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Overview of materials for Nylon 12, 20% Glass Fiber Filled

    • Product Name: Overview of materials for Nylon 12, 20% Glass Fiber Filled
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 412338
    Density 1.23 g/cm³
    Water Absorption 0.25%
    Tensile Strength 90.0 MPa
    Tensile Modulus 7.50 GPa
    Elongation At Break 3.0%
    Flexural Strength 130.0 MPa
    Flexural Modulus 6.50 GPa
    Izod Impact Notched 50.0 J/m
    Melting Point 178.0 °C
    Heat Deflection Temperature At 1 82 Mpa 165.0 °C
    Coefficient Of Linear Thermal Expansion 5.0e-5 /°C
    Electrical Resistivity 1.0e14 Ohm-cm

    As an accredited Overview of materials for Nylon 12, 20% Glass Fiber Filled factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Nylon 12, 20% glass fiber filled resin supplied as pellets in moisture-resistant polyethylene-lined paper bags, 25 kg net per bag.
    Container Loading (20′ FCL) Nylon 12 with 20% glass fiber loaded in a 20′ FCL, packed in sealed bags on pallets, weight-optimized, requiring dry, ventilated container.
    Shipping Ship as non-hazardous plastic granules in sealed, moisture-proof bags or drums. Avoid compression and excessive heat. Store dry, away from ignition sources. Label as "Nylon 12, 20% Glass Fiber Filled" with proper documentation. No special transport restrictions, but ensure containers are intact to prevent contamination and exposure.
    Storage Store in a cool, dry area, ideally below 25°C (77°F), in original sealed packaging to prevent moisture absorption, which degrades mechanical properties. Avoid direct sunlight, UV exposure, and high humidity. Keep away from heat sources, sparks, and incompatible chemicals. Use within recommended shelf life to ensure optimal performance.
    Shelf Life Shelf life is indefinite when stored dry, sealed, and away from UV light; moisture absorption can degrade properties.
    Application of Overview of materials for Nylon 12, 20% Glass Fiber Filled

    Across automotive evaporative emissions hardware, 20 wt% glass fibre-reinforced PA12 is injection moulded into fuel quick-connect coupling bodies, fuel sender flanges and vapour canister brackets where the reinforcement trades some unfilled PA12 ductility for lower creep under clamp load. The material is dried to a residual moisture of not more than 0.10% by weight as measured by ISO 15512, typically in a desiccant dryer with a dew point of -40°C or lower and an 80°C air stream for 4 h to 8 h. Production-scale injection machines in the 800 kN to 1,600 kN clamp force range run barrel zone set points from 240°C to 270°C with a core-cooled tool at 80°C to 100°C. The barrel is equipped with a hardened check ring and bimetal barrel lining because the short glass fibres raise screw-tip and non-return-valve wear rates, producing shot-weight drift when the cushion position is not monitored. The shot size is held between 40% and 65% of barrel capacity because a partially filled screw yields inconsistent fibre distribution and a fully filled screw leaves no smoothing of the melt buffer. Because the fibres align along the fill stream, mould shrinkage measured to ISO 294-4 is typically 0.2% to 0.4% in the flow direction and 0.6% to 0.8% transverse to flow, so the tool geometry is not cut as a uniform-scale reproduction of the part print. The gate is located on a non-sealing surface; the melt meeting line around the core pin is pushed away from the O-ring groove and retainer finger roots because that knit line is the principal leak path. Component validation is run with the surrogate test fuels of SAE J1681, including fuel C and ethanol blends, while assembly-level quick-connector pull-off, leak, vibration and corrosion requirements follow the SAE J2044 performance envelope. Melt residence time is held below 8 min wherever possible and screw speed is capped at 150 rpm for a 20:1 to 24:1 L/D screw, because polyamide 12 degrades by hydrolysis and thermal chain scission when the melt is kept hot with residual moisture. The glass content does not remove the need for dry handling; post-moulding moisture conditioning to 0.6% to 1.0% by weight is recorded before pull-off testing because moisture affects glass transition and retention force.

