| HS Code | 101031 |
| Polymer Type | HDPE |
| Grade | PE100 |
| Tensile Yield Strength Mpa | ≥23 |
| Tensile Strength At Break Mpa | ≥30 |
| Elongation At Break | ≥600 |
| Flexural Modulus Mpa | ≥1000 |
| Notched Impact Strength 23 C Kj M² | ≥20 |
| Environmental Stress Crack Resistance H | ≥5000 |
| Oxidation Induction Time 200 C Min | ≥20 |
| Carbon Black Content | 2.0-2.5 |
| Moisture Content | ≤0.03 |
| Volatile Matter | ≤0.1 |
| Ash Content | ≤0.1 |
| Color | Black |
| Form | Pellets |
As an accredited PetroChina Dushanzi HDPE TUB121RC factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Typically packaged in 25 kg bags, 40 bags per pallet, totaling 1,000 kg. |
| Container Loading (20′ FCL) | 20′ FCL container loading: PetroChina Dushanzi HDPE TUB121RC, 25 kg bags, palletized, shrink-wrapped, and securely loaded for ocean export. |
| Shipping | PetroChina Dushanzi HDPE TUB121RC is shipped as a non-hazardous thermoplastic resin, typically in 25 kg PE bags on pallets, stretch-wrapped. Transport in clean, dry containers or trucks, protected from moisture, sunlight, heat, and contamination. Follow MSDS and local regulations. Store cool, ventilated; avoid sharp objects and open flames. |
| Storage | Store PetroChina Dushanzi HDPE TUB121RC in a cool, dry, well-ventilated warehouse. Keep original packaging sealed and palletized. Protect from sunlight, rain, moisture, heat, flames, and contaminants. Avoid strong oxidizers. Maintain safe stacking to prevent deformation. Use first-in, first-out stock rotation. Do not store near food, feed, or incompatible materials. Ensure good ventilation and housekeeping. |
| Shelf Life | Store in cool, dry, ventilated area; shelf life approximately 12 months in original unopened packaging, away from direct sunlight. |
In buried potable water service, TUB121RC granulate is converted into solid-wall pipe on grooved feed machines. The critical control parameter is not melt flow rate alone but the long-term hydrostatic strength classification established under ISO 9080 and ISO 12162. A resin classified as PE100-RC must sustain a minimum required strength of 10 MPa at 50 years and 20 °C. Melt temperature is held between 190 °C and 220 °C at the adapter; excursions above 230 °C with extended residence time initiate oxidative degradation, visible later as surface microcracking along the pipe axis. Vacuum calibration tanks are operated with water at 15–25 °C to balance collapse resistance against residual stress. Haul-off speed and extruder output are synchronized to keep diameter and wall-thickness variation within the dimensional requirements of EN 12201-2. On a production line using a 38:1 L/D grooved feed extruder with barrier screw and melt pump, screw speed variation above ±2% directly produces wall-thickness trending. Worn feed-groove bushings commonly cause output drop when backpressure exceeds 30 MPa. The melt pump suction pressure should remain above 1.5 MPa; lower suction pressure produces cavitation and periodic melt fracture on the inner pipe surface.
The supplied black compound contains carbon black dispersion at 2.0–2.5 wt% and is assessed by ISO 18553; no additional carbon black masterbatch is required. Clean in-house regrind from the same pipe production may be reintroduced at up to 10 wt%. The rework ceiling is valid only when oxidation induction time remains at or above 20 min when tested by EN 728 at 210 °C. Mixing with non-RC grades or with external recycled HDPE is not permitted because weld-line slow crack growth resistance is not retained across different molecular weight distributions. Finished pipes are specified as SDR 17, SDR 13.6, or SDR 11 according to ISO 4427-1 and EN 12201-2. Using a service coefficient of 1.25, the design stress for water at 20 °C is 8.0 MPa. The maximum permissible operating pressure is derived from the SDR and design stress, not from short-term burst strength. Pipe joints are made by butt fusion following ISO 21307; fusion bead geometry and interfacial pressure are recorded for each joint because cold joints are the dominant field failure mode in pressure pipe networks.
