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Mitsui Chemicals Evolue mLLDPE SP2520

    • Product Name: Mitsui Chemicals Evolue mLLDPE SP2520
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: sales8@ascent-chem.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 266360
    Density 0.922 g/cm³
    Melt Flow Rate 2.0 g/10 min (190°C, 2.16 kg)
    Melting Point 118 °C
    Vicat Softening Point 95 °C
    Tensile Strength At Break 30 MPa
    Tensile Elongation At Break 700%
    Flexural Modulus 220 MPa
    Haze 2.5%
    Gloss 45 100
    Dart Drop Impact 120 g
    Elmendorf Tear Strength Md 120 N/mm
    Elmendorf Tear Strength Td 150 N/mm

    As an accredited Mitsui Chemicals Evolue mLLDPE SP2520 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Mitsui Chemicals Evolue mLLDPE SP2520 is supplied in 25 kg paper bags, palletized and wrapped for industrial shipment.
    Container Loading (20′ FCL) 20′ FCL container loaded with palletized 25 kg bags of Mitsui Chemicals Evolue mLLDPE SP2520, shrink-wrapped and secured for export shipment.
    Shipping Mitsui Chemicals Evolue mLLDPE SP2520 is a non-hazardous polyethylene resin in pellet form, typically packed in 25 kg moisture-resistant bags or 500–1000 kg jumbo bags on pallets. Ship in dry, ventilated containers, protected from sunlight, heat, and moisture; avoid bag punctures and ignition sources.
    Storage Store resin pellets in a covered, clean warehouse in a cool, dry, well-ventilated area, away from direct sunlight, heat, moisture, and ignition sources. Keep original packaging tightly closed and protect from contamination, dust, and UV exposure. Avoid prolonged high temperatures and moisture pickup. Use first-in-first-out rotation, inspect containers for damage, and handle pellets to prevent spillage/slip hazards.
    Shelf Life Shelf life is typically 24 months from date of manufacture when stored dry, cool, and in unopened original packaging.
    Application of Mitsui Chemicals Evolue mLLDPE SP2520

    Evolue SP2520 is a metallocene-catalyzed linear low-density polyethylene with a nominal density of 0.925 g/cm³ (ISO 1183-1:2019) and a melt flow rate of 2.0 g/10 min (ISO 1133-1:2022, 190 °C/2.16 kg). The grade is specified primarily for cast film extrusion, extrusion coating, and extrusion lamination because the narrow molecular weight distribution and controlled short-chain branching reduce seal initiation temperature and improve hot-tack strength while maintaining drawdown on high-speed converting lines. The downstream scenarios below are limited to established industrial applications for this resin: food-contact flexible packaging lamination, liquid packaging board coating, modified-atmosphere cast sealant webs, medical form-fill-seal lidding, industrial cast stretch hood film, and heavy-duty sack film. Each scenario records the applicable compliance framework, formulation addition ratio, production-scale equipment parameters, and terminal article class.

    A 0.925 g/cm³ Sealant Resin on Tandem Extrusion Lamination Lines

    In tandem extrusion lamination lines running PET and BOPP webs at speeds above 200 m/min, Evolue SP2520 is processed as a sealant layer at 100 wt% neat resin or as a 70–80 wt% SP2520/20–30 wt% LDPE blend. The blend addition is driven by edge neck-in and draw resonance control, not by seal strength deficit; neat SP2520 at coating weights below 15 g/m² can develop unstable edges on dies wider than 1,200 mm. Industry compliance for food-contact structures is anchored to FDA 21 CFR 177.1520 for olefin polymers, (EU) No 10/2011 with overall migration limits of 10 mg/dm² and the relevant specific migration limits in Annex I, and REACH SVHC screening for non-food industrial laminates. The production process on tandem lines uses single-screw extruders with screw diameters of 90–120 mm, 28:1–33:1 L/D barrier screws, and melt temperatures between 280 °C and 320 °C. A die gap of 0.6–0.9 mm is combined with an air gap of 150–250 mm prior to the nip; chill roll surface temperature is maintained at 15–25 °C, and nip pressure is set within 3–5 bar to minimize entrapped air at the polymer-web interface. Seal strength is evaluated under ASTM F88/F88M-23 and hot-tack performance under ASTM F1921-18; peel adhesion to primed PET or BOPP is checked with ASTM D1876. Terminal finished products include stand-up pouches for dry and liquid food, three-side-seal sachets, gusseted coffee pouches, and laminated rollstock for form-fill-seal lines. The operational boundary for this grade in extrusion lamination is the combination of low coating weight and high line speed; if adhesion drops below 1.0 N/15 mm on primed substrates, the melt temperature or ozone dose must be increased before reducing the LDPE component.

