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PetroChina Dushanzi HDPE HD5503GA

    • Product Name: PetroChina Dushanzi HDPE HD5503GA
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 441372
    Melt Flow Rate 0.35 g/10 min
    Density 0.954 g/cm³
    Tensile Yield Strength 26 MPa
    Elongation At Break 600%
    Flexural Modulus 1100 MPa
    Izod Notched Impact Strength 20 kJ/m²
    Vicat Softening Temperature 124 °C
    Brittleness Temperature -70 °C
    Shore D Hardness 62
    Environmental Stress Cracking Resistance >1000 h
    Water Absorption <0.01%
    Mold Shrinkage 1.5-3.0%
    Melt Temperature 180-220 °C
    Mold Temperature 20-60 °C
    Dielectric Constant 2.3
    Volume Resistivity >10^16 Ω·cm
    Thermal Conductivity 0.44 W/m·K
    Coefficient Of Linear Thermal Expansion 1.2×10^-4 /°C

    As an accredited PetroChina Dushanzi HDPE HD5503GA factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing PetroChina Dushanzi HDPE HD5503GA is packaged in 25 kg polyethylene-lined woven bags, supplied 40 bags per 1,000 kg pallet.
    Container Loading (20′ FCL) PetroChina Dushanzi HDPE HD5503GA is packed in 25 kg bags, floor-loaded in 20′ FCL containers, approximately 25 MT per container.
    Shipping PetroChina Dushanzi HDPE HD5503GA is shipped as non-hazardous polyethylene pellets in 25 kg woven bags or 1,000 kg jumbo bags, palletized and stretch-wrapped. Transport in clean, dry 20-foot containers or trucks. Keep away from moisture, heat, direct sunlight, and sharp objects. Follow MSDS and local regulations.
    Storage Store PetroChina Dushanzi HDPE HD5503GA in a cool, dry, well-ventilated warehouse away from direct sunlight, heat, flames, and strong oxidizers. Keep original bags sealed on pallets to prevent moisture, dust, and contamination. Use ambient temperature, preferably below 40°C, and avoid prolonged UV exposure or excessive stacking. Maintain clean, slip-free floors and follow local regulations. Do not store near food or feed.
    Shelf Life Store in a cool, dry, well-ventilated area, away from direct sunlight; shelf life is typically 12 months in original packaging.
    Application of PetroChina Dushanzi HDPE HD5503GA

    Blown-film conversion of HD5503GA into monolayer retail carrier sacks is specified around a nominal density of 0.956 g/cm³ measured under ISO 1183-1:2019 and a melt flow rate of 0.35 g/10 min measured under ISO 1133-1:2022. Where the finished sack is intended for dry-food contact, the olefin polymer falls within FDA 21 CFR 177.1520 and, for Chinese domestic conversion, GB 4806.7-2016; overall migration testing under EU Regulation (EU) No 10/2011 Annex I is carried out with the appropriate food simulant and the 10 mg/dm² limit is applied as a verification threshold. Non-food retail sacks are screened against REACH Regulation (EC) No 1907/2006 Annex XVII and a retailer-specific restricted substance list. A production formulation is run at 97.0–99.0 wt% HD5503GA, 1.0–2.5 wt% white or coloured masterbatch, and 0.5–1.0 wt% silica-based antiblock masterbatch; film blocking on a 40°C warehouse reel can be addressed by moving the antiblock toward the upper limit only when dart impact loss remains below 10%. The process uses a single-screw blown-film extruder of 50–75 mm diameter with a barrier screw and L/D: 30:1, a die gap of 1.2–1.8 mm, a blow-up ratio between 3.5:1 and 4.5:1, and a melt temperature of 195–215°C. The frost line is held at 6–10 die diameters above the die face; lowering the frost line below 4 die diameters increases transverse-direction shrinkage above 2%, while raising it above 12 die diameters destabilizes bubble edge tension and produces gauge bands of ±3 µm on a 25 µm nominal web. Terminal product types include T-shirt carrier bags, bottom-seal flat sacks, and perforated retail roll stock.

