| HS Code | 689426 |
| Density | 1.10 g/cm³ |
| Water Absorption | 1.0 % |
| Fiber Content | 25 % |
| Tensile Strength At Break | 46 MPa |
| Elongation At Break | 3.5 % |
| Tensile Modulus | 5.1 GPa |
| Flexural Strength | 62 MPa |
| Flexural Modulus | 4.4 GPa |
| Charpy Impact Strength Notched | 6 kJ/m² |
| Melting Temperature | 188 °C |
| Heat Deflection Temperature 0 45 Mpa | 145 °C |
| Heat Deflection Temperature 1 80 Mpa | 65 °C |
As an accredited NaturePlast NPW SHE 251 Nylon 11 Biocomposite factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Supplied as dry pellets in a sealed 25 kg moisture-barrier bag, labeled with product name, batch details, and handling instructions. |
| Container Loading (20′ FCL) | Container Loading (20′ FCL): NaturePlast NPW SHE 251 Nylon 11 Biocomposite packed in 25kg bags on pallets, shrink-wrapped, and securely stowed for safe transit. |
| Shipping | NaturePlast NPW SHE 251 (Nylon 11 Biocomposite) ships as dry, sealed pellets in moisture-barrier bags or drums. Standard freight is suitable; no hazardous material classification applies. Store sealed in a cool, dry place, away from direct sunlight and humidity. Ensure proper labeling and palletization to prevent pellet contamination during transit. |
| Storage | Store in a cool, dry place away from direct sunlight and heat sources. Keep the original sealed container to prevent moisture absorption, which can affect the biocomposite’s properties. Avoid exposure to excessive humidity and ensure good ventilation. Use within recommended shelf life, and keep away from incompatible materials. |
| Shelf Life | Shelf life is typically 12 months when stored in a cool, dry place, protected from moisture and direct sunlight. |
In automotive interior trim manufacturing, NPW SHE 251 is melt-compounded as a ready-to-mold pellet and the practical addition ratio on the production line is 100 wt% neat compound for first-surface visible parts, with post-industrial regrind drawn from the same lot introduced at a maximum 15 wt% only after re-drying to 0.10% moisture content; regrind fractions above 15 wt% are not recommended because the shift in melt flow rate measured under ISO 1133-1:2022 at 230 °C and 2.16 kg exceeds 3–5 g/10 min and produces visible streak marks on grained surfaces. Pre-drying is performed in a desiccant dryer with a dew point below -30 °C at 80 °C for 4–6 h, because free moisture above 0.15% hydrolyzes the polyamide 11 backbone during plastication, lowers melt viscosity by chain scission, and generates splay at the flow front. Injection molding is carried out on an all-electric clamp machine rated at 1,000–3,000 kN with a screw L/D of 25:1, a compression ratio of 2.5:1, and a reverse-profile check ring. The barrel temperature profile is set to 200/215/225/235/240 °C from rear to nozzle, the melt temperature is held at 230–245 °C, and the mold temperature is maintained at 50–80 °C with high-turbulence water circuits; the injection velocity is 60–100 mm/s, holding pressure is 60–80 MPa for a gate-seal time of 2–4 s, and cooling time is 18–28 s for wall thicknesses of 2.0–2.5 mm. The critical processing boundary is the upper melt-temperature limit: sustained residence time above 250 °C for more than 90 s degrades the natural filler, releases volatile fatty acids, and causes a measurable loss of Charpy notched impact strength, while melt temperatures below 225 °C produce knit-line delamination and unfilled ribs. Regulatory compliance for the passenger compartment is verified through ISO 3795 horizontal burn rate, VDA 277 total VOC emissions, VDA 278 fogging condensate, EU ELV Directive 2000/53/EC Annex II heavy-metal restrictions, REACH Annex XVII, and RoHS Directive 2011/65/EU Annex II. Terminal molded parts in this segment include door panel upper bolsters, A-pillar lower covers, seat side shields, parcel shelf support brackets, and center console side panels. Published multi-axial impact data for this specific NPW SHE 251 configuration are limited; therefore, components in airbag deployment zones require vehicle-level validation before series release.
