction elongation for pallet wrap.
Table 2 lists the regulatory references commonly requested for food-contact and non-food film. Conformity is determined on the final article, not the pellet alone. Specific migration testing under EU Regulation 10/2011 requires food simulants and time-temperature conditions aligned with final use.
| Regulatory reference | Scope | Status basis |
|---|---|---|
| FDA 21 CFR 177.1520 | Olefin polymers for food contact | Conforms when extraction tests are completed on the final article |
| EU Regulation 10/2011 | Plastic materials and articles intended for food contact | Subject to overall migration and specific migration limits |
| REACH (EC) 1907/2006 | SVHC candidate list | No SVHC expected above 0.1% |
| RoHS 2011/65/EU | Heavy metals and brominated flame retardants | Conforms |
| China GB 4806.7 | Food-contact plastic materials | Conforms under specified use conditions |
In solventless lamination for stand-up pouches, corona treatment of HPR1018HA film is specified at 38–42 mN/m wetting tension immediately before coating. The lamination is then tested for bond strength under ASTM F88/F88M and for seal integrity under ASTM F2029. Published data for this specific configuration is limited, and converters must qualify the final pouch structure on their production line because sealant thickness, coating weight, and retort conditions change the failure mode from cohesive film deformation to interfacial adhesive failure.