| HS Code | 498385 |
| Product Name | Nippon A&L ABS AP-2 |
| Manufacturer | Nippon A&L Inc. |
| Material Type | Acrylonitrile Butadiene Styrene (ABS) |
| Density | 1.04 g/cm³ |
| Melt Flow Rate | 20 g/10 min (220°C, 10 kg) |
| Tensile Strength | 45 MPa |
| Elongation At Break | 20% |
| Flexural Strength | 75 MPa |
| Flexural Modulus | 2300 MPa |
| Izod Notched Impact Strength | 20 kJ/m² |
| Rockwell Hardness | 105 R |
| Heat Deflection Temperature | 80°C (1.82 MPa) |
| Vicat Softening Temperature | 95°C |
| Molding Shrinkage | 0.4–0.6% |
| Ul Flammability Rating | HB |
As an accredited Nippon A&L ABS AP-2 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Nippon A&L ABS AP-2 is typically supplied in 25 kg moisture-resistant paper sacks, palletized for industrial use. |
| Container Loading (20′ FCL) | Nippon A&L ABS AP-2 is packed in 25 kg bags and loaded into a 20′ FCL dry container, evenly distributed and securely restrained. |
| Shipping | Nippon A&L ABS AP-2 is a solid ABS thermoplastic resin, usually supplied as pellets in sealed bags or containers. Ship dry, protected from moisture, heat, and sunlight. It is typically not classified as dangerous goods; follow the SDS and applicable transport regulations. |
| Storage | Store Nippon A&L ABS AP-2 in a cool, dry, well-ventilated area away from direct sunlight, heat, sparks, and open flames. Keep containers or bags tightly closed, clearly labeled, and palletized off the floor. Store only in original or compatible packaging. Prevent moisture, dust, and contamination. Avoid strong oxidizers and follow the manufacturer’s SDS and local regulations. Do not stack excessively. |
| Shelf Life | Shelf life is approximately 24 months when stored unopened in a cool, dry, well-ventilated area away from direct sunlight. |
Nippon A&L ABS AP-2 is an unfilled injection-molding acrylonitrile-butadiene-styrene grade with polybutadiene rubber morphology engineered for decorative electroplating, high-gloss metallized surfaces, painted housings, and cosmetic trim. The application entries below are limited to downstream sectors where electroplating-grade ABS is used in industrial practice; each entry records the regulatory boundary, formulation or addition ratio, downstream processing sequence, and finished article class. Processing values are stated as typical ranges for electroplating ABS because lot-specific melt volume-flow index under ISO 1133-1:2022 at 220°C/10 kg, rubber particle size distribution, and residual moisture specification must be read from the Nippon A&L certificate of analysis. Where published data for AP-2 in an exact tooling geometry or bath configuration are limited, the limitation is stated rather than inferred.
In automotive radiator grille and exterior trim production, Nippon A&L ABS AP-2 functions as the unfilled electroplating substrate because the dispersed polybutadiene domains create etchable anchoring sites when oxidized in chromic acid, removing the need for conductive fillers or secondary adhesion primers. The press-side formulation is 100 parts virgin AP-2 pellets by weight; an ABS-carrier carbon black masterbatch may be added at 0.5–2.0 wt% only when a pre-color is required on hidden non-plated surfaces, and regrind from unplated sprues is limited to 20 wt%. Drying is carried out in desiccant hopper dryers with actual dew point below −30°C, at 80°C for 2–4 h, to hold pellet moisture below 0.02 wt%; higher moisture produces splay and sub-surface voids that later emerge as blisters during electroplating bake cycles. Molding is executed on hydraulic or servo-electric injection molding machines with clamp force between 12,000 kN and 30,000 kN, reciprocating screw L/D of 20:1 or 24:1, and