| HS Code | 363565 |
| Product Name | Mitsubishi FGF ASA-X 3D Printing Polymer |
| Manufacturer | Mitsubishi Chemical |
| Polymer Type | ASA (Acrylonitrile Styrene Acrylate) |
| Printing Technology | Fused Granulate Fabrication (FGF) |
| Form | Pellets |
| Density | approx. 1.07 g/cm3 |
| Tensile Strength | approx. 45 MPa |
| Tensile Modulus | approx. 2200 MPa |
| Elongation At Break | approx. 20% |
| Flexural Strength | approx. 65 MPa |
| Flexural Modulus | approx. 2200 MPa |
| Notched Izod Impact | approx. 10 kJ/m2 |
| Heat Deflection Temperature | approx. 95 C at 0.45 MPa |
| Vicat Softening Temperature | approx. 105 C |
| Glass Transition Temperature | approx. 110 C |
| Uv Resistance | Excellent |
| Chemical Resistance | Good |
| Water Absorption | approx. 0.3% |
| Processing Temperature | 240-260 C |
| Drying Temperature | 80 C |
| Shrinkage | approx. 0.5-0.8% |
As an accredited Mitsubishi FGF ASA-X 3D Printing Polymer factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Sealed moisture-barrier foil bag containing 1 kg of Mitsubishi FGF ASA-X 3D printing polymer, labeled with safety and batch details. |
| Container Loading (20′ FCL) | Mitsubishi FGF ASA-X 3D Printing Polymer, palletized and shrink-wrapped, loaded into a 20′ FCL dry container, secured for safe transport. |
| Shipping | Mitsubishi FGF ASA-X ships as a non-hazardous, non-DG polymer in sealed moisture-barrier bags or drums. Store below 30°C, away from direct sunlight, moisture, and ignition sources. Handle with standard PPE; no special ventilation required. Follow local regulations and the manufacturer’s SDS for transport documentation. |
| Storage | Mitsubishi FGF ASA-X 3D Printing Polymer should be stored in a cool, dry, well-ventilated area away from direct sunlight, heat, sparks, and open flames. Keep original containers or moisture-barrier bags tightly sealed. Protect from humidity and UV light; use desiccant after opening. Store at moderate room temperature, preferably below 30°C, away from food, drink, and strong oxidizers. Follow SDS and local regulations. |
| Shelf Life | Shelf life is approximately 24 months when stored sealed in original packaging, in a cool, dry place away from sunlight. |
In automotive tier-one trim manufacturing, thermoforming mold inserts and drill fixtures are printed directly from dried ASA-X granulate rather than machined from polyurethane board or aluminium-filled epoxy tooling board. The feedstock blend uses 100 wt% virgin ASA-X granulate, with regrind from machined ASA-X surfaces permitted to 18 wt% maximum after screen classification to retain particles between 0.5 mm and 2.0 mm; fines below 0.3 mm are excluded because they lower melt-flow stability and produce a narrower processing window. Process conditions are desiccant hopper drying at 80 °C for 4 h to a dew point of −40 °C, extrusion through a single-screw pellet extruder with 25:1 L/D ratio and 2.8:1 compression ratio, melt temperature 235 °C ± 5 °C, bead width 5 mm to 7 mm, layer height 1.2 mm to 2.0 mm, bed temperature 95 °C, chamber temperature 70 °C, and cooling fan output at 15% after layer 10. Acceptance criteria are ISO 178:2019 for flexural modulus, ISO 604:2002 for compressive strength, ISO 75-2:2013 method A at 1.80 MPa for deflection temperature, and ISO 1133-1:2022 for melt volume-flow rate after drying. On production-scale gantry machines with build envelopes of 2,000 mm × 3,000 mm, batch-to-batch MVR variation exceeding ±1.5 cm³/10 min has been observed to widen the deposited bead and create local fusion arrests; pre-extrusion MVR checks at 230 °C under 2.16 kg load are therefore used as a lot acceptance gate. Printed tooling is thermally stress-relieved at 85 °C for 2 h before CNC machining at 18,000 rpm spindle speed and 2,500 mm/min feed rate, because as-printed residual stress can release during machining and alter flatness by more than 0.5 mm/m. Finished part classes include vacuum-form tool inserts, trim fixture bodies, drill templates, and assembly jig housings. Continuous tool-face exposure should remain 10 °C below the lot-specific ISO 75-2:2013 method A value to limit creep under mould-clamp pressure.