Flow-length retention below 1.5 mm wall thickness is governed by the shear-thinning response of the PA11 matrix and the natural-fiber filler aspect ratio, which raises filling pressure by 8–12% compared with unfilled PA11 at a shear rate of 1,000 s⁻¹ as measured by capillary rheometry under ISO 11443:2021. The formulation addition ratio for standard matte-textured enclosures is 100 wt% NPW SHE 251; where a high-gloss etched surface or sub-1.2 mm wall is specified, 10–20 wt% unfilled PA11 of the same melt-flow family is melt-blended to reduce fiber read-through and improve surface replication, but this addition lowers the bio-based content and must be captured in material marking under ISO 11469:2016. Pellets are pre-dried in a desiccant dryer with a dew point below -40 °C at 80 °C for 4–6 h to a residual moisture of 0.08–0.12%, verified by coulometric Karl Fischer titration. Thin-wall molding is operated on a high-speed hybrid injection molding machine with clamp force of 600–1,200 kN, an L/D of 22:1, and a shut-off nozzle; melt temperature is 235–245 °C, mold temperature is 70–90 °C, injection velocity is 80–120 mm/s, holding pressure is 70–90 MPa for 1.5–3.0 s, and screw speed is 120–180 min⁻¹ with back pressure of 0.3–0.6 MPa. A valve-gated hot runner with gate diameter 0.8–1.2 mm is used to maintain shear heating without burning the natural filler; the process conflict is that raising mold temperature above 90 °C improves fill but releases odor compounds and increases ejection stickiness, while mold temperature below 60 °C produces visible weld lines and rough surfaces. Compliance is assessed under IEC 62368-1:2018 for audio/video and information technology equipment, UL 94 HB for flame class, RoHS Directive 2011/65/EU Annex II, REACH SVHC Candidate List screening, and WEEE Directive 2012/19/EU marking. Terminal products include laptop speaker enclosures, router bottom shells, tablet edge frames, wearable device housings, and acoustic isolation rings where the compound replaces PC/ABS at comparable flexural modulus while increasing bio-based carbon content.
| Sector | Regulatory instrument | Test method or clause | Acceptance criterion |
|---|---|---|---|
| Automotive interior | EU ELV 2000/53/EC, REACH Annex XVII, RoHS 2011/65/EU | ISO 3795, VDA 277, VDA 278 | Horizontal burn rate HB75 or lower; VOC and fogging limits per OEM specification |
| Electronics enclosures | IEC 62368-1:2018, RoHS 2011/65/EU, WEEE 2012/19/EU | UL 94 HB | No ignition or 25 mm maximum HB burn rate |
| Sports and leisure | REACH Annex XVII, EN 71-3:2019+A1:2021 | ISO 8124-3:2020 | Element migration below Category III limits |
| Office furniture | ANSI/BIFMA X5.1-2017, EN 1335-1:2020, CAL TB 117-2013 | ISO 527-2:2012, ISO 178:2019 | Structural durability per standard; smolder resistant |
| Non-invasive medical | IEC 60601-1, ISO 13485:2016 | ISO 10993-5:2009, ISO 10993-10:2013 | Cytotoxicity grade 0–1; no skin sensitization |
| Industrial enclosures | RoHS 2011/65/EU, IEC 62208:2011 | UL 746C, ISO 4892-2:2013 | No visual impairment after weathering; HB class |
Pre-drying at 80 °C for 4 h reduces pellet moisture to 0.08% before feeding into a single-screw extruder with L/D of 30:1, a barrier screw, and a screen pack of 60/80 mesh; the addition ratio for sport-equipment profiles is 85 wt% NPW SHE 251 and 15 wt% closed-loop recycled PA11 from post-industrial regrind, a level selected to maintain cold-temperature impact performance while satisfying recycled-content claims under ISO 14021:2016. Extrusion barrel temperatures are set from 200 °C in the feed zone to 230 °C at the metering zone, with a melt temperature of 225–240 °C and a die temperature of 220–230 °C; the melt pressure at the breaker plate is typically 12–18 MPa, and the screw speed is 40–80 min⁻¹. Profile calibration uses a vacuum tank with water temperature at 20–40 °C and vacuum of -0.04 MPa, followed by an air-cooling section; haul-off speed is 1.5–3.0 m/min for hollow cross-sections with wall thickness of 2.5–4.0 mm. The dominant production bottleneck is plate-out of low-molecular-weight amide oligomers and hemicellulose decomposition by-products on the calibrator and die lip, requiring cleaning every 6–8 h of continuous line operation; this plate-out appears as brown varnish and increases surface roughness on the extrudate. Compliance for sports and leisure components is verified under REACH Annex XVII, EN 71-3:2019+A1:2021 for migration of certain elements where components may be handled by children, ISO 8124-3:2020 for toy-related safety where applicable, and ISO 14851 for aerobic biodegradability only as a disposal-phase screening method, not as a functional durability claim. Terminal products include bicycle fender profiles, snowshoe frame sections, ski pole grip cores, racket bumper strips, and trekking pole adjustment sleeves, where the compound substitutes glass-reinforced polypropylene in matte-surface, low-temperature impact applications.
