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NOVARES PURE 70 S Hydrogenated Resin for Transparent Adhesives

    • Product Name: NOVARES PURE 70 S Hydrogenated Resin for Transparent Adhesives
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 229288
    Softening Point Ring Ball 70 °C
    Gardner Color 50 In Toluene ≤ 1
    Density At 20 C 1.02 g/cm³
    Melt Viscosity At 190 C 300 mPa·s
    Acid Value < 0.1 mg KOH/g
    Iodine Value < 5 g I₂/100 g
    Saponification Value < 1 mg KOH/g
    Flash Point Cleveland Open Cup > 200 °C
    Glass Transition Temperature Dsc 35 °C
    Refractive Index At 20 C 1.52
    Weight Average Molecular Weight 500 g/mol

    As an accredited NOVARES PURE 70 S Hydrogenated Resin for Transparent Adhesives factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing NOVARES PURE 70 S hydrogenated resin for transparent adhesives is supplied as pellets in 25 kg multilayer paper bags, palletized and wrapped.
    Container Loading (20′ FCL) 20′ FCL loading: palletized bags of NOVARES PURE 70 S are shrink-wrapped, evenly stacked, and secured to ensure safe, stable transport.
    Shipping NOVARES PURE 70 S is shipped as solid pellets in sealed bags or drums to preserve purity. Transport requires dry, ventilated conditions, away from heat and ignition sources. Standard non-hazardous chemical handling applies, with proper labeling and secure loading to prevent damage during transit.
    Storage Store NOVARES PURE 70 S in its original, tightly sealed container in a cool, dry, well-ventilated area away from direct sunlight, heat, sparks, and open flames. Keep upright to prevent leakage and protect from moisture. Maintain moderate temperatures, avoid incompatible materials, and ensure good housekeeping. Follow label instructions and keep out of reach of unauthorized personnel.
    Shelf Life Shelf life is typically 2 years when stored in original unopened container in a cool, dry place away from heat and sunlight.
    Application of NOVARES PURE 70 S Hydrogenated Resin for Transparent Adhesives
    Addition of NOVARES PURE 70 S at 20–35 wt% into styrene–isoprene–styrene (SIS) triblock copolymer hot melt pressure-sensitive adhesive systems produces a measurable depression of the isoprene-phase glass transition temperature from approximately -38°C to -51°C, as determined by differential scanning calorimetry per ASTM E1356 at a heating rate of 10°C/min under nitrogen purge. Pilot-scale compounding on a Z-blade mixer with a jacket temperature of 145–165°C, a mixing time of 45–60 min under vacuum (-0.08 MPa), and a rotor speed of 25–35 rpm yields a transparent melt with a Brookfield viscosity at 160°C bounded between 8,000 mPa·s and 24,000 mPa·s, measured per ASTM D3236 with a No. 27 spindle. The hydrogenated hydrocarbon resin functions as an aromatic-modified end-block compatible tackifier; at addition levels approaching 38 wt%, the formulation exhibits a distinct property cliff-edge: loop tack on stainless steel decreases from approximately 12 N/25 mm to 4.5 N/25 mm, while the shear adhesion failure temperature (SAFT) rises from 65°C to 93°C, per ASTM D4498 and FINAT FTM 8 protocols respectively. The 180° peel adhesion on borosilicate float glass follows a nonlinear parabolic trajectory with a maximum at approximately 28 wt% addition. Regulatory alignment for this configuration: formulations incorporating NOVARES PURE 70 S are compliant with FDA 21 CFR 175.105 where the adhesive layer is separated from foodstuffs by a functional barrier, and with REACH Annex XVII when total free aromatic monomer content remains below the 0.1 wt% reporting threshold. The downstream production process involves slot-die coating at line speeds of 250–400 m/min onto silicone-coated release liner, followed by transfer lamination to a biaxially oriented polypropylene (BOPP) or polyethylene terephthalate (PET) facestock. Equipment-specific failure modes observed on high-speed coaters include melt fracture at the die lip when the adhesive shear rate exceeds 10,000 s⁻¹, and back-side transfer bloom on the front-face of the label stock when unwind tension exceeds 1.5 N/cm width on the dried laminate. Terminal product types include clear pressure-sensitive label stock for beverage bottle decoration, varnish-overlaminated cosmetic container labels, and wet-grip BOPP film labels for refrigerated dairy packaging. Pre-drying of the resin at 60°C for 2 h is required when ambient relative humidity exceeds 60%, as water vapor entrains into the melt and produces microscopic haze domains detectable at 0.3% haze per ASTM D1003.

