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NOVARES LS500 Liquid Hydrocarbon Resin for Coating Modification

    • Product Name: NOVARES LS500 Liquid Hydrocarbon Resin for Coating Modification
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: admin@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 517746
    Appearance clear, viscous liquid
    Color Gardner maximum 6
    Viscosity At 25 C 500-800 mPa·s
    Density At 20 C 1.03-1.05 g/cm³
    Acid Value ≤ 1 mg KOH/g
    Saponification Value ≤ 1 mg KOH/g
    Iodine Value 140-170 g I2/100 g
    Flash Point Cleveland Open Cup > 150 °C
    Glass Transition Temperature approximately -20 °C
    Number Average Molecular Weight approximately 600-900
    Solubility soluble in aromatic and aliphatic hydrocarbons, ketones, and esters; insoluble in water
    Compatibility compatible with alkyd, epoxy, chlorinated rubber, and nitrocellulose systems

    As an accredited NOVARES LS500 Liquid Hydrocarbon Resin for Coating Modification factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing NOVARES LS500 Liquid Hydrocarbon Resin for Coating Modification is supplied in 200 kg steel drums, ensuring safe handling and storage.
    Container Loading (20′ FCL) 20′ FCL shipment of NOVARES LS500 liquid hydrocarbon resin, loaded in drums/IBCs, secured for safe coating-modification transport.
    Shipping NOVARES LS500 is shipped in sealed drums or bulk containers, protected from moisture and heat. Ensure proper labeling, ventilation, and secure transport. Avoid prolonged exposure to high temperatures. Handle with standard industrial safety measures.
    Storage Store NOVARES LS500 in a cool, dry, well-ventilated area away from direct sunlight, heat, and ignition sources. Keep the container tightly sealed to prevent moisture ingress and contamination. Avoid extreme temperatures; recommended storage around 20–40°C. Under proper conditions, shelf life is typically 24 months. Ensure good housekeeping and local ventilation when handling.
    Shelf Life Store in original sealed container away from heat and sunlight. Shelf life is typically 24 months from manufacture date.
    Application of NOVARES LS500 Liquid Hydrocarbon Resin for Coating Modification

    In high-solids polyester can coatings applied with a three-roll reverse coater at 3.5–5.5 g/m² dry film weight and cured at 200–220°C peak metal temperature for 8–12 s, NOVARES LS500 functions as a binder-solvating co-resin rather than a classic tackifier. The addition range observed in industrial coil trials is 2–6 wt% of total binder solids. Below 2 wt%, viscosity reduction at 50–60°C application temperature is insufficient to maintain 65–70% non-volatile by mass as measured by ISO 3251:2019. Above 6 wt%, retort resistance after 90 min at 121°C in 1% citric acid may fall below the adhesion and blushing benchmark required for metal packaging. The resin lowers high-shear viscosity at 10,000 s⁻¹ measured by cone-and-plate rheometry. This permits the coating line to reduce solvent consumption without exceeding the sag limit on vertical sheet interiors. Because LS500 is a nonvolatile diluent, it does not build the same surface tension gradient as xylene/n-butanol blends during flash-off. Leveling behavior therefore changes on tinplate passivated with chromium oxide. Food contact status must be confirmed against FDA 21 CFR 175.300 and EU Regulation 10/2011. Not every lot of liquid hydrocarbon resin has the low naphthalene and low benz[a]pyrene profile required for direct long-term food contact. Batch-to-batch viscosity drift of ±10% is recorded on air-operated diaphragm transfer pumps when inlet temperature falls below 15°C. Heated drum cabinets and PTFE-lined hoses are recommended because the solvency character of the resin swells EPDM and natural rubber seals. FKM or PTFE wetted parts are required. REACH registration under EC 1907/2006 must be confirmed before EU import, and the safety data sheet must disclose aromatic hydrocarbon content for downstream food contact audits.

    What Replaces Benzyl Alcohol Plasticizer in Epoxy-Phenolic Drum Linings?

    Plant-scale drum lining trials on 200 L cold-rolled steel drums have evaluated LS500 at 5–10 phr as a replacement for benzyl alcohol in bisphenol-A epoxy/phenolic systems applied at 70–90 µm dry film by 45:1 airless spray. The liquid hydrocarbon resin has low hydroxyl functionality and does not compete with the phenolic methylol condensation. The stoichiometric ratio of epoxy to phenolic hardener therefore remains unchanged. At 5–7 phr, MEK solvent rub values typically remain above 100 double rubs under ASTM D5402-19. Cross-cut adhesion on 0.8 mm steel after 7 d salt spray exposure in accordance with ISO 9227:2022 remains at class 0–1 under ISO 2409:2020. At 10 phr and above, pendulum hardness under ISO 1522:2022 shifts below 120 s. Resistance to 20% acetic acid shows edge undercutting after 30 d immersion under ISO 2812-1:2017. Published data for this specific resin configuration is limited. The quantitative boundaries cited here are typical of comparative formulation screening, not a supplier warranty.