melt temperature held at 230–250°C; steel mold temperature is controlled at 40–80°C to balance surface gloss and residual stress. Mold wall temperature below 40°C raises residual stress, which can appear as microcracking after thermal cycling, while wall temperature above 80°C lengthens cycle time without proportional gloss advantage. Automotive plating lines typically sequence hot soak degreasing, chromic acid-sulfuric acid etch at 380–420 g/L CrO₃ and 350–400 g/L H₂SO₄, 60–70°C, 5–15 min, acid neutralization, tin-palladium activation, electroless nickel at 30–40°C, electrolytic acid copper at 2–4 A/dm², semi-bright/bright nickel at 3–6 A/dm², and microcracked chromium at 10–20 A/dm². Etch depth is held between 0.5 µm and 1.5 µm; under-etching below 0.2 µm commonly reduces peel strength, while over-etching above 2 µm roughens the substrate and lowers final gloss. Adhesion is verified after thermal cycling by ASTM B533-85 peel testing, and decorative plating performance is classified under ASTM B604-91 service condition SC 4. Automotive compliance additionally references RoHS 2011/65/EU and ELV 2000/53/EC for the absence of restricted cadmium and hexavalent chromium in the finished plated surface. Published lot-to-lot data for AP-2 in very wide radiator grille geometries under the most aggressive OEM thermal-cycle protocols are limited; qualification therefore includes plated 150 mm × 100 mm × 3 mm plaques from the same lot to detect lot-level rubber morphology shift. Terminal finished parts drawn from this process include radiator grilles, tailgate appliques, wheel covers, mirror housings, door handle bezels, and front emblem bases.
Bathroom and sanitary fitting molders use ABS AP-2 for nonstructural decorative components such as faucet handles, lever trims, shower escutcheons, tub spout covers, and pop-up drain flanges where bright chromium or satin nickel must survive wet-bath humidity and occasional cleaning-product contact. Because electroplating adhesion is controlled by the surface concentration of finely distributed polybutadiene domains, the molding formulation prohibits external lubricants and non-ABS carriers: 100 parts AP-2 by weight, regrind from unplated runners held at or below 10 wt% when the molded part is installed in a humid bathroom environment, and ABS or MABS masterbatch at 1.0–2.0 wt% only when the base color must be adjusted before plating. Zinc stearate, calcium stearate, silicone oil, and wax-based mold releases are incompatible with the etch process because they remain on the part surface and generate skip plating or local adhesion loss. Multi-cavity sanitary trim is usually molded on hot-runner tools with sequential valve gating; melt temperature is held at 230–250°C, mold temperature at 50–70°C, and hold pressure is profiled to minimize sink marks around bosses. The pre-plate sequence for bathroom parts uses a slightly shortened etch cycle—380–400 g/L CrO₃, 350–380 g/L H₂SO₄, 65–70°C for 4–8 min—to avoid excessive micro-roughness on polished thin-wall surfaces below 2.0 mm. Electroless nickel is followed by copper, bright nickel, and chromium; adhesion is checked by thermal cycling and ASTM B533-85 peel testing. Regulatory references for potable water catchment or incidental contact are NSF/ANSI 61 for wetted surfaces and AS 4020 for the Australian market, while nickel release for skin-contact metallic coatings is assessed by EN 1811. Published data for AP-2 under sustained hot-water extraction cycles are limited, so pre-production samples should be tested on the final plated part rather than on unplated plaques. The terminal product set comprises faucet handles, escutcheons, spout covers, drain flanges, and shower trim rings.