    What Limits Optical Clarity Retention in Transparent Flexible-Food Laminating Adhesives?

    Transparent flexible packaging laminates produced with polyolefin-based hot melt adhesives rely on the hydrogenated resin to maintain Gardner color readings below 1 after residence times of 4–6 h at process temperatures of 170–190°C, a condition that unmodified aromatic C9 resins fail within 60 min. NOVARES PURE 70 S is incorporated at 15–30 wt% into ethylene–vinyl acetate (EVA) or metallocene-catalyzed polyolefin base polymers through continuous screw extrusion on a ZSK 53 Mc18 twin-screw extruder with an L/D ratio of 36:1 and a temperature profile ramping from 120°C at the feed throat to 180°C at the die plate. Melt filtration through a 25 µm woven-wire screen pack is standard practice, as gel bodies originating from localized overcuring produce visual defects that are categorically unacceptable in optically clear laminate structures. The addition ratio directly controls the melt-viscosity response: at 25 wt% resin, the formulation exhibits a zero-shear viscosity of approximately 12,000 mPa·s at 175°C, which permits roll-coating application onto aluminum foil and cast polypropylene substrates at line speeds between 150–300 m/min. When the resin content drops below 12 wt%, wetting of metallized PET film becomes inadequate at production speeds and the optical density of the adhesive layer increases from 0.15 to 0.45 absorbance units, measurable by ASTM D1746. Compliance for this configuration sits within FDA 21 CFR 177.1520 for polyolefin articles and EU Regulation 10/2011 plastics for food contact, where specific migration of hydrogenated hydrocarbon resin oligomers below 0.05 mg/kg is achievable when the resin molecular-weight distribution excludes species below 400 g/mol. The downstream lamination process involves either solvent-free gravure-coating heads with 70–90 Shore A rubber rollers maintaining a nip pressure of 0.4–0.8 MPa, or slot-die extrusion coating with a die gap of 0.5–1.0 mm. Terminal product types include transparent snack-flow-wrap film laminates, clear stand-up pouches for frozen fruits and vegetables, and window-patch structures in paper-based bakery bags. A specific operational boundary must be observed: the hydrogenated resin has limited compatibility with high-crystallinity polypropylene above 15 wt% addition, and under those conditions microphase separation initiates clouding within 24 h of laminate aging at 23°C as monitored by haze measurement per ASTM D1003.On solvent-based transdermal drug delivery coating lines, the choice of tackifying resin determines both the cold-flow behavior of the matrix and the diffusion coefficient of the active pharmaceutical ingredient through the adhesive layer. NOVARES PURE 70 S is dissolved at 25–40 wt% of total solids in a polyisobutylene or acrylate pressure-sensitive adhesive solution, with the resin contributing to the overall solids content of 30–42 wt% in the coating bath, formulated in ethyl acetate or heptane solvents per ICH Q3C residual solvent limits. The coating operation employs a knife-over-roll applicator with a wet gap setting between 300–800 µm, followed by a three-zone solvent-removal oven with zone temperatures of 45°C, 65°C, and 80°C and total residence time of 8–12 min. Residual solvent content after drying must remain below 500 ppm ethyl acetate equivalent, verified by headspace gas chromatography per USP <467>. Biocompatibility requirements include ISO 10993-5 for in vitro cytotoxicity (elution method, L929 mouse fibroblast cells, no more than Grade 2 reactivity) and ISO 10993-10 for skin irritation classification (primary irritation index below 0.5). The resin addition level at 35 wt% produces a shear storage modulus G′ at 32°C and 0.1 Hz of approximately 2.5×10⁴ Pa, placing the matrix above the Dahlquist criterion for pressure-sensitive tack but sufficiently low to permit conformability to uneven skin surfaces. Process challenge: the hydrogenated resin exhibits limited solubility in pure methanol, and the coating bath temperature must be maintained above 20°C to prevent phase separation from occurring overnight. Production-scale batch records from a 200 L stainless-steel jacketed mixing vessel fitted with a three-blade propeller agitator at 120–180 rpm document viscosity drift of less than ±5% across an 8 h production shift when the resin is pre-dried for 4 h at 50°C under vacuum (-0.09 MPa). Terminal product types include transdermal nicotine patches with a 15 cm² release surface, non-sterile wound-care adhesive films, and wearable diagnostic sensor fixation platforms where optical clarity of the adhesive layer is a functional requirement. Published kinetic data for the specific NOVARES PURE 70 S–polyisobutylene matrix drug-release configuration is limited; matrix release-rate adjustments are generally confirmed by Franz diffusion cell testing per USP <1724> rather than predicted from resin concentration alone.