    What Limits Draw Resonance in Liquid Packaging Board Coating?

    The primary constraint on liquid packaging board coating speed is the onset of draw resonance at coating weights below 12 g/m². Evolue SP2520 is used at 100 wt% as an extrusion coating on paperboard or in 70–85 wt% SP2520/15–30 wt% LDPE blends when the line is designed for high-speed aseptic carton production. Compliance for paperboard-contact coatings includes FDA 21 CFR 176.170(c) for components of paper and paperboard in contact with aqueous and fatty foods, (EU) No 10/2011 for the plastic layer, and EN 15593:2008 for hygiene management in food packaging manufacturing. The coating line typically uses a 105–150 mm single-screw extruder with 30:1–33:1 L/D, a coextrusion feedblock when a tie layer is incorporated, and a slot die with a gap of 0.5–0.8 mm. Melt temperature is held between 290 °C and 330 °C, while the air gap from die exit to nip is shortened to 120–200 mm to limit oxidation and improve adhesion. Ozone treatment of the paperboard surface is applied at a dose that raises surface energy above 38 mN/m before the polymer melt contacts the substrate; chill roll temperature is set at 10–18 °C for rapid quench. Coating weight is monitored online and maintained between 10 g/m² and 25 g/m². Terminal finished articles include gable-top milk and juice cartons, cupstock for hot and cold beverages, aseptic brick packaging, and paperboard trays with heat-sealable surfaces. A processing boundary occurs when the line speed exceeds 450 m/min at coating weights below 10 g/m²; in this operating window, draw resonance can generate transverse thickness variation above ±5%, requiring a reduction in melt temperature or a blend adjustment toward higher LDPE content. Published data for this specific configuration is limited at speeds above 500 m/min, so pilot trials on the target line are required before setting final coating parameters.

    Modified-atmosphere cast film lines allocate SP2520 to the sealant layer at 15–30 wt% of total film mass, with the sealant layer itself containing 70–100 wt% SP2520 and 0–30 wt% LDPE or a lower-density plastomer. The regulatory framework is food-contact-specific: FDA 21 CFR 177.1520, (EU) No 10/2011 with Annex III food simulant assignment, and ISO 22000:2018 for food safety management at the converting site. The cast film process uses three single-screw extruders in the 50–75 mm screw diameter range, each with 28:1–33:1 L/D, feeding a combining block and a slot die of 300–500 mm die width on pilot and mid-scale lines; production lines may use die widths above 2,000 mm. Melt temperatures in the skin layers are held at 220–260 °C, while the core layer is run 5–10 °C higher to reduce viscosity mismatch and interface instability. The air gap is set at 25–60 mm, chill roll temperature at 18–25 °C, and winding tension is tapered from 80 N/m to 40 N/m as roll diameter increases to prevent blocking and telescoped rolls. Seal initiation temperature is characterized by ASTM F88/F88M-23 using a 0.5 s dwell and 40 psi jaw pressure; hot-tack strength is measured by ASTM F1921-18 at 100 °C and 120 °C. Terminal finished product types include MAP lidding films for fresh-cut produce, dairy pouch films, flow-pack wraps for bakery and confectionery, and high-integrity sealant webs for gas-flushed packaging. If the SP2520 content in the sealant layer exceeds 90 wt%, screw slippage can occur in smooth-bore feed sections, causing output fluctuation of 3–5%; grooved feed throats or a 2–3 wt% processing aid masterbatch are used to stabilize mass flow. The outer skin layer, when based on HDPE or polypropylene, must maintain a melt temperature above the solidification point of SP2520 to avoid delamination at the tie-layer interface.