| Application sector | Standards framework | Key test method | Processing boundary for AP-2 |
|---|---|---|---|
| Automotive electroplated trim | ASTM B604-91, RoHS 2011/65/EU, ELV 2000/53/EC | ASTM B533-85 peel adhesion; thermal cycle −30°C/80°C | Regrind ≤20 wt%; etch depth 0.5–1.5 µm |
| Sanitary fittings | NSF/ANSI 61, AS 4020 | Potable water extractables; nickel release EN 1811 | Regrind ≤10 wt%; no zinc stearate or silicone release |
| Household appliances | IEC 60335-1:2020, UL 94 HB | Clause 30 resistance to heat and fire; visual gloss retention | Unfilled grade only HB; V-0 requires alternative grade |
| Consumer electronics | IEC 62368-1:2023, RoHS 2011/65/EU | ASTM B604-91 SC 1/SC 2; ASTM B533-85 | Regrind 10–20 wt%; weld lines must be relocated |
| Cosmetic packaging | EC 1223/2009, REACH (EC) No 1907/2006 Annex XVII | EN 1811 nickel release | Regrind ≤10 wt%; fragrant ester contact requires immersion testing |
| Office automation | IEC 62368-1:2023, UL 94 HB | Dimensional control ±0.05 mm; paint adhesion | Not for V-0 fire enclosures |
Because household appliance control consoles are exposed to detergent vapor, polycarbonate lens heat, and repeated touch wear, ABS AP-2 is injection-molded into high-gloss decorative panels that are either electroplated with bright chrome or painted with UV-cured topcoats. The press-side ratio is 100 parts AP-2; color masterbatch with an ABS carrier is limited to 0.5–1.5 wt% and regrind is restricted to 15 wt% so that visible surfaces do not accumulate fine black specks or yellowing. Injection is run on 1000–4500 kN hydraulic machines with 20:1 L/D general-purpose screws, melt temperature at 230–250°C, mold temperature at 50–70°C, and gate positions moved behind decorative trim or into non-visible edges because gate blush persists after chromium plating. Electroplated appliance parts use a copper-nickel-chromium stack per ASTM B604-91 SC 1 or SC 2, and painted parts receive cleaning/plasma pretreatment followed by primer and UV topcoat to reach specification gloss. Household equipment compliance is evaluated under IEC 60335-1:2020 Clause 30 for resistance to heat and fire and UL 94 HB; V-0 is not available for unfilled AP-2, so this grade is confined to decorative panels, bezels, and trim that fall outside uninhabited appliance flame-retardant requirements. Finished articles include washing machine control consoles, refrigerator door trim strips, air-conditioner display surrounds, knob rings, and badge strips.
For consumer electronics bezels, the dominant processing failure is not plate peeling but weld-line surface porosity: two melt streams meeting inside a thin-wall monitor bezel produce a V-notch-like surface that is amplified after bright nickel and chromium deposition. Molding practice therefore positions valve-gate hot runners at the highest wall section and uses overflow tabs to relocate weld lines to hidden edges. The formulation is 100 parts AP-2; regrind is permitted only up to 10–20 wt% when it consists of unchromated runners and rejected pre-plate parts dried to below 0.02 wt% moisture. Etched but not plated parts are excluded from regrind because palladium-tin residues from activation can nucleate defects in the next molding shot. Melt temperature is controlled at 235–250°C, mold temperature at 40–70°C, and hot-runner manifold temperature is set to match melt temperature within ±5°C to avoid thermal degradation at residence times beyond 5 min. Electroplating for electronics cosmetic surfaces follows ASTM B604-91 service condition SC 1 or SC 2; adhesion is verified by ASTM B533-85 peel testing and thermal cycling between −30°C and +80°C. Equipment compliance references IEC 62368-1:2023 for audio/video and ICT enclosures and RoHS 2011/65/EU for the plated finish. Terminal finished goods include monitor bezels, television front frames, router housings, and portable speaker decorative rings.
Fragrance caps, lipstick sleeves, and toiletry outer jackets are molded from Nippon A&L ABS AP-2 when the brand specification requires mirror-bright chromium or gold-tone electroplated surfaces with press-fit or snap-fit attachment to glass bottles and polypropylene collars. The molding ratio is 100 parts AP-2; in-house regrind is capped at 10 wt% and post-consumer recycled ABS is excluded where packaging contact with fragrance formulations requires traceability under EC 1223/2009. High-gloss cosmetic parts are produced on polished P20 or S136H tooling with diamond-polished cavities, mold temperature at 60–80°C to reproduce cavity gloss, and injection speed profiled to prevent gate jetting. Electroplating uses a shortened chromic acid etch—380–400 g/L CrO₃, 350–380 g/L H₂SO₄, 65–70°C for 4–8 min—to preserve the polished substrate, followed by electroless nickel and bright nickel-chromium. Heavy-metal and nickel-release constraints for skin-contact metallic surfaces are governed by REACH (EC) No 1907/2006 Annex XVII and EN 1811; if the plated layer is topcoated with a transparent lacquer, the nickel-release test is performed on the lacquered state. The terminal produced parts are fragrance caps, lipstick sleeves, jar collars, and vanity box bezels. A limitation applies: continuous contact with ester-rich perfume or alcohol above 45°C may attack unbarrier-coated ABS AP-2, so chemical compatibility under the actual fragrance filling formulation is required by ISO 175 immersion testing before volume production.