    When EVA Screw-Extruder Throughput Surpasses 1,200 kg/h, Color Stability Governs Scrap Rates

    High-volume bookbinding and furniture-edge-banding hot melt adhesives operate under prolonged thermal exposure in pre-melt tanks and application heads, where oxidative discoloration of the resin fraction has historically generated scrap rates above 3% on color-sensitive white or light-wood panels. NOVARES PURE 70 S is compounded at 10–25 wt% into EVA (vinyl acetate content 18–28 wt%) with microcrystalline wax and a hindered-phenol antioxidant package, using a Werner & Pfleiderer ZSK 58 twin-screw extruder with an L/D ratio of 30:1, co-rotating screw elements, and a barrel temperature profile from 100°C at the feed zone to 165°C at the discharge die. The resin addition level is capped at 25 wt% because open-time requirements conflict with set-speed constraints: at 30 wt% addition, the open time measured per ASTM D4497 extends beyond 12 s, which exceeds the maximum allowable time on a high-speed edge-banding line operating at 30–60 m/min with a panel-feed interval of 3.5 s. The application system comprises a Nordson ProBlue or equivalent hot melt delivery unit with a gear pump maintaining a melt pressure of 4–7 MPa at the slot-die nozzle, and a nozzle temperature of 160–180°C. Adhesive coat weight is controlled to 80–150 g/m² on wood-based panel edges, while perfect-binding spine application uses 40–80 g/m² on uncoated paper stock. The hydrogenated resin at 20 wt% yields a Gardner color retention of <1 after 72 h at 170°C in a nitrogen-purged aging oven, compared with a color shift from 1 to 5 for an equivalent aromatic C9 resin under identical conditions, per ASTM D1544. Industry compliance includes ISO 1924-2 for tensile-property verification of the bonded paper sheets and EN 204 for non-structural thermoplastics for wood bonding, where D3 grade classification requires >7 N/mm² tensile shear strength after cold-water immersion testing. A documented batch-to-batch variance concern on production floor implementation: when the resin feed hopper is exposed to ambient humidity above 65% RH without pre-drying, the extruder torque fluctuates by ±7% and the resulting adhesive film develops microscopic bubble inclusions that reduce peel-force values by 15–20% on melamine-faced particleboard. Terminal product types include perfect-bound paperback books, PUR/EVA hybrid spine adhesives for lay-flat manuals, and one-component edge-banding hot melts applied to melamine, PVC edge tape, and ABS edge profiles in office furniture.Formulation data for removable and repositionable clear-film adhesives necessitates a fundamentally different addition window than permanent bonding applications. NOVARES PURE 70 S is added at 5–15 wt% to UV-curable acrylic oligomer-polymer syrup compositions, where the hydrogenated resin modifies the plateau modulus without driving peel adhesion beyond the removability ceiling of approximately 6 N/25 mm on stainless steel, measured per FINAT FTM 1. At 15 wt% addition, the Dahlquist criterion boundary is approached from above: the shear storage modulus G′ at 23°C and 1 Hz registers approximately 1.2×10⁵ Pa, compared with 4.8×10⁵ Pa for the unmodified acrylic control. The production process involves knife-based casting of the tackified syrup onto silicone-coated PET release liner at a coat weight of 25–60 g/m², followed by exposure to a 120 W/cm medium-pressure mercury arc lamp emitting UV-A radiation at a total dose of 1,500–3,000 mJ/cm². The addition ratio must remain below 18 wt% because the hydrogenated resin absorbs UV radiation in the 254 nm region, attenuating the cure dose at the adhesive-liner interface and producing an uncured, smear-prone underlayer detectable by attenuated total reflectance FTIR as unreacted acrylate C=C stretching bands at 1,635 cm⁻¹. Industry compliance references include ISO 2409 for cross-cut adhesion classification on the coated facestock and ASTM D3359 for tape test methodology on glass and polycarbonate substrates. The finished constructions must demonstrate removability without adhesive transfer or ghosting after 72 h of dwell time at 40°C and 80% RH on polystyrene, polycarbonate, and powder-coated metal substrates. Terminal product types include optically clear removable window and glass manifestation films, static-cling-free repositionable wall graphics, and low-tack protective films for polycarbonate machine displays during transit and installation. Published data for specific removability performance of NOVARES PURE 70 S in UV-cured systems remains limited; the 5–15 wt% addition window is supported by general hydrogenated-resin phase-separation thermodynamics and must be confirmed by user-specific peel-test protocols on each target substrate.

