| HS Code | 280330 |
| Density | 0.945 g/cm3 |
| Melt Index | 0.45 g/10 min |
| Environmental Stress Crack Resistance Escr | >1000 hr |
| Tensile Strength At Yield | 24.8 MPa |
| Tensile Strength At Break | 31.0 MPa |
| Elongation At Break | 600% |
| Flexural Modulus | 1100 MPa |
| Hardness Shore D | 65 |
| Vicat Softening Point | 125 °C |
| Brittleness Temperature | -70 °C |
| Thermal Conductivity | 0.33 W/m·K |
| Coefficient Of Linear Thermal Expansion | 1.2E-4 /°C |
| Specific Heat | 1.9 J/g·°C |
As an accredited NOVA Chemicals HDPE HE-Y449-A factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | NOVA Chemicals HDPE HE-Y449-A is typically supplied in 25 kg polyethylene bags, with 1,000 kg bulk bags and bulk truck/railcar options available. |
| Container Loading (20′ FCL) | 20′ FCL container loaded with palletized 25 kg bags of NOVA Chemicals HDPE HE-Y449-A, shrink-wrapped and secured for ocean transport. |
| Shipping | NOVA Chemicals HDPE HE-Y449-A is shipped as non-hazardous polyethylene resin pellets in 25 kg bags, bulk bags, octabins, or bulk trucks/railcars. Keep containers closed, dry, clean, and away from heat, sunlight, and contaminants. No special DOT/IMDG/IATA hazard classification applies; follow local regulations and the SDS. |
| Storage | Store NOVA Chemicals HDPE HE-Y449-A indoors in a cool, dry, well-ventilated area, away from sunlight, heat, flames, and oxidizing agents. Keep original bags or containers closed, palletized, and off the floor to prevent moisture and contamination. Avoid excessive stacking and prolonged UV exposure. Maintain good housekeeping and first-in, first-out inventory. Do not store near incompatible materials or ignition sources. |
| Shelf Life | Typically stable for at least 24 months when stored unopened in a cool, dry, well-ventilated area away from sunlight and heat. |
In the closure and fitment moulding segment, HDPE HE-Y449-A is processed almost exclusively on high-cavitation hot-runner injection moulding systems, where valve-gate sequencing controls melt delivery to 48–96 cavities. The grade's melt mass-flow rate of 4.5 g/10 min under ASTM D1238 at 190 °C and 2.16 kg combined with a solid-state density of 0.949 g/cm³ under ASTM D792 positions it for short filling times in the thin tamper-evident band region. In a 2.2 g still-water closure run on a 48-cavity hot-runner system, barrel set points of 210–240 °C, mould temperatures of 8–16 °C, and peak injection velocities of 120–180 mm/s are typical, yielding cycle times between 4.5 s and 6.5 s. Gate diameters at the valve-gate tip are held to 0.6–0.9 mm; narrower gates create excessive shear heating and part-surface streaking, while wider gates extend gate-seal time and reduce cavitation balance. Tamper-evident slit bridges of 0.25–0.40 mm thickness require peak cavity pressures above 35 MPa to prevent short bridges and to maintain post-fill dimensional reproducibility. The closure body's flexural modulus contribution is anchored to a reported secant modulus of 1,180 MPa under ASTM D790; when paired with a dome thickness of 0.9–1.2 mm, this reduces ovalisation in capping chucks. For food-contact closure shells, the resin is evaluated under FDA 21 CFR 177.1520(c) olefin polymer provisions and under Regulation (EU) No 10/2011 with overall migration limits of 10 mg/dm² using EN 1186 methods; organoleptic threshold testing follows EN 1622 for water taint and odour. Moisture-related splay is not a dominant failure mode in this segment, but when granulated start-up purge is stored in open bins above 60% relative humidity, a 2 h hopper drying step at 80 °C is applied to maintain surface quality.