When office automation enclosure dimensions must be held within ±0.05 mm, painted ABS AP-2 substitutes for plated housing shells because electroplating adds 15–30 µm of metal thickness that can close snap-fit clearances and alter part mass. The molding formula is 100 parts AP-2; titanium dioxide or carbon black masterbatch is added at 1.0–2.0 wt% to adjust base shade for paint cover, and regrind up to 20 wt% is accepted because the primer and topcoat mask minor yellowing. Injection molding is carried out at 230–250°C melt temperature in hardened tooling with interchangeable inserts for printhead window apertures; post-mold surface treatment includes antistatic air cleaning, adhesion-promoting primer, and UV-curable acrylic topcoat. Office equipment enclosures are evaluated under IEC 62368-1:2023 and UL 94 HB; V-0 housings are outside the capability of unfilled AP-2, so a flame-retarded ABS or PC/ABS grade is specified where fire enclosures require a V-0 burn classification. Terminal parts are printer front panels, scanner housings, and multifunction printer document trays.
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Nippon A&L ABS AP-2 is a plating-grade acrylonitrile-butadiene-styrene resin supplied as cylindrical pellets for injection molding of metallized automotive, sanitary, and consumer-electronic components. The terpolymer comprises a continuous styrene-acrylonitrile phase and a dispersed polybutadiene rubber phase; this two-phase structure is retained during molding and is selectively etched in subsequent electroplating. Grade-specific lot certificates rather than generic datasheets should govern machine settings. For preliminary process design, class-typical values for plating ABS include a density of 1.04–1.06 g/cm³ under ISO 1183-1, a melt volume-flow rate of 15–25 cm³/10 min under ISO 1133-1:2022 at 220 °C and 10 kg, tensile yield stress of 40–50 MPa under ISO 527-2, flexural modulus of 2,200–2,500 MPa under ISO 178, notched Charpy impact strength of 20–30 kJ/m² at 23 °C under ISO 179-1/1eA, Vicat softening temperature of 96–104 °C under ISO 306/B50, and heat deflection temperature of 82–90 °C under ISO 75-2/Af at 1.80 MPa. Because Nippon A&L does not publish a single fixed specification for every production lot, the above should be treated as a class reference, not a contractual value.
Processing on production-scale reciprocating-screw machines requires attention to shot size, residence time, and moisture. On a 180 t clamp-force injection molder with a 50 mm screw and 20:1 L/D, shot weights above 65% of barrel capacity can reduce melt homogeneity and increase pressure variation at transfer. The material should be processed at a melt temperature measured at the nozzle of 230–250 °C. Mold temperatures below 40 °C are not recommended because they produce high frozen-skin orientation and lower electroplate adhesion. A mold temperature of 60–80 °C is used when low molded-in stress is critical. Injection velocity should be set to produce a fill time between 1.5 s and 3.0 s for wall sections of 2.0–3.0 mm; higher speeds reduce hesitation marks but can generate shear-induced gel specks.
The primary distinction between AP-2 and a high-flow general-purpose ABS is not the SAN continuous phase but the dispersed butadiene particle size distribution and grafting density. Plating-grade ABS of this class typically contains rubber particles with a bimodal size distribution centred near 0.2 μm and 0.8 μm, producing a high density of etchable surface sites without forming continuous rubber networks that reduce plate leveling. General-purpose injection grades may carry rubber content of 10–15 wt%; AP-2-class materials often operate at 18–25 wt% butadiene, which raises low-temperature ductility and reduces melt flow relative to high-flow grades. Heat-resistant ABS based on alpha-methylstyrene or maleimide comonomers will exhibit Vicat values from 110 °C to 125 °C but require melt temperatures above 260 °C and show longer relaxation times; this makes them less suitable for deep-etch electroplating because internal orientation can produce differential swelling at the etch interface. A PC/ABS blend offers lower-temperature impact below -30 °C, but its carbonate phase is susceptible to hydrolysis at high-humidity storage unless dried to ≤0.02 wt% and it is not uniformly etched by a chromic-sulfuric bath, so plate adhesion depends on special pre-treatment. AP-2 is therefore positioned for applications where moderate heat resistance is acceptable and metallization quality is the controlling requirement.
