| HS Code | 146973 |
| Polymer Type | Metallocene Linear Low-Density Polyethylene (mLLDPE) |
| Catalyst System | Metallocene |
| Comonomer | 1-Hexene |
| Density | 0.920 g/cm³ |
| Melt Flow Rate | 3.0 g/10 min (190°C, 2.16 kg) |
| Melting Point | 118 °C |
| Vicat Softening Point | 95 °C |
| Tensile Strength At Break | 30 MPa |
| Elongation At Break | 600% |
| Tensile Modulus | 200 MPa |
| Dart Impact Strength | 200 g |
| Haze | 6% |
| Gloss | 100 |
| Seal Initiation Temperature | 105 °C |
| Molecular Weight Distribution | Narrow |
| Brittleness Temperature | < -70 °C |
As an accredited Mitsui Chemicals Evolue mLLDPE SP2030 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Mitsui Chemicals Evolue mLLDPE SP2030 is supplied in 25 kg moisture-barrier bags, typically 1,000 kg per pallet. |
| Container Loading (20′ FCL) | Mitsui Chemicals Evolue mLLDPE SP2030 is loaded in a 20′ FCL container in original bags, palletized and secured for ocean shipment. |
| Shipping | Mitsui Chemicals Evolue mLLDPE SP2030 is shipped as solid polyethylene resin pellets in sealed 25 kg bags or jumbo bags on pallets. It is non-hazardous under normal transport conditions and should be kept cool, dry, and away from direct sunlight, heat, and ignition sources. |
| Storage | Store Mitsui Chemicals Evolue mLLDPE SP2030 in a cool, dry, well-ventilated area, away from direct sunlight, heat, ignition sources, and moisture. Keep in original, sealed, undamaged packaging on pallets; protect from UV, weather, and physical damage. Maintain good housekeeping and follow the manufacturer’s SDS and local regulations. |
| Shelf Life | Shelf life is typically 24 months from date of manufacture when stored unopened in original packaging under dry, recommended conditions. |
In extrusion lamination lines producing woven polypropylene and natural kraft sacks for dry bulk products, Evolue SP2030 functions as a low-neck-in olefin layer without the addition of adhesion promoters. The resin is processed at a melt temperature of 290–310 °C on a 90 mm single-screw extruder with a 30:1 L/D screw and a coat-hanger die set to a die gap of 0.8 mm. Coating weight is maintained between 12 g/m² and 25 g/m² depending on moisture barrier targets. Formulation addition is either 100 % SP2030 or a 10–30 wt% blend with LDPE; the LDPE fraction reduces edge neck-in and improves draw-down at line speeds above 150 m/min. At an air gap of 150–220 mm, adhesion to woven polypropylene frequently reaches 2.0 N/15 mm or higher in T-peel testing under ASTM F904 when the substrate is corona-treated to a surface tension of 38–42 mN/m. Food-contact compliance for dry staples and pet-food sacks is normally evaluated under FDA 21 CFR 177.1520(c), Regulation (EU) 10/2011, and EN 15593:2008 for packaging hygiene. Terminal products include cement, fertiliser, resin pellets, grain, pet food and animal feed sacks, where the SP2030 layer provides puncture resistance and moisture vapour transmission control, but continuous exposure to grease, fatty acids or solvents above ambient temperature should be confirmed by end-use migration testing rather than inferred from resin type alone. Batch-to-batch variance in neck-in measured on a 1200 mm die at 200 m/min normally remains within ±3 mm when melt temperature is stabilised within ±2 °C.
