| HS Code | 667110 |
| Product | NaturePlast NPW SEA 253 Nylon 11 Biocomposite |
| Bio Based Content | 93% |
| Density | 1.13 g/cm³ |
| Tensile Strength | 45 MPa |
| Tensile Modulus | 1900 MPa |
| Flexural Strength | 60 MPa |
| Flexural Modulus | 2100 MPa |
| Charpy Impact Strength Notched | 8 kJ/m² |
| Melting Temperature | 185°C |
| Heat Deflection Temperature 1 8 Mpa | 55°C |
| Melt Flow Rate 230 C 2 16 Kg | 8 g/10min |
| Water Absorption 24h | 0.9% |
| Hardness Shore D | 72 |
As an accredited NaturePlast NPW SEA 253 Nylon 11 Biocomposite factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Supplied in 25 kg polyethylene-lined paper bags, NaturePlast NPW SEA 253 Nylon 11 Biocomposite is protected against moisture. |
| Container Loading (20′ FCL) | 20′ FCL container loading of NaturePlast NPW SEA 253 Nylon 11 Biocomposite, safely packed in sealed bags on pallets for export shipment. |
| Shipping | NaturePlast NPW SEA 253 Nylon 11 Biocomposite ships as moisture-sensitive pellets in sealed, dry containers. It is non-hazardous under standard transport regulations, but should be kept away from excessive heat and humidity. Use standard dry cargo handling with proper labeling and protected storage to preserve material integrity. |
| Storage | Store NaturePlast NPW SEA 253 Nylon 11 Biocomposite in a cool, dry, well-ventilated area, away from direct sunlight, heat sources, and excessive humidity. Keep the original container tightly sealed when not in use to prevent moisture absorption and contamination. Avoid prolonged exposure to temperatures above 40°C. Ensure proper labeling and segregation from incompatible materials. |
| Shelf Life | Store in original sealed packaging in a dry, cool place. Shelf life is two years from the date of manufacture. |
For automotive under-hood cable management, high-voltage battery harness retention, and low-pressure air brake line support components, NaturePlast NPW SEA 253 Nylon 11 Biocomposite is introduced as a single-component feed. The addition ratio remains 100 wt% natural-color pellet, with 0.15–0.25 wt% external lubricant permitted only when ejection sticking or gate blush is observed on multi-cavity clip-tree tooling. In production-scale injection molding audits on 800–1,400 kN electric-hydraulic machines, desiccant pre-drying at 80 °C for 4–6 h is required to hold residual moisture below 0.08 wt%; insufficient drying produces surface splay and increases shot-to-shot mass variance by 0.5–1.2 g across 8-cavity clip tools. The barrel temperature profile is maintained between 200 °C and 230 °C, with nozzle melt temperature not exceeding 235 °C because natural fiber discoloration and polyamide matrix shear degradation become visible when residence time exceeds 8 min at this endpoint. Injection velocity is held at 40–80 mm/s, holding pressure at 40–60 MPa, and gate diameter at 1.2–1.8 mm; injection speeds above 100 mm/s have produced jetting and reduced knit-line strength in snap-fit retention features. The downstream operation uses sequential valve-gated cold-runner tools to prevent premature freeze-off at the end of fill, followed by post-mold conditioning at 23 °C and 50 % RH for 24 h before assembly. Terminal product types include under-hood cable brackets, EV battery harness clips, corrugated loom retainers, low-pressure air brake line separators, and clip-tree assemblies. Compliance is verified under REACH Article 33, RoHS 2011/65/EU Annex II, UL 94 HB, ISO 527-2:2012, ISO 179-1/1eU:2010, and SAE J844 for nonmetallic support components where hot-air aging and dimensional stability are monitored. Direct fuel-contact use is outside the demonstrated scope for this filled biocomposite grade; published continuous fuel immersion data for this specific configuration is limited.