For external façade louvre elements intended for installation above 3 m on a ventilated façade, printed ASA-X is treated as a non-structural cladding component and carries no automatic reaction-to-fire classification; EN 13501-1:2018 requires a project-specific classification report from the full assembly including mounting rail, insulation, and cavity detailing. For architectural louvres, the addition ratio is 100 wt% virgin ASA-X, or 85 wt% virgin with 15 wt% clean in-house regrind from unpainted CNC chips; mineral fillers above 3 wt% are not recommended because they reduce interlayer elongation and can shift the failure mode from ductile deformation to interlaminar shear. The production sequence uses a robotic pellet extruder with a 12 mm screw, 24:1 L/D ratio, melt temperature 230 °C to 245 °C, bead width 6 mm to 8 mm, layer height 1.5 mm to 2.5 mm, and chamber temperature 60 °C; after printing, parts are annealed at 85 °C for 2 h and machined on a two-stage CNC router at 18,000 rpm and 2,000 mm/min feed. Mechanical acceptance is evaluated under ISO 178:2019, weathering under ISO 4892-2:2013 cycle 1, and water absorption under ISO 62:2008; dimensional stability after weathering is checked at 2,000 h total UV exposure. Terminal component types include louvre blades, spandrel infill panels, parapet capping, and non-structural cladding elements. Where project specifications demand B-s2,d0 or better, published data for this specific printed wall configuration is limited, and a full assembly classification test is required before façade application.
Outdoor telemetry cabinets replacing coated steel enclosures impose a multi-factor compliance burden that is solved only when UV performance and ingress protection are demonstrated together, because the polymer wall must maintain dimensional stability under solar load and internal heat from power electronics. Enclosure shells are prepared with 100 wt% virgin ASA-X and halogen-free colour masterbatch at 2 wt% maximum; external lubricants, mould-release agents, and ABS-carrier masterbatch are excluded because they reduce print-bed adhesion and can transfer to sealing surfaces. Drying uses a desiccant hopper at 80 °C for 6 h when relative humidity exceeds 60%, followed by extrusion through a 15 mm single-screw pellet extruder with 25:1 L/D ratio at melt temperature 235 °C; layer height is 1.0 mm to 2.0 mm, nozzle diameter 4 mm, bed temperature 100 °C, and chamber temperature 65 °C. The shell is printed with a nominal wall thickness of 5 mm and post-machined with thread inserts tapped at 2,500 rpm; corner bosses and cable gland seats are integrated into the print to avoid secondary bonding. Compliance standards include UL 746C for UV and water exposure of polymeric materials, UL 94 HB for polymer combustibility, IEC 62208:2011 for empty enclosures for low-voltage switchgear and controlgear assemblies, and IEC 60529 for assembled enclosure ingress protection at IP54. Terminal finished product types are outdoor telemetry cabinet shells, power distribution enclosure covers, and antenna radome frames. ASA-X is not a substitute for UL 94 V-0 enclosure grades unless a specific V-0 formulation has been validated; gaskets, cable glands, and mounting brackets remain separate parts and are not covered by this application.
Marine hatch liners printed from ASA-X replace vacuum-formed PMMA/ASA sheet only when salt-spray resistance and low-temperature impact are demonstrated on the actual wall-section geometry; the substitution is not automatically accepted for load-bearing deck hardware. The formulation for marine trim is 100 wt% virgin ASA-X granulate, with marine-white ASA-based masterbatch at 3 wt%; ABS-carrier masterbatch is unsuitable because it depresses UV retention and can accelerate chalking. Drying at 80 °C for 4 h to −40 °C dew point precedes pellet extrusion at melt temperature 240 °C, bead width 4 mm to 6 mm, layer height 1.0 mm to 1.5 mm, chamber temperature 65 °C, and interlayer time below 30 s to keep the fusion interface above 105 °C. Post-processing sanding uses 240 grit to 600 grit, and solvent wiping before adhesive bonding is avoided; mechanical fastening is preferred for removable panels. Compliance testing is conducted under ISO 9227:2022 for neutral salt spray, ISO 179-1:2010/1eU for Charpy impact, ISO 306:2022 Vicat softening temperature method B50, and ISO 62:2008 for water absorption. Terminal part types include non-structural hatch liners, instrument panel blank panels, and exterior trim covers. Continuous service above 70 °C is not recommended due to creep under fastener clamp load, and contact with diesel, glycol-based coolants, or aggressive cleaning solvents is excluded.