    Where Does 20% Glass-Reinforced PA12 Replace Metal in Pneumatic Push-In Fittings?

    The principal material demand in compressed-air push-in fittings is not continuous load-bearing strength but retention of the collet anchoring detail after repeated tube insertion and withdrawal cycles. Under ISO 14743, the fitting is tested as an assembly with the specified thermoplastic tubing; the glass-reinforced PA12 body must hold the locking collet, seal ring and release sleeve without cracking at the sharp internal groove transitions where stress concentration is highest. Moulding practice for these parts uses a hot-runner tool with generous flow channels in the runner drop to prevent stagnation; a barrel temperature of 250°C to 280°C, a tool temperature of 70°C to 90°C and a metering zone residence time below 6 min are common. The 20 wt% glass content raises the hoop stiffness of the internally threaded or cartridge-style body, which reduces diametral expansion under repeated pressurisation, but it also produces a measurable fibre orientation pattern at thread roots that can lower local elongation at break. For this reason, sharp V-thread roots are replaced by rounded root profiles or buttress variants when glass-filled PA12 is substituted for brass. Published processing guides for glass-reinforced PA12 recommend a nominal wall thickness of 1.5 mm to 4.0 mm, and thin sections below that range are avoided because the glass fibres shorten the melt flow path relative to unfilled PA12. Pneumatic circuit assemblies are typically qualified for leakage at 1.0 MPa air pressure and for pull-out resistance after specified insertion cycles, but the pass value is tube-size-dependent and appears in the OEM specification rather than in a single material standard. Drying to 0.10% moisture or less, checked by ISO 15512, is mandatory because water vapour in the melt hydrolyses polyamide 12 and reduces weld-line integrity. The grade also appears in hose-barb couplings for air suspension lines where road-induced vibration demands higher fatigue endurance than unfilled polyamide 12, though the exact improvement is geometry-specific and is verified on hydraulic servo-pulser test stands at 5 Hz to 20 Hz according to OEM protocols.

    Within low-speed gear trains for office automation and light industrial actuators, 20% glass-reinforced PA12 replaces die-cast zinc gear wheels where corrosion, noise or lubricant-free running dominates the specification. Gear design is not carried out by direct metal substitution; VDI 2736 is used for tooth-root stress, flank temperature and wear calculation, and the glass-reinforced grade requires a larger root fillet radius, typically not less than 0.4 to 0.5 times the module, because the reinforcement decreases ductility and increases notch sensitivity at the root. Injection moulding is performed on a two-platen hydraulic press with clamp force in the 1,200 kN to 2,400 kN range, a 22:1 to 26:1 L/D screw, and a melt temperature of 250°C to 275°C; tool temperature is set at 60°C to 80°C to promote rapid solidification but high enough to prevent excessive surface skin formation that freezes fibre orientation before packing. The cavity is typically gated from the gear hub or centre, producing a radial fibre orientation that improves hoop strength but leaves a knit line at the rim if spokes or lightening holes are present; that knit line is a frequent batch-to-batch failure origin when tooth load is applied opposite the gate. Moisture conditioning after moulding is part of dimensional acceptance because polyamide 12 reaches an equilibrium water content of approximately 0.6% to 1.0% at 23°C and 50% relative humidity when measured by ISO 62, and tooth backlash can close if a dry-machined or dry-moulded gear later absorbs plant humidity. Typical tensile modulus for the dry-as-moulded compound falls in the 4,000 MPa to 5,500 MPa range and flexural modulus near 3,800 MPa to 4,300 MPa under ISO 527-2 and ISO 178, but actual load-bearing capacity in a gear depends on PV conditions, lubricating film and duty cycle; published data for a specific gear geometry is limited. Operational limits for dry-running PA12 GF20 are frequently set below 0.1 MPa·m/s PV in continuous mesh, and the part is derated when ambient temperature rises above 60°C because the glass transition of PA12 is near 45°C as measured by dynamic mechanical analysis to ISO 6721. Regrind content is usually limited to 10% to 20% by weight because repeated shearing shortens the fibre below the critical length needed for effective load transfer, and the resulting notch-sensitivity shift is not acceptable for high-cycle gear teeth.

