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Mitsubishi FGF ASA Recycled ASA-X 20% Glassfibe

    • Product Name: Mitsubishi FGF ASA Recycled ASA-X 20% Glassfibe
    • Factroy Site: Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry: sales8@sinochem-nanjing.com
    • Manufacturer: Ascent Petrochem Holdings Co., Limited
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    Specifications
    HS Code 150364
    Material Type ASA with 20% glass fiber
    Polymer Family ASA
    Reinforcement Material Glass fiber
    Glass Fiber Content 20%
    Recycled Content Yes
    Density 1.20 g/cm³
    Tensile Modulus 7000 MPa
    Tensile Strength 70 MPa
    Elongation At Break 2.5%
    Flexural Modulus 6500 MPa
    Flexural Strength 100 MPa
    Charpy Notched Impact Strength 5 kJ/m²
    Heat Deflection Temperature At 1 8 Mpa 100 °C
    Vicat Softening Temperature 105 °C
    Molding Shrinkage 0.3-0.6%
    Water Absorption 0.3%
    Flammability Rating UL 94 HB
    Processing Method Injection molding

    As an accredited Mitsubishi FGF ASA Recycled ASA-X 20% Glassfibe factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Supplied in standard 25 kg moisture-resistant, polyethylene-lined paper bags, securely palletized for industrial storage and transport.
    Container Loading (20′ FCL) 20′ FCL container loaded with Mitsubishi FGF ASA Recycled ASA-X 20% Glassfiber chemical in securely packed bags for shipment.
    Shipping Mitsubishi FGF ASA Recycled ASA-X 20% Glass Fiber is shipped as thermoplastic pellets in moisture-barrier bags or octabins on pallets. It is non-hazardous for transport and should be kept dry, away from direct sunlight and heat, with standard industrial handling precautions.
    Storage Store Mitsubishi FGF ASA Recycled ASA-X 20% Glassfibe in a cool, dry, well-ventilated area away from direct sunlight, heat, moisture, and ignition sources. Keep in original sealed containers or moisture-barrier liners, palletized and off the floor. Avoid dust generation; wear dust protection when handling. Keep away from incompatible chemicals, protect from contamination, and follow local regulations and manufacturer guidance.
    Shelf Life Shelf life is typically 12 months from date of manufacture when stored dry, cool, and in sealed containers under recommended conditions.
    Application of Mitsubishi FGF ASA Recycled ASA-X 20% Glassfibe

    Across unpainted exterior mirror housing programs for light commercial vehicles, the substitution of mineral-filled polypropylene with Mitsubishi FGF ASA-X Recycled ASA-X 20% Glassfiber is driven by the need to hold A-surface gloss after multi-year UV exposure while reducing creep in cantilevered boss sections. The compound enters the plant as hygroscopic pellets that require desiccant drying with a dew point no higher than -40 °C at 80 °C for 4 h, yielding residual moisture below 0.05 % when verified by ISO 15512 Karl Fischer titration. Moulders processing on a 40 mm screw with 24:1 L/D maintain melt temperatures between 240 °C and 260 °C; excursions above 270 °C accelerate yellowing of the acrylate phase and produce surface streaking from degraded recycled fractions. Tool temperature is held at 60–80 °C to promote fibre wet-out and reduce exposed glass at the part surface. On production machines, screw recovery time increases when melt temperature is lowered below 250 °C because the recycled ASA-X fraction exhibits a steeper viscosity curve than prime ASA, a shift that alters cushion control and pack pressure stability in thin-wall housing ribs.

    Gate placement is controlled by the anisotropic shrinkage of short glass fibres. Along-flow shrinkage is constrained to 0.15–0.35 %, while cross-flow shrinkage may exceed 0.5 %; this differential requires rectangular or trapezoidal gates with a land length below 1.0 mm and a gate thickness above 60 % of the nominal wall. Multi-gated mirror housings create weld lines at latch bosses and mounting pedestals. In short-glass ASA systems, weld line tensile strength can drop 30–50 % relative to non-weld-line bulk material because fibres orient parallel to the weld plane and do not cross the knit interface. Sequential valve gating reduces weld line movement but raises clamp force requirements. Clamp force is sized by projected area at 4–5 kN/cm²; insufficient clamp force opens the parting line at deep boss bases and creates flash that must be manually trimmed. After moulding, parts are conditioned per ISO 291 at 23 °C and 50 % RH before notched Charpy testing per ISO 179-1/1eA. Dry as moulded notched Charpy values for 20 wt% short-glass ASA reference grades typically fall between 6 kJ/m² and 8 kJ/m², but this value alone is not a reliable predictor of field performance. Accelerated weathering per ISO 4892-2 with a 0.35 W/m²·sr irradiance at 340 nm and a 3000 h cycle is used to track a ΔE ceiling of 3.0 and gloss retention above 50 % at 60° incident angle. Published data for this specific post-industrial recycled ASA-X configuration is limited; these ranges are representative of short-glass ASA reference grades and must be confirmed on first article from the qualified production tool.

    What Actually Limits Threaded Brass Insert Retention in Recycled ASA-X 20 % Glass Fibre Outdoor Enclosures?

    The limiting factor in threaded insert service life is not static pull-out but cyclic thermal shock across the -40 °C to 85 °C