In street furniture structural profiles, bead-width selection above 5 mm introduces a cooling-rate gradient that controls void formation more strongly than extrusion temperature, because the core of a thick bead remains above the glass transition while the surface contracts. Bench and bin components are compounded from 100 wt% ASA-X, UV-stable outdoor masterbatch at 2 wt% to 3 wt%, and regrind from unpainted trim at 20 wt% maximum; painted or metallised scrap is excluded to avoid hydrolysis and gas porosity. The production cell is a gantry-type pellet extruder with an 8 mm nozzle, bead width 5 mm to 7 mm, layer height 2.0 mm to 3.0 mm, chamber temperature 60 °C, and bed temperature 90 °C; after printing, components are annealed at 85 °C for 3 h to reduce residual stress before routing. Joints for bench slats are produced by hot-air welding at 240 °C or with mechanical fasteners; adhesive bonding is limited to non-structural caps. Compliance standards are EN 581-1:2017 for outdoor seating safety, ISO 4892-2:2013 for weathering, ISO 178:2019 for flexural modulus, and ISO 179-1:2010/1eU for impact. Terminal component types include bench slats, litter bin outer shells, and outdoor table frames. Load-bearing legs should incorporate internal metal reinforcement, and published data for long-term creep under continuous load at 60 °C is limited; therefore a proof-load test on each new seat geometry is recommended before outdoor installation.
Automotive exterior trim evaluation coupons and low-volume service parts are produced with ASA-X when OEM design-validation loops require weathered surfaces to match injection-moulded benchmarks after paint or in-mould texture. Trim coupon feedstock is set at 100 wt% virgin ASA-X, or 85 wt% virgin with 15 wt% uncontaminated unpainted regrind; painted scrap is excluded because residual paint reduces interlayer adhesion and creates gas porosity. The extrusion system uses a 20 mm screw with 22:1 L/D ratio, melt temperature 230 °C, bead width 3 mm to 5 mm, layer height 0.8 mm to 1.2 mm, chamber temperature 70 °C, and bed temperature 95 °C. Surface preparation is sanding with 240 grit to 600 grit, cleaning with deionised water, application of an adhesion promoter, and coating with a 2K polyurethane system at 60 μm dry film thickness. Compliance testing uses SAE J2527 for exterior accelerated weathering, ISO 2409:2020 cross-cut adhesion with rating 0 to 1 after 240 h humidity ageing, ISO 178:2019 for flexural properties, and ISO 179-1:2010/1eA for notched Charpy impact. Terminal component types include exterior mirror caps, rocker panel extensions, aero trim test articles, and OEM evaluation coupons. At layer heights below 0.8 mm, heat accumulation on small parts can produce gloss banding; primer adhesion and paint film thickness therefore require validation on each new toolpath before production quantities are approved.
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Mitsubishi FGF ASA-X 3D Printing Polymer is a pelletized acrylonitrile–styrene–acrylate terpolymer supplied for fused granular fabrication (FGF) systems, in which a rotating screw melts and deposits polymer granules through a large-diameter nozzle. The product is specified as an FGF pellet feedstock, not a filament, and is used on machines with nozzle orifices from 1.2 mm to 8.0 mm and throughputs above 1 kg/h. Lot-release documentation for this chemistry generally includes density according to ISO 1183-1:2019, melt volume-flow rate according to ISO 1133-1:2022, tensile properties from ISO 527-2:2012 Type 1A specimens, and notched impact resistance from ISO 180:2023. The defining chemical difference from ABS is the replacement of the polybutadiene impact modifier with an acrylic ester elastomer; the absence of unsaturated main-chain double bonds in that elastomer phase is the primary mechanism behind improved colour stability and impact retention under ISO 4892-2:2013 Xenon-arc exposure. Typical applications include assembly fixtures, outdoor enclosures, low-rate tooling, and large-format mock-ups that require styrenic processability with better atmospheric ageing than ABS.
