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Overview of materials for Nylon 12, 50% Glass Fiber Filled

    • Product Name: Overview of materials for Nylon 12, 50% Glass Fiber Filled
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 481260
    Density 1.60 g/cm³
    Filler Content 50% Glass Fiber
    Water Absorption 24h 0.20%
    Tensile Strength Ultimate 150 MPa
    Elongation At Break 2.5%
    Flexural Modulus 10000 MPa
    Flexural Strength 190 MPa
    Izod Impact Notched 120 J/m
    Heat Deflection Temperature At 1 8 Mpa 175 °C
    Melting Point 178 °C
    Thermal Conductivity 0.30 W/m-K
    Volume Resistivity 1.0e+15 ohm-cm

    As an accredited Overview of materials for Nylon 12, 50% Glass Fiber Filled factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Packaged in a sealed 25 kg moisture-barrier bag with desiccant, purged with nitrogen, labeled with Nylon 12, 50% glass fiber filled specifications.
    Container Loading (20′ FCL) A 20-foot FCL shipment of Nylon 12, 50% glass fiber filled material, safely packed in sealed containers for efficient transport.
    Shipping Shipping: Not regulated as dangerous goods. Non-hazardous for transport by ground, air, or sea. Pack in sealed, moisture-proof containers to prevent degradation. Avoid dust generation during handling. No special temperature controls required. Standard industrial packaging and labeling apply.
    Storage Store Nylon 12, 50% glass fiber filled material in a cool, dry environment, ideally below 30°C, to prevent moisture absorption and degradation. Keep in original sealed containers or moisture-barrier bags, away from direct sunlight, UV radiation, and heat sources. Ensure adequate ventilation to avoid dust accumulation, and follow standard handling precautions.
    Shelf Life Shelf life is indefinite if stored sealed, dry, and cool; avoid humidity to prevent property degradation.
    Application of Overview of materials for Nylon 12, 50% Glass Fiber Filled

    On a 1200 kN hydraulic clamp injection moulding machine with a 32 mm diameter three-zone screw and an L/D 24 barrel, PA12 GF50 is processed at a set barrel profile of 220 °C in the feed zone, 250 °C in the compression zone, and 260 °C at the nozzle. The 50 wt% short-glass fibre loading increases the dry-as-moulded tensile modulus to 12 000–15 000 MPa when tested per ISO 527-1/-2, permitting 1.2 mm thick automotive quick-connector bodies to resist fuel-line pull-off forces in SAE J2044-type couplings. Pre-drying in a desiccant dryer at 80 °C for 4–6 h to residual moisture at or below 0.10 wt% is mandatory before plastication; hydrolysis at melt temperature otherwise evolves water vapour, producing surface splay and a loss of weld-line burst strength commonly measured at 15–25% in production trials. Fibre orientation created during filling of the locking-shoulder geometry produces anisotropic post-moulding shrinkage of 0.1–0.3% in the flow axis and 0.5–0.7% transverse per ISO 294-4; an uncontrolled tool temperature shift away from 80–100 °C can move these values enough to cause failure under the insertion force gauge. Fuel contact qualification follows ISO 1817 immersion in Fuel C at 60 °C for 168 h, with no cracking under 10× optical inspection and no visible delamination at the glass-resin interface. The glass content must be confirmed by ashing at 600 °C per ISO 3451-1, with acceptable production variance of 48–52 wt%. Terminal components include 9.5 mm male quick connectors, 8 mm evaporative-emission vapour elbows, and 7.89 mm canister port fittings. Operational boundaries are significant: continuous exposure to sour gasoline containing peroxides above 70 °C can embrittle the polyamide matrix, and published data for 50 wt% glass-loaded PA12 exposed to Fuel C beyond 1 000 h are limited, so burst validation on production parts remains the only fully reliable method.

    Representative property profile for short-glass PA12 GF50 in dry-as-moulded and conditioned states
    PropertyTest standardDryConditioned 23 °C / 50% RH
    DensityISO 1183-11.44–1.47 g/cm³No significant change
    Tensile modulusISO 527-1/-212 000–15 000 MPa10 500–13 000 MPa
    Tensile stress at breakISO 527-1/-2140–170 MPa120–150 MPa
    Charpy notched impactISO 179-1/1eA10–15 kJ/m²12–16 kJ/m²
    HDT-AISO 75-1/-2165–180 °C160–175 °C

    What Limits the Burst Pressure Rating of PA12 GF50 Pneumatic Manifold Bodies?