Thin-wall dairy cups, portion pack inserts, and deli containers moulded from HE-Y449-A are constrained less by plastication capacity than by gate-to-freeze-off time and the associated packing window. At wall stock of 0.35–0.60 mm and flow length-to-thickness ratios from 150:1 to 280:1, the resin must remain molten long enough for packing pressure to propagate through the solidified layer without exceeding the thermal degradation ceiling. In this segment, melt temperatures are generally held at 220–250 °C, while chilled water mould temperatures of 6–12 °C are used to strip heat; the practical lower bound is set by condensation and mottling on polished core surfaces. Injection velocity profiles are staged with an initial high-velocity segment of 150–220 mm/s to outrun premature freeze-off, followed by a reduced packing segment at 25–45 MPa cavity pressure. Gate thickness between 0.45 mm and 0.70 mm is maintained because freeze-off below 0.3 s after switchover results in unrelieved sink marks around the gate boss. Part ejection is validated with mould-open time short enough to prevent reheat bending; automated side-entry robots with vacuum cups and active de-misting are used when cycle time falls below 3.8 s.
| Regulatory framework | Cited provision | Test method | Basis |
|---|---|---|---|
| United States | FDA 21 CFR 177.1520(c) | Finished-article extractives and end-use conditions | Use conditions A–H |
| European Union | Regulation (EU) No 10/2011 | EN 1186 series | Overall migration < 10 mg/dm² |
| European Union | Regulation (EC) No 1907/2006 Annex XVII | Chemical restriction screening | SVHC candidate list |
Hot-fill upstream conditions above 80 °C are excluded because the Vicat softening point of 127 °C under ASTM D1525 and the 72 °C HDT under ASTM D648 leave narrow safety margins under head-space vacuum and lid-closure load. For cold-fill dairy dessert cups, sidewall deflections are controlled by rim-stacking ribs rather than by increased part mass; a rim cross-section of 1.0–1.3 mm with a 0.8 mm inner fillet is sufficient when the mould is fitted with valve gates that sequence from the centre gate to the rim gates to avoid weld-line side-entry failures.
For open-head industrial pails and tight-head inserts, the critical processing boundary is not flow length but the interaction between cooling time, sidewall crystallinity, and environmental stress-crack resistance. Nominal sidewall thickness of 1.8–2.2 mm in a 5 L to 20 L pail requires cooling times of 18–28 s, with mould temperatures of 10–25 °C and melt temperatures of 220–250 °C; the dominant failure mode on high-speed lines is warpage after lid sealing when the sidewall is demoulded with excessive residual stress. Peak injection pressure at the screw tip is typically 80–120 MPa, with a switchover position set at 6–8 mm of cushion and a packing stage of 40–60 MPa for 3–5 s. Bucket handle lugs and lid-retaining beads are processed with core-out or gas-counterpressure to avoid hollow sections, and the top rim is thickened to 2.5–3.0 mm to withstand stacking load. For hazardous-goods pails requiring UN packaging certification, design-type tests under ADR/RID/IMDG include a drop test from 1.2 m for Packing Group II and a 28-day stacking test at 40 °C; the requirement is not met by raw material selection alone, because weld-line integrity at the gate and handle insert zones dominates drop survival. Published data for this specific grade under 100% Igepal ASTM D1693 Condition A is limited, and therefore aggressive surfactant-containing liquids, especially those adjusted above pH 9 or containing high nonylphenol-ethoxylate fractions, require pre-qualification with the actual filled product. Where permeation resistance to hydrocarbons or flavour compounds is required, the pail surface is post-fluorinated to reduce weight loss below 0.5 g/m²·day in hydrocarbon barrier tests; the resin itself is not a barrier grade.
Beverage crates, logistics totes, and vented stack/nest containers moulded from HE-Y449-A usually carry nominal wall stock of 2.5–4.0 mm and intersecting ribs that drive differential shrinkage. Shrinkage anisotropy is controlled by packing-pressure decay profiling; cavity pressure is held at 40–60 MPa for 2–4 s, then stepped down in 10 MPa increments over 3–5 s to avoid overpacking at the rib root. On a 1,200–2,500 kN toggle clamp injection moulding machine with a cold-runner manifold, melt temperatures of 225–250 °C and mould temperatures of 12–25 °C are applied; the lower mould-temperature limit is dictated by sink marks at the handle bosses, and the upper limit by cycle-time extension beyond 35 s. Melt-flow length from centre gate to perimeter can exceed 350 mm, requiring four-valve-gate sequential opening when wall thickness falls below 2.5 mm, otherwise freezing at the flow front produces surface splay and weld-line weakness. Low-temperature impact is evaluated with ASTM D256 notched Izod; when crates are used in cold-chain logistics at -20 °C, a minimum notched Izod value of 35 J/m is generally used as an internal acceptance threshold, and if the raw resin does not meet this after regrind processing, the fill speed is reduced and the melt temperature raised 5 °C to shift molecular orientation away from the notch-sensitive plane. Outdoor exposure requires a UV-stabilised masterbatch at 2–4 wt% containing hindered amine light stabilisers and, for black crates, 0.5–1.0 wt% carbon black; accelerated weathering per ISO 4892-2 cycle 1 for 1,500 h is commonly used to screen colour shift and impact retention, though published data for this specific grade after weathering is limited.