In industrial FGF practice, ASA-X is dried before processing because pelletized styrenics absorb enough surface moisture at ambient relative humidity above 60 % to generate splay and microvoids. A desiccant dryer set at 80 °C with a dew point of -40 °C for 4 h is the reference conditioning profile; target pellet moisture is below 0.05 % by mass. On large-format machines with build volumes above 1 m³, wet material produces screw torque fluctuation and feed-throat bridging in single-screw extruders with 20:1 to 30:1 L/D ratios, since steam release in the compression zone reduces pellet conveying efficiency.
Moisture control is the first processing boundary. Pelletized styrenic feedstock stored at ambient relative humidity above 60 % requires closed-loop desiccant drying before extrusion. A drying profile of 80 °C for 4 h in a dryer with a dew point of -40 °C is used to reduce moisture to below 0.05 % by mass. Moisture above this threshold appears as splay, internal microvoids, and reduced melt strength in the deposited bead. On production-scale single-screw extruders with 20:1 to 30:1 L/D ratios, wet feedstock also produces feed-throat bridging and screw torque fluctuation because steam release in the compression zone reduces bulk density and conveying efficiency.
Melt conditioning for ASA-X is governed by the melt volume-flow rate. If the supplier reports MVR at 220 °C/10 kg under ISO 1133-1:2022, values below 8 cm³/10 min increase extruder backpressure and require barrel temperatures near 260 °C, while values above 25 cm³/10 min reduce bead stability and can cause sag on vertical walls. The practical melt-temperature window is treated as 240 °C to 270 °C; sustained operation above 270 °C accelerates thermo-oxidative degradation of the acrylate phase, producing a visible yellow shift and a drop in notched impact strength measured by ISO 180:2023. Below 240 °C, interlayer polymer diffusion is insufficient unless chamber and nozzle pressures are raised, which is limited on open-architecture machines.
Rheological conflict in pellet-fed ASA-X arises between high melt strength needed for stable large-bead deposition and low melt viscosity needed for interlayer wetting. On a 30 mm single-screw extruder with 24:1 L/D, melt pressure at the nozzle typically spans 5 MPa to 15 MPa; screw speed is adjusted between 10 rpm and 60 rpm to keep residence time below 45 min. If the material’s MVR under 220 °C/10 kg falls below 8 cm³/10 min, backpressure rises and the drive may overload unless barrel temperatures are raised toward 270 °C. If MVR exceeds 25 cm³/10 min, the bead spreads excessively and vertical walls lose shape retention above 1.5 m in height. The practical thermal window is therefore narrow: 240 °C to 270 °C, with the lower bound set by interlayer diffusion and the upper bound set by thermo-oxidative degradation of the acrylic ester phase.
| Feedstock | Impact-modifier chemistry | Form | UV ageing benchmark | Drying condition | Principal FGF process risk |
|---|---|---|---|---|---|
| Mitsubishi FGF ASA-X | Acrylic ester | Pellet | Higher impact and gloss retention than ABS under ISO 4892-2:2013 | 80 °C / 4 h desiccant drying | Interlayer delamination below 70 °C chamber air |
| ABS FGF | Polybutadiene | Pellet | Rapid yellowing and impact loss under UV | 80 °C / 4 h desiccant drying | Warpage and melt odour at high temperature |
| ASA filament | Acrylic ester | Filament, 1.75 mm or 2.85 mm | Similar UV resistance to ASA-X | Lower thermal mass but same moisture target | Anisotropy and low deposition rate |
Operators should map the chamber and platen before production. For sections thicker than 6 mm, a heated chamber between 70 °C and 95 °C and a bed temperature between 90 °C and 110 °C are used to control warpage. Edge-loss of chamber heat is a common field failure in gantry-style FGF machines; thermocouple mapping must maintain the critical surface temperature within ±5 °C to avoid corner lifting. Sustained operation above 270 °C accelerates chain scission and generates low-molecular-weight volatile products that appear as yellowing and reduced notched impact strength under ISO 180:2023. Large hot-air soak periods in a heated chamber should not exceed the supplier-documented residence time. Thermocouple placement in the nozzle adaptor and melt zone is required because small cartridge-heater offsets of 5 °C produce non-trivial viscosity variation across wide beads.