    The short-term burst pressure of a PA12 GF50 compressed-air manifold is not controlled by handbook tensile strength but by weld-line integrity at threaded port bosses and by creep rupture under sustained air load. In a typical 40 mm internal diameter manifold, the 50 wt% glass reinforcement lifts dry tensile strength to 140–170 MPa per ISO 527-1/-2, but the melt fronts meeting at a boss produce fibre orientation parallel to the knit line that can reduce local strength by 30–50%. Conversion of the tool to sequential valve gating or a heated boss pin can maintain a local melt temperature of 260–280 °C at the knit line, allowing glass fibres to bridge the interface and restoring approximately 85–95% of unwelded strength. The processed part must show a glass content of 48–52 wt% by ash testing per ISO 3451-1; a lower value indicates fibre attrition in the screw and directly reduces long-term creep resistance. Working pressure is established by applying a 2.0 design factor to the short-term burst value, followed by a 1.5-times nominal working pressure pneumatic leak test at 23 °C and 70 °C using dry compressed air. For industrial piping-system approval, ISO 15493 requires regression analysis of creep rupture data, but for non-piping manifolds many end users accept a 1 000 h sustained-pressure test at 95 °C as a substitute. Thread retention in production components is measured as insertion torque for metal fittings at 2.0 N·m for 1/8 inch BSPP and 4.5 N·m for 1/4 inch BSPP; an unconditioned PA12 GF50 boss may crack at the outermost thread root if torque exceeds 6.0 N·m. Oil-mist compatibility is acceptable with mineral compressor lubricants, but phosphate ester or polyol ester synthetic oils can plasticize the amide matrix and reduce glass-resin interfacial shear strength. Terminal products include 1/8 inch-to-1/2 inch ported valve bodies, vacuum generator blocks, and silencer housings.

    Substitution of bronze wear rings in a split-case centrifugal pump exposes the PA12 GF50 component to near-continuous contact with a rotating shaft sleeve and to waterborne abrasive fines. The 50 wt% glass loading increases dry surface hardness to 150–170 N/mm² ball indentation hardness per ISO 2039-1, while reducing dry density to 1.44–1.47 g/cm³ per ISO 1183-1 and thereby cutting the rotating mass of the ring assembly. For a clearance of 0.25–0.35 mm between ring and sleeve, the saturated water uptake of PA12 is 0.8–1.1 wt% per ISO 62; this causes a radial swell that must be accounted for by machining the injection-moulded blank after conditioning at 70 °C in water for 48 h. In a 25 mm cross-section ring, cooling time from a melt temperature of 260 °C to a demoulding temperature of 140 °C is 4–6 min, and an uncontrolled cooling rate may generate an amorphous skin over a crystalline core, leading to post-machining distortion. The moulded blank is typically turned with polycrystalline diamond tools at a surface speed of 200–250 m/min and a feed of 0.05–0.10 mm/rev; sharp tungsten carbide is acceptable because glass fibres produce severe abrasive tool wear. The terminal wear ring is press-fitted into the pump casing with an interference of 0.05–0.10 mm and grooved to provide three axial pressure-balancing channels of 3 mm width. Continuous service above 95 °C in water reduces wear resistance because the glass-resin interface degrades via hydrolysis; exposure to sodium hypochlorite above 5 ppm accelerates surface attack, so this substitute is reserved for closed-loop industrial water, not chlorinated potable distribution. Published data on abrasive wear rates for PA12 GF50 in sand-laden water are limited; pump retrofit validation therefore requires a Taber abrasion baseline per ISO 9352 or a bespoke slurry test.

    When Hydraulic Cylinder Guide Rings Are Moulded in PA12 GF50 Instead of Glass-Filled Phenolic

    When a hydraulic cylinder guide ring is converted from machined glass-filled phenolic to PA12 GF50, the key process conflict is balancing the lubricity of the polyamide matrix against the abrasive character of the 50 wt% glass fibres. The glass reinforcement lowers the dynamic coefficient of friction against a hard-chromed piston rod to 0.20–0.30 under grease-lubricated conditions, but exposed fibres can polish the rod surface if the moulded ring is not machined to create a resin-rich sliding layer. Production tooling uses a film gate at the outer circumference to orient fibres circumferentially, and a post-moulding annealing step at 120 °C for 2 h under nitrogen reduces residual stress before final machining. The radial wall thickness is 2.5 mm for a 50 mm bore cylinder, with radial clearance of 0.2 mm on the rod and axial clearance of 0.3 mm in the retainer groove per ISO 3601-1 housing dimensions. Fitness for hydraulic service is assessed by immersion in a mineral hydraulic oil according to ISO 1817 at 80 °C for 168 h, with tensile property retention above 80% and hardness change below 5 Shore D points as per ISO 868. The component is not recommended for use with phosphate ester fire-resistant hydraulic fluids, because the ester swells the PA12 matrix and strips resin from the glass interface. Terminal parts include 40–100 mm bore cylinder guide rings, piston spacer bands, and shim rings.