    Downstream segmentMelt temperatureTool temperatureDryer dew pointResidual moistureScrew L/DProcess control emphasis
    Fuel quick-connector bodies240°C to 270°C80°C to 100°C-40°C or lower<0.10%20:1 to 24:1Knit line off sealing surfaces
    Pneumatic push-in fittings250°C to 280°C70°C to 90°C-40°C or lower<0.10%18:1 to 22:1Hot runner without stagnant zones
    Low-speed gear wheels250°C to 275°C60°C to 80°C-40°C or lower<0.10%22:1 to 26:1Centre gate and radial fibre orientation
    Medical housings240°C to 260°C90°C to 110°C-50°C or lower<0.08%19:1 to 23:1Anneal after moulding
    Sports load-bearing shells250°C to 270°C70°C to 100°C-40°C or lower<0.10%20:1 to 24:1Gate away from bending axis

    When Medical Device Enclosures Require Annealed Dimensional Stabilisation

    Because the glass fibres orient during filling, the coefficient of linear thermal expansion in the flow direction is lower than in the transverse direction; the difference is quantified by ISO 11359-2 thermomechanical analysis on plaques cut from the moulding. Annealing in a circulating-air oven at 120°C to 130°C for 2 h to 4 h is therefore applied to relax frozen-in orientation before critical bores and snap-fit features are machined or inspected. The 20 wt% glass-filled PA12 is intended for surgical instrument handles, diagnostic equipment housings and laboratory automation brackets, not for implantable or long-term blood-contact applications. Biocompatibility evaluation is conducted at the finished-part scale, normally including cytotoxicity testing to ISO 10993-5; when ethylene oxide sterilisation is used, residual ethylene oxide is assessed to ISO 10993-7 under the manufacturer's sterilisation validation protocol. Suppliers may declare master-batch or polymer-level conformity to USP Class VI, but that certification is for the resin formulation and does not replace device-level testing. Drying requirements are tighter than in industrial moulding: residual moisture below 0.08% by weight, measured by ISO 15512, is maintained through a floor-mounted desiccant dryer with a dew point of -50°C or lower. Where multi-cavity tools are used, cavity-to-cavity filling imbalance shifts the knit line; shot-to-shot cushion monitoring and per-cavity pressure transducers are recommended when the housing contains snap-fit latches. Steam autoclaving at 121°C is feasible only for limited cycles because polyamide 12 undergoes hydrolytic degradation in saturated steam above approximately 80°C; hydrogen peroxide plasma or ethylene oxide is generally preferred for this material system. Dimensional acceptance is verified at 23°C and 50% relative humidity after conditioning, and flexural modulus is measured on dry-as-moulded test bars to ISO 178, where supplier bulletins cite values of 3,800 MPa to 4,300 MPa. The glass reinforcement creates a matte, fibre-reinforced surface that is difficult to polish to a high gloss, so parts requiring cosmetic smoothness are textured or overmoulded with unfilled PA12.

    Application segmentStandard or methodProperty or conditionData generated
    Fuel quick connectorsSAE J2044Assembly pull-off, leak, corrosionAssembly-specific pass values
    Fuel material conditioningSAE J1681Surrogate test fuel ageingAged mechanical retention
    Pneumatic push-in fittingsISO 14743Burst, leakage, tube retentionTube-size dependent
    Low-speed gear trainsVDI 2736Tooth-root stress, flank temperature, wearGeometry-specific design curves
    Medical housingsISO 10993-5, ISO 10993-7Cytotoxicity, ethylene oxide residualDevice-level batch data
    Sports componentsISO 179-1/1eANotched Charpy at -20°CLot release impact values
    Electrical componentsIEC 60112, UL 746BComparative tracking index, RTIGrade-specific Yellow Card data