    When SP2520 Replaces LDPE in Medical Device Form-Fill-Seal Lidding

    Medical device form-fill-seal lidding converted on horizontal thermoform lines requires a sealant layer that reaches a minimum seal strength of 1.0 N/15 mm on coated Tyvek or rigid PETG trays under ASTM F88/F88M-23. Evolue SP2520 is incorporated at 80–100 wt% in the sealant layer, with the balance as LDPE or a plastomer to adjust seal initiation below 110 °C; the sealant layer itself is coextruded at 20–40 µm thickness within a multilayer lidding film. The applicable standards are ISO 11607-1:2019 and ISO 11607-2:2019 for terminally sterilized medical device packaging, EN 868-5:2018 for paper and plastic constructions, FDA 21 CFR 177.1520 for the olefin polymer, and USP <661.1> for plastic components of packaging systems. The cast coextrusion process uses 45–65 mm single-screw extruders with 28:1–32:1 L/D, melt temperatures of 230–260 °C, a die gap of 0.5–0.8 mm, and a chill roll set at 18–22 °C to limit haze and surface defects. In-line corona treatment raises the outer surface energy to 40–44 mN/m before lamination or coating; sealant layer thickness is controlled within ±5% by gravimetric feed or automated die bolts. Terminal finished products include chevron pouches for catheters, header bags for syringes, lidstock for rigid trays, and rollstock for ethylene oxide and radiation sterilization processes. A critical boundary appears in steam sterilisation at 121 °C; if the lidding film is to be exposed to saturated steam, the sealant layer must be validated for post-sterilization seal strength, because low-sealing mLLDPE grades can exhibit a drop in seal integrity after thermal cycling. Peelable seal systems involving SP2520 require blending with polybutene or EVA to control peel force between 4 N/15 mm and 8 N/15 mm; published data for this specific configuration is limited, so seal-peel curves must be generated on the target tray material before release.

    Because SP2520 narrows the molecular weight distribution of cast stretch hood blends, its addition is limited to 10–25 wt% in a three-layer A/B/A structure, where the core layer is a C8-LLDPE or LDPE matrix and the skin layers contain a cling modifier such as polyisobutylene in the 1–3 wt% range. Compliance for industrial stretch films is driven by REACH and Directive 2011/65/EU RoHS for heavy metals, with optional food-contact compliance under FDA 21 CFR 177.1520 when the film is used for secondary food packaging; mechanical performance is evaluated under ASTM D5748-95(2019) for puncture resistance and ASTM D882 for tensile elongation. The cast line configuration includes extruders of 75–120 mm screw diameter with 30:1 L/D, a die width of 2,000–3,000 mm, an air gap of 25–50 mm, and a chill roll temperature of 15–20 °C. Melt temperatures are maintained between 240 °C and 280 °C; line speeds for stretch hood film can reach 600 m/min with automatic gauge control maintaining thickness uniformity within ±2%. SP2520 increases elongation at break and puncture resistance in the machine direction, but its narrow molecular weight distribution can reduce melt strength and cause edge weave on cast lines with excessive die-to-chill roll distance; the edge trim is recycled into the core layer at up to 20 wt% regrind. Terminal finished goods include machine stretch hoods for logistics hubs, pallet wrap, protective wrapping for appliances and glass, and industrial rollstock for hand wrappers. A production limitation arises when SP2520 is added above 25 wt%: the cling force of the finished roll can drop below the target of 0.5 N/25 mm, requiring additional cling agent or corona treatment of the outer surface.