    High-Voltage Connector Retainers: Dimensional Audit After 85 °C/85% RH Storage

    The dimensional audit of a PA12 GF50 retainer in a high-voltage industrial plug after 1 000 h at 85 °C and 85% RH demonstrates the value of a 50 wt% glass phase in resisting moisture-induced swelling. Unreinforced PA12 matrix can absorb 1.4–1.6 wt% water under such conditions, but the glass filler restricts saturated water uptake to 0.8–1.1 wt% per ISO 62, reducing post-ageing linear dimensional change to 0.04–0.06% in the flow axis. This is critical because the retainer must maintain a 0.15 mm snap-fit engagement with a nickel-plated copper contact. The compound is processed at a melt temperature of 250–270 °C, and the tool is held at 80–100 °C with conformal cooling near the crimp-barrel seat to control differential shrinkage; sections thicker than 4 mm require a pack pressure of 600–800 bar for 8–12 s to eliminate internal voids. Electrical acceptance is verified on 2 mm dry plates after ageing at 23 °C and 50% RH: volume resistivity per IEC 60093 is 10¹⁰–10¹² Ω·m, and comparative tracking index per IEC 60112 is commonly in the 500–600 V range, though the glass-rich surface can produce local tracking if contaminated with conductive dust. Unmodified PA12 GF50 is classified HB under UL 94; applications requiring V-2 or V-0 must switch to a flame-retarded heat-stabilised subgrade, and the addition of red phosphorus flame retardants may reduce CTI. Terminal products include 600 V-class modular connector retainers, cable strain-relief bodies, and insulated busbar supports.

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    Certification & Compliance
    More Introduction

    The product class identified as Overview of materials for Nylon 12, 50% Glass Fiber Filled is a short-glass-fibre-reinforced compound based on polylaurolactam (PA12) with a nominal filler loading of 50 wt% E-glass fibre. The material model is a generic class within ISO 1874, designated PA12, GF50; commercial supplier grades vary by colour, heat stabilization, and supplier-specific suffix. The primary specification distinction is filler mass fraction, determined after ignition by ISO 3451-1, with typical acceptance limits of 48–52 wt% ash. The compound is produced by compounding PA12 with silane-sized glass fibre in a co-rotating twin-screw extruder with side feeding to preserve fibre length. Published data for this specific configuration is limited to a small number of compounder technical data sheets; the values cited here are representative ranges and should be confirmed against the selected grade. The compound is specified for externally loaded housings, fluid connectors, impellers, sensor bodies, and structural brackets that require low moisture uptake, high creep resistance, and dimensional stability.

    What changes when the glass fibre content moves from 30% to 50%?

    The largest mechanical change is a sharp increase in stiffness and tensile strength, accompanied by loss of ductility. Representative dry as-moulded values for a 50 wt% glass-filled PA12 are 13,500 MPa tensile modulus and 165 MPa tensile stress at break under ISO 527-2, compared with approximately 8,500 MPa and 120 MPa for a 30 wt% glass-filled grade. Elongation at break falls from roughly 3.0–5.0% to 2.0–3.5%. Notched impact strength under ISO 179/1eA drops to approximately 12–16 kJ/m², making the material more notch-sensitive than lower-filler grades. Heat deflection temperature at 1.8 MPa under ISO 75-2/A rises to approximately 170–175°C, roughly 15–25°C higher than a 30% glass-filled PA12. Melt flow is also reduced: melt volume-flow rate at 235°C/5 kg under ISO 1133-1:2022 is typically below 10 cm³/10 min, compared with 20–40 cm³/10 min for lower-filler compounds. Weld-line tensile strength is commonly 45–55% lower than bulk tensile strength because of fibre orientation perpendicular to the flow front; this can be measured with a double-gated tensile specimen under ISO 527-2.

    Glass fibre orientation produces anisotropic shrinkage and mechanical response. Mould shrinkage measured after 48 h at 23°C under ISO 294-4 typically ranges from 0.15% parallel to flow to 0.45% perpendicular at 2 mm wall thickness. Tensile specimens cut at 90° to flow direction show 30–40% lower strength than parallel specimens. Gate position and melt front split lines must therefore be placed outside load-bearing regions, and mould-filling simulation should include fibre orientation tensors rather than assuming isotropic properties. The increase in filler from 30% to 50% also raises compound viscosity, intensifies screw and mould abrasion, and may reduce flow length by 20–30% in thin sections.