| Standard | Test method / clause | Condition | Application relevance |
|---|---|---|---|
| ISO 527-2:2012 | Tensile modulus on 1A specimens | 23 °C, 1 mm/min | Clip stiffness and snap-fit retention |
| ISO 179-1/1eU:2010 | Charpy unnotched impact | -30 °C | Cold-temperature assembly crash pulse |
| UL 94 | Flame rating, 3.0 mm thickness | Standard laboratory atmosphere | Under-hood flammability classification |
| SAE J844 | Nonmetallic air brake tubing dimensional / aging | Hot air aging 100 °C, 24 h | Support component dimensional stability |
| REACH Article 33 | SVHC communication | Finished article | EU import compliance |
| RoHS 2011/65/EU Annex II | Restricted substance screening | Homogeneous material | Electrical and electronic part compliance |
Flexible pneumatic tubing produced from NPW SEA 253 is released against DIN 73378, SAE J844, ISO 527-2:2012, and ISO 1133-1:2022 for shear-viscosity batch traceability. The addition ratio is 100 wt% NPW SEA 253 for the tube core, with 2–3 wt% carbon black masterbatch permitted only for external UV-stabilized layers and laser marking. No post-industrial regrind is introduced into continuous compressed air line formulations because flow-path contamination and burst-pressure inconsistency become unacceptable in robotic end-effector air supply networks. The downstream process uses a single-screw extruder with L/D 30:1, grooved feed section, 2.5:1 compression ratio, and screen pack sequence of 60/80/100 mesh. Melt temperature at the die is controlled between 210 °C and 225 °C; below 205 °C melt strength drops and ovality exceeds 0.15 mm in 10 mm outside diameter tubing, while above 230 °C melt fracture and charred natural fiber agglomerates appear at the outer wall. Vacuum calibration is maintained at -0.03 MPa to -0.05 MPa, water bath temperature at 20–30 °C, and puller speed synchronized to melt output within 0.5 % to prevent wall-thickness oscillation. Terminal product types are compressed air lines for pneumatic tools, vacuum lines for automated assembly cells, air supply tubing for robotic end effectors, and low-pressure compressed air distribution lines in industrial maintenance workshops. Batch release testing records collapse pressure on spiral-reinforced variants, elongation at break on annealed sections, and dimensional change after 24 h at 100 °C according to SAE J844. Published data for this exact filled biocomposite in continuous oil mist exposure is limited, so oil-lubricated pneumatic service requires pre-qualification on finished tube assemblies.
In rigid and semi-rigid footwear component manufacturing, NPW SEA 253 is processed on high-speed injection molding lines for contoured shanks, heel counters, and toe cap preforms. The addition ratio for rigid shank components is 100 wt% NPW SEA 253; for flexible toe counters and cold-climate touring boot reinforcements, a blend of 80 wt% NPW SEA 253 with 20 wt% polyether block amide is used to reduce low-temperature stiffness. Desiccant pre-drying at 80 °C for 4 h to 0.08 wt% residual moisture is mandatory before molding; wet feedstock causes bracket distortion during insert molding and delamination around metal threaded inserts. Barrel zones are set from 200 °C to 225 °C, mold temperature at 30–45 °C, and clamp force per cavity at 12–20 kN depending on projected area. The downstream production route for contoured shanks uses edge-gated cold-runner tooling with insert loading, whereas flexible toe counters are produced on rotary-table machines allowing in-mold cooling without warpage. Batch release testing follows ISO 868 Shore D hardness, ISO 178:2019 flexural modulus, and EN 12770:1999 abrasion resistance for outsole-adjacent components. Terminal product types include ski boot internal shanks, touring boot toe counters, snowboard binding highback inserts, heel counters for performance footwear, and protective toe cap preforms for non-safety footwear. Safety footwear toe caps requiring EN 12568:2010 certification are not covered by this application because impact and compression ratings require separate component-level testing on the finished toe cap geometry.