Textured houseware surfaces impose a different constraint: etch depth, draft angle, and release force intersect with HDPE shrinkage and low surface hardness. Storage totes, laundry baskets, and home organisation trays moulded from HE-Y449-A frequently use chemically etched cavity textures of 25–75 µm, which demands draft angles of at least 1° per 0.025 mm texture depth to prevent scuffing and ejection drag. The coefficient of friction against a polished steel core is reduced when the tool includes an incremental ejection stroke of 3–5 mm with mould-open delay rather than relying solely on elevated mould temperature; ejection force data from stripper-plate systems shows that textured surfaces above 60 µm can require ejection forces 15–25% higher than polished counterparts. For a typical 1.5–2.0 mm wall home-storage tray, melt temperature is set at 220–240 °C, mould temperature at 12–20 °C, and holding pressure at 30–45 MPa; cycle time is constrained more by texture replication than by heat transfer because insufficient cavity pressure at the end of fill leaves micro-texture valleys incompletely formed. Gate placement is moved to the base plane rather than the rim to reduce visible flow marks on the textured exterior, and valve gates are preferred over edge gates when surface grain depth exceeds 50 µm. In electroplated or high-gloss inserts used as highlights, the resin's low melt temperature window reduces insert washout, but published data for this specific grade with in-mould labelling films is limited. Consumer articles in this segment must comply with REACH candidate-list screening for SVHCs and, where the article has a toy-like shape or is marketed for children, EN 71-3 migration limits for heavy metals; the resin must be blended with compliant colour concentrates because the base grade is not supplied with the finished-colour compliance package.
When post-consumer recycled high-density polyethylene is blended with HE-Y449-A at ratios above 15 wt%, the resulting melt-pressure trace on an injection moulding machine changes non-negligibly: screw recovery time increases, and first-stage injection pressure rises by 5–15% because the rheological blend is broader in molecular-weight distribution and may contain fractional-melt fractions from upstream blow-moulded scrap. Filtration levels before the melt accumulator should target 60 mesh or finer when the PCR stream includes detergent-bottle flake, but screen-pack retention can remove stabiliser and slip additives, so melt temperatures should not exceed 240 °C to limit additional carbonyl formation and yellowing. If the PCR content rises above 30 wt%, shut-off nozzle wear becomes measurable and check-ring leakage can begin to destabilise cushion control; therefore, the moulding cell should monitor screw cushion variability at ±0.5 mm and the shot weight coefficient of variation at ±0.2% or tighter. In food-contact applications, the blend does not inherit virgin compliance automatically; under Regulation (EU) 2022/1616, recycled plastics used in food-contact articles require either a suitable decontamination technology approval or novel technology status, and an extractives/migration assessment following EN 1186 must be carried out on the finished article, not only on the input flake. Published data for this specific virgin grade in PCR blends is limited; therefore, dimensional stability, impact retention, and odour migration must be evaluated per formulation rather than predicted from melt-flow ratio alone.
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NOVA Chemicals HDPE HE-Y449-A is a high-density polyethylene extrusion resin supplied as a pellet. The grade is defined by a nominal density of 0.949 g/cm³ when tested under ASTM D792 and a melt index of 4.9 g/10 min at 190°C / 2.16 kg per ASTM D1238. Under ASTM D883 polyethylene classification, a density above 0.941 g/cm³ places the material in the high-density category. The designation HE-Y449-A follows the NOVA Chemicals product nomenclature in which the letter prefix identifies the polyethylene density class and the numeric suffix encodes the nominal density and flow designation. The material is intended for extrusion blow molding, sheet extrusion, and thermoforming of industrial containers, agricultural storage tanks, and structural packaging. The supplier’s lot certificate should be consulted for product-specific lot values; the figures cited in this document are representative datasheet values and should not replace technical data sheets.