| Property and test method | Plating-grade ABS class, AP-2 reference | High-flow general-purpose ABS | Heat-resistant ABS |
| Melt volume-flow rate at 220 °C, 10 kg, ISO 1133-1 | 15–25 cm³/10 min | 30–60 cm³/10 min | 5–15 cm³/10 min |
| Notched Charpy impact strength at 23 °C, ISO 179-1/1eA | 20–30 kJ/m² | 10–18 kJ/m² | 15–25 kJ/m² |
| Vicat softening temperature, ISO 306/B50 | 96–104 °C | 95–100 °C | 110–125 °C |
| Heat deflection temperature at 1.80 MPa, ISO 75-2/Af | 82–90 °C | 80–86 °C | 100–115 °C |
A desiccant-bed dryer with a dew point no higher than -30 °C is required when ambient relative humidity exceeds 60%. Drying at 80 °C for 3–4 h is common, but the actual time must be extended to 6 h when pellets have been stored in unsealed containers at 23 °C and 70% RH. Residual moisture above 0.05 wt% produces splay, silver streaks, and voiding at the gate; in electroplating, steam expansion during plasticating creates microporosity that later traps chromic acid and produces skip plating or adhesion loss. Hot-air dryers should not replace desiccant systems because the equilibrium moisture content of ABS pellets in humid air remains above 0.08 wt%. The dryer hopper should be cleaned to remove fines; static-discharge devices at the feed throat reduce dust adhesion to pellets, which can cause etch shadowing in later metallization.
When the melt temperature at the nozzle exceeds 255 °C or total barrel residence time exceeds 8 min, the polybutadiene phase undergoes thermo-oxidative degradation, generating yellowing, black specks, and a fall in notched Charpy impact strength of 15–25% relative to the as-specified value. On a 50 mm screw with 20:1 L/D and a shot-to-barrel capacity ratio under 0.35, residence time may become excessive if cycle interruption occurs; a shot capacity of 50–70% of the barrel is preferred. Back pressure should be maintained between 0.5 MPa and 1.0 MPa to ensure melt homogeneity without frictional heating. Screw speed should be limited to 80–120 rpm on a 50 mm screw; higher speeds raise melt temperature by shear and may damage gelled rubber particles. The use of vented barrels is not recommended for this grade because melt can accumulate in the vent and degrade if screw retraction is aggressive.
Injection transfer should occur at 90–95% of total part volume, with packing pressure held at 60–80 MPa for 4–8 s depending on gate freeze. Excessive packing pressure above 90 MPa produces density gradients near the gate and can increase molded-in stress, which appears after electroplating as blistering or cracking during thermal cycle testing. Mold temperature should be held at 60–80 °C for parts that will be chromium-plated. Batch-to-batch variation in rubber particle size can change the optimal etch time by 1–3 min; therefore, plating lines should establish upper and lower etch windows using a reference plaque molded under identical conditions.
For exterior automotive components such as radiator grilles and wheel covers, the molder typically targets a post-mold dimensional tolerance of ±0.1 mm over 100 mm under ISO 294-4 after conditioning at 23 °C and 50% RH for 48 h. Warpage is controlled more by mold-temperature uniformity than by packing pressure; differential mold temperatures above 10 °C between core and cavity produce out-of-plane distortion that can exceed 0.3 mm across a 400 mm radiator-grille length. After electroplating, the composite part undergoes thermal cycling from -40 °C to 85 °C; the mismatch between metal thermal expansion and ABS creates interfacial stress at the plate boundary. AP-2 is formulated to reduce this stress concentration by moderating the coefficient of linear thermal expansion below 90 × 10-6 K-1; published data for this specific configuration is limited and should be confirmed with the lot certificate.