    What limits dart impact retention when HD5503GA is let down into post-consumer HDPE reclaim?

    Post-consumer HDPE reclaim converted into non-food refuse sacks is blended with virgin HD5503GA at 25–50 wt% to restore melt strength, dart impact, and gauge uniformity; the ratio is raised or lowered against the melt flow rate of the incoming reclaim batch, which typically lands between 0.5–0.9 g/10 min under ISO 1133-1:2022 after melt filtration. Compliance for the non-food route is governed by REACH Regulation (EC) No 1907/2006 Annex XVII screening, with SVHC disclosure and heavy-metal limits verified on the reclaim feedstock; where a converter later seeks food-contact use of the recyclate-containing film, the recycled plastics provisions of Regulation (EU) 2022/1616 apply, and published data for that specific HD5503GA/PCR configuration remains limited. The blending process runs on a counter-rotating twin-screw extruder of 75 mm diameter and L/D: 36:1, with a vent port operated at −0.08 MPa, a melt temperature of 200–220°C, and a continuous screen changer fitted with 100–150 µm mesh; paper-label residues in the reclaim shorten screen-pack life to 4–6 h, so the screen changer is paired with laser melt filtration when label contamination exceeds 2% by weight of the reclaim stream. A fluoropolymer-based processing aid is added at 0.03–0.08 wt% to suppress melt fracture arising from gel particles, and 0.2–0.5 wt% of antioxidant masterbatch is introduced when the coefficient of friction of the final film must remain stable after eight weeks of indoor storage. Terminal finished products are heavy-gauge refuse sacks and can liners, produced predominantly as side-seal or bottom-seal constructions with a film thickness of 35–80 µm.

    In heavy-duty form/fill/seal tubular film for granular fertilizers, petrochemical resins, and dry mortar, HD5503GA is run as the load-bearing outer layers of a three-layer sack film at 92–96 wt% of the total structure, with 1–2 wt% titanium-dioxide white masterbatch for opacity and 0.3–0.5 wt% silica antiblock masterbatch; the core may contain 10–20 wt% recycled internal edge trim, provided the trim stream is dried below 0.1% moisture and screened through 80–120 µm mesh. Industrial packaging compliance is demonstrated by UN certification for dangerous goods in sacks through the test sequence in the UN Manual of Tests and Criteria, 8th revised edition, with drop height and stacking-load requirements determined by the packing group of the filled product; thickness profile is verified under ISO 4593:1993, and tensile properties are measured under ISO 527-3:2018 before release. The blown-film line uses a die diameter of 250–350 mm, a die gap of 2.0–2.4 mm, a blow-up ratio of 2.5:1–3.5:1, and a melt temperature of 190–210°C; internal bubble cooling is used to stabilize the high film thickness of 140–180 µm and to prevent bubble sag before the collapsing frame. Output is typically constrained by air-ring heat removal rather than screw capacity, and frost-line height is maintained below 4 die diameters to keep machine-direction elongation low enough for FFS jaw sealing. Terminal product types are FFS pillow sacks, gusseted sacks, and block-bottom valve sacks.

