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North Huajin Chemical ABS 345

    • Product Name: North Huajin Chemical ABS 345
    • Factroy Site: Yinchuan, Ningxia, China
    • Price Inquiry: sales8@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 307305
    Density 1.05 g/cm3
    Melt Flow Rate 2.0 g/10 min
    Tensile Strength 43 MPa
    Elongation At Break 25%
    Flexural Strength 65 MPa
    Flexural Modulus 2200 MPa
    Notched Izod Impact Strength 22 kJ/m2
    Heat Deflection Temperature 85 °C
    Vicat Softening Temperature 98 °C
    Rockwell Hardness 105 R
    Molding Shrinkage 0.4-0.6%
    Water Absorption 0.2-0.4%
    Flammability HB

    As an accredited North Huajin Chemical ABS 345 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing North Huajin Chemical ABS 345 is supplied in 25 kg moisture-proof woven bags, palletized for industrial handling.
    Container Loading (20′ FCL) North Huajin Chemical ABS 345 loaded in a 20′ FCL container, palletized and secured for safe export transport.
    Shipping North Huajin Chemical ABS 345 is shipped as non-hazardous ABS resin, usually in 25 kg moisture-proof bags or jumbo bags, palletized and stretch-wrapped. Transport in dry containers by sea/land; keep away from moisture, heat, and direct sunlight. No special dangerous-goods handling required.
    Storage Store North Huajin Chemical ABS 345 in a cool, dry, well-ventilated area away from direct sunlight, heat, flames, and ignition sources. Keep original packaging sealed to prevent moisture and contamination. Avoid prolonged high humidity and stack securely to prevent bag damage. Maintain good housekeeping and follow local regulations for combustible polymer storage.
    Shelf Life Shelf life is typically 12 months when stored in a cool, dry, ventilated area, away from direct sunlight and moisture.
    Application of North Huajin Chemical ABS 345

    Lot-specific control of ABS 345 in automotive interior substrates begins with closed-loop dehumidifying drying at 80 °C for 3–4 h, with a drying hopper air dew point no higher than −40 °C and residual moisture held at ≤ 0.02 wt%. On an injection-molding line equipped with a general-purpose screw of 20:1 to 24:1 L/D and compression ratio 2.0:1 to 2.5:1, the barrel profile is commonly set from 180 °C near the feed throat to 230–250 °C in the metering zone and 220–250 °C at the nozzle. Mold temperature is maintained at 40–70 °C. Injection velocity is typically held at 40–80 mm/s to limit hesitation marking on grained tool surfaces, while pack pressure is set at 50–70% of peak injection pressure for 4–8 s. These conditions support thin rib fill and surface replication without exceeding the thermal degradation threshold of the styrene-acrylonitrile matrix or over-shearing the butadiene rubber phase.

    Production-scale failure modes observed in this application segment include splay formation when dryer dew point drifts above −30 °C, delamination at weld lines when melt temperature drops below 220 °C, and gloss variation across large instrument-panel substrates when mold temperature fluctuates beyond ± 5 °C. For cockpit components, qualification commonly includes fogging condensate limits under DIN 75201/B, volatile organic compound emission screening under VDA 278, and notched Charpy impact retention after heat aging at 100 °C for 300 h. Mold shrinkage is evaluated according to ISO 294-4; typical mold shrinkage for ABS within this processing window is between 0.4% and 0.7%, but final tool correction values must be derived from the lot certificate and tool trials. Published data for this specific grade configuration is limited; processing boundaries should be established on the actual injection cell.

    When Chromic–Sulfuric Etching Precedes Electroless Nickel Deposition on ABS 345

    Decorative electroplating uses selective oxidation of the polybutadiene phase to generate microporous anchor sites on the molded surface. The etch bath for general electroplating ABS is controlled with chromium trioxide at 350–400 g/L, sulfuric acid at 180–250 g/L, and trivalent chromium below 30 g/L, with bath temperature maintained at 60–70 °C for 8–15 min. Surface tension and drag-out losses are controlled by wetting-agent concentration. Inadequate etch time leaves residual butadiene domains that fail to anchor the electroless nickel strike, while excessive etch time produces oversized surface voids that lower leveling and final chromium reflectivity. After etching, a reducing neutralization step removes hexavalent chromium residue before palladium/tin activation and subsequent electroless nickel deposition. Published data for ABS 345 in this specific etch configuration is limited; the ranges stated are industrial electroplating ABS targets and require lot-specific validation.