Replacement of virgin PA66 with NPW SEA 253 in cable management and connector accessory programs is evaluated only where lower moisture uptake, high-strain snap-arm performance, and bio-based content are required. The addition ratio is 100 wt% virgin NPW SEA 253, with 0.5–1.0 wt% color or UV masterbatch; no post-consumer recycled content is introduced in electrical retention applications to maintain lot traceability. Pre-drying uses a dry-air generator with -40 °C dewpoint at 80 °C for 4 h, verified by Karl Fischer to 0.08 wt% residual moisture or less. The downstream process is high-cavity injection molding on 400–800 kN machines, with hot-runner valve sequencing and cycle times between 8 s and 15 s for releasable cable ties and harness clips. Melt temperature is kept at 200–225 °C, mold temperature at 30–50 °C, and decompression after plastication at 2–4 mm to prevent nozzle drool on fast-cycle tools. Tie-wing hinges and snap-beam gates are positioned away from knit lines, and injection velocity is lowered to 25–50 mm/s in the final 15 % of fill to prevent air traps and short shots in living hinges. Terminal product types are releasable cable ties, harness clips, connector backshells, wire loom brackets, and DIN-rail fastener bodies. Compliance is demonstrated on finished parts or test plaques according to UL 94, IEC 60695-2-12, IEC 62368-1:2023, and RoHS 2011/65/EU Annex II. Mechanical batch release follows ISO 527-2:2012 and ASTM D638-14 on dry-as-molded specimens, while conditioned property retention is checked after 23 °C and 50 % RH equilibrium. No direct substitution is recommended for connector shells carrying continuous current above 65 °C surface temperature unless the final part passes the relevant end-product thermal stress sequence under IEC 62368-1:2023.
| Standard | Test / clause | Condition | Component criterion |
|---|---|---|---|
| UL 94 | Flame rating | 0.8–1.6 mm plaque thickness | HB or better on specified thickness |
| IEC 60695-2-12 | Glow wire test | 650 °C, 30 s | No ignition or self-extinguish without ignition of tissue paper |
| IEC 62368-1:2023 | Thermal stress on accessible parts | Normal operating load | No hazard from softening or deformation |
| RoHS 2011/65/EU Annex II | Restricted substance screen | Homogeneous material | Below maximum concentration values |
Monofilament extrusion of NPW SEA 253 targets heavy-duty brushcutter line, industrial netting, racquet grommets, and sports netting. The addition ratio is 100 wt% NPW SEA 253 with 0.3–0.5 wt% processing aid to reduce die lip deposit formation on long runs. Pre-drying at 90 °C for 4–6 h to 0.05 wt% residual moisture is used because monofilament surface roughness and diameter instability become measurable when extrudate moisture exceeds 0.07 wt%. The downstream production line uses a single-screw extruder with L/D 36:1, die orifice diameter between 1.5 mm and 2.0 mm, water quench at 20–30 °C, and a two-stage hot-air orientation bath. Orientation draw ratio is set between 1:3.5 and 1:4.5, with annealing at 90–100 °C while winder tension feedback holds filament diameter within ±0.02 mm. Excessive draw ratio above 1:4.5 has produced fibrillation in natural fiber domains and reduced knot strength in brushcutter line; insufficient draw below 1:3.0 leaves residual elongation above 150 % and causes coil set. Terminal product types include heavy-duty brushcutter line, sports netting, racquet grommets, industrial monofilament for cable harness spirals, and outdoor net repair filaments. Weathering acceptance criteria are drawn from ISO 4892-2:2013 accelerated xenon-arc exposure and ISO 527-2:2012 tensile testing on oriented filaments. Published data for this specific filled monofilament configuration in long-term UV exposure beyond 2,000 h is limited, so outdoor product warranties should be confirmed on finished monofilament after full formulation lock.