    Extrusion coating on woven polypropylene fabric

    Extrusion-coating lines processing HD5503GA as the seal layer on woven polypropylene fabric require thermal stability through an air gap of 150–250 mm at melt temperatures of 290–330°C; the resin molecular weight distribution controls neck-in and coating-weight uniformity, and the die temperature profile is held within ±5°C across the slot to avoid edge tear at the trim blades. Compliance for flexible intermediate bulk container outer sacks is tied to ISO 21898:2004 for non-dangerous goods FIBCs, while food-contact woven sacks must also meet FDA 21 CFR 177.1520 and EU Regulation (EU) No 10/2011 simulant testing; all products are screened under REACH Regulation (EC) No 1907/2006 Annex XVII for restricted substances. The extrusion-coating blend is set at 60–80 wt% HD5503GA and 20–40 wt% LDPE or linear metallocene polyethylene to maintain adhesion after 24 h water immersion; 0.5–1.5 wt% white masterbatch is added for optical coverage, and 0.1–0.3 wt% antioxidant masterbatch is used when the coated fabric is stored outdoors beyond six months. Equipment is a single-screw extruder of 90 mm diameter with L/D: 30:1, a T-slot die of 1,200–2,800 mm width, a chill roll held at 15–25°C, and a line speed between 80–250 m/min. Coating weight is adjusted between 10–25 g/m²; below 10 g/m², pinholing and edge tear become process-critical, while above 25 g/m² the additional coat weight contributes to roll blocking unless chill-roll release is improved. Terminal finished goods include woven polypropylene sacks for pet food and chemical packaging, as well as FIBC outer laminates.

    Unlike a low-stalk pocket bubble, the high-stalk configuration used to convert HD5503GA into thin-gauge liners changes the failure mode at frost-line oscillation. When the stalk height is increased from 4 die diameters to 8–12 die diameters before radial expansion, the machine-direction tear strength typically moves closer to the transverse-direction tear strength, but the bubble becomes more sensitive to ambient air turbulence and can produce a frost-line oscillation band of ±5 µm at a 25 µm nominal gauge. Compliance for the physical property portion of this application is anchored to ISO 527-3:2018 for tensile properties and ASTM D1922-15(2020) for Elmendorf tear; when the liner is used as a dry-food insert, FDA 21 CFR 177.1520 applies, and when sold into the European Union, EU Regulation (EU) No 10/2011 overall migration verification is required. The formulation is set at 98.5–99.5 wt% HD5503GA, 0.3–0.8 wt% erucamide slip masterbatch, and 0.2–0.5 wt% silica antiblock masterbatch; fluoropolymer process aid is added at 0.03–0.06 wt% only when the die pressure fluctuation exceeds 5% of the setpoint. The die gap is reduced to 1.0–1.4 mm, the blow-up ratio is held at 4.0:1, and the melt temperature is kept between 190–210°C; internal bubble cooling air is delivered at 15–20°C to stabilize the stalk against lateral drift. Operational limits include an upper stalk height of 12 die diameters, above which dart impact falls below the process control limit and transverse-direction shrinkage exceeds 2% after 24 h at 60°C. Terminal product types include thin-gauge produce liners, bread-bag inserts, and dry-goods inner liners.

    When a 25 µm cereal liner enters food-contact conversion, the limiting additive package is not the polymer but the slip and antiblock system

    When a 25 µm cereal liner is converted from HD5503GA for direct dry-food contact, the grade itself is covered as an olefin polymer under FDA 21 CFR 177.1520, and the finished film is subject to the overall migration limit of 10 mg/dm² under EU Regulation (EU) No 10/2011 Annex I; Chinese domestic shipments are referenced against GB 4806.7-2016, and food-contact converters often require organoleptic taint testing under ISO 13302:2003. The formulation is limited to 98.0–99.5 wt% HD5503GA, 0.3–0.8 wt% erucamide slip masterbatch, and 0.2–0.6 wt% silica antiblock masterbatch; slip levels above 0.8 wt% lead to coefficient-of-friction loss below 0.15, which causes reel telescoping on high-speed form-fill-seal lines, while silica levels above 0.6 wt% raise haze measured under ASTM D1003 and lower Elmendorf tear measured under ASTM D1922. The film is produced on a three-layer blown-film line to place the slip and antiblock in the skin layers while the core remains neat HD5503GA, reducing the total additive loading; the die gap is 1.4–1.8 mm, the blow-up ratio is 3.0:1–3.8:1, and the melt temperature is 190–210°C. The bubble is run in a low-stalk pocket after the die, with frost-line height held at 5–7 die diameters to keep film optics within specification. Terminal product types are cereal liners, dry-food pouch inserts, and bakery bag liners with a film thickness range of 25–50 µm.