Outdoor tooling produced from pellet-fed ASA-X is evaluated primarily for colour change, impact retention, and dimensional stability under ISO 4892-2:2013 or ASTM G154-23 fluorescent UV testing. The absence of polybutadiene unsaturation in the elastomer phase reduces the formation of hydroperoxides that initiate yellowing in ABS. Comparative panels printed with 6 mm parallel-path infill and 100 % outer shells have shown acceptable visual gloss retention after 500 h Xenon-arc testing; however, published data for this specific configuration is limited, and the supplier certificate for lot-specific UV stabilizer loading must be reviewed before long-term exterior deployment. Dimensional stability is controlled by the grade’s coefficient of linear thermal expansion, and for unfilled ASA the value is typically in the range of 70 × 10−6 to 90 × 10−6 m/(m·K) under ISO 11359-2:2021.
Compared with ABS FGF, the reduction in warpage is not absolute. ASA-X retains a styrenic shrinkage envelope, and large flat parts still lift from the build sheet when the chamber floor-to-ceiling temperature difference exceeds 10 °C. The use of a heated chamber between 70 °C and 95 °C, combined with a bed temperature between 90 °C and 110 °C, is specified for sections thicker than 6 mm. In gantry-style FGF machines with build volumes above 1 m³, edge-loss of chamber heat is a common field failure; thermocouple mapping of the platen and chamber walls is required to maintain the window at ±5 °C.
Interlayer mechanical response in pellet-fed ASA-X is not equivalent to injection-moulded ASA. Deposited beads cool below the glass transition before the next adjacent pass, so tensile elongation at break perpendicular to the build direction may be 50 % or less of the moulded value when measured under ISO 527-2:2012 at 23 °C. Tensile strength in the bead direction can approach 85 % to 95 % of the moulded reference if a 0.8 mm layer height and 30 % to 50 % overlap are used. Designers should not replace moulded load-bearing components without conducting orientation-specific testing on the actual FGF machine; generic ISO data from the pellet supplier is not a direct substitute for build-direction validation.
Heat deflection temperature for unfilled ASA typically spans 88 °C to 98 °C at 1.8 MPa when tested under ISO 75-2:2013 Method A or ASTM D648-18. Service above this range is not recommended for load-bearing applications; creep under static load should be screened under ISO 899-1:2017 if continuous temperature exceeds 70 °C. Notched Charpy impact for pellet-printed ASA-X depends on raster orientation and bed temperature, but production-scale samples often fall between 8 kJ/m² and 15 kJ/m² when conditioned and tested under ISO 180:2023. The failure mechanism at low chamber temperatures is brittle interlayer fracture; at high chamber temperatures, impact energy is retained but part edges may sag.
Chemical resistance of ASA-X follows styrenic-copolymer behaviour: aromatic solvents, ketones, esters, and chlorinated hydrocarbons cause stress cracking, particularly at build-line interfaces. Isopropyl alcohol or mild soap solution is used for surface cleaning; aggressive solvents must not be applied because residual stresses in large beads accelerate environmental stress-cracking under ISO 22088-3:2006 bent-strip screening. The grade should not be compounded with unapproved nucleating agents or amine-based heat stabilizers without extrusion-scale verification; additive packages that raise melt pH or generate volatile amines can produce odour and reduce molecular weight stability at 260 °C.
On production-scale FGF systems, batch-to-batch variation in melt flow and impact strength is managed by incoming inspection of pellet moisture and MVR. A lot that exceeds 0.05 % moisture on receipt should be returned to dryer or rejected if drying time extends beyond 6 h without reaching the target. The grade is intended for large-orifice bead deposition, not fine-resolution filament printing; minimum practical feature size is governed by a 1.2 mm nozzle and bead compression to roughly 0.8 mm. Use in medical, food-contact, or aerospace-qualified parts requires separate regulatory and process validation because the generic REACH/RoHS documentation attached to many styrenic feedstock lots does not include application-specific migration or flame-smoke-toxicity testing. After the last print run, purge with an unfilled styrenic carrier and reduce barrel temperature to 180 °C before shutdown to limit residence-time degradation of the acrylic ester phase.