Hot-tack performance in coextruded blown sealant films is governed less by total thickness than by short-chain branching distribution; in three-layer coextruded blown film for fresh-cut produce and frozen food, SP2030 is directed to the sealant layer as a 30–70 wt% blend with LDPE or C4 mLLDPE, while the core uses HDPE or LLDPE. The sealant layer is typically 5–8 µm within a total film thickness of 25–35 µm. Because SP2030 possesses a low seal-initiation temperature relative to conventional hexene LLDPE, dwell times in vertical form-fill-seal lines can be reduced, but the actual hot-tack curve must be measured with ASTM F1921 and heat-seal strength with ASTM F88 for each film construction. On a 200 mm three-layer blown-film die with a 2.2 mm die gap, BUR of 2.0–2.5, and frost line height of 150–250 mm, melt temperatures in the sealant extruder are maintained at 195–210 °C. Processing above 220 °C causes film blocking on contact rolls, while below 185 °C visible melt fracture and gauge bands can appear in the seal layer. Food-contact compliance is supported by FDA 21 CFR 177.1520 and EU 10/2011; for frozen food packaging, EC 1935/2004 Good Manufacturing Practice under EC 2023/2006 applies. Terminal film types include pillow packs for pre-washed salads, frozen vegetable films, bakery bread bags and side-gusset pouches. The limitation is that SP2030 should not be combined with high levels of process lubricants containing migratory erucamide above 1000 ppm, because the resultant slip profile can mask the low-seal-temperature advantage in high-speed sealing.
On cast film lines producing pallet stretch wrap and collation film, SP2030 is introduced either as 100 % resin in 12–18 µm film or as a 10–20 wt% modifier in LDPE formulations to raise dart impact and tear resistance without sacrificing film clarity. Extrusion uses a 75 mm single-screw extruder with 30:1 L/D, a 0.8–1.0 mm slot die, and melt temperatures of 230–245 °C. Chill roll temperature is held at 10–18 °C, because higher surface temperatures reduce pinning force and promote gauge bands at line speeds above 180 m/min. Edge weave is controlled by an air gap of 80–120 mm and edge vacuum boxes; the absence of long-chain branching in SP2030 increases melt extension viscosity, so a higher vacuum level than LDPE is frequently needed to pin the web to the chill roll. Tensile properties are verified by ISO 527-3, tear resistance by ISO 6383-2, and cling performance by ASTM D5458. Compliance for industrial stretch film does not require food-contact certification, but where the film is sold into food-service secondary packaging, EU 10/2011 and FDA 21 CFR 177.1520(c) are declared. Terminal products include hand pallet wrap, pre-stretch machine film, bundling collation film and industrial liners. Batch-to-batch variation in cast film haze at 12 µm is typically below 0.5 % on a BYK Gardner haze meter when SP2030 content is kept at 10 wt%; at 30 wt% or higher, chill roll release can become poor, requiring antistatic control or increased slip additive optimisation.
In foil-based liquid packaging and aseptic brick cartons, SP2030 is extrusion-coated directly onto 6.35 µm or 9 µm hard temper aluminium foil at coating weights of 7–12 g/m². The formulation is normally 100 % SP2030, although 5–10 wt% LDPE may be added to reduce edge neck-in on wider dies exceeding 1400 mm. Processing occurs on a tandem extrusion coating line at melt temperatures of 295–315 °C, with an air gap of 120–180 mm and a line speed of 150–250 m/min. At 315 °C, oxidation promotes adhesion to the foil, but residence time above 310 °C must remain below 10 minutes to limit gel formation and CO₂ decomposition products. The critical defect is railroading, a periodic transverse gauge variation caused by melt instability at the die lip; it is controlled by die-bolt adjustment within ±0.05 mm and melt pump speed variation below 0.5 %. For aseptic packaging, the relevant standards include FDA 21 CFR 176.170(c) for paper and paperboard in contact with aqueous and fatty foods, EU 1935/2004, EU 10/2011, and ISO 11607-1:2019 for terminally sterilised barrier packaging where applicable. Terminal products are UHT milk and juice cartons, tomato paste sachets, medical diagnostic strip pouches and aluminium-foil-based lidding. Published data for the specific T-peel values of SP2030 on unprimed foil at 9 g/m² is limited; conversion trials should generate adhesion data using ASTM F904 rather than relying on solvent-based adhesive benchmarks.