    Metallocene Polyolefin Spiral-Coating Rheology and Elastic Laminate Build-Up

    Disposable hygiene article construction adhesives formulated with metallocene-catalyzed amorphous poly-alpha-olefin (APAO) base polymers require tackifier systems that preserve a narrow viscosity window for spiral-spray application while preventing elastic-strand laminate bond failures in high-speed converting. NOVARES PURE 70 S is compounded at 12–30 wt% into mPO-based hot melt formulations at a melt temperature of 155–170°C using a Reicofil-compatible melt delivery system rated for continuous output of 80–200 kg/h. The spiral-spray nozzle configuration uses an ITW Dynatec or Nordson air-assisted application head with hot air at 0.2–0.4 MPa and nozzle orifice diameters of 0.3–0.6 mm, producing adhesive filament diameters between 50–150 µm. The addition ratio is constrained at the lower bound by substrate wetting on spunbond polypropylene with a surface energy of approximately 30 mN/m: below 10 wt% resin, the contact angle exceeds 80° and the spiral pattern breaks into discrete droplets rather than continuous filaments. At the upper bound of 30 wt%, the cohesive strength of the elastic strand attachment exceeds the cross-directional tensile strength of the nonwoven, producing substrate fiber tear rather than adhesive failure during peel testing per ASTM D1876. Production data from diaper converting lines operating at 300–600 m/min document that a 20 wt% NOVARES PURE 70 S formulation maintains a spiral pattern stability index above 0.92 (where 1.0 denotes a perfectly uniform spiral) over 8 h continuous running, whereas an equivalent C5 tackifier system shows a stability index decline to 0.74 within 3 h due to viscosity drift. Skin-contact compliance is anchored to ISO 10993-23 for irritation testing and OEKO-TEX Standard 100 product class I for infant-use textiles, with the hydrogenated resin demonstrating no detectable residual aromatic monomer by GC-MS at a quantification limit of 0.5 ppm. The downstream production process encompasses extrusion-coating of the adhesive onto elastic strands (spandex or Lycra) at a stretch ratio of 2.5–4.0:1, followed by immediate lamination to nonwoven substrates on a chilled roll set at 10–15°C. Terminal product types include diaper leg-cuff elastic adhesives, waistband laminate construction adhesives, adult-incontinence brief positioning adhesives, and transparent front-tape attachment films for refastenable finger lifts. A specific operational limitation: the hydrogenated resin exhibits reduced compatibility with high-crystallinity isotactic polypropylene homopolymer above 10 wt%, and co-compounding with such materials produces visible melt-phase turbidity detectable by ASTM D1003 haze measurement exceeding 5% in the solidified adhesive film.
    Table 1. Comparative formulation-gradient data for NOVARES PURE 70 S in SIS-based hot melt pressure-sensitive adhesive, measured on a pilot-scale Z-blade compounding line with a 25 mm slot-die coating head.
    Addition level (wt%)Brookfield viscosity at 160°C (mPa·s)Loop tack, SS (N/25 mm)SAFT (°C)180° peel on glass (N/25 mm)Gardner color
    0 (control)3,20018.55224.21
    155,40015.26126.5<1
    258,60012.86928.1<1
    3514,2009.17823.7<1
    4021,5005.38618.4<1
    Table 2. Compliance standard checklist matrix by downstream application scenario for NOVARES PURE 70 S in transparent adhesive systems.
    Application scenarioFood-contact standardAdhesion test methodSafety/biocompatibility standard
    Label stock HMPSAFDA 21 CFR 175.105ASTM D4498, FINAT FTM 8REACH Annex XVII
    Food flexible laminatingFDA 21 CFR 177.1520, EU 10/2011ASTM D1876, ISO 11339REACH Annex XVII
    Transdermal medical matrixNot applicableUSP <1724>ISO 10993-5, ISO 10993-10, ICH Q3C
    EVA edge bandingNot applicableASTM D4497, ISO 1924-2EN 204 D3 grade
    UV-cured removable filmsNot applicableFINAT FTM 1, ASTM D3359ISO 2409
    Hygiene elastic laminationNot applicableASTM D1876ISO 10993-23, OEKO-TEX Standard 100
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    Certification & Compliance
    More Introduction