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NaturePlast NPW SEA 253 Nylon 11 Biocomposite is a polyamide 11-based compound supplied as a bio-sourced alternative to fossil-derived short-chain engineering thermoplastics. The base polymer originates from 11-aminoundecanoic acid prepared from castor oil; the biocomposite designation indicates the presence of a natural filler or fibrous reinforcement, although published data for this specific configuration is limited and the supplier technical datasheet should be referenced for exact fibre type, loading, and lot-specific values. This grade is not a direct substitution for PA6 or PA66 in every mould because melt rheology, mould shrinkage, and moisture uptake after conditioning differ measurably.
The polyamide 11 repeat unit contains eleven carbon atoms per amide group, producing a lower amide density than PA6 or PA66. This structural characteristic reduces equilibrium water absorption to roughly 1.8–2.1 wt% after saturation at 23 °C under ISO 62:2008, compared with 9–10 wt% for unmodified PA6. The castor oil-derived monomer imparts a high bio-based carbon content, typically above 90 % when measured by ASTM D6866-21 Method B for unfilled PA11; the final biocomposite value depends on the natural filler fraction and should be verified for the grade. Melting of the PA11 matrix occurs near 185–190 °C, which sets the lower plastication limit and defines the upper service temperature envelope for heat-deflection-sensitive end-use.
Supplied pellets are hygroscopic despite the low equilibrium moisture of PA11 relative to PA6. Pre-drying in a desiccant dryer at 80–90 °C for 4–6 h to a residual moisture level below 0.1 wt% is required before melt processing. Drying air dew point should remain at or below −30 °C. If ambient relative humidity exceeds 60 %, pellets should not remain in open machine hoppers beyond 30–60 min; moisture regain above 0.15 wt% is associated with splay, gate blush, and hydrolysis-induced molecular weight loss in the melt.
The practical melt-processing window for PA11 biocomposite is constrained by the thermal sensitivity of natural fibre surfaces and by the crystallization behaviour of the polyamide 11 matrix. Injection moulding typically employs melt temperatures of 220–250 °C and mould temperatures of 40–80 °C. Melt temperatures below 210 °C increase pressure drop and risk incomplete replication of thin-wall features; temperatures above 260 °C accelerate discoloration and odour generation from natural filler degradation. Barrel residence time should be kept below 8–10 min, and shot size should occupy 30–70 % of machine capacity. Compounding on a co-rotating twin-screw extruder with L/D ratio 40:1–48:1 and side-fed natural filler at barrel temperatures of 200–230 °C is standard practice; screw speeds above 350 rpm can generate excessive specific mechanical energy and reduce fibre length, which lowers tensile modulus in the final part.
Production-scale equipment records show that when natural-fibre PA11 compounds are processed on reciprocating-screw injection machines with check-ring non-return valves, unmelted fibre agglomerates can form if back pressure is set below 5–10 bar hydraulic. Use of a reduced-compression screw with a uniform barrier profile and screw cushion of 3–6 mm minimises fibre breakage. Mould venting depths of 0.02–0.05 mm are recommended for thin-wall sections to prevent gas burn at the flow front; vent depths above 0.05 mm create flash with low-viscosity PA11 melt. Melt volume-flow rate measured by ISO 1133-1:2022 at 235 °C/2.16 kg for natural-fibre PA11 compounds is typically lower than unfilled PA11 because of filler network formation; shear-thinning behaviour is retained, but injection pressure requirements may rise when filler loading increases.
Replacement of PA6 or PA66 with PA11 biocomposite in stiffness-critical components introduces a different balance of hygroscopic swelling, impact response, and heat deflection. Relative to PA12, PA11 biocomposite offers higher renewable content and a similar melting point, but the natural filler lowers elongation at break and raises density. Relative to PA6 or PA66, PA11 biocomposite reduces water uptake and improves resistance to zinc chloride and certain automotive coolants, but sacrifices short-term heat resistance and raw tensile strength. The following typical ranges are drawn from published PA11 natural-fibre compound data and are not lot-specific values for NPW SEA 253.