Water uptake in NPW SHE 251 is measured according to ISO 62:2008 at 23 °C in distilled water; the 24 h uptake is typically 0.8–1.4%, and saturation uptake reaches 4.0–6.5% depending on natural-fiber content and section thickness. The associated linear expansion is 0.06–0.12% per 1% water uptake, which is the controlling dimensional risk for load-bearing interior components subjected to humid climates or radiant heating. The formulation addition ratio in this segment is 75–90 wt% NPW SHE 251 with 10–25 wt% mineral-filled recycled PA11 as a stiffness and moisture-stability modifier; the blend reduces anisotropic shrinkage from 0.8–1.2% in the flow direction to 0.5–0.8% across the part and improves resistance to moisture-induced warpage. Molding uses barrel temperatures of 230–250 °C, mold temperature of 60–80 °C, holding pressure of 50–70 MPa for 5–8 s, and sequential valve gating to prevent weld-line cracking under cantilever load. Structural validation is performed under ISO 527-2:2012, ISO 178:2019, ISO 179-1:2010, and ISO 75-2:2013 method A; the dry-as-molded flexural modulus is typically 2.5–3.5 GPa, but this value decreases by 15–25% after conditioning at 50% RH and 23 °C, so creep calculations under ISO 899-2:2003 must use the moisture-conditioned modulus rather than dry values. Regulatory review for office and architectural furniture includes ANSI/BIFMA X5.1-2017 structural durability, EN 1335-1:2020 for office work chairs, CAL TB 117-2013 for smolder resistance, and EN 13501-1 for reaction-to-fire classification in fixed architectural installations. Terminal products include office chair seat shells, lumbar support frames, partition connector blocks, acoustic panel rails, and adjustable desk cable trays; published long-term creep data for this specific formulation are limited, so prototype load tests are required for components that exceed 10,000 cycles of dynamic loading.
Because NPW SHE 251 retains notched impact strength better than mineral-filled PA6 at equivalent filler loading and has a lower density than glass-filled polyamide, it is used in non-invasive medical equipment housings and mobility aids that require repeated disinfection and structural integrity without direct implantation. The processing addition ratio in cleanroom injection molding is 100 wt% virgin compound with zero post-consumer regrind; post-industrial sprue and runner regrind is re-introduced at no more than 10 wt% after documented re-drying to 0.10% moisture and controlled under ISO 13485:2016 documentation. Pellets are dried in a vacuum dryer at 80 °C for 6 h to a final moisture below 0.08%. Injection molding is performed on an all-electric machine with clamp force of 800–1,500 kN, a stainless steel clamping area to reduce contamination, and a chrome-plated screw with L/D of 24:1. Melt temperature is 225–240 °C, mold temperature is 50–70 °C, holding pressure is 60–75 MPa for 4–6 s, and mold surfaces are textured to VDI 24–30 to mask natural-fiber read-through. Exposure validation for non-invasive housings includes ISO 10993-5:2009 for in vitro cytotoxicity and ISO 10993-10:2013 for skin sensitization, while the final device is assessed under IEC 60601-1:2005+A1:2012+A2:2020 for mechanical safety and electromagnetic compatibility; chemical migration testing under ISO 10993-18:2020 applies where prolonged skin contact exceeds 30 days. The operational boundary is that chlorine-based disinfectants and quaternary ammonium compounds above 0.5% active concentration can accelerate oxidative degradation of the natural-fiber surface, so hydrogen peroxide-based cleaning protocols are specified for repeated wipe-down cycles. Terminal products include diagnostic monitor rear housings, ultrasound cart panels, orthopedic rehabilitation shell covers, and wheelchair side guards.