    In injection-moulded bicycle clipless pedal bodies and snowshoe deck frames, the 20% glass loading is selected as a middle point between the high stiffness of 30% glass grades and the low-temperature ductility of unfilled PA12. The moulding is gated away from the cleat engagement edge; mould-filling analysis is used to position the knit line away from the bending axis because weld-line strength in glass-filled PA12 is the dominant failure origin in cold impact. Notched Charpy impact is tested at -20°C to ISO 179-1/1eA after conditioning at laboratory temperature and again after cold soak; the numerical value for lot release is set by the OEM because moisture level, fibre orientation and gate position shift the result by more than 10% between production tools. The material is dried to 0.10% moisture by weight before moulding, with moisture verification by ISO 15512. Screw speed is limited to 100 rpm to 150 rpm to reduce fibre length reduction; back pressure is kept in the 0.3 MPa to 0.7 MPa range to avoid excessive shear heating. A typical moulding cycle uses a melt temperature of 250°C to 270°C and a tool temperature of 70°C to 100°C; the lower end of the mould-temperature range is used for fast cycle times, while the upper end improves knit-line strength. Fatigue testing for pedal bodies is performed on a servo-hydraulic fixture simulating cleat release cycles at 1 Hz to 3 Hz; published data for PA12 GF20 in this specific geometry is limited, so life targets are established by comparison with control lots. Taber abrasion testing with CS-17 wheels under ASTM D4060 reveals early fibre bloom on exposed surfaces; designs that require a uniform appearance use a textured cavity surface or a thin unfilled PA12 overmould.

    Cable Gland and Terminal Box Mouldings Under IEC 60112 Tracking Stress

    Designers specifying 20% glass-reinforced PA12 in electrical enclosures face a trade-off between dimensional stability and surface-tracking performance. The glass reinforcement raises the flexural modulus and permits thinner wall sections than unfilled PA12, but it also introduces glass-resin interfaces that can promote surface erosion under electrical stress. Comparative tracking index is determined according to IEC 60112 using Test Solution A; for many glass-reinforced polyamide 12 grades, supplier Yellow Card data cite CTI values in the 500 V to 600 V range, although exact values are grade-specific and must be verified for the specific masterbatch. Dielectric strength is measured on 2.0 mm plaques according to IEC 60243-1; the presence of glass fibres lowers the breakdown value relative to unfilled PA12, so creepage and clearance distances are designed to IEC 60664-1 pollution degree 2 with a material group assignment taken from the CTI result. Unless a flame-retardant variant is specified, the base glass-filled PA12 is normally UL 94 HB; flame-retardant modification alters CTI and requires re-qualification. Outdoor cable glands and terminal boxes in rail or renewable-energy installations are typically tested for water immersion and humid heat; PA12 absorbs less water than PA6, but fibre bundles can wick moisture along the polymer-glass interface when the gate or machining operation exposes fibres at a sealing face. For this reason, overmoulded elastomer seals, hot-melt sealing of exposed machining surfaces, or a generously radiused gate vestige are used. Moulding uses a melt temperature of 240°C to 260°C and a tool temperature of 80°C to 100°C; drying to 0.10% residual moisture is required. Long-term thermal ageing is assessed by UL 746B RTI; typical published RTI mechanical values for glass-filled PA12 fall between 80°C and 100°C, but the exact value is grade-specific. The material is not recommended for continuous service above 1,000 V or in unprotected outdoor sealing faces with wetting cycles, and it is generally limited to low- and medium-voltage accessory components rather than primary insulation.

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    Certification & Compliance
    More Introduction

    PA12-GF20 is a semi-crystalline thermoplastic compound consisting of polyamide 12 resin reinforced with 20% by mass E-glass fibre. No single commercial model is implied; the generic material designation is PA12-GF20 under ISO 1874-1, and commercially supplied grades may contain heat stabilisation, lubricant packages, nucleating agents, or carbon black pigmentation. The glass fibre is incorporated by melt compounding on twin-screw extruders with an L/D ratio of 40:1 or higher, typically using side-fed chopped strands or roving to preserve fibre aspect ratio after pelletising. The PA12 matrix is synthesised from laurolactam or ω-aminododecanoic acid, producing a lower amide density than PA6 or PA66, which reduces equilibrium moisture uptake and contributes to dimensional stability in humid service environments.