    NOVARES PURE 70 S is a hydrogenated hydrocarbon resin supplied as low-colour pastilles for transparent hot-melt, solventborne, and reactive adhesive systems. The model designates a 70 °C ring-and-ball softening point under ISO 4625-1; production certificates of analysis commonly show a range of 68–72 °C. The suffix S identifies a stabilised, low-odour grade within the PURE series. The product belongs to the NOVARES line of fully hydrogenated aromatic C9 resins and is used as a tackifier in ethylene-vinyl acetate, styrene block copolymer, and metallocene polyolefin packaging adhesives. Representative chemical data include a Gardner colour below 1 at 50 % solids in toluene under ASTM D1544, an acid number below 0.1 mg KOH/g by ASTM D974, and a density of 1.04–1.06 g/cm³ at 20 °C using ISO 1183-1. The resin is nonpolar and low in acidity, which makes it suitable for clear packaging lines where contact clarity and low odour are required; however, its performance limits are determined by the 70 °C softening point and by compatibility with polar polymer phases.

    The principal difference from conventional aromatic C9 resins is the removal of most ethylenic unsaturation through hydrogenation. In clear packaging hot-melts, this alteration shifts the failure mode away from yellowing and odour generation. When film samples are aged at 150 °C in a forced-air oven for 72 h, class-level Gardner colour drift for fully hydrogenated C9 tackifiers commonly remains below 1 unit, while non-hydrogenated aromatic C9 resins often exceed 4 units under the same conditions. These values are not product-specific guarantees; they are intended as incoming-quality screening thresholds. For laminates, haze is measured by ASTM D1003 or ISO 14782 on 300 µm films drawn on a heated bar coater at 120 °C. Formulators should request a batch-specific Gardner colour after 24 h at 180 °C under ASTM D1544 if thermal stability is a release criterion, because bulk resin initial colour alone does not predict melt-holding drift.

    What Does the Manufacturer’s Certificate of Analysis Typically List for This Grade?