    Melt processing constraints and screw wear in GF50 PA12

    The dominant processing risk is moisture-induced hydrolysis. Sealed containers should be opened only at ambient temperature. Desiccant drying at 80°C for 4–8 h with a dew point of ≤ -30°C is typical; residual moisture should be held at ≤ 0.10 wt% measured by ISO 15512:2019 or Karl Fischer titration. Barrel temperatures are commonly set from 230°C in the rear zone to 260°C at the nozzle, with melt temperature measured by pyrometer not exceeding 280°C to limit oxidation of the PA12 matrix. Mould temperature should be 60–80°C to achieve sufficient crystallinity and dimensional stability; lower mould temperatures reduce heat deflection temperature and can increase post-mould shrinkage. The compound’s low melt flow requires medium-to-high injection speed, screw back pressure of 0.5–1.5 MPa, and gate diameters of at least 60% of wall thickness. Because of abrasive glass fibre, a bimetallic barrel, hardened screw, and wear-resistant check ring are specified, with a compression ratio of 1.8:1–2.0:1 and an L/D ratio of 18:1–22:1 for general-purpose screws. Hold pressure is typically 50–80 MPa and should be set by gate seal studies; insufficient hold pressure produces microporosity at the gate region and increases part-to-part mass variation. Published data for this specific configuration indicates that batch-to-batch fibre length distribution can shift tensile modulus and MVR; incoming lot control should compare ash content under ISO 3451-1 and melt volume-flow rate under ISO 1133-1:2022.

    When dimensional stability in humid or chemical environments controls design

    The reason this grade is selected over a 50% glass-filled PA66 is the lower water uptake of the PA12 matrix. Water uptake in a 50% glass-filled compound is reduced in proportion to filler content; a representative saturated value for PA12 GF50 is 0.8–1.2% under ISO 62, compared with approximately 5.0–6.5% for a 50% glass-filled PA66. At 23°C/50% RH, the conditioned PA12 composite absorbs roughly 0.4–0.6% moisture. Lower moisture absorption means less matrix plasticization, less dimensional change, and better retention of tensile modulus in humid service. Tensile modulus decline from dry to conditioned is typically 15–25% for PA12 GF50, compared with 25–40% for PA66 GF50. This is critical for close-tolerance pump impellers, pneumatic valve bodies, fuel line connectors, and electrical sensor housings. The PA12 matrix also provides good resistance to aliphatic hydrocarbons, diesel fuel, hydraulic oils, greases, zinc chloride solutions, and many alcohols; it is unsuitable for concentrated mineral acids, phenols, and some halogenated organic solvents. Glass fibre does not alter matrix solubility, but it can accelerate interfacial attack in hot aqueous glycol mixtures above 120°C.

    PropertyTest methodPA12 GF50PA12 GF30PA66 GF50
    DensityISO 1183-1:20191.54 g/cm³1.28 g/cm³1.56 g/cm³
    Tensile modulusISO 527-213,500 MPa8,500 MPa16,000 MPa
    Tensile stress at breakISO 527-2165 MPa120 MPa200 MPa
    Elongation at breakISO 527-22.5%4.0%3.0%
    Flexural modulusISO 178:201912,000 MPa8,000 MPa14,000 MPa
    Notched Izod impactISO 180/A13 kJ/m²15 kJ/m²11 kJ/m²
    Heat deflection temperature at 1.8 MPaISO 75-2/A172°C150°C250°C
    Water absorption at saturationISO 621.0%1.4%5.5%

    Following the comparative data, the principal differences from other products become clear. A 50% glass-filled PA12 is lower in density and water absorption than a 50% glass-filled PA66, but it also has lower tensile modulus, lower tensile strength, and lower heat deflection temperature at 1.8 MPa. Compared with a 30% glass-filled PA12, the 50% grade provides higher stiffness and HDT but lower elongation, lower impact, reduced melt flow, and greater mould abrasion. Compared with higher-temperature semicrystalline compounds such as PPS GF50, PA12 GF50 has a lower continuous service temperature but offers higher elongation, lower density, and easier melt processing. The selected grade should therefore be justified by the service environment: where moisture resistance and dimensional stability dominate over maximum dry strength, PA12 GF50 is preferred; where dry stiffness and short-term heat resistance dominate, PA66 GF50 may be more suitable.

    When regulatory compliance is evaluated, standard black grades are typically declared compliant with REACH and RoHS Directive 2011/65/EU Annex II, but declarations are grade-specific. Food-contact and medical uses require verification against EU 10/2011 or FDA 21 CFR 177.1500; glass fibre sizing may contain organosilane processing aids that are not automatically cleared. Published data for fatigue and creep of this exact configuration is limited; design loads involving cyclic stress should be based on grade-specific SN curves rather than monotonic tensile values. Long-term hot-water or hot-glycol exposure above 120°C may degrade the glass-matrix interface and reduce tensile strength before the PA12 matrix itself reaches chemical equilibrium.

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