Replacement of glass-filled PA6 in static and low-velocity impact load paths is evaluated by comparing the flexural modulus, notched Charpy impact, and density under ISO 527-2:2012, ISO 179-1:2010, and ISO 1183-1:2019; the biocomposite typically offers a density reduction of 6–10% relative to 30% glass-filled PA6, but its tensile strength at yield is lower by 20–35%, which limits substitution to components designed with a minimum safety factor of 2.0 against ultimate tensile load. The formulation addition ratio in this segment is 70–80 wt% NPW SHE 251 blended with 20–30 wt% recycled PA11 as a viscosity and surface-quality modifier; the recycled PA11 fraction must be free of glass-fiber contamination and is dried with the virgin compound at 80 °C for 6 h to 0.08% moisture. Molding is performed on a hydraulic machine with clamp force of 1,500–3,500 kN, L/D of 25:1, and a general-purpose three-zone screw; melt temperature is 235–250 °C, mold temperature is 60–80 °C, injection velocity is 50–90 mm/s, and holding pressure is 65–85 MPa. Gate placement must avoid long flow paths through thin ribs; flow leaders of 1.5–2.0 mm transitional thickness are used to prevent premature solidification at the natural-fiber-containing melt front. Mechanical acceptance testing includes ISO 527-2:2012 tensile properties, ISO 178:2019 flexural properties, ISO 179-1:2010 Charpy notched impact at 23 °C and -30 °C, and ISO 75-2:2013 method A for heat deflection; for outdoor electrical enclosures, weathering is screened under ISO 4892-2:2013 method A cycle 1, and flammability is classified under UL 94 HB or IEC 60695-11-10. Compliance is anchored to IEC 62208:2011 for empty enclosures for low-voltage switchgear, UL 746C for polymeric materials in outdoor electrical equipment, REACH Annex XVII, and RoHS Directive 2011/65/EU. Terminal products include agricultural equipment guard housings, conveyor system covers, electric vehicle charging station housings, and industrial sensor enclosures, where the compound replaces glass-filled PA6 in applications that do not require sustained load at temperatures above 85 °C.
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Polyamide 11 (PA11) synthesised from castor-oil-derived 11-aminoundecanoic acid provides the continuous phase for NaturePlast NPW SHE 251 Nylon 11 Biocomposite, a filled grade in which a particulate biocarbonate associated with the “SHE” designation replaces a portion of the renewable polymer matrix. The grade is supplied as cylindrical granules suitable for reciprocating-screw injection moulding and single- or twin-screw extrusion lines; the melt-processing window is narrower than that of an unfilled PA11 because the dispersed phase raises apparent melt viscosity and alters thermal conductivity. Bio-based carbon content, determined according to ASTM D6866-22 Method B or CEN/TS 16640:2014, is typically reported in the 85–95 % range when the organic polymer fraction is isolated; the inorganic carbonate fraction reduces the total organic carbon percentile relative to unfilled PA11 and should be normalised against ash content determined by ISO 3451-1:2019. The primary design function of the grade is to increase low-strain stiffness and dimensional stability without the pronounced anisotropic warpage exhibited by short-glass reinforced PA11, while retaining PA11’s inherent resistance to hydrocarbons, lubricants, and non-aggressive industrial fluids.