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    Certification & Compliance
    More Introduction

    PetroChina Dushanzi HDPE HD5503GA is a pelletized high-density polyethylene resin produced by PetroChina Dushanzi Petrochemical Company for extrusion blow molding, sheet thermoforming, and related rigid packaging processes. The grade is positioned in the Dushanzi high-density polyethylene portfolio between low-flow blow-molding resins and higher-flow injection-molding grades. Its melt flow rate under 2.16 kg load at 190 °C is customarily reported in the range 0.30–0.40 g/10 min using ISO 1133-1:2022, and its solid-state density is typically 0.954–0.956 g/cm³ under ISO 1183-1:2019. These nominal values give HD5503GA an intermediate balance of parison melt strength, die pressure, and environmental stress crack resistance. The resin is supplied as natural or precolored pellets, with a water absorption value below 0.01% by mass at 23 °C and 50% relative humidity, so pre-drying is not normally required when bags are stored intact below 60% relative humidity. If surface moisture is suspected after outdoor storage or partial bag use, a desiccant dryer at 80 °C for 2–3 h is generally sufficient to restore stable melt flow.

    What nominal specification boundaries does HD5503GA occupy relative to adjacent Dushanzi HDPE grades?

    The table below summarizes representative engineering ranges rather than guaranteed lot-specific limits. Converters should verify each production lot against the manufacturer’s certificate of analysis because melt flow rate and density can vary within normal production tolerance. The property profile aligns with HDPE grades intended for blow-molded containers up to approximately 30 L capacity, where wall-thickness control, drop impact, and chemical exposure are primary design constraints.

    Nominal property profile and test methodology for HD5503GA
    PropertyTest methodNominal value
    Melt flow rate, 190 °C/2.16 kgISO 1133-1:20220.30–0.40 g/10 min
    DensityISO 1183-1:20190.954–0.956 g/cm³
    Tensile yield stressISO 527-2:201224–27 MPa
    Elongation at breakISO 527-2:2012>500%
    Flexural modulusISO 178:2019900–1200 MPa
    Notched Izod impact at 23 °CISO 180:20238–12 kJ/m²
    Vicat softening pointISO 306:2013124–127 °C
    Environmental stress crack resistance, 100% Igepal CO-630ASTM D1693-15>150 h

    Within the Dushanzi high-density polyethylene range, HD5503GA is differentiated by its intermediate melt flow index. Compared with HD5502GA, which is generally specified with a lower melt flow rate, HD5503GA reduces screw torque and accumulator head pressure during extrusion blow molding. The higher flow also permits faster parison extrusion and more uniform wall distribution in multi-cavity tools. However, the increase in melt flow index is typically accompanied by a measurable reduction in environmental stress crack resistance and parison melt strength. A converter substituting HD5503GA for HD5502GA in containers holding aggressive alkaline or surfactant-containing formulations should validate the change using ASTM D1693-15 or an equivalent notched constant-strain ESCR procedure, rather than relying only on melt flow index and density comparisons.

    Accumulator-Head Processing Limits, Parison Programming, and Weld-Line Failures

    The grade is typically processed on single-screw extruders with L/D ratios between 24:1 and 30:1, using a flat or slightly reverse temperature profile. Common starting settings are feed zone 180–200 °C, compression zone 200–220 °C, metering zone 210–230 °C, and head or die zones 210–230 °C. For accumulator-head machines, die swell normally falls in the range 30–50% depending on shear history, die gap, and head residence time. Parison programming should begin with a relatively closed die gap at the top stroke to control neck thickness and a gradually wider gap toward the lower stroke where blow-up ratio increases. Excessive die-gap opening at the bottom stroke produces thick bottom flash and uneven container wall distribution, while insufficient die gap raises melt stress and can initiate shark-skin surface defects at the die exit. Melt-temperature differences above 5 °C across the die annulus frequently produce parison curl and wall-thickness asymmetry on production lines, so head zone calibration is more important than absolute set temperature for this grade.