    Why Does 20% Fibre Loading Shift the Mechanical Response of Polyamide 12?

    Reinforcement at 20% by mass introduces a discontinuous glass-fibre load-transfer phase that increases stiffness while suppressing post-yield ductility. For dry-as-moulded specimens at 23 °C, tensile modulus measured to ISO 527-2 using a type 1A test specimen at 5 mm/min is typically 45005500 MPa, compared with 13001600 MPa for unreinforced PA12. Tensile stress at break falls between 90 and 110 MPa, while elongation at break drops to 24%, indicating a brittle failure mode controlled by fibre debonding and matrix cracking. Flexural modulus under ISO 178 is generally 40005000 MPa. Charpy notched impact strength under ISO 179-1/1eA is commonly 812 kJ/m² for dry specimens; conditioned values at 23 °C and 50% RH are typically higher because moisture plasticises the PA12 matrix. These properties are anisotropic in moulded parts, as fibre orientation parallel to flow produces higher tensile stiffness than transverse or through-thickness directions.

    PropertyTest methodUnitRepresentative range dry-as-moulded
    DensityISO 1183-1g/cm³1.221.24
    Tensile modulusISO 527-2MPa45005500
    Tensile stress at breakISO 527-2MPa90110
    Elongation at breakISO 527-2%24
    Flexural modulusISO 178MPa40005000
    Charpy notched impact strengthISO 179-1/1eAkJ/m²812
    Heat deflection temperature at 1.8 MPaISO 75-2°C160170
    Mould shrinkage parallel to flowISO 294-4%0.20.4
    Water absorption after 24 hISO 62%0.60.7

    Predrying is mandatory for PA12-GF20 because residual moisture above 0.1% by mass can hydrolytically degrade the polymer during melting and lower molecular weight. A desiccant dryer set at 80 °C for 46 h with a dew point of -30 °C or lower is used in production. Barrel temperature profiles from rear to nozzle generally span 220250 °C; melt temperature should not exceed 270 °C to avoid thermal decomposition, while mould temperature is maintained at 4080 °C. Higher mould temperatures improve surface gloss and glass-fibre wet-out but extend cycle time and increase mould shrinkage anisotropy. A general-purpose injection screw with L/D ratio 18:122:1 and compression ratio 2:12.5:1 is acceptable, although wear-protected screw and barrel assemblies are advised because glass fibre accelerates abrasive wear. Clamp force requirements are typically 68 kN per cm² of projected part area for thin-wall parts.

    Moisture Uptake, Dimensional Stability, and Conditioning Protocols

    Under ISO 62, PA12-GF20 absorbs approximately 0.60.7% water by mass after 24 h immersion. Saturation in water at 23 °C is usually 1.52.0%, significantly below PA6-GF20 grades that typically reach 46% at saturation. This lower water uptake derives from the longer aliphatic repeat unit and reduced amide concentration of PA12. Dimensional change after moisture absorption is anisotropic because glass fibres constrain linear expansion; mould shrinkage under ISO 294-4 is commonly 0.20.4% parallel to flow and 0.30.5% perpendicular to flow. Parts requiring tight post-mould tolerances are conditioned at 23 °C and 50% RH before dimensional inspection; assemblies fitted with dry-as-moulded PA12-GF20 components can exhibit small but measurable dimensional growth after exposure to humid air. Pre-drying is not a substitute for conditioning when the application is humidity-sensitive.