    Adhesion of the plated stack is evaluated after sequential deposition of copper, semi-bright nickel, bright nickel, and microporous chromium. Peel strength under ASTM B533 is generally specified above 2.0 N/mm for plated ABS components with wall stock above 2.5 mm, but this value is a general target rather than a certification value for ABS 345. Thermal cycling under ISO 2179 or OEM-defined shock schedules is used to expose loss of adhesion at gate areas, weld lines, and sharp corners. Etching time is therefore controlled as a narrow process window because both under-etching and over-etching create field failures that cannot be corrected after plating.

    Electroplating qualification matrix for ABS 345 substrates
    StandardParameterTypical acceptance window for general electroplating ABS
    ISO 15512:2019Residual moisture before molding≤ 0.02 wt%
    ASTM B533-85(2024)Peel strength of plated cross-section≥ 2.0 N/mm at 2.5 mm wall stock
    ISO 2179:2021Thermal cycling adhesionNo blistering or peeling over specified OEM cycles

    What Restricts Minimum Wall Thickness in Injection-Molded Appliance Front Panels?

    Minimum wall thickness in thin-wall front panels is governed by flow length to wall thickness ratio, gate location, and notched Charpy impact retention under ISO 179-1/1eA. At a nominal wall of 2.0 mm, flow ratios above 150:1 may require melt temperature near 250 °C; operation above 260 °C accelerates matrix degradation and can generate visible splay from volatilized additives. Hot-runner valve gates and sequential valve-pin control are used to maintain a narrow melt residence-time distribution and to reduce pressure loss across long flow paths. Weld lines formed between gate boundaries reduce impact strength more than the nominal wall reduction alone; mold-filling simulation using viscosity data obtained under ISO 1133-1:2022 is used to reposition weld lines outside snap-fit and screw-boss areas. Sink marks at reinforcing ribs are controlled by maintaining rib thickness at no more than 60% of the adjacent wall and by setting a stepped pack-pressure decay profile. Published data specific to ABS 345 in this thin-wall configuration is limited; production trials on the intended tool are required.

    Sheet extrusion lines processing ABS 345 commonly use a single-screw extruder with 30:1 to 34:1 L/D, barrier-flighted mixing geometry, and vacuum venting. Melt temperature at the sheet die is held between 220 °C and 240 °C, while the polished three-roll stack operates at 60–90 °C for high-gloss surfaces; lower roll temperatures reduce gloss uniformity and increase orientation stress. Sheet thickness from 1.5 mm to 5.0 mm is post-trimmed through gauging systems with ± 0.05 mm variation. Thermoforming requires sheet surface temperature of 140–170 °C and mold temperature of 60–80 °C; sag control is managed by infrared heating zone profiling. Impact resistance under ASTM D256 or ISO 180/1A is influenced by sheet orientation, with transverse impact retention frequently lower than machine direction. Fabricated parts exposed to oil, grease, or screen-cleaning solvents require compatibility testing because ABS is not resistant to ketones, esters, or chlorinated hydrocarbons.

    Flame-Retardant Masterbatch Dilution and Processing-Stabilizer Selection

    Halogen-free flame-retardant compounds based on ABS 345 are produced by twin-screw compounding with typical L/D between 32:1 and 40:1. When resorcinol bis(diphenyl phosphate) type flame-retardant packages are used, the phosphate plasticizes the SAN phase, reduces melt viscosity, and narrows the thermal processing window because high-shear zones above 240 °C promote acid-catalyzed degradation and black speck formation. Barrel temperature profiles are therefore set 10–20 °C lower than unfilled ABS compounding conditions. Volatile phosphate species can plate out on vacuum pump components and pelletizer water systems if venting is insufficient; a vent-port vacuum of −0.08 MPa or better is typically required to control deposit formation. Amine-based antistatic additives are incompatible in this system because they can hydrolyze phosphate ester flame retardants and accelerate molecular-weight loss.