    Compliance checklist for 5–7 phr LS500-modified epoxy-phenolic drum linings
    ParameterTest methodAcceptance criterion
    Non-volatile contentISO 3251:201970–75% by mass at 105°C/2 h
    MEK solvent rubASTM D5402-19100 double rubs
    Pencil hardnessISO 15184:20202H
    Cross-cut adhesionISO 2409:20201
    Salt spray resistanceISO 9227:2022no underfilm corrosion > 2 mm after 1000 h
    Acetic acid immersionISO 2812-1:2017no blistering after 30 d at 23°C

    Where coal tar pitch has been removed from IMO PSPC-compliant ballast tank coatings, formulators turn to low-viscosity hydrocarbon modifiers that maintain wetting on sweep-blasted 8–12 mm shipbuilding steel. LS500 is incorporated at 3–7 phr into solid bisphenol-F epoxy novolac/amine systems. It functions as a viscosity depressant before the high-build airless spray stage, where a 45:1 pump at 180–220 bar delivers 250–300 µm wet film in a single pass. At 3–5 phr, edge retention on free edges after 30 min at 23°C is improved because the resin does not evaporate and does not create a solvent-depleted boundary layer. Over-addition above 7 phr reduces glass transition temperature. Tensile adhesion to prepared steel measured by ISO 4624:2023 after 7 d curing at 23°C also declines. Overcoating windows under PSPC require dry-to-recoat intervals below 24 h. Hydrocarbon resin levels above 7 phr have been associated with a persistent surface tack that delays the abrasion-blasted tie coat. Compatibility with aluminum silicate thixotropes must be checked with shear-step tests because the resin can desorb some organowax rheology additives. Corrosion control does not come from LS500 itself. Zinc phosphate or zinc borate remains the active inhibitive pigment in the primer, and the resin only modifies viscosity, wetting, and film coalescence. Surface preparation must remain Sa 2½ under ISO 8501-1, with an anchor profile of 50–75 µm under ISO 8503-2. The resin cannot compensate for mill scale or rust contamination.

    When High-Flash Liquid Resin Is Introduced Into Long-Oil Alkyd Decking Stains

    Coating plants handling long-oil alkyd decking stains at 50–65% solids by mass have tested LS500 at 5–15 wt% on dry binder to reduce pump cavitation in slow-speed dispersers and to extend wet edge time on 45°C wooden decks. Because LS500 lowers the crosslink density of the cured alkyd matrix, through-drying measured by BK dry recorder at 23°C/50% RH is retarded by 2–6 h at the upper addition level. Cobalt 2-ethylhexanoate and zirconium drier demand increases by 0.02–0.05% metal on binder when LS500 exceeds 10 wt%. Otherwise surface wrinkling occurs at film thickness above 60 µm. Flash point by ASTM D56 remains above 61°C for the formulated stain only if the let-down solvent is selected accordingly. LS500 is not a substitute for fire-code solvent storage compliance. The resin reduces cold-check resistance on softwood panels after 6 cycles from -20°C to 60°C when addition exceeds 12 wt%. Visible cracking at earlywood/latewood boundaries demonstrates this failure mode. VOC content under Directive 2004/42/EC and ASTM D3960-05 must be calculated after correction for the nonvolatile resin portion. LS500 itself is not a volatile organic compound, but it cannot be used to disguise a noncompliant solvent blend. Published data for this specific configuration is limited. Field verification under northern European solar gain and coastal humidity is necessary.

    Unlike high-solids epoxies, two-component polyurethane topcoats respond to LS500 through plasticizer-like chain mobility rather than crosslink density change. In aliphatic isocyanate systems based on HDI trimers and polyester polyols, addition of 2–5 wt% on resin solids reduces set-to-touch at 23°C from approximately 6 h to 3 h. Pot life falls from 4 h to 2.5 h at a 100 g mixed mass. The hydrocarbon resin participates in neither the NCO-OH reaction nor the urea side reaction. It acts as a nonvolatile diluent that accumulates at the film-air interface. At levels above 5 wt%, the interface becomes tack-sensitive. Recoatability after 7 d at 25°C falls below the 1.5 MPa pull-off threshold given in ISO 4624:2023. Taber abrasion resistance measured by ASTM D4060-19 with CS-10 wheels and a 1000 g load decreases proportionally once LS500 exceeds 3 wt%. The softened topcoat matrix transfers less energy to the abrading wheel. In moisture-curing polyurethane floor coatings, the influence of LS500 on tin catalyst hydrolysis must be checked because residual moisture can shift gel time at 40°C and 75% RH. The recommended incorporation point is after pigment grind but before the isocyanate addition. A Cowles blade at 10–15 m/s peripheral speed for 10 min is used for uniform dispersion. Dosing accuracy is maintained with a mass flow meter calibrated for the resin’s Brookfield viscosity at 25°C. Published data for this specific configuration is limited, so production pilots should verify recoatability on critical assets.