The plating sequence begins with a chromic acid-sulfuric acid etch bath operating at 360–400 g/L CrO₃ and 300–350 g/L H₂SO₄, heated to 65–70 °C for 5–12 min depending on the part’s molded-in stress and wall thickness. This etch selectively oxidizes the butadiene domains, creating surface cavities with a depth of 0.2–0.5 μm. After neutralization in 10–20% hydrochloric acid or sodium bisulfite, the component is immersed in a palladium-tin colloid, accelerated in dilute sulfuric or fluoroboric acid, and then processed through electroless nickel or copper. Electrolytic copper is then applied at 20–30 μm, followed by semi-bright nickel at 10–15 μm, bright nickel at 5–10 μm, and chromium at 0.25–0.50 μm. Each layer thickness is measured by ISO 2177 or ASTM B568, and peel strength is evaluated by ASTM B533 after 24 h conditioning at 23 °C. Parts that show skip plating at the gate region typically carry excessive mold release or degraded low-molecular-weight SAN at the surface; washing with 2–5% alkaline cleaner at 50–60 °C for 5 min is required before etch.
Materials that interfere with etch uniformity must be excluded. Silicone-based external mold release agents, waxes, and processing lubricants that bloom to the surface can cause wetting defects and adhesion failure; only water-compatible, low-residue release agents should be used, and they should be eliminated from the molding process if adhesion loss exceeds 5% in trial lots. Regrind addition should be limited to 20 wt% because repeated shear history reduces the gel fraction of the rubber phase and increases the number of small gel particles, yielding higher variability in plate peel values. The resin should not be blended with PVC or flame-retardant packages without plating-line approval; halogenated additives and antimony oxide can alter the etch rate and create non-uniform surface topography. Contact with ketone-based cleaners should be avoided because ketones attack the SAN phase and cause stress cracking. If parts are stored for more than 72 h before plating, they should be sealed in moisture-barrier packaging to prevent surface oxidation.
Relative to Nippon A&L high-flow injection grades, AP-2 requires a lower melt temperature and higher mold temperature because its higher rubber content reduces flow length. In thin-wall applications below 1.5 mm, flow length may fall by 10–20% compared with a 30 g/10 min general-purpose grade. Relative to heat-resistant ABS, AP-2 is easier to etch at standard plating lines because the polybutadiene domains remain accessible after molding; heat-resistant grades containing alpha-methylstyrene can require longer etch time and tend to develop higher residual stress at the gate. Relative to PC/ABS, AP-2 does not require drying at 100–110 °C and is less sensitive to alkaline cleaning; however, the low-temperature impact below -20 °C is lower. Published data for this specific configuration is limited; comparative trials should be conducted on the intended tool with the exact plating line chemistry.
Regulatory compliance for AP-2 is documented through the supplier’s certificate of conformity. Typical ABS pellets are supplied in accordance with RoHS Directive 2011/65/EU, as amended, and REACH Regulation EC 1907/2006; substances of very high concern should be declared below 0.1 wt% per article. For plumbing or potable-water components, only the complete electroplated assembly can be tested against NSF/ANSI 61 or equivalent national approvals, because the resin alone does not determine the final compliance of a multi-layer composite.
In a 12-cavity hot-runner tool for automotive wheel covers, mold-temperature uniformity of ±2 °C across the cavity set is often required to keep plating thickness deviation below 0.3 μm after electroplating. Hot-runner manifold temperature is set at 235–245 °C to maintain flow without degrading the rubber phase. Initial gate-seal verification is performed by recording part mass variation; a mass standard deviation above 0.05% across 20 consecutive shots indicates inconsistent packing or backflow through the check ring. Such variance appears after electroplating as local adhesion differences, particularly in the gate region. These production-scale conditions, rather than laboratory specimen values, determine whether AP-2 meets the application requirement.