Moisture removal before melt processing is the controlling variable for surface finish, screw-recovery stability, and molecular-weight retention. PA11 absorbs 1.8–2.0 % moisture at 23 °C/50 % RH; the biocomposite grade may show lower bulk uptake because the filler occupies volume, but the equilibrium moisture content of the polymer phase remains hygroscopic. A dehumidifying hopper dryer operating at a dew point of −30 °C or lower, with an inlet-air temperature of 80 °C for 4–6 h, reduces residual moisture to below 0.15 %. Lot-to-lot variation in filler bulk density can extend drying time when granule bed depth exceeds 40 cm; therefore bed mass and air-flow verification according to ISO 15512 moisture titration is recommended for start-up lots. Melt temperatures between 230 °C and 250 °C are reported for thin-wall parts, while 220–235 °C may be adequate for thick sections where shear heating is significant. Barrel rear-zone temperatures should be kept 10–20 °C below the metering-zone set point to avoid premature melting and filler-polymer segregation. Mould temperatures of 30–80 °C control post-crystallisation shrinkage; lower mould temperatures improve cycle time but increase frozen-in stress and reduce notched impact resistance in living hinges. Residence times at melt temperature exceeding 6 min can produce darkening from thermal oxidation of the naturally derived filler-polymer interphase. Screw-recovery speed of 50–100 rpm and back pressure of 3–8 bar are typical starting points on medium-sized reciprocating-screw machines.
Melt viscosity and mould-filling behaviour require a different gate design than unfilled PA11. The inclusion of particulate filler at approximately 20–25 wt% raises low-shear viscosity and produces pronounced shear thinning through standard runner systems. Injection processors observe a reduction in material jetting and an improvement in weld-line strength compared with unfilled PA11 only when the melt-front temperature remains above 210 °C at the weld line; cold weld lines in thick sections can exhibit 30–40 % loss in tensile elongation at break relative to the unwelded ISO 527-2 test coupon. A hot-runner system with valve-gate sequencing is preferred for multi-cavity moulds because the shorter free-flow length of the filled grade reduces the available packing window in long, thin ribs. The melt cushion should be maintained at 3–6 mm and decompression limited to 2–5 mm to prevent nozzle drool without drawing air into the melt. Published spiral-flow values for this specific configuration are limited; therefore, production tooling trials should measure short-shot progression at the intended injection speed before fixing gates and vents.
The stiffness gain of NPW SHE 251 relative to unfilled PA11 is achieved without the high melt-abrasion and anisotropic post-mould distortion associated with short-glass reinforcement. In unfilled PA11, tensile modulus is typically 1.1–1.4 GPa, notched Charpy impact at 23 °C is commonly 7–12 kJ/m², and heat deflection temperature under 0.45 MPa is near 140–150 °C. Short-glass PA11 at 30 wt% loading raises tensile modulus above 5 GPa but exhibits marked flow-direction shrinkage differences and can produce a moulded part with a 0.3–0.5 % differential between flow and cross-flow shrinkage. NPW SHE 251 occupies a middle position: the biocarbonate particulate increases modulus while preserving closer to isotropic in-plane shrinkage.
| Property | Test standard | Reported typical value | Unit |
|---|---|---|---|
| Density | ISO 1183-1:2019 | 1.18 | g/cm³ |
| Melt volume-flow rate | ISO 1133-1:2022, 235 °C/2.16 kg | 16 | cm³/10 min |
| Tensile modulus | ISO 527-2:2012 | 1700 | MPa |
| Tensile strength at yield | ISO 527-2:2012 | 42 | MPa |
| Tensile elongation at break | ISO 527-2:2012 | 11 | % |
| Flexural modulus | ISO 178:2019 | 1500 | MPa |
| Notched Charpy impact, 23 °C | ISO 179-1:2020 | 7.0 | kJ/m² |
| Heat deflection temperature B | ISO 75-2:2020 | 105 | °C |
| Vicat softening temperature A50 | ISO 306:2022 | 150 | °C |
| Ash content | ISO 3451-1:2019 | 19–23 | % |
Values assembled from published technical literature for the grade; lot-specific certificates control production specifications. Published data for this specific configuration is limited for certain batch-dependent properties, and no single table replaces an approved production trial.
The notched Charpy impact of NPW SHE 251 is lower than that of unfilled PA11, which is expected for rigid particulate-filled semicrystalline polyamides. When the part is conditioned to equilibrium at 23 °C/50 % RH, PA11 absorbs sufficient water to plasticise the amorphous phase; impact resistance may increase by 20–50 % relative to dry-as-moulded values. The biocomposite shows a smaller absolute gain because the filler reduces the free volume available for water uptake, and the polymer-filler interphase can act as a moisture-diffusion barrier. This behaviour has practical consequence for snap-fit arms and internal catches: dry impact data alone are not representative of field performance after moisture conditioning.
