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Ordos Energy Chemical LLDPE 7042

    • Product Name: Ordos Energy Chemical LLDPE 7042
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 558003
    Product Name Ordos Energy Chemical LLDPE 7042
    Manufacturer Ordos Energy Chemical Co., Ltd.
    Grade 7042
    Polymer Type Linear Low-Density Polyethylene (LLDPE)
    Density 0.918-0.922 g/cm³
    Melt Flow Rate 190 C 2 16 Kg 1.7-2.3 g/10 min
    Tensile Strength At Yield ≥8 MPa
    Tensile Strength At Break ≥17 MPa
    Elongation At Break ≥500%
    Vicat Softening Temperature ≥90 °C
    Brittleness Temperature ≤-60 °C
    Melting Point 120-125 °C
    Film Haze ≤15%
    Film Gloss ≥70%
    Film Impact Strength ≥80 g

    As an accredited Ordos Energy Chemical LLDPE 7042 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Ordos Energy Chemical LLDPE 7042 comes in 25 kg woven bags, palletized, or 500–1,000 kg jumbo bags.
    Container Loading (20′ FCL) Ordos Energy Chemical LLDPE 7042: 20′ FCL loading, 25 kg bags, typically 25 MT per container, securely stowed and sealed for export.
    Shipping Ordos Energy Chemical LLDPE 7042 ships as a non-hazardous polymer resin, typically in 25 kg bags or 500/1000 kg jumbo bags, palletized and stretch-wrapped. Transport as general cargo. Store cool, dry, ventilated, away from sunlight, moisture, and heat; use clean equipment to avoid contamination.
    Storage Store Ordos Energy Chemical LLDPE 7042 in a cool, dry, well-ventilated warehouse, away from direct sunlight, heat, sparks, flames, and oxidizing agents. Keep original packaging sealed and palletized off the floor to prevent moisture, dust, and contamination. Avoid prolonged UV exposure and extreme temperatures. Maintain clean handling areas and rotate stock first-in, first-out. Ensure good ventilation and avoid damaging bags.
    Shelf Life Ordos Energy Chemical LLDPE 7042: store cool, dry, away from direct sunlight; typical shelf life 12–24 months in unopened packaging.
    Application of Ordos Energy Chemical LLDPE 7042

    Where blown-film flexible packaging requires a balance between dart impact, tear propagation resistance, and stable bubble geometry, Ordos Energy Chemical LLDPE 7042 is processed as a major blend component rather than a monolayer resin. The grade is characterized by a butene-comonomer short-chain branch distribution and an MFR of 2.0 g/10 min at 190°C/2.16 kg per ISO 1133-1:2022, with density 0.920 g/cm³ per ISO 1183-1:2019. Compliance for direct food-contact use is governed by FDA 21 CFR 177.1520(c) 3.1a, EU Regulation 10/2011 Annex I with overall migration limits under EN 1186-1:2002, and GB 4806.7-2016 when converted for PRC market requirements. In production, 60–80 wt% LLDPE 7042 is dry-blended with 20–40 wt% high-pressure LDPE having an MFR of 1.8–2.2 g/10 min to stabilize frost-line height and increase melt strength; slip masterbatch is added at 0.5–1.0 wt% and antiblock masterbatch at 1.0–3.0 wt% depending on post-seal friction and blocking tendency. The blend is extruded on single-screw blown film lines with L/D ratios of 25:1 to 30:1 and barrier screws, through die gaps of 1.8–2.8 mm at blow-up ratios 2.0–3.0; melt temperatures are maintained between 190°C and 215°C, with frost-line height fixed at 8–12 die diameters. Output on 2500–3500 mm wide die lines typically ranges from 180 kg/h to 350 kg/h, while bubble stability becomes machine-specific above 350 kg/h on 3000 mm die circumference unless internal bubble cooling is used. Downstream finished products include food pouches, frozen food bags, produce bags, carrier bags, and internal liners for corrugated boxes where high dart impact and low gel count are specified.

    Why Does Quench Roll Temperature Govern Film Clarity and Tear Propagation in Cast Stretch Film?