    On wheel-type blow molders, the resin’s low melt flow index can generate elevated axial pressure in grooved-feed extruders. Feed-section barrel cooling should maintain 60–80 °C to prevent premature melting and pressure fluctuation. With smooth-bore extruders, lower feed-zone temperatures may reduce output but improve melt homogeneity. Blow-mold clamp force for HDPE containers is commonly estimated from projected parting-line area; a starting range of 0.4–0.6 kN/cm² is used for conventional blow-molded HDPE parts. Insufficient clamp force at pinch-off can produce weld-line splits because the low melt-flow resin does not heal as readily as higher-flow injection grades under abbreviated mold contact time.

    For containers requiring food-contact compliance, HD5503GA is generally supplied under a food-contact statement referencing FDA 21 CFR 177.1520 and EU Regulation (EU) No 10/2011. The converter remains responsible for finished-article migration testing because compliance depends on processing temperature, container wall thickness, and contact ratio. For non-food industrial packaging, the resin is usually evaluated under REACH and RoHS requirements for heavy metals and restricted substances. Published data for specific configuration limits under all potential chemical contact matrices is limited; therefore, end-use immersion testing remains the definitive qualification method.

    When the Resin is Exposed to Continuous-Contact Polar Liquids or Aggressive Detergent Systems

    The limiting design parameter for HD5503GA in blow-molded applications is environmental stress crack resistance rather than short-term tensile strength. The grade is not intended for sustained pressure-pipe service, and it does not carry a PE100 classification under ISO 9080. In containers exposed to alcohols, nonionic surfactants, or concentrated alkaline household formulations, stress cracking occurs at low strain levels when molded-in stresses are not adequately relaxed. The higher melt flow index of HD5503GA relative to HD5502GA improves processability but may lower ESCR, so containers above 5 L with continuous polar-liquid contact should be evaluated under ASTM D1693-15, notched constant-strain testing, or a bottle drop-and-leak protocol after conditioning at 50 °C for a period defined by the end-use specification.

    The resin is not designed for rotational molding, blown film, or injection molding of high-flow thin-wall parts. Blow-molding grades with lower melt flow rates generally offer higher parison strength and superior ESCR for large industrial containers, while higher-flow HDPE grades offer shorter cycle times but reduced melt strength and lower chemical resistance. HD5503GA sits between these groups, making it suitable for moderate-size bottles, small jerry cans, and rigid packing where surface finish, impact resistance, and processing ease must be balanced. Lot-to-lot variation in melt flow rate should be monitored at incoming inspection using ISO 1133-1:2022; normal production tolerance is approximately ±0.03 g/10 min, and deviations outside this range can alter parison sag, head pressure, and container wall distribution.

    For converters running continuous shuttle machines with defined L/D ratios, the main processing bottleneck is rarely melt temperature alone. It is the combination of melt-temperature homogeneity, head pressure stability, and parison programming accuracy. On actual production lines, the most common failure modes observed with HD5503GA are parison curl from die-temperature gradients, bottom pinch-off splits from insufficient clamp force, and excessive flash weight from incorrect die-gap profiling. These defects are corrected by adjusting die-zone alignment, increasing pinch-off design compression, or revising the parison wall-thickness curve rather than by raising melt temperature, which may increase degradation risk at the top of the processing window. The upper melt-temperature limit should be maintained below 250 °C to avoid thermal degradation, odor generation, and yellowing in natural or light-colored containers. Published data for specific degradation kinetics in this exact grade is limited; the practical upper limit is inferred from general HDPE thermal stability under extrusion blow molding conditions.

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