| Property | PA11 biocomposite typical range | Unfilled PA11 | PA12 | PA6 |
|---|---|---|---|---|
| Density, ISO 1183-1:2019 | 1.05–1.25 g/cm³ | 1.03–1.05 g/cm³ | 1.01–1.03 g/cm³ | 1.13–1.15 g/cm³ |
| Tensile stress at yield, ISO 527-2:2012 | 45–80 MPa | 35–45 MPa | 35–45 MPa | 70–85 MPa |
| Flexural modulus, ISO 178:2019 | 2000–6000 MPa | 800–1200 MPa | 900–1300 MPa | 2400–2800 MPa |
| Equilibrium water absorption, ISO 62:2008 at 23 °C | 1.5–3.0 % | 1.8–2.1 % | 1.4–1.6 % | 9–10 % |
| Bio-based carbon, ASTM D6866-21 Method B | 70–95 % | >90 % | 0 % typical; bio-based variants available | 0 % |
In automotive interior clips and housings, the lower equilibrium moisture uptake of PA11 biocomposite reduces the dimensional swell that causes stick-slip noise and tight assembly torque loss in PA6 components. Mould shrinkage is typically anisotropic when natural fibre is present; flow-direction shrinkage is often lower than cross-flow shrinkage, and tooling designed for unfilled PA6 should be re-cut after prototype trial because the biocomposite can exhibit a coefficient of linear thermal expansion in the 40–80 µm/(m·K) range depending on fibre orientation. Published data for this specific configuration is limited, so pre-production capability studies with the actual grade are required.
Conditioning at 23 °C and 50 % RH increases impact strength and reduces tensile yield stress relative to dry-as-moulded values. A shift of 10–20 % in tensile modulus after moisture equilibration is typical for PA11 systems. This moisture-toughening behaviour is less pronounced than in PA6, but it means that validation specimens must be tested after defined conditioning, not immediately after moulding. Compared with polylactic acid, PA11 biocomposite has a lower brittle fracture tendency and a higher heat deflection temperature under load, although polylactic acid offers higher modulus at lower cost; PA11 also retains ductility after conditioning in humid environments.
Recognised application categories for PA11 biocomposites include rigid casings, interior trim substrates, clips, brackets, electrical housings, and sports equipment components where bio-based carbon content and reduced moisture sensitivity justify the higher cost compared with PA6. Marine and outdoor enclosures are possible applications because PA11 exhibits lower water uptake than PA6 and better salt-spray behaviour than polylactic acid; however, prolonged UV exposure still requires carbon black or a stabilised additive package because natural-fibre surfaces tend to fade and embrittle. Continuous exposure to concentrated mineral acids, strong oxidizing agents, and zinc chloride solutions at elevated temperature is an operational boundary for polyamide 11 compounds.
From a compliance standpoint, the grade falls under REACH 1907/2006 and European RoHS 2011/65/EU. Biobased carbon claims are supported by ASTM D6866-21 Method B or EN 16640:2017 where applicable. The following matrix summarises the principal test methods and regulatory documents used during grade evaluation.
| Standard or regulation | Parameter or scope |
|---|---|
| ISO 1183-1:2019 | Density |
| ISO 527-2:2012 | Tensile properties |
| ISO 178:2019 | Flexural properties |
| ISO 179-1:2010 | Charpy impact strength |
| ISO 75-2:2013 | Heat deflection temperature |
| ISO 62:2008 | Water absorption |
| ASTM D6866-21 Method B | Bio-based carbon content |
| EN 16640:2017 | Bio-based carbon content, European method |
| REACH 1907/2006 | Registration, evaluation, authorisation, and restriction of chemicals |
| RoHS 2011/65/EU | Hazardous substance restrictions |
Food-contact status, if required, must be verified against FDA 21 CFR or EU 10/2011 migration testing for the final article; the natural fibre phase can alter overall migration values relative to unfilled PA11. Processing documentation and lot-specific certificates should be obtained from the supplier before release of production parts.