    In cast pallet stretch film, LLDPE 7042 supplies puncture resistance and pre-stretch retention, but its process response is dominated by chill-roll thermal gradients rather than melt temperature alone. The relevant compliance set includes EU Regulation 10/2011 for food-adjacent logistics film, FDA 21 CFR 177.1520(c) 3.1a for incidental food contact in warehouse environments, ISO 527-3:2018 for tensile strength at break, and ASTM D5748-95(2019) for puncture resistance. A typical formulation uses 70–90 wt% LLDPE 7042 as the structural base, 10–20 wt% metallocene LLDPE to raise elongation at break, and 0.5–2.5 wt% polyisobutylene or hydrogenated hydrocarbon tackifier to adjust cling force; LDPE may replace up to 10 wt% of the 7042 fraction when higher melt strength is needed at low film thickness. On cast film lines with slot dies 2000–4000 mm wide, melt temperatures are held at 230–255°C, air gap is set between 20 mm and 50 mm, and quench roll temperature is controlled at 15–25°C; line speeds of 300–800 m/min are common for film thicknesses of 12–35 µm. The quench roll window is critical: surface temperature below 18°C can produce flow-mark haze and uneven gauge, while sustained temperature above 28°C reduces subsequent pre-stretch retention and increases unwind blocking in production-scale trials. Terminal products include machine-applied pallet wrap, hand stretch film, logistics center bundling film, and automated storage and retrieval system palletization film where consistent unwind force and edge toughness are acceptance criteria.

    Greenhouse Film Weathering Resistance, UV Stabilizer Loading, and the 200 µm Extrusion Window

    Agricultural transparent covering film is a distinct and substantive downstream segment for LLDPE 7042 because butene-branching provides a balance between low-temperature flexibility and bubble stability at high film thickness. Compliance for this segment is anchored to EN 13206:2017 for transparent covering films, including tensile and tear measurements after weathering exposure, while UV durability is evaluated under ISO 4892-2:2013 xenon-arc conditions and ASTM G154-16 fluorescent UV exposure. The formulation contains 50–70 wt% LLDPE 7042, 15–25 wt% EVA with vinyl acetate content 12–18%, 10–20 wt% high-pressure LDPE, 5–8 wt% UV stabilizer masterbatch based on hindered amine light stabilizers and benzotriazole absorbers, and 1–2 wt% anti-drip/anti-fog masterbatch. Downstream extrusion occurs on IBC-equipped blown film lines with die gaps of 1.8–2.4 mm, blow-up ratios 2.0–3.5, and melt temperatures 180–210°C; film thickness is typically 80–200 µm. The upper temperature boundary is not arbitrary: above 220°C the EVA phase can begin thermal decomposition with acetic acid odor and localized gel formation. Terminal product types include multi-season greenhouse cladding, low tunnel covers, and solarization films, with anti-drip persistence and UV lifetime as specification-critical properties.

    Compliance matrix by downstream segment
    Application segmentCompliance anchorTest method or clauseScope
    Blown-film food packagingFDA 21 CFR 177.1520(c) 3.1a; EU 10/2011 Annex IEN 1186-1:2002; GB 4806.7-2016Direct food-contact olefin film
    Cast stretch filmISO 527-3:2018; ASTM D5748-95(2019)Tensile strength at break; puncture resistanceStretch wrap mechanical acceptance
    Greenhouse covering filmEN 13206:2017ISO 4892-2:2013; ASTM G154-16Weathering and mechanical retention
    Heavy-duty sack filmISO 527-3:2018; ASTM D1709-16a; ASTM D1922-15Dart drop; Elmendorf tearIndustrial sack mechanical threshold
    Extrusion laminationISO 1133-1:2022; ASTM D2578-17MFR control; wetting tensionCoating-line feed quality