The melt flow ratio, expressed as I21/I2 under ASTM D1238, is typically near 52. This ratio describes shear thinning behavior and is a useful process-control parameter for extrusion blow molding. A moderate molecular weight distribution supports both acceptable parison stability and reasonable extrusion head pressure. In comparison with fractional-melt HDPE grades having melt index values below 1.0 g/10 min, HE-Y449-A exhibits lower melt strength and faster parison sag but permits lower head pressure and shorter cooling time in thick-walled articles. Conversely, compared with injection-molding HDPE grades having melt index values greater than 20 g/10 min, HE-Y449-A retains greater melt strength and higher environmental stress-crack resistance, but the flow length is shorter and thin-wall filling is more limited.
In extrusion blow molding, melt flow index controls parison sag, die swell, and extruder head pressure. For HE-Y449-A, the 4.9 g/10 min value places the material between low-flow large-part blow molding grades and high-flow injection grades. Processing on a single-screw extruder with an L/D ratio from 24:1 to 30:1 and a barrier screw is typical. A temperature profile beginning at 170°C in the feed zone, rising to 190°C in the compression zone, and stabilizing at 200°C to 210°C in the metering zone is used on production-scale lines. The melt temperature at the die is maintained between 190°C and 220°C. Above 220°C, oxidative degradation reduces melt strength and increases gel formation; below 190°C, higher melt viscosity increases head pressure and can produce melt fracture at die gaps below 2 mm. The acceptable processing window is therefore approximately ±10°C around a midpoint of 205°C.
Die swell in this flow class is lower than in fractional-melt HDPE. To compensate, die gap may be set 10% to 15% wider than for a 0.3 g/10 min grade. Blow ratios above 3:1 can produce non-uniform wall thickness in large industrial containers unless parison programming is used. In field trials, parison sag becomes measurable at draw lengths above 1,200 mm when the melt temperature exceeds 210°C. Processors using shuttle or reciprocating blow molding machines should monitor parison weight variation across molds; lot-to-lot melt index drift greater than ±0.5 g/10 min may require die gap adjustment to hold wall thickness within tolerance.
Moisture pickup on cold pellets is a surface-quality risk rather than a hydrolytic degradation mechanism. When pellets stored below 10°C are brought into a plant with relative humidity above 60%, condensation can produce splay, voids, or surface streaks in the parison. Pre-drying at 60°C to 70°C for 1 h to 2 h in a desiccant dryer removes surface moisture. The material should not be processed above 220°C with residence times exceeding 15 min, because crosslinking and gel formation can occur in dead zones behind the die spider legs or in accumulator heads.
Environmental stress-crack resistance is a key differentiator for HE-Y449-A in rigid packaging applications. The test is conducted in accordance with ASTM D1693, Condition B, 100% Igepal CO-630, F50. Published datasheet values for HE-Y449-A exceed 1,000 h, which is above the threshold typically required for agricultural chemical containers and industrial detergent packaging. The property is sensitive to molded-in stress, especially at pinch-off welds, parting-line flash, and corners with abrupt thickness transitions. In blow molded containers, weld-line regions may exhibit ESCR reductions of 30% to 50% relative to flat sidewall material unless mold temperature and pinch-off design are controlled.
The grade is compatible with many aqueous salt solutions, dilute acids, and mild alkaline cleaners at ambient temperature. Continuous exposure to strong oxidizing acids, aromatic hydrocarbons, or ketones above 40°C is not recommended. Service testing in accordance with ASTM D543 should be performed for aggressive formulations. HDPE density and ESCR are inversely related in general polyethylene design; a higher-density HDPE may raise flexural modulus but reduce ESCR by an order of magnitude under Condition B when density approaches 0.960 g/cm³. HE-Y449-A therefore occupies an intermediate position: it provides higher stiffness than 0.940 g/cm³ medium-density polyethylene while retaining sufficient ESCR for many structural containers.