Transparent lamination structures for stand-up pouches, dried fruits and detergent refill packs differ from foil-based systems because optical defect detection drives process control more than barrier loss. SP2030 is applied between 15 g/m² and 30 g/m² as a lamination layer on reverse-printed BOPET or BOPP film, often in a 90:10 or 100:0 SP2030:LDPE formulation. The substrate is pre-treated to 42–48 mN/m; the melt temperature is held at 285–305 °C; and the air gap is shortened to 100–150 mm to limit thermal degradation of the printed surface. On a 105 mm extruder with 32:1 L/D and a gear pump, coating weight variation is maintained within ±1 g/m² at 180 m/min. The film layer must pass ASTM F88 seal strength tests after lamination and ASTM F1921 hot-tack tests at 110–130 °C jaw temperature. Compliance for food pouches is normally documented under FDA 21 CFR 177.1520 and (EU) 10/2011, with overall migration below 10 mg/dm² under EN 1186-1:2002. Terminal product types include transparent stand-up pouches, windowed snack packs, dried fruit and nut pouches, and detergent refill packs. The operational boundary is that SP2030 is not suitable as a direct replacement for acid-modified lamination grades where high metal adhesion to foil is required without surface oxidation; on transparent substrates, however, the clarity loss from thermal degradation is less than 1 % haze at 25 g/m² when melt temperature is controlled within ±5 °C.
Lidding films for polypropylene and PET trays containing mayonnaise, sauces or oily ready meals require a sealant layer that forms a robust seal through limited product contamination. SP2030 is used in the sealant skin of lidding film at 20–40 wt% with LLDPE or plastomer, and the total film thickness is 30–40 µm. Because the sealing surface must remain openable yet leak-proof, heat-seal strength is measured under ASTM F88 at 120–150 °C, while hot-tack is measured under ASTM F1921 with a 0.5 second dwell and 0.4 N/mm seal force. On a three-layer cast or blown line, the sealant extruder is set to 200–220 °C, but the actual sealant temperature at the die lip should not exceed 225 °C; above this threshold, the low-molecular-weight fraction can bloom to the surface and reduce seal strength after 72 hours of storage. The lidding film is then coated or laminated to a reverse-printed PET or aluminium foil membrane. Compliance is documented under FDA 21 CFR 177.1520(c) and EU 10/2011, with specific migration limits for fatty food simulants under EU 2017/752 where applicable. Terminal products are lidding for PP and PET trays, single-serve condiment lidding, coffee capsule films and sauce portion packs. The main incompatibility is with high levels of mineral-oil-based printing diluents, which can migrate through the lidding layer during storage; if mineral-oil migration exceeds the limits of the applicable national legislation, the structure must be redesigned with a barrier layer.
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The designation Mitsui Chemicals Evolue mLLDPE SP2030 refers to a metallocene-catalysed linear low-density polyethylene released for blown and cast film conversion. The grade is supplied as free-flowing pellets and is typically specified for monolayer and coextruded lamination films, food packaging webs, hygiene backsheets, and industrial liners where low seal initiation temperature, optical clarity, and puncture resistance are required. Unlike conventional Ziegler-Natta linear low-density polyethylene, SP2030 is produced with a single-site catalyst system that narrows the short-chain branching distribution and lowers the concentration of low-comonomer, high-density fractions. This molecular architecture reduces amorphous-phase extractables and modifies the crystallisation behaviour of the film, which has direct consequences for seal strength, hot-tack, and blocking resistance in high-speed packaging lines.
The primary structural difference is the placement of comonomer along the polyethylene backbone. In SP2030, the metallocene catalyst produces a narrower molecular weight distribution and a more uniform comonomer incorporation than a conventional Ziegler-Natta grade of equivalent density and melt mass-flow rate. Gel-permeation chromatography data for metallocene linear low-density polyethylene in this class generally show polydispersity indices of approximately 2.0–2.5, whereas conventional butene-based Ziegler-Natta LLDPE typically falls between 3.5 and 5.0. This narrower distribution reduces the fraction of extremely high-molecular-weight species that contribute to melt memory effects and optical haze, while also reducing the low-molecular-weight extractable fraction that can migrate into packaged contents.