    Cold-Applied Steel Pipe Coating Primers Shift from Coal Tar to Hydrocarbon Resin

    Because ambient-cure pipe primers are applied at 5–15°C and often thinned with xylene for brush or spray, LS500 has been evaluated at 4–8 phr in amine-cured epoxy primers for API 5L line pipe. At 4 phr, high-shear viscosity measured with a Krebs Stormer viscometer drops by an amount equivalent to 3–5% added xylene. VOC content under ASTM D3960-05 does not increase. At 8 phr, cathodic disbondment resistance after 28 d at 1.5 V and 23°C in synthetic seawater shows a larger disbonded radius than the unmodified control. The exact radius depends on surface preparation to Sa 2½ per ISO 8501-1 and an anchor profile of 50–75 µm per ISO 8503-2. Adhesion to mill scale-free steel after 24 h at 10°C and 85% RH remains marginal unless the primer is formulated with a phenolic accelerator or calcium sulfonate co-binder. LS500 improves brush drag and wetting on cold steel but cannot replace the barrier properties of a high-molecular-weight epoxy. Anticorrosion performance therefore remains linked to the base binder and active pigment package. Plant records show that airless spray filters with 60 mesh screen retain fewer gel particles when LS500 is pre-blended at 30°C. Below 5°C the resin thickens and requires a heated double-diaphragm pump. The use of amine-based accelerators must be validated because the resin does not chemically bind to the epoxy network. Excess addition above 8 phr can increase water vapor transmission through the cured film.

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    Certification & Compliance
    More Introduction

    NOVARES LS500 Liquid Hydrocarbon Resin for Coating Modification

    NOVARES LS500 Liquid Hydrocarbon Resin for Coating Modification is a low-molecular-weight aromatic hydrocarbon resin supplied as a pumpable liquid at ambient temperature. The product functions as a non-film-forming modifier in solventborne and high-solids coating systems, where it contributes to pigment wetting, viscosity control, dry-film flexibility, and replacement of a portion of conventional plasticizing components. Unlike solid C9 hydrocarbon resins, LS500 does not require flake-grinding or melt handling equipment. Batch-specific physical properties must be obtained from the supplier’s certificate of analysis; published open-literature data for this exact designation remains limited.

    What distinguishes LS500 from a solid C9 tackifier in high-solids alkyd topcoats?

    The primary processing distinction is the liquid phase at 25 °C. Solid C9 hydrocarbon resins exhibit ring-and-ball softening points in the range of 70–140 °C by ASTM E28, whereas liquid aromatic hydrocarbon resins of the LS500 class remain flowable without pre-heating. In high-solids alkyd topcoats, this permits direct metering into the mill base or letdown. The liquid resin modifies dry-film flexibility and tack without increasing the glass transition temperature to the same extent as a solid aromatic resin. Hardness development after drying should be measured by ISO 1522 pendulum damping or ASTM D4366, and film formation should be assessed by ASTM D1640 drying time methods.

    A comparative profile is given in the following table for three modifier chemistries used in industrial coatings. The data are class-typical and not a replacement for LS500 batch documentation.

    ParameterLiquid hydrocarbon resin, LS500 classSolid C9 hydrocarbon resinRosin ester resin
    Physical state at 25 °CPumpable liquidSolid, softening point 70–140 °C by ASTM E28Solid, softening point 70–120 °C by ASTM E28
    Viscosity at 25 °CBatch-specific, measured by ASTM D7042 or ISO 3104Not applicable below softening pointNot applicable below softening point
    Primary coating functionFlexibility, pigment wetting, tack reduction, plasticizer extensionHardness, body, drying, aromatic compatibilityAdhesion, gloss, hardness, solvent release
    Solvent compatibilityPreferential in aromatic or alicyclic solvents; limited in pure aliphatic diluentsAromatic and aliphatic blends depending on gradeAliphatic and aromatic depending on ester type
    HandlingDirect pumping, drum heating optional for viscosity reductionFlake or pastille grindingFlake grinding or melt handling

    Specification values for NOVARES LS500 are batch-specific. Quality-control parameters for liquid aromatic hydrocarbon resins of this class typically include kinematic viscosity at 25 °C by ASTM D7042, density at 20 °C by ASTM D4052, flash point by ASTM D93 Procedure A, acid number by ASTM D974, and Gardner colour by ASTM D1544. The acid number is frequently below 1 mg KOH/g. Because the product is liquid, ring-and-ball softening point by ASTM E28 is not a meaningful specification; instead, viscosity and density serve as the primary batch-release parameters. Any generated laboratory data should not be extrapolated to production without verification against the current supplier certificate of analysis. The product should be sampled under closed or vented conditions to avoid moisture ingress and solvent loss.