| Property | Test method | Required result |
|---|---|---|
| Long-term hydrostatic strength | ISO 9080 | MRS 10 MPa at 50 years, 20 °C |
| Material classification | ISO 12162 | PE100-RC |
| Oxidation induction time | EN 728 | ≥ 20 min at 210 °C |
| Density | ISO 1183-1 | 0.955–0.960 g/cm³ |
| Melt mass-flow rate | ISO 1133-1 | 0.20–0.40 g/10 min at 190 °C/5 kg |
When a pipeline is installed by horizontal directional drilling, the pipe wall is subjected to axial pulling force, bending strain, annular bore pressure, and external scraping from cobbles in the reamed path. Pull-in loads are calculated using ASTM F1962; the calculated safe pulling stress is typically limited to 8–10 MPa at 20 °C. The allowable force is reduced when installation temperature drops below 5 °C because notched impact energy decreases. Field crews use a swivel between the pulling head and the pipe string; without a swivel, twist exceeding 45° can propagate a crack from the fusion bead into the pipe wall. The reamed bore is typically 1.2–1.5× the outside diameter of the pipe; annular space is maintained with drilling fluid to avoid dry contact that generates frictional drag spikes.
For pull-in service, pipe sections are produced from 100 wt% virgin compound. In-house regrind is excluded because contamination particles act as point-load initiation sites under slow crack growth conditions. The governing laboratory test is the notched pipe slow crack growth test of ISO 13479; pipes with less process-induced orientation at the inner wall perform better under tensile strain. Butt fusion is conducted on site with a data-logging machine and an interfacial pressure of 0.15 MPa as defined in ISO 21307. Heating plate temperature is maintained at 200–220 °C; heating time follows the pipe wall thickness, with typical values of 60–90 seconds for SDR 11 pipe up to 200 mm outside diameter.
The most common field failure during pull-in is not tensile rupture but compressive buckling at the exit side when the bend radius approaches 20 × OD. Buckling appears as local kinking near the fusion bead and is preceded by a rapid increase in pulling load without corresponding advancement. To prevent buckling, the drill path keeps entry and exit angles below 15° from horizontal and uses a breakaway link set to 80% of the calculated safe pull force. Finished strings are used for potable water and sewage force mains under highways, river crossings, and rail corridors. They are tested hydrostatically before pull-in and again after installation; the second test detects damage that may not be visible on the outer surface.
Gas distribution pipe fabricated from this resin is qualified by rapid crack propagation resistance rather than long-term creep alone. The full-scale RCP test of ISO 13477:2008 is performed on the final pipe dimensions at 0 °C or lower; the critical pressure must exceed the maximum operating pressure by the safety margin specified in ISO 4437-2. A running crack must arrest before it reaches the next fitting, because natural gas decompression can sustain crack speed in the pipe wall. PE100-RC resins typically show improved crack arrest capability, but the relationship is not automatic; each pipe size and SDR must be tested independently.
Gas pipe extrusion permits clean rework from the same production lot at a maximum of 5 wt%. The lower rework ceiling compared with water pipe is required because gas service life is dominated by long-term static pressure at weld zones. Carbon black dispersion is checked by ISO 18553, and volatile processing aids or external release agents are not used. Residual volatile compounds can migrate to the inner pipe surface and are considered a contamination source for gas quality.
Electrofusion welding in humid trenches introduces moisture at the fusion interface if the pipe surface is not scraped to remove the oxidized layer. Failure at 3–5 bar hydrostatic testing is commonly traced to insufficient scraping depth or misalignment. Dimensional inspection after extrusion includes wall thickness and ovality; gas distribution pipes are yellow-striped or black with yellow identification markings according to operator specification, but the polymer matrix itself is the same black compound. The final pipe is leak-tight tested under pressure and must meet color, dimension, hydrostatic strength, and RCP requirements of ISO 4437-1.