    Heavy-Duty Sack Film Output Falters When Melt Pressure Exceeds 380 bar

    In heavy-duty industrial sack production, LLDPE 7042 is combined with film-grade HDPE to increase modulus and creep resistance, but blending error becomes visible first as dart impact loss and bubble instability. The governing standards are ISO 527-3:2018 for tensile stress at break, ASTM D1709-16a for dart drop impact, and ASTM D1922-15 for Elmendorf tear. The formulation range is 65–85 wt% LLDPE 7042, 10–25 wt% HDPE with a density of 0.945–0.960 g/cm³, 5–15 wt% high-pressure LDPE, 0.3–1.0 wt% fluoroelastomer processing aid, and 2–4 wt% carbon black masterbatch when UV protection is required for outdoor storage. On high-stalk blown film lines with die diameters 250–600 mm, die gaps 2.0–2.5 mm, blow-up ratios 2.5–4.0, and melt temperatures 200–230°C, flat width typically reaches 1200–1800 mm at outputs of 250–400 kg/h. The operational limit is melt pressure before the screen changer: values above 380 bar on production lines indicate gel accumulation or incomplete dispersion of the HDPE fraction, and the resulting melt-fracture streaks can initiate tear propagation in the finished sack. Terminal products include fertilizer sacks, resin packaging sacks, mineral filler sacks, and construction waste liners where puncture resistance and filled-bag drop strength control end-user acceptance.

    In extrusion lamination of woven polypropylene fabrics, LLDPE 7042 is used only in blended form because its 2.0 g/10 min MFR produces higher draw resonance and higher neck-in than dedicated coating grades when run neat. The compliance set for this application includes ISO 1133-1:2022 for incoming MFR control, ASTM D1238-20 for comparative batch release, FDA 21 CFR 177.1520(c) 3.1a for food-contact outer ply construction, and REACH EC 1907/2006 for EU industrial chemical registration. The formulation uses 60–80 wt% LLDPE 7042 with 20–40 wt% LDPE coating-grade resin to reduce neck-in and improve draw-down; where adhesion to woven PP fabric is required, corona treatment of the substrate to 42–46 mN/m or an EVA-based tie layer of 10–15 µm is used. Downstream processing takes place on extrusion lamination lines with T-die bodies, melt temperatures 290–315°C, air gaps 100–150 mm, line speeds 100–250 m/min, and coating thicknesses of 15–30 µm. Published data for this specific configuration is limited because draw resonance is highly machine-specific; each line must be qualified by trial rather than by direct transfer of parameters from blown film operations. Prolonged residence time at 315°C increases gel build-up at die lips, and purge intervals of 72 h are reported as a practical upper limit in converting lines. Terminal product types include laminated PP woven sacks, paper-based flexible packaging, insulation facing laminates, and coated fabric intermediate bulk container liners.

    When LLDPE 7042 Coextrusion Replaces Single-Layer Structures in Frozen Food Packaging

    Three-layer frozen food packaging uses LLDPE 7042 in the outer layers where low-temperature toughness and acceptable seal initiation must be retained after exposure to −25°C storage conditions. The relevant compliance set includes FDA 21 CFR 177.1520(c) 3.1a, EU Regulation 10/2011 Annex I, ISO 527-3:2018, and ASTM D882-18 for thin-film tensile behavior. In a typical structure, the outer layers contain 55–75 wt% LLDPE 7042, 15–25 wt% high-pressure LDPE, and 1–3 wt% combined slip/antiblock masterbatch, while the core uses EVA with vinyl acetate content 12–18% to provide impact absorption and interlayer adhesion. The film is produced on three-layer blown film lines with die gaps 2.0–2.6 mm, blow-up ratios 2.2–3.2, melt temperatures 190–220°C, and outer-layer thickness ratios of 25–35% of total film thickness. Total finished film thickness is normally 40–90 µm. Operating outside the upper melt temperature limit increases gel formation in the 7042-rich outer layer, while operation below 190°C raises melt pressure and can reduce interlayer adhesion through lower weld-line temperature. Terminal products include frozen vegetable bags, ice cream outer-wrap, frozen seafood bags, and frozen bakery bags where puncture resistance, seal integrity, and visual clarity after freezing are specified by converters.