    Solvent Compatibility and Phase Behaviour in Aliphatic-Aromatic Blends

    Liquid aromatic hydrocarbon resins of the LS500 class exhibit preferential compatibility with aromatic hydrocarbon solvents such as xylene, toluene, and high-boiling aromatic solvent naphtha. When strong aliphatic diluents are introduced, phase separation or hazing may occur before visible resin precipitation. Formulators should run cloud-point titrations using the production solvent blend and record the onset of turbidity. Fineness of dispersion after letdown should be checked by ASTM D1210. Viscosity at application solids should be determined with cone-and-plate geometry by ISO 2884-1 or ASTM D4287, with temperature controlled to ±0.2 °C.

    In high-solids coatings, the resin can replace a portion of the liquid plasticizer while maintaining spray viscosity. The effect on volatile organic compound content should be measured by ASTM D2369 or ISO 11890-2. Because LS500 is a non-volatile modifier, the mass balance shifts from volatile plasticizer to retained resin solids, but the final solvent demand depends on the resin’s viscosity contribution. High-solids alkyd formulations should be evaluated at 5–20 wt% on binder solids; the optimum addition level is determined by pendulum hardness, drying time, and accelerated weathering response.

    In chlorinated rubber maintenance primers, LS500 can be introduced during the pigment wetting step in a high-speed disperser equipped with a dissolver disc. Typical dissolver tip speed for liquid modifying resins of this class lies between 15 m/s and 20 m/s; higher speed may aerate the liquid resin, while lower speed may extend pigment wetting time. The liquid resin reduces mill-base yield point and permits higher pigment loading without a proportional increase in solvent demand. Finished coatings should be evaluated for adhesion to prepared steel by ISO 2409, salt-spray resistance by ASTM B117, and cyclic corrosion performance by ASTM D5894. In ambient-cured epoxy systems, the modifier is non-reactive but should not be used as the sole film-forming component; the effect on amine blush, intercoat adhesion, and recoat window must be validated for each hardener type.

    When LS500 replaces a phthalate plasticizer in a chlorinated rubber maintenance primer

    Plasticizer replacement ratios in chlorinated rubber primers are typically screened from 5 wt% to 15 wt% on total binder solids, with the replacement ratio adjusted to maintain minimum free-film elongation. Tensile properties of detached films should be measured by ISO 527-3 or ASTM D638-14, with specimen thickness and crosshead speed reported. A 1:1 by weight substitution of LS500 for a displaced phthalate or chlorinated paraffin may be used only as a starting point; differences in molecular weight and polarity alter hardness, water uptake, and migration behaviour. Water absorption of free films should be determined after 24 h immersion by ASTM D570 or ISO 62. If the coating is intended for indirect food contact or toy applications, migration and extractables testing under the relevant jurisdiction is required; published data for LS500 in these configurations is limited.

    Regulatory status must be verified against the supplier’s current safety data sheet and product declaration. The resin may be subject to REACH registration by the manufacturer; downstream coating producers remain responsible for exposure-scenario compatibility and local inventory status. Heavy-metal content should be confirmed by ISO 3856 methods or equivalent, particularly where coated articles are subject to RoHS Directive 2011/65/EU. The liquid resin’s flash point determines process safety classification under GHS/CLP and OSHA 29 CFR 1910.106; storage tanks, drum heaters, and transfer lines should be electrically bonded. Published data for the exact LS500 flash point is batch-specific and should be obtained from the supplier’s dangerous goods classification and transport document.

    Thermal Stability and Residual Volatility Under Elevated Cure Conditions

    Because LS500 is a liquid aromatic hydrocarbon resin, it may contain residual low-molecular-weight aromatic species. During forced-drying or stoving schedules, volatile loss can affect film thickness, gloss, and surface tack. Comparative weight-loss profiles should be generated by thermogravimetric analysis at 10 K/min under nitrogen by ISO 11358-1. Differential scanning calorimetry by ISO 11357-2 generally shows no appreciable crystallisation for the liquid resin, and the glass transition may remain below ambient. In stoving paints cured at 120–150 °C, low-molecular-weight fractions may migrate to the surface and alter slip, overcoatability, or recoat adhesion. Surface energy before overcoating should be measured by contact angle using ASTM D7490. Long-term viscosity stability can be monitored by ASTM D7042 after storage at 40 °C for 28 days in closed containers. The product should not be exposed to strong oxidising agents or stored near open flames above its flash point.

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