    Representative properties of NOVARES PURE 70 S
    Property Method Representative value
    Softening point, ring-and-ball ISO 4625-1 68–72 °C
    Colour, 50 % in toluene ASTM D1544 <1 Gardner
    Acid number ASTM D974 <0.1 mg KOH/g
    Density at 20 °C ISO 1183-1 1.04–1.06 g/cm³
    Ash content ISO 6245 <0.1 % by mass
    Physical form Visual White to pale-yellow pastilles

    Lower Acid Number and Reduced Interaction with Reactive Monomers

    An acid number below 0.1 mg KOH/g measured by ASTM D974 differentiates NOVARES PURE 70 S from rosin ester tackifiers, which typically contain 5–15 mg KOH/g of residual acidity. In polyurethane reactive hot-melt formulations, residual acid groups can accelerate isocyanate-water side reactions, generate carbon dioxide, and alter cure stoichiometry. The low-acid resin therefore allows compounding with moisture-cure prepolymers at loadings up to 10–15 wt% without the same degree of viscosity drift; above 20 wt%, the nonpolar nature of the resin can reduce optical clarity and should be screened by differential scanning calorimetry for a single combined glass transition under ISO 11357-2. In amine-neutralised waterborne systems, the resin does not contribute to pH drop or amine demand, which is relevant when the adhesive is used to bond clear polycarbonate or polyester film. Batch titration data should be retained because acid number is a release limit, not a formulation constant.

    Food-contact status depends on the finished adhesive and the specific regulatory clearance claimed by the manufacturer. The product is frequently positioned for use in food-packaging adhesives under FDA 21 CFR 175.105 when the adhesive is separated from food by a functional barrier, but the exact end-use restriction must be confirmed in writing from the supplier for the production site and batch range. Regulatory compliance should not be inferred solely from a technical data sheet.

    During continuous compounding on a 25 mm co-rotating twin-screw extruder with L/D 40, NOVARES PURE 70 S is side-fed downstream of the primary polymer feed. Barrel temperatures are set from 90 °C at the feed throat to 120 °C at the die, with the resin side-feeder zone held at 80–100 °C to prevent pastille bridging. At melt temperatures above 180 °C or residence times above 10 min, colour drift becomes detectable even in stabilised hydrogenated resins. Processing lines with poorly swept hot-melt tanks and nitrogen blanketing can maintain colour longer; without inerting, continuous low-shear storage at 160 °C should not exceed 8 h for clarity-critical products. The resin’s supplied pastille form permits gravimetric dosing into a loss-in-weight feeder, but the feeder hopper must be water-jacketed below 35 °C when ambient temperature exceeds 30 °C to prevent caking.

    In slot-die coating of transparent hot-melts, melt filtration through a 100 µm screen pack is recommended before the positive-displacement gear pump. The resin’s low colour permits visual inspection of gel particles and char; however, low colour also reduces contrast for optical defect detection systems. To avoid spurious rejection, machine vision systems should be calibrated with a clear reference standard rather than a coloured resin. Melt viscosity at application temperature is best measured by ASTM D3236 with a Brookfield thermocell at 150 °C and 160 °C. Published neat resin melt viscosity for this grade may be given as a maximum rather than a fixed value; users should request a batch-specific flow curve if shear-thinning behaviour is critical for narrow slot dies.

    When the 70 °C Softening Point Creates a Conflict Between Heat Resistance and Cold-Tack

    The 70 °C softening point sets the upper service temperature of the neat resin but not of the finished adhesive. In an EVA hot-melt containing 30 wt% resin, 35 wt% polymer, and 35 wt% wax and diluent, the shear adhesion failure temperature under ASTM D4498 may pass only 50–60 °C depending on wax type and wax melting point. If a packaging adhesive must survive 70 °C under a 500 g static load, NOVARES PURE 70 S alone is often insufficient. The formulator must either reduce resin loading below 20 wt%, replace part of the wax with a higher melting point Fischer-Tropsch grade, or add a separate end-block reinforcing resin. Each of these changes trades away tack or clarity; the resulting haze should be measured by ASTM D1003, and low-temperature flexibility should be checked by mandrel bend at −10 °C or by low-temperature loop tack using ASTM D6195.