The controlled comonomer placement shifts the seal initiation temperature downward compared with a Ziegler-Natta grade of the same density. In comparative seal testing under ASTM F1921 and ASTM F88/F88M-23, metallocene grades in this density range typically reach a seal strength of 4.4 N/25 mm at temperatures 10–15 °C lower than a conventional reference material. This permits faster jaw cycles and lower heat input on form-fill-seal machinery. The penalty is a reduction in melt elasticity and bubble stability in pure blown-film extrusion, so the processing window must be managed through die gap, blow-up ratio, and frost-line height rather than by increasing melt temperature alone.
| Property | Test method | Typical value |
|---|---|---|
| Density, base resin | ISO 1183-1:2019 | 0.918 g/cm³ |
| Melt mass-flow rate | ISO 1133-1:2022 at 190 °C and 2.16 kg | 2.0 g/10 min |
| Melting temperature, DSC second heating | ISO 11357-3:2024 | 121 °C |
| Vicat softening temperature A50 | ISO 306:2022 | 102 °C |
| Tensile yield strength, 25 µm cast film | ISO 527-3:2018 | 10.5 MPa |
| Dart impact F50, 25 µm blown film | ASTM D1709-22 Method A | 120 g |
| Haze, 25 µm cast film | ASTM D1003-21 | 2.8 % |
| Gloss at 60°, 25 µm cast film | ASTM D2457-21 | 130 GU |
These values are typical for conditioned specimens at 23 °C ± 2 °C and 50 % ± 5 % relative humidity and are not to be interpreted as specification limits. Batch-to-batch variation and conversion history influence film properties; the certificate of analysis supplied with each lot governs the rated melt mass-flow rate and density. Published data for some multilayer configurations containing SP2030 is limited, particularly where coextruded layer ratios and additive packages alter seal, slip, and antiblock behaviour.
On a 55 mm single-screw extruder with an L/D ratio of 30:1, a barrier screw with a Maddock mixing section, and a 250 mm annular die having a 1.8 mm die gap, stable bubble operation is usually attained at blow-up ratios between 2.0:1 and 2.6:1. Operation above 2.8:1 can induce stalk oscillation and transverse gauge variation because the low melt strength of the narrow-distribution metallocene grade cannot resist radial strain as effectively as a high-pressure LDPE or a broad-distribution Ziegler-Natta LLDPE. Frost-line height in this configuration is normally held between 250 mm and 500 mm. Lowering the frost line too far, below 200 mm, increases film blocking and reduces heat-seal plateau width because the oriented tie chains in the amorphous phase retain residual stress.
Die lip build-up is a recognized operational failure mode for metallocene LLDPE extrusion. The low-molecular-weight fraction is lower than in conventional LLDPE, but oxidation products generated at the die lip can accumulate within 2–6 h of continuous operation, producing edge tear and visible gel streaks in cast film. A fluoropolymer processing aid at 200–600 mg/kg is commonly used to suppress melt fracture and reduce die lip deposit formation. Screw amperage and back pressure should be monitored when processing SP2030 because the narrower molecular weight distribution can produce melt pressures 10–15 % higher than a conventional LLDPE of equivalent melt mass-flow rate at the same screw speed.
Cast film conversion of SP2030 is generally performed with barrel set points between 190 °C and 240 °C and a measured melt temperature at the die exit of 220–250 °C. Melt temperatures above 260 °C should be avoided because thermal-oxidative degradation increases gel formation and reduces seal strength. Chill roll temperatures are typically set between 18 °C and 30 °C; lower chill roll temperatures increase quench depth and reduce haze, but excessive cooling below 15 °C can create condensation and surface defects in high-humidity production halls. Draw ratios between 2.5:1 and 4.0:1 are commonly used for lamination webs, and neck-in at these ratios is lower than that of high-pressure LDPE because of the better balance between viscous and elastic response in the metallocene grade.