| Property | Test Method | Typical Value |
|---|---|---|
| Density | ASTM D792 | 0.949 g/cm³ |
| Melt Index, 190°C/2.16 kg | ASTM D1238 | 4.9 g/10 min |
| Melt Flow Ratio, I21/I2 | ASTM D1238 | 52 |
| Tensile Strength at Yield | ASTM D638 | 26 MPa |
| Elongation at Break | ASTM D638 | >800% |
| Flexural Modulus | ASTM D790 | 1,150 MPa |
| ESCR, Condition B, 100% Igepal, F50 | ASTM D1693 | >1,000 h |
| Vicat Softening Point | ASTM D1525 | 126°C |
| Brittleness Temperature | ASTM D746 | < -75°C |
In sheet extrusion and thermoforming, the polymer is processed on a single-screw extruder with a barrier screw and a sheet die. Melt temperature at the die should be maintained between 200°C and 215°C. Sheet thickness is commonly produced in the range 2 mm to 12 mm. Low melt strength relative to fractional-melt HDPE requires proper die lip adjustment and roll stack contact to avoid sag between the die and polishing rolls. Thermoforming conditions for HE-Y449-A sheet generally require sheet surface temperature from 140°C to 165°C. Below 140°C, the sheet may not replicate mold geometry; above 165°C, the surface may show gloss variation or sheet thinning at mold corners. Tooling should allow for post-mold shrinkage of 1.5% to 2.5% in the machine direction and 1.0% to 2.0% in the transverse direction, with final dimensional checks made after 48 h at 23°C.
Thermoformed parts produced from HE-Y449-A sheet are used for dunnage trays, agricultural liners, and equipment housings. The primary processing conflict is between sheet temperature uniformity and cycle time. Ovens with zoned infrared heating are recommended when part draw depth exceeds 150 mm. A heating gradient from edge to center of more than 10°C leads to non-uniform wall thickness and can reduce ESCR at corner areas. On a production-scale three-station rotary thermoformer, cycle times for 6 mm HDPE sheet are generally limited by cooling rather than heating; mold temperature is held below 80°C to prevent post-demolding distortion. Aluminum tooling with water lines sized for 6 L/min to 12 L/min per mold segment is used to maintain local surface temperatures.
Comparison with medium-density polyethylene and high-density fractional-melt grades shows a predictable trade-off. Medium-density polyethylene of 0.940 g/cm³ density has lower flexural modulus but better low-temperature impact and lower thermoforming sheet sag. A fractional-melt HDPE of 0.955 g/cm³ density has higher stiffness and higher melt strength, but slower extruder throughput and higher orientation in formed parts. HE-Y449-A sits at an intermediate density and melt flow, making it suitable when the part requires structural stiffness and still needs to fill deep mold cavities. However, ultra-deep draw ratios above 4:1 may be limited unless the sheet is pre-stretched by plug assist. Published data for this specific configuration is limited for ultra-deep-draw applications; prototyping is required.
Regulatory compliance depends on the final article, additive package, and conversion history. The base resin may meet FDA 21 CFR 177.1520(c) for olefin polymers if the finished article density is above 0.94 g/cm³ and extractable limits are met. European food-contact use requires migration testing under EU Regulation No 10/2011 using the assigned food simulant and time-temperature exposure. The grade is subject to REACH registration requirements as an imported substance in the European Union. No lead, cadmium, mercury, or hexavalent chromium additives are intentionally added in the standard formulation, but finished-article concentration limits under RoHS Directive 2011/65/EU should be verified by XRF or digestion testing if the part is used in electrical or electronic equipment.
The material should be stored in a dry area below 40°C and protected from direct sunlight. Recycled material may be used in some non-food applications when the recycled content is from known HDPE sources and does not contain more than 5% polypropylene contamination; polypropylene forms a discrete phase that lowers ESCR and impact resistance at pinch-off seams. The grade is not recommended for outdoor service without ultraviolet stabilization. Carbon black or hindered amine light stabilizer additives are required for prolonged exposure, typically at loadings of 2% to 3% by weight for carbon black in sheet or rotomolded parts. The interaction of such additives with processability should be verified because carbon black can reduce melt index slightly and increase head pressure. Published data for the specific additive response of HE-Y449-A is limited; quality-control runs are advised.