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    Certification & Compliance
    More Introduction

    Ordos Energy Chemical LLDPE 7042 is a butene-based linear low-density polyethylene extrusion grade supplied as free-flowing cylindrical pellets. The resin is produced by gas-phase copolymerization and is intended for blown film and cast film conversion. Nominal melt flow rate is 2.0 g/10 min under 2.16 kg at 190 °C per ISO 1133-1:2022, and nominal density is 0.918 g/cm³ per ISO 1183-1:2019. Batch-to-batch variation on production-scale continuous extrusion lines is normally controlled within ±0.2 g/10 min for melt flow rate and ±0.002 g/cm³ for density. The grade is differentiated from high-pressure LDPE film resins by the absence of long-chain branching and from metallocene LLDPE grades by a broader molecular weight distribution. It is commonly selected as a blend partner with LDPE or as a core layer in multilayer films where dart impact, tear propagation resistance, and drawdown are more critical than optical clarity.

    Resin Specification and Standardized Film Test Data

    Lot release for LLDPE 7042 is typically governed by melt flow rate, density, ash content, and pellet uniformity. The following values are representative for 25 µm monolayer blown film processed at a blow-up ratio of 2.4:1 and a frost line height of 30 mm; they are not intended as minimum or maximum acceptance limits.

    PropertyTest methodRepresentative valueUnit
    Melt flow rateISO 1133-1:20221.8–2.2g/10 min
    DensityISO 1183-1:20190.917–0.920g/cm³
    Tensile yield strength MDISO 527-3:201810–12MPa
    Elongation at break MDISO 527-3:2018600–800%
    Dart drop impactASTM D1709-16a Method A70–100g
    Elmendorf tear MDASTM D1922-09120–220g
    HazeASTM D1003-1310–15%

    Film property values are highly dependent on die gap, frost line height, and cooling air velocity. The tensile yield strength in the machine direction is generally 10–15% higher than in the transverse direction because of orientation effects during bubble stretching. Ash content is typically below 0.05 wt% when determined by ISO 3451-1:2019, and pellet bulk density is normally 0.52–0.56 g/cm³. These values influence screw feeding characteristics and hopper residence time distribution.

    On a 90 mm grooved-feed single-screw extruder with an L/D ratio of 30:1, barrel temperatures from 170 °C to 210 °C and adapter/die temperatures from 210 °C to 230 °C are commonly used for LLDPE 7042. The grooved feed section must maintain stable pellet slip. Die pressure fluctuations above 5% of nominal are usually traceable to feed throat temperature drift, worn screw elements, or regrind particle size variation. A die gap below 1.5 mm on conventional blown film dies can produce sharkskin at output rates above 180 kg/h, because the melt passes through the die lip at shear rates approaching the critical shear stress for butene-based linear low-density polyethylene. The replacement of a metering section with a Maddock mixer can reduce gel formation but requires an additional 10–15% drive torque.

    What Distinguishes Butene-Based 7042 from LDPE 2426H and Metallocene LLDPE Film Grades?

    LLDPE 7042 contains short-chain branches from butene comonomer and lacks the long-chain branching present in high-pressure LDPE 2426H. In comparative 25 µm blown film, LLDPE 7042 typically shows higher dart drop impact and Elmendorf tear strength than LDPE 2426H at equivalent melt flow rate, but lower melt strength. The lower melt strength narrows the bubble stability window and requires a lower blow-up ratio, typically 2.0:1 to 2.8:1 for 7042, compared with 2.5:1 to 3.5:1 for LDPE 2426H. Optical haze is generally higher for 7042 than for LDPE 2426H, so converters frequently blend 7042 with LDPE at 20–30 wt% LDPE to balance tear resistance and film clarity.

    Against metallocene LLDPE grades such as mLLDPE 1018, LLDPE 7042 has a broader molecular weight distribution and lower melt strength sensitivity. mLLDPE typically provides better dart impact, lower seal initiation temperature, and lower haze, but 7042 produces lower extrusion pressure and wider operating latitude on older blown film lines with conventional screw designs. The butene comonomer in 7042 contributes less to tear strength than the hexene or octene comonomer used in many metallocene grades, which is a key reason 7042 is selected for general-purpose packaging rather than high-performance stretch-film or heavy-duty sack applications. The seal initiation temperature of 7042 is generally 5–10 °C higher than that of mLLDPE 1018 when measured by heat-seal testing under ASTM F88/F88M-21 at 0.5 N/15 mm seal strength.