For blown film, a die gap of 1.5–2.5 mm is preferable to reduce shear stress at the die lip. Narrow die gaps below 1.2 mm can trigger sharkskin melt fracture unless a processing aid is present. The recommended melt temperature for blown film extrusion is between 185 °C and 215 °C, with barrel profiles starting at 165 °C in the feed zone and increasing toward the die. Pre-drying is not normally required when pellet surface moisture remains below 0.02 % by weight. If pellets are transferred from cold storage into a warm production hall and visible condensation forms, a hopper dryer at 70 °C for 2 h is sufficient to restore surface dryness; extended drying above 80 °C may promote oxidation and should be avoided.
Comparison of SP2030 with a conventional Ziegler-Natta linear low-density polyethylene of equivalent density and melt mass-flow rate reveals the trade-off between optical performance and bubble stability.
| Parameter | SP2030 typical behaviour | Conventional Ziegler-Natta LLDPE reference | Evaluation method |
|---|---|---|---|
| Molecular weight distribution index | 2.0–2.5 | 3.5–5.0 | Gel-permeation chromatography |
| Seal initiation temperature at 4.4 N/25 mm | 90–100 °C | 105–115 °C | ASTM F1921, ASTM F88/F88M-23 |
| Dart impact F50 at 25 µm | 110–140 g | 70–95 g | ASTM D1709-22 |
| Haze at 25 µm | 2–4 % | 5–9 % | ASTM D1003-21 |
| Gloss at 60° | 120–140 GU | 80–105 GU | ASTM D2457-21 |
| Melt pressure at constant screw speed | higher by 10–15 % | lower reference value | Extruder transducer measurement |
In coextruded structures, SP2030 is often placed in the sealant layer because its low seal initiation temperature permits a wider sealing window without distorting the adjacent core layer. The modulus and stiffness contribution of SP2030 is moderate at a density of 0.918 g/cm³; applications requiring higher stiffness or lower blocking tendency should evaluate higher-density metallocene grades or blends with HDPE. When SP2030 is blended with LDPE to improve bubble stability, addition levels of 10–30 wt% LDPE are typical. At LDPE addition above 30 wt%, haze may increase above 5 % in 50 µm films, and the seal initiation advantage begins to erode toward that of LDPE. Published data for this specific blend configuration is limited; pilot-scale validation is necessary before commercial substitution.
Regulatory compliance statements should be obtained from the supplier for each lot. The neat resin is typically covered under FDA 21 CFR 177.1520(c) for olefin polymers in food contact and is evaluated under EU Regulation (EU) No 10/2011 as amended for plastic materials intended to come into contact with food. Assembled laminates require overall migration testing under EN 1186-1:2002 and specific migration limits for additives used in the sealant layer. Under RoHS Directive 2011/65/EU, the grade is generally expected to remain below the maximum concentration values of 1000 mg/kg for lead and 100 mg/kg for cadmium, but a supplier declaration is required for documented compliance.
SP2030 is not intended for sustained outdoor exposure without UV stabilisation. Unstabilised film exposed to xenon-arc ageing under ASTM G155-21 or fluorescent UV condensation testing under ASTM G154-23 typically shows carbonyl index increase and tensile elongation loss before a mechanically functional life is achieved. For aggressive liquid packaging, environmental stress cracking resistance should be evaluated under ASTM D1693-23 condition B, and chemical resistance testing should include realistic fill temperatures and contact times. Avoid prolonged contact with strong oxidising agents, aromatic hydrocarbons, and halogenated solvents, which can swell the polyethylene matrix and reduce seal integrity. For hot-fill or retort conditions above 100 °C, SP2030 alone is generally not suitable because thermal softening and loss of seal strength occur before process completion. Published long-term ageing data for SP2030 in these specific configurations is limited.