    Heavy-Duty Sack Film: Melt Temperature, Frost Line Height, and Curl Control

    Blown-film extrusion of heavy-duty sack material with SP2520 blends demands a melt temperature between 190 °C and 220 °C to avoid excessive backpressure and maintain bubble stability. The grade is incorporated at 15–35 wt% with HDPE or MDPE in monolayer and three-layer sack film lines, where it improves dart impact resistance and seal strength while reducing film curl caused by unbalanced layer crystallinity. Industry compliance for non-food industrial sacks is tied to REACH, ISO 21898:2004 for sack classification and testing, and ASTM D1709 for dart drop impact, with food-contact secondary packaging falling under FDA 21 CFR 177.1520 and (EU) No 10/2011 when the sack contains dry food ingredients. The production process uses single-screw extruders of 65–90 mm diameter with 25:1–30:1 L/D, a die gap of 1.2–2.0 mm, and a blow-up ratio between 2.5:1 and 3.5:1. Frost line height is controlled between 600 mm and 900 mm; when the frost line rises above 900 mm, the blend with SP2520 can develop higher transverse orientation and increased curl. Layflat widths in production range from 400 mm to 1,200 mm, with throughputs of 150–300 kg/h depending on die diameter and cooling air temperature. Terminal finished articles include heavy-duty shipping sacks for polymer pellets, FIBC inner liners, construction material bags, and agricultural product sacks. A critical boundary occurs at SP2520 loadings above 35 wt%: the lower melt strength of the metallocene grade reduces bubble stability below the 2.5:1 BUR threshold, and edge creasing increases on gusseted sacks. In such cases, the blend is reformulated with high-pressure LDPE at 10–15 wt% or the backpressure is raised through a higher screen pack density to restore bubble geometry.

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    Certification & Compliance
    More Introduction

    Mitsui Chemicals Evolue SP2520 is a metallocene-catalyzed linear low-density polyethylene specified for cast film, extrusion lamination, and coextruded sealant webs. The product is defined by a melt mass-flow rate of 2.0 g/10 min at 190 °C under 2.16 kg load in accordance with ISO 1133-1:2022 and by a density of 0.925 g/cm³ measured under ISO 1183-1:2019. The single-site catalyst architecture produces a narrower molecular weight distribution and a more uniform short-chain branching distribution than conventional Ziegler-Natta linear-low-density polyethylene. That structural difference is the primary driver for lower seal initiation temperature, reduced cold-solvent extractables, and a broader hot-tack plateau relative to conventional resins of the same density class. The product is used on high-speed form-fill-seal packaging lines, lamination sealant webs, and industrial liners where low-temperature seal response, dart impact resistance, and controlled optical clarity are required.

    What specification values are reported for resin and film performance?

    Resin-level specifications are supplied under standardized conditions. Film-level tensile, tear, dart, and haze values are gauge-dependent and are reported in the supplier technical data sheet for cast film produced under defined die temperature, draw ratio, and chill-roll conditions. The following table lists the principal resin values reproduced from published product literature for Evolue SP2520.

    Parameter Test method Value
    Melt mass-flow rate, 190 °C/2.16 kg ISO 1133-1:2022 2.0 g/10 min
    Density, 23 °C ISO 1183-1:2019 0.925 g/cm³
    DSC peak melting endotherm, 10 °C/min ISO 11357-3:2018 approx. 123 °C

    Film-property data for SP2520 should be obtained from the supplier’s current technical datasheet because fabrication parameters such as die gap, air gap, line speed, and quench temperature alter mechanical and optical values more than resin specification changes alone. Published values for 0.925 g/cm³ metallocene cast films typically show haze below 5% when measured according to ASTM D1003, but the exact value for SP2520 depends on additive package, melt temperature, and chill-roll surface.

    Heat-seal response is conventionally assessed on a gradient heat sealer at 0.2 MPa seal pressure and 0.5 s dwell time. Because the α-olefin comonomer is distributed uniformly across the molecular weight range, SP2520 reaches a practical seal-initiation plateau at a lower temperature than Ziegler-Natta LLDPE of the same 0.925 g/cm³ density. Hot-tack strength, measured according to ASTM F1921, remains above the minimum required for vertical form-fill-seal operation across a wider temperature interval. Seal strength per ASTM F88/F88M must be confirmed on the finished laminate or blown web, because antiblock, slip, and corona treatment levels shift the absolute seal force.