    Thermal stabilizer selection for the halogen-free system uses hindered phenolic antioxidants at 0.1–0.3 phr and phosphite secondary stabilizers at 0.1–0.2 phr; overdosing raises extractables and can alter UL 94 after-aging performance. Flame-retardant compound qualification uses UL 94 vertical burn classification, glow-wire ignitability at 750 °C according to IEC 60695-2-12, and limiting oxygen index under ISO 4589-2. Impact retention after flame-retardant addition follows ISO 180/1A; when notched impact falls below the application requirement, the compounder must rebalance rubber graft content rather than continue increasing flame-retardant loading. Published multivariate optimization data for ABS 345 in halogen-free flame-retardant systems is limited; laboratory compounding with production-scale twin-screw equipment is required to establish the grade-specific response surface.

    Flame-retardant ABS 345 compound qualification matrix
    StandardTestSpecimen or apparatus
    UL 94Vertical burn classificationBar 125 mm × 13 mm, thickness tested
    IEC 60695-2-12Glow-wire ignitabilitySpecimen 60 mm × 60 mm, test temperature 750 °C
    ISO 4589-2Limiting oxygen indexBar 80 mm × 10 mm × 4 mm
    ISO 1133-1:2022Melt mass-flow rate220 °C, 10 kg

    Low-temperature impact requirements for checked luggage shells are achieved with ABS 345 when the lot certificate confirms notched Charpy impact retention adequate for the defined application. The shell is formed from extruded sheet stock and trimmed with CNC routers; parts are stress-relieved at 80 °C for 2 h to reduce solvent crazing at routed edges. Corners and wheel-well areas remain the highest stress concentrations, with impact resistance qualified under ISO 179-1/1eA at −20 °C. Chemical resistance test protocols include surface exposure to jet fuel, mineral oil, and perspiration simulant; ABS surfaces show stress cracking when exposed to ketone-containing cleaning agents. Recyclate reincorporation beyond 20 wt% can reduce high-shear melt strength and lower the thermoforming window by 5–10 °C, requiring tighter control of sheet temperature and screw torque. Lot-to-lot melt flow variation should be maintained within ± 5% of the qualified value to preserve sheet gauge uniformity in production.

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    Certification & Compliance
    More Introduction

    North Huajin Chemical ABS 345 is a medium-flow acrylonitrile-butadiene-styrene injection molding resin produced by North Huajin Chemical Industries Group. The numeric designation 345 identifies a specific viscosity-rubber balance within the supplier’s ABS grade slate and does not directly encode a melt flow rate or Izod impact value. Published lot-specific datasheet values for this grade are limited in secondary industrial databases; procurement-grade verification therefore requires the supplier’s certificate of analysis and, where available, a production trial lot. Segment-level property descriptions for medium-flow ABS injection molding resins place the material within an ISO 1133-1:2022 melt mass-flow rate range of 10 g/10 min to 30 g/10 min at 220 °C/10 kg, an ISO 1183-1:2019 density range of 1.04 g/cm³ to 1.06 g/cm³, and an ISO 180:2019 notched Izod impact range of 18 kJ/m² to 28 kJ/m² at 23 °C. These ranges define the class in which ABS 345 is positioned; they are not certified lot-release values.

    Tensile yield stress for this medium-flow segment is typically measured at 40 MPa to 48 MPa under ISO 527-2:2012, flexural modulus at 2100 MPa to 2600 MPa under ISO 178:2019, and Vicat softening temperature B50 at 95 °C to 105 °C under ISO 306:2022. The melt exhibits pronounced shear thinning; capillary rheometry at 230 °C generally records apparent viscosity below 100 Pa·s at shear rates above 1000 s−1. These rheological characteristics support short residence-time injection molding in complex tool geometries while limiting the ability to extrude thick profiles with melt strength. The two-phase morphology comprises a rigid styrene-acrylonitrile matrix and dispersed polybutadiene or styrene-butadiene rubber particles. Medium-flow grades such as ABS 345 balance rubber content and matrix molecular weight to obtain sufficient melt fluidity while retaining notched impact. Capillary rheometry at 230 °C shows shear-thinning behavior typical of ABS: apparent viscosity falls from approximately 300 Pa·s at 100 s−1 to below 100 Pa·s at 1000 s−1. This viscosity decline is important when filling ribs, thin bosses, and flow-length-to-wall-thickness ratios above 150:1.

    Mechanical property comparisons are valid only when test specimens are injection molded and stored according to ISO 294-1:2017 and ISO 291:2008. Variations in mold surface temperature, injection velocity, and packing pressure can shift notched Izod impact by more than 10% even when the same resin lot is tested.