    Compared with high-density polyethylene film grades of melt flow rate 2.0 g/10 min, LLDPE 7042 shows lower flexural modulus, lower density, higher dart impact, and higher tear propagation resistance in thin film. However, it is not suitable for applications requiring low water vapor transmission rates or high-temperature stiffness above 80 °C.

    In cast film, LLDPE 7042 is drawn down to gauges below 15 µm only when the melt curtain is stabilized by a narrow air gap, typically 15–20 mm, and a chill roll temperature of 18–25 °C. The resin shows higher neck-in than LDPE because of the absence of long-chain branching; on a die width of 1 200 mm, edge trim increases when the draw ratio exceeds 20:1. Pinning devices or vacuum boxes are usually required for line speeds above 150 m/min. Published data for this specific configuration is limited, but production trials document that melt temperature above 220 °C further increases neck-in and reduces cold-edge stability. For cast film, die gaps from 0.5 mm to 0.8 mm are common, and chill roll temperatures below 15 °C can cause condensation-related surface defects.

    When Output Exceeds 220 kg/h on a 90 mm Grooved-Feed Extruder

    On a 90 mm grooved-feed extruder operating at 120 rpm, LLDPE 7042 typically develops a melt pressure at the die of 28–35 MPa at 200 °C melt temperature. When output is increased to 220 kg/h, the pressure can rise to 38–45 MPa, depending on die gap and filtration. The relationship between screw speed and output remains linear up to 150 rpm; beyond this, melt pressure oscillations exceeding 5% of nominal are observed if the feed section temperature is not lowered by 10 °C. The use of a barrier screw with a length-to-diameter ratio of 30:1 reduces melt temperature at the same output by 4–7 °C compared with a conventional three-zone screw.

    Processors deploying automatic screen changers should size filtration for a 200–400 µm mesh pack when regrind content exceeds 15 wt%. Premature screen blockage is observed when the melt temperature at the screen changer falls below 200 °C, because high-molecular-weight fractions in the broad molecular weight distribution create elevated back pressure. A screen changer inlet pressure exceeding 12 MPa is usually an early indicator of filter cake consolidation or insufficient backflush frequency.

    Coextrusion Layer Distribution and Edge Stability Limits

    In three-layer coextruded film structures, LLDPE 7042 is typically placed in the core or as a blend partner in skin layers. When the skin layer share exceeds 30 wt% of total structure, the absence of long-chain branching reduces melt stability and increases edge weave on cast lines with die widths above 1 200 mm. Extruder back pressure often drops 8–12% at the same output when 7042 replaces LDPE in the skin, requiring screw speed adjustment to maintain layer uniformity. Published data for this specific configuration is limited; operators commonly raise melt temperature 5–10 °C and narrow the air gap to 15 mm to reduce edge weave. In blown film, bubble stability decreases when 7042 exceeds 70 wt% of the total structure in high-stalk processes; a bubble stabilizing cage with adjustable position is recommended.

    Moisture Uptake, Additive Interactions, and Food-Contact Compliance

    LLDPE 7042 is non-hygroscopic under normal storage, but if outdoor storage or high-humidity conditions above 60% RH are encountered, pre-drying at 70–80 °C for 2–4 h is recommended to maintain residual moisture below 0.05 wt%. Regrind streams should be dried before re-extrusion; moisture above 0.1 wt% can produce surface splay and gel formation in thin film. Fluoroelastomer processing aids, when used to suppress melt fracture, may require a conditioning period of 1–3 h before the die surface is fully coated and pressure stabilizes. Avoid combining 7042 with incompatible acid scavenger packages that have not been qualified for polyolefin film; such combinations can generate gel specks at die temperatures above 230 °C. The base resin is typically supplied with antioxidant and neutralizer packages; converters must verify food-contact status under FDA 21 CFR 177.1520 and regional migration limits before use in direct food packaging.

    Typical end uses include general-purpose packaging film, lamination film, agricultural film, and blend partner in LDPE/LLDPE structures. Converter trials on 1 200 mm cast lines and 1 600 mm blown film lines show that 7042 performs as a blend partner in LDPE/LLDPE structures when melt temperature is kept within the specified window.

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