    When SP2520 is processed on single-screw cast-film lines with high-shear barrier screws

    Conversion on a 90 mm single-screw extruder with a 30:1 L/D ratio and double-flight barrier section is typically conducted with a flat-to-reverse temperature profile: feed zone 170–190 °C, compression zone 200–220 °C, metering zone 230–240 °C, and die zones 240–250 °C. The narrow molecular weight distribution of metallocene resins reduces shear thinning compared with conventional Ziegler-Natta LLDPE, so melt pressure at the die can be 10–20% higher at equivalent output. That pressure elevation increases shear stress at the die land. If the critical shear stress for sharkskin is exceeded, surface roughness appears on the cast web and must be corrected by raising die temperature or reducing output.

    Die lip deposit formation is governed by shear stress at the die land. On commercial cast-film lines running SP2520, fluoropolymer processing aids are commonly used at 400–800 ppm to suppress die lip accumulation, lower apparent melt viscosity at the die wall, and delay the onset of melt fracture. Die gap settings of 0.8 mm and chill-roll temperatures of 20–30 °C are typical for 40 µm film. Higher chill-roll temperatures reduce quench stress and haze but increase blocking tendency in wound film. Batch-to-batch variation in melt flow rate should be tracked against ISO 1133-1:2022; a drift of ±0.2 g/10 min can alter extrusion pressure by approximately 3–5% and change the draw resonance limit on high-draw-ratio lines. Draw resonance in SP2520 cast film is controlled by maintaining a short air gap, typically 10–20 mm, and by avoiding excessive line-speed modulation at draw ratios above 20:1.

    Comparative Behavior of Metallocene and Ziegler-Natta Sealant Webs

    Compared with a conventional Ziegler-Natta LLDPE of identical density and melt flow rate, SP2520 exhibits typical polydispersity below 3.0 and a more uniform distribution of short-chain branches across the molecular weight distribution. The practical effect is a lower heat-seal initiation temperature, generally 5–10 °C lower than that of conventional LLDPE of comparable density. The hot-tack window remains open at lower temperatures, which allows faster jaw cycling on form-fill-seal equipment. Because the metallocene-catalyzed resin contains lower levels of low-molecular-weight and highly branched fractions, surface migration of extractable species is reduced; this supports more stable coefficient of friction after corona treatment and lower organoleptic contribution in packaged contents.

    Dart impact resistance per ISO 7765-1 is often higher for SP2520 than for conventional LLDPE at the same density, but machine-direction Elmendorf tear per ASTM D1922 may be lower if the film is oriented under high draw. Within the Evolue cast-film family, SP2520 differs from 0.920 g/cm³ grades by higher modulus and improved stiffness, while higher-melt-flow grades are preferred for very thin gauges and high-speed lamination. SP2520 is therefore positioned where draw stability, mechanical strength, and low-temperature sealing must be balanced rather than maximized in a single property direction.

    Extractables and Migration Limits Require Finished-Article Testing

    Food-contact status for SP2520 is evaluated under polymer specifications rather than as an absolute performance claim. The base resin falls within the scope of FDA 21 CFR §177.1520 for olefin polymers intended for direct food contact. Under Commission Regulation (EU) No 10/2011, compliance is determined on the finished article, not on the resin pellet alone. The following checklist identifies the primary regulatory and test references applicable to the product.

    Requirement Reference Scope
    Food-contact olefin polymer FDA 21 CFR §177.1520 United States; specifications for polyethylene food-contact use
    Plastic materials and articles for food contact EU Commission Regulation (EU) No 10/2011 European Union; overall migration and specific migration limits
    Melt flow rate measurement ISO 1133-1:2022 Thermoplastics melt mass-flow rate and melt volume-flow rate
    Density measurement ISO 1183-1:2019 Determination of density of non-cellular plastics

    SP2520 is not hydrolytically sensitive, so dedicated drying is not required at ambient relative humidity below 60%. At higher humidity, surface moisture on pellets can cause vacuum splay and film surface defects; a hopper dryer at 60–80 °C or adequate vented barrel sections should then be used. Melt temperature should remain below 300 °C; above that threshold oxidative degradation increases carbonyl index and can create gel defects. Recycled edge trim may be reintroduced at typical ratios of 10–20% by weight, but post-consumer recyclate streams require migration compliance assessment before use in food-contact or high-purity applications. The final article, including any adhesive, printing ink, or coating, must be tested according to the applicable migration limits of the intended regulatory jurisdiction.

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