    Conditioning, Drying, and Reciprocating Screw Processing Boundaries

    ABS is hygroscopic, and the processing boundary for ABS 345 is set by residual moisture. Pellets stored in open containers at ambient relative humidity above 60% require dehumidifying forced-air drying at 80 °C for 2 h to 4 h; target moisture content before melt processing is below 0.1%. Drying at 90 °C or higher can cause pellet surface tack and bridging in the hopper if residence time exceeds 6 h. The moisture limit is not a minor recommendation: injection at residual moisture above 0.2% produces hydrolysis-induced molecular weight loss, splay and silver streaking in thick sections, and measurable loss of notched Izod impact according to ISO 180:2019.

    On a general-purpose reciprocating screw injection molding machine, the recommended barrel temperature profile for medium-flow ABS is typically 200 °C rear, 220 °C middle, 230 °C front, and 235 °C nozzle, with actual melt temperature checked by needle-probe pyrometry at 235 °C to 245 °C. Mold surface temperature should be regulated with pressurized water or oil thermolators at 40 °C to 80 °C. Lower mold temperatures reduce cycle time but intensify frozen-in orientation and lower weld-line strength; higher mold temperatures improve surface gloss and impact but lengthen cooling and increase sink mark risk.

    For a 45 mm general-purpose screw in a 2500 kN clamp force machine, screw recovery speed should be limited to 0.15 m/s to 0.25 m/s to prevent gas entrapment and shot-weight instability. Cushion control should hold ±1.5 mm to maintain packing reproducibility. Injection velocity is usually set from 30 mm/s to 80 mm/s depending on flow length and wall thickness. Packing pressure typically falls between 40 MPa and 70 MPa hydraulic, held for 3 s to 8 s on parts with nominal wall 2 mm to 3 mm.

    Screw design for ABS 345 favors a general-purpose polyolefin screw with a compression ratio between 2.0:1 and 2.8:1, length-to-diameter ratio 20:1 to 24:1, and a check ring of ball-check or ring-check type. Vented barrels are generally unnecessary and may increase gas entrainment if the vent is not matched to screw decompression.

    Processing envelope for medium-flow ABS injection molding grades
    ParameterTypical RangeMonitoring Method
    Drying temperature80 °CDehumidifying forced-air dryer, outlet dew point below -20 °C
    Drying time2 h–4 hResidual moisture below 0.1%
    Barrel temperature profile200 °C/220 °C/230 °C/235 °C rear to nozzleImmersion melt probe 235 °C–245 °C
    Mold temperature40 °C–80 °CPressurized water or oil thermolator
    Screw recovery speed0.15 m/s–0.25 m/sScrew rotation limit on injection unit
    Cushion tolerance±1.5 mmPosition transducer on injection ram

    When a molded enclosure must balance cost, dimensional reproducibility, and impact resistance without requiring higher flame retardance than UL 94 HB, ABS 345 is deployed in appliance fascia, electrical switch covers, consumer electronics housings, and general-purpose industrial guards. Dimensional tolerance capability is contingent on mold temperature uniformity and post-mold shrinkage control; processing with mold temperatures in the 50 °C to 70 °C range typically yields shrinkage of 0.4% to 0.7% in flow direction and 0.5% to 0.8% transverse, evaluated after 48 h at 23 °C and 50% relative humidity per ISO 291:2008. Unmodified ABS 345 should not be specified for applications requiring UL 94 V-0 at 1.5 mm; flame-retardant ABS formulations occupy that service space.

    Field data on 2800 kN hydraulic presses with multi-cavity hot-runner tools indicates that medium-flow ABS can maintain gate-to-gate weight variation below 0.35% when melt pressure at the nozzle is held within ±1.0 MPa and hot-runner manifold temperature is held below 245 °C. Failures observed in production include gate blush and cosmetic flow lines when injection velocity exceeds 80 mm/s for polished mold surfaces, and plate-out on valve-gate stems after continuous running above 250 °C for more than 8 h. Hot-runner nozzle tips should be profiled with separate temperature zones to avoid local overheating. Multi-cavity filling imbalance can be corrected by independent nozzle temperature offsets of ±5 °C rather than by raising overall melt temperature.