For abrasive slurry transport, the governing failure mode is often slow crack growth from gouges rather than internal pressure alone. Mining tailings and dredge discharge lines assembled from HDPE pipe are butt fused to ISO 21307. The slurry is typically a sand-water mixture with solids content up to 30 wt% and flow velocity between 2 m/s and 5 m/s. Below 2 m/s, a sliding bed forms at the pipe invert and accelerates local wear; above 5 m/s, erosion at bends increases rapidly. No filler or processing aid is added to the pipe wall for abrasion resistance. The black compound contains sufficient carbon black dispersion for outdoor UV exposure under ISO 18553, but the pipe wall thickness is the primary wear allowance.
Wall thickness selection must include an erosion allowance based on site-specific particle angularity, solids concentration, and flow regime. Published data for this specific configuration is limited; no universal wear allowance can be applied across all slurry applications. Finished lines are produced as SDR 11 to SDR 26, with larger diameters requiring field butt fusion and heavy-wall pipe for wear allowance. Design stress for industrial pressure service is not always fixed at 8.0 MPa; the service coefficient changes when the conveyed medium temperature exceeds 20 °C and when the pipeline is exposed to direct sunlight in above-ground installations. External gouges from rocks or backfill compaction must be assessed by slow crack growth testing rather than tensile yield alone.
Close-fit sliplining and pipe bursting impose a different stress state on the resin: the new pipe passes through a reduction die or an expanding bore while the outer wall is scraped by fragments of the host pipe. The critical property is scratch resistance under sustained tensile load, not short-term internal pressure. In close-fit lining, the PE pipe is temporarily reduced in cross-section, pulled into the host pipe, and allowed to revert. This process opens microcracks at the outer surface if the resin lacks adequate slow crack growth resistance; those microcracks become leak paths after the host pipe returns to service. Liner wall thickness is specified as SDR 26 or SDR 33 to balance hydraulic capacity against insertion force and annular clearance. The annulus is normally not grouted; the liner must withstand external static groundwater pressure when the host pipe is structurally compromised.
Only 100 wt% virgin compound is used for reduction die close-fit lining. Regrind particles may initiate splits during the reduction stage because they act as hard inclusions under compressive strain. The liner string is butt fused on the right-of-way; fusion parameters follow ISO 21307, and the pipe is left to cool below 40 °C at the joint before insertion. Pulling speed is limited to prevent frictional heating at the reduction die, which can create oriented surface scoring. Rehabilitated water and sewer mains are hydrostatically tested after insertion and again after the host pipe is reconnected; the governing installation standard for water supply renovation is ISO 11298-1.
In closed-loop geothermal systems, water-glycol mixtures circulate through vertical boreholes or horizontal trenches at low positive pressures. The pipe wall must resist longitudinal scrapes during insertion, chemical contact with heat transfer fluid, and long-term creep under static pressure. The resin's slow crack growth resistance reduces leak risk in vertical boreholes where the pipe is pulled over rock edges and left in contact with saturated backfill. Pipe circuits are assembled with socket fusion or electrofusion; butt fusion is often avoided in vertical boreholes because the bead interferes with insertion and occupies annular space.
The heat transfer fluid should be an inhibited propylene glycol-water mixture with pH maintained between 7.0 and 8.5. pH outside this range accelerates oxidative degradation at fittings and can reduce pipe service life. Continuous fluid temperatures above 60 °C exceed the long-term creep resistance plateau of the material and require derating of pressure capacity. Typical ground-source loops operate below 4 bar and are pressure-tested to 1.5× maximum operating pressure before backfilling. The pipe is supplied in SDR 9 or SDR 11 configurations; the heavier SDR 9 wall is selected when the loop is installed in rocky ground where external scoring is likely. External contact with chemically aggressive groundwater requires site-specific exposure testing before burial.