    When PA12-GF20 Is Compared With PA12-GF30 and PA6-GF20

    Selection between PA12-GF20 and PA12-GF30 requires a trade-off between stiffness, impact resistance, density, and warpage. The 30% glass-filled variant typically raises tensile modulus to 65008000 MPa and tensile stress at break to 110130 MPa, but it also increases density to 1.281.32 g/cm³ and reduces notched Charpy impact strength to approximately 710 kJ/m². Fibre orientation-induced shrinkage differentials are more pronounced in the 30% grade, increasing the risk of warpage in flat or slender mouldings. Against PA6-GF20, PA12-GF20 offers lower density, lower moisture absorption, and better resistance to zinc chloride and aliphatic hydrocarbon environments; however, PA6-GF20 typically provides higher dry tensile strength in the 130150 MPa range and a higher melting point of approximately 220 °C. PA6-GF20 also tends to have higher heat deflection temperature, but its mechanical properties are more sensitive to moisture conditioning than those of PA12-GF20.

    Thermal and Electrical Properties Remain Stable Within a Defined Operating Window

    Heat deflection temperature at 1.8 MPa under ISO 75-2 is commonly 160170 °C for PA12-GF20; at 0.45 MPa, values commonly reach 175180 °C. The crystalline melting temperature measured by differential scanning calorimetry to ISO 11357-3 is generally 175180 °C. Continuous service temperature in air is normally 80120 °C depending on antioxidant package, load level, and exposure duration; published data for this specific configuration is limited above 120 °C, and oxidative embrittlement can occur when stabilisers are consumed. Volume resistivity under IEC 62631-3-1 is typically 10^1310^14 ohm·m for natural grades. Surface resistivity under IEC 62631-3-2 is commonly 10^1210^13 ohm. Comparative tracking index under IEC 60112 is frequently 600 V for unfilled or lightly pigmented variants, but carbon black or flame-retardant additives may reduce the value. Flammability of generic PA12-GF20 is typically HB at 1.5 mm under UL 94; V-0 classifications require specific flame-retardant formulations and are not inherent to the base glass-filled compound.

    Chemical resistance is governed by the PA12 matrix rather than the glass phase. The material resists fuels, lubricating oils, greases, hydraulic fluids, and aliphatic hydrocarbons at service temperatures below 80 °C. Strong acids, polar solvents, and zinc chloride solutions attack PA12, and low-molecular-weight alcohols can induce environmental stress cracking in stressed mouldings with high fibre orientation. Glass fibre addition raises heat deflection temperature but does not substantially broaden the chemical resistance envelope of the base polymer. Exposure to hot salt spray or pressurised fuel requires specific part-level validation because generic PA12-GF20 does not carry universal chemical resistance approval.

    Regulatory areaReference standard or regulationEvaluation basisScope limitation
    Hazardous substances restrictionRoHS Directive 2011/65/EU, Annex IIXRF screening and wet chemical verification to IEC 62321Grade-specific; requires supplier declaration
    Chemical safetyREACH Regulation (EC) No 1907/2006, Article 33SVHC concentration and communication obligationsSupplier-specific; not a material property
    Food contactRegulation (EU) No 10/2011Overall migration to EN 1186Only designated food-contact grades
    Medical device biocompatibilityISO 10993-5In vitro cytotoxicity testingGrade- and extraction-ratio dependent

    What Production Applications Use PA12-GF20 Within Its Validated Envelope?

    PA12-GF20 is processed into pneumatic and fuel line connectors, cable ties, electrical connector housings, sensor brackets, and structural clips where low moisture uptake, chemical resistance, and moderate stiffness are required. In fuel line connectors, injection gate placement must orient glass fibres along the primary tensile load path; gas entrapment at fibre-rich knit lines can reduce burst strength by 2030% relative to gate-aligned regions. Short shots are observed in production when wall sections fall below 1.0 mm and barrel temperature remains below 230 °C. For automotive clips exposed to thermal cycling, part-level validation under ISO 16750 is used to confirm retention force after conditioning. Electrical connector housings benefit from the material’s low moisture uptake, but comparative tracking index and flammability must be re-evaluated for each pigmented or flame-retarded grade. Applications requiring sustained contact with pressurised fuel, hot salt spray, or strong polar fluids require additional validation because generic PA12-GF20 does not possess universal chemical resistance approval.

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