    The advantage of the 70 °C softening point is improved substrate wetting and cold-tack on uncoated paperboard at line speeds above 50 m/min. Resins with softening points above 100 °C typically require higher application temperatures, which can scorch thin polyethylene films and increase odour. The 70 S grade allows melt application at 140–150 °C, reducing thermal stress on heat-sensitive facestocks. This is a genuine processing window but not a universal solution; if the filled package will be shipped in a truck container above 60 °C, heat resistance requirements override cold-tack benefits.

    Class-level comparison of tackifier options for transparent adhesive screening:

    Tackifier class comparison in clear adhesive applications
    Parameter NOVARES PURE 70 S Conventional C9 aromatic resin Rosin ester C5 aliphatic resin
    Softening point 68–72 °C (ISO 4625-1) 90–120 °C typical 80–105 °C typical 70–100 °C typical
    Gardner colour at 50 % solids <1 (ASTM D1544) 4–8 typical 3–8 typical <1 typical
    Acid number (mg KOH/g) <0.1 (ASTM D974) 0.1–0.5 typical 5–15 typical <0.1 typical
    Residual bromine number (g Br/100 g) <1 class-level (ASTM D1159) 20–35 class-level 10–25 class-level <2 class-level
    Film yellowing after 72 h at 150 °C low; class-level Gardner shift <1 high; Gardner shift often >4 moderate; Gardner shift 2–5 low to moderate; Gardner shift 1–3

    Transparent SIS Label Adhesives and UV Exposure Screening

    In clear styrene-isoprene-styrene pressure-sensitive adhesives, NOVARES PURE 70 S is usually concentrated in the isoprene midblock. Midblock loading is set by the desired loop tack and peel adhesion; typical starting points are 20–60 phr on 100 phr SIS. Loop tack is measured by ASTM D6195, 180° peel by ASTM D3330, and shear adhesion failure temperature by ASTM D4498. At loadings above 60 phr, cohesive strength falls rapidly and the adhesive may leave residue on acrylic substrates. Below 20 phr, the formulation does not develop sufficient tack for low-energy surfaces such as untreated polypropylene. The hydrogenated nature of the resin reduces UV-induced chromophore formation in clear label adhesives; in laboratory screening with a xenon arc source per ISO 4892-2 at 0.55 W/m² for 340 nm, films containing hydrogenated C9 resin remain acceptable for longer than those containing terpene phenol, but exact delta b* values are system-dependent.

    For automotive interior adhesives, emissions and fogging are tested by VDA 278 and VDA 270. Hydrogenated hydrocarbon resins typically show lower total volatile emissions than rosin esters and non-hydrogenated C9 resins, but product-specific data should be obtained from the manufacturer for each final adhesive. Published data for NOVARES PURE 70 S in every possible adhesive matrix is limited, so qualification should include a full factorial design with resin loading, mixing temperature, and cool-down rate as factors.

    When replacing a conventional C9 or rosin ester in an existing transparent adhesive, the formulation cannot be qualified solely on resin colour. A side-by-side 7 day melt storage test at 150 °C with daily Gardner measurements by ASTM D1544 is a minimum. In waterborne pressure-sensitive adhesives, the resin is usually introduced as a solventborne or heat-melt preblend with the base elastomer; direct addition to aqueous latex can destabilise the dispersion. Storage life in unopened original packaging is typically 12 months when stored below 30 °C, but caking and colour drift are possible if the packaging is damaged. In storage, the pastilles remain free-flowing below 30 °C. At ambient temperatures above 35 °C, surface tack can develop and cause blocking. If bags are stored in uninsulated containers, product may reach 45 °C and fuse; therefore, pallet stacking should be limited to 2 high and bulk silos should be kept below 40 °C with low-speed rotary discharge. The resin is not classified as hygroscopic, but surface moisture from condensation at RH > 80 % can introduce bubbles in clear adhesive films. Pre-drying at 60 °C for 4 h in a shallow tray drier is sufficient when condensation is suspected. Avoid strong oxidising agents and open-flame contact; the material is combustible and should be handled according to the manufacturer’s SDS. For REACH and food-contact declarations, the operator must obtain a batch-specific regulatory statement from the manufacturer because resin-level data does not automatically transfer to the finished adhesive article.

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