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PetroChina Dushanzi HDPE TUB121RC is a bimodal high-density polyethylene pipe resin classified as PE 100-RC under ISO 12162. The grade is specified for pressure pipe applications where the hydrostatic design is based on a minimum required strength of 10 MPa at 20°C for 50 years, determined by ISO 9080. The RC designation denotes a raised resistance to slow crack growth relative to the conventional PE100 baseline; this is achieved through a bimodal molecular weight distribution, a controlled high-molecular-mass fraction, and controlled short-chain branching. The product is supplied as a pelletized extrusion material for solid-wall pipe, with a typical density of 0.958–0.963 g/cm³ under ISO 1183-1:2019 and a melt mass-flow rate of 0.20–0.30 g/10 min at 190°C / 5 kg under ISO 1133-1:2022. In black pipe formulations, carbon black is incorporated at 2.0–2.5 wt% with dispersion quality evaluated by ISO 18553:2002. The stated values are representative of the PE100-RC envelope; batch-specific certificates must be used for acceptance testing.
Because the grade is used in buried pressure mains, the primary specification metrics are hydrostatic design stress, slow crack growth resistance, and melt stability. The table below lists representative property ranges for the PE100-RC class and the associated test methods. The tensile yield stress, measured by ISO 527-2:2012 at 50 mm/min, is commonly above 23 MPa, while elongation at break exceeds 600%. Flexural modulus under ISO 178:2019 is typically 900–1100 MPa. Charpy notched impact strength at 23°C is reported above 20 kJ/m² using ISO 179-1/1eA:2010. The high-density polyethylene backbone also provides a Vicat softening temperature in the 122–126°C range under ISO 306:2013 method A50, but this is a short-term thermal indicator and does not define continuous service temperature.
| Property | Test method | Representative range or value |
|---|---|---|
| Density | ISO 1183-1:2019 | 0.958–0.963 g/cm³ |
| Melt mass-flow rate | ISO 1133-1:2022, 190°C / 5 kg | 0.20–0.30 g/10 min |
| Tensile yield stress | ISO 527-2:2012 | 23–25 MPa |
| Elongation at break | ISO 527-2:2012 | >600% |
| Flexural modulus | ISO 178:2019 | 900–1100 MPa |
| Charpy notched impact strength, 23°C | ISO 179-1/1eA:2010 | >20 kJ/m² |
| Minimum required strength | ISO 9080 / ISO 12162 | 10 MPa |
On grooved-feed single-screw extruders with barrel L/D ratios between 30:1 and 38:1, the high melt viscosity of the PE100-RC grade produces elevated head pressure and requires torque-limited drive sizing. Barrel temperature profiles are typically set from 180°C to 210°C, with die zones at 200°C to 220°C; sustained melt temperatures above 230°C can initiate thermo-oxidative degradation, visible as surface oxidation or gel particles. Screen packs of 60/80/100 mesh are used to remove contaminants, but the pressure drop across the screen pack should remain below 15 MPa to avoid excessive shear heating. Moisture absorption is not the primary processing constraint; however, condensation on cold pellets at relative humidity above 60% can generate surface pits and internal steam bubbles. Storage in a dry environment at 15–30°C is therefore recommended. Vacuum calibration sleeves and spray cooling water in the 15–20°C range are employed to control wall thickness and reduce frozen-in stress. Co-rotating twin-screw extruders are not required for single-layer solid-wall pipe production; they are used only when compounding carbon black masterbatch or additional stabilizers into the resin.
When slow crack growth resistance becomes the controlling parameter—such as in sandless bedding, pipe bursting, horizontal directional drilling, or rock impingement—the RC designation is evaluated through notched pipe testing and full-notch creep testing. In the notched pipe test under ISO 13479, notched specimens are internally pressurized at 80°C and a hoop stress of 4.0 MPa; conventional PE100 materials may fail at relatively short intervals, while PE100-RC grades are typically required to survive extended durations agreed between the pipe manufacturer and the end user. Published data for this specific configuration is limited; therefore, converter qualification should include both a notched pipe test and a full-notch creep test under ISO 16770:2004 at 80°C in a stress-cracking agent. The performance difference arises from the high-molecular-mass fraction and tie-molecule concentration in the amorphous regions, which reduce craze propagation rates under point loads. Resins without the RC classification may still meet minimum hydrostatic strength but can fail by slow crack growth before the design lifetime when installed in damaged backfill or without sand bedding.