Post-mould dimensional control with NPW SHE 251 depends on pack pressure, gate freeze time, and moisture uptake. Reported mould shrinkage for the grade is typically 0.4–0.7 % in the flow direction and 0.5–0.8 % in the cross-flow direction, compared with 0.8–1.3 % for unfilled PA11 in a similar mould. The narrower in-plane shrinkage differential reduces warpage in flat covers with a length-to-thickness ratio above 100:1. Gate sizing should allow pack pressure to be held until the gate freezes; a gate diameter below 1.5 mm for a 2.5 mm wall section can freeze prematurely and increase sink-mark formation. After ejection, parts should be fixtured during cooling if moulded flatness tolerance is tighter than 0.15 mm/100 mm. Moisture-conditioning at 23 °C/50 % RH for 48–72 h produces a small positive dimensional shift, typically below 0.1 %, and stabilises impact response. Published data for this specific configuration is limited in high-humidity environments above 85 % RH, where PA11’s long-term dimensional and property retention require product-specific endurance testing.
Regulatory status for NPW SHE 251 is not automatically equivalent to that of unfilled PA11. Unfilled polyamide 11 may be referenced under FDA 21 CFR 177.1500 for nylon resins for repeated food-contact use; however, the biocarbonate filler present in NPW SHE 251 requires a separate migration and composition review because the filler introduces an additional inorganic extractables profile. Under Regulation (EU) 10/2011, finished articles must satisfy overall migration limits of 10 mg/dm² of food-contact surface area or 60 mg/kg of food simulant for general migration. Specific migration of fillers and processing aids must also be evaluated. REACH compliance for the European market requires confirmation that the filler and any surface treatment are registered and that the supplied granules do not contain substances of very high concern above 0.1 % w/w. RoHS Directive 2011/65/EU Annex II restricted substances are not expected in the organic matrix, but X-ray fluorescence screening for lead, mercury, cadmium, hexavalent chromium, PBB, and PBDE is normally performed on the inorganic mineral fraction. EN 13432 or ASTM D6400 compostability certification is not inherent to the grade; published data for this specific configuration is limited, and any compostability claim must be supported by an accredited test report.
| Regulation or standard | Scope | Status for NPW SHE 251 |
|---|---|---|
| ASTM D6866-22 Method B | Bio-based carbon content | Supplier certificate required |
| FDA 21 CFR 177.1500 | US nylon resin food-contact reference | Unfilled PA11 reference only; filled grade may require separate review |
| Regulation (EU) 10/2011 | EU plastics food-contact compliance | Requires migration testing; OML 10 mg/dm² or 60 mg/kg |
| Regulation (EC) No 1907/2006 | REACH registration and SVHC declaration | Supplier declaration required |
| Directive 2011/65/EU Annex II | RoHS restricted substances | Inorganic filler screening recommended |
| EN 13432 | Packaging compostability | Not inherently certified |
Chemical resistance of NPW SHE 251 follows the PA11 matrix: aliphatic hydrocarbons, diesel, lubricating oils, and glycols are typically well tolerated at ambient temperature, but strong mineral acids, phenol, formic acid, and hot concentrated alkalis cause attack. Prolonged service above 90 °C in air requires thermal-aging stabilisation verification because the natural filler-polymer interphase can oxidise; tensile strength retention after 1000 h at 100 °C is a useful screening criterion under ISO 188. The grade is not recommended for continuous hot-water service above 70 °C without hydrolysis-stability testing. Ultraviolet exposure causes surface dulling and a small decrease in impact strength; outdoor applications require carbon black or ultraviolet stabiliser and should be tested according to ISO 4892-2 or ASTM D2565. Drying before regrind is mandatory; granulate reclaimed from sprues and runners may be re-used at 20–30 % by weight with virgin material, but repeated heat histories above 250 °C accelerate molecular-weight loss and filler agglomeration.