    What Separates a Medium-Flow ABS 345 from High-Impact Extrusion Grades and High-Flow Thin-Wall ABS?

    ABS 345 is differentiated primarily by its melt-flow/rubber-toughness balance. High-impact ABS grades, often intended for extrusion or thick-section molding, contain a higher rubber-phase volume fraction and exhibit lower ISO 1133-1:2022 melt flow, commonly below 8 g/10 min at 220 °C/10 kg, with notched Izod impact above 30 kJ/m². They deliver greater crack-arrest capability in thick-wall components but require higher barrel temperatures, consume more energy in plasticization, and are less suited to filling ribs and thin sections. High-flow ABS grades occupy the opposite end of the design space; melt flow rates may exceed 30 g/10 min at 220 °C/10 kg, but notched Izod impact can fall below 15 kJ/m². These materials fill thin-walled parts but show lower toughness and greater susceptibility to embrittlement after heat aging.

    Relative to HIPS, ABS 345 has higher tensile yield strength and heat resistance but lower resistance to polar solvents such as ketones and esters. Relative to PC/ABS blends, ABS 345 has lower notched impact and lower heat deflection temperature but offers lower density, lower processing temperature, and lower melt pressure required to fill long thin sections. When an application requires recovery from high-speed impact at low temperature below -20 °C, ABS 345 is not a direct substitute for PC/ABS or high-impact ABS; the lower rubber content limits low-temperature ductility.

    Comparative positioning of ABS 345 within the ABS grade spectrum
    PropertyMedium-flow ABS (ABS 345 position)High-impact ABSHigh-flow ABS
    Melt mass-flow rate, ISO 1133-1:2022 at 220 °C/10 kg10 g/10 min–30 g/10 min<8 g/10 min>30 g/10 min
    Notched Izod impact, ISO 180:2019 at 23 °C18 kJ/m²–28 kJ/m²>30 kJ/m²<15 kJ/m²
    Vicat softening temperature B50, ISO 306:202295 °C–105 °C95 °C–105 °C90 °C–100 °C
    Typical wall thickness capability1.5 mm–3.2 mm2.5 mm–4.5 mm0.8 mm–1.5 mm

    If the material is molded in a tool with long flow lengths exceeding 200 mm, melt flow rate alone does not predict fill; flow-length-to-wall-thickness ratio, gate size, and packing pressure dominate. Medium-flow ABS at 240 °C melt can often fill a 150:1 flow ratio at 2.5 mm wall thickness, but a 250:1 ratio generally requires a high-flow grade or a higher melt temperature. This boundary separates ABS 345 from high-flow ABS used in thin-wall appliance covers.

    Regrind addition up to 20% by weight is common for non-appearance parts when granulate is clean and dried. Higher regrind fractions may reduce notched Izod impact and color consistency. For appearance-critical components, regrind is typically limited to 10% and controlled with melt filtration to avoid black specks from degraded hot-runner residues.

    For electrical and appliance applications, material acceptance may include RoHS recast 2011/65/EU Annex II substance restrictions and REACH candidate list verification. ABS 345 unmodified is not inherently UV-stable; outdoor exposure requires pigmentation or paint when UV resistance is specified. Lot-to-lot consistency should be assessed by melt flow rate per ISO 1133-1:2022, notched Izod per ISO 180:2019, and Vicat B50 per ISO 306:2022. Dimensional release testing should reference ISO 294-4:2018 for shrinkage.

    If ABS 345 is dried below 0.1% residual moisture but the melt is held above 260 °C for more than 12 min, thermal degradation initiates, producing yellowing, butadiene-phase crosslinking, and a measurable drop in notched Izod impact. The same thermal boundary applies to hot-runner overflows and long residence-time color changes. Production scheduling should avoid barrel residence times above 15 min and use melt decompression zones no deeper than 3 mm on the screw to minimize air entrapment.

    Chemical incompatibility boundaries include exposure to ketones, esters, aldehydes, and chlorinated solvents; these cause stress cracking in molded parts under applied strain. The grade should not be compounded with amine-based flame retardants that can accelerate thermo-oxidative degradation in the butadiene phase during melt processing. Because published data for ABS 345 under specific heat-aging protocols is limited, long-term end-use qualification should include thermal aging at 90 °C for 500 h per ASTM D3045-18 or customer-specific thermal cycling when electrical enclosure standards apply.

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