Sag resistance and large-diameter thick-wall pipe processing are governed by melt stiffness and extensional viscosity. In diameters above 500 mm with SDR 11 or SDR 17 wall thicknesses, gravitational sag at the die exit produces eccentric wall thickness unless the resin has a sufficiently high low-shear viscosity. TUB121RC belongs to the PE100-RC class with enhanced sag resistance; the bimodal molecular weight distribution increases low-shear viscosity without proportionally increasing high-shear extrusion pressure. Dynamic oscillatory measurements at 190°C typically show a crossover frequency below 10 rad/s for the high-molecular-mass tail, indicating long relaxation times. On production lines, the calibration sleeve length is maintained at 2–3 pipe diameters, and haul-off speed is matched to extruder output to prevent drawdown. Pipe wall thickness is monitored by ultrasonic gauges; eccentricity must remain within the tolerance specified in ISO 4427-2 or ISO 4437-2 depending on the service medium.
For buried water lines, the resin is processed into solid-wall PE100-RC pipes that permit installation without sand bedding and with reduced imported backfill. In gas distribution, the material is specified under ISO 4437-2 and EN 1555-2 for natural gas and manufactured gas; hydrostatic design stress is based on ISO 9080. In industrial effluent and slurry transport, chemical resistance follows the paraffinic structure of high-density polyethylene at temperatures below 60°C; continuous operation above this temperature requires derating factors from ISO 13760 or case-specific testing. The resin is not intended for chlorinated hot-water piping, because oxidative degradation accelerates above 60°C and chloride species can initiate stress cracking at elevated temperature. For potable water, migration and organoleptic performance must be confirmed against ISO 8795 or applicable national regulations; black pipe formulations with carbon black provide ultraviolet weathering resistance for outdoor storage under ISO 16871:2003.
The distinction from conventional PE100 is not a single parameter but a shift in the slow crack growth failure envelope. Conventional PE100 and PE100-RC share the same minimum required strength of 10 MPa under ISO 12162; the difference appears in notched pipe test lifetime, full-notch creep test failure mode, and allowable installation loads. PE80 has a minimum required strength of 8 MPa, requiring thicker walls for the same pressure rating. The table below summarizes the operational differences on the basis of standard classification parameters.
| Classification | MRS under ISO 12162 | Slow crack growth resistance | Typical density | Typical MFR at 190°C / 5 kg |
|---|---|---|---|---|
| PE100-RC (TUB121RC) | 10 MPa | Enhanced, notched pipe and FNCT | 0.958–0.963 g/cm³ | 0.20–0.30 g/10 min |
| Conventional PE100 | 10 MPa | Standard, notched pipe | 0.950–0.960 g/cm³ | 0.20–0.40 g/10 min |
| PE80 | 8 MPa | Lower | 0.940–0.950 g/cm³ | 0.40–1.0 g/10 min |
Operational boundaries include upper service temperature, ultraviolet exposure, and additive compatibility. The resin must not be combined with amine-based additives or certain phenolic antioxidants that can interfere with the catalyst residue and lower the oxidation induction time. In black pipe formulations, carbon black is added at 2.0–2.5 wt% with a mean particle size below 25 nm; dispersion quality must be assessed by ISO 18553:2002 because undispersed agglomerates reduce impact strength. If pipe is stored outdoors for more than one year, oxidation induction time should be verified by ISO 11357-6:2018 and compared with the supplier’s stated minimum. The maximum continuous operating temperature for pressure service is 40°C for water unless derating factors from ISO 4427-2 are applied; short-term excursions above 60°C require case-by-case evaluation. The resin should not be processed on machines with high-compression screws and no melt pump, because excessive shear heating can reduce the notched pipe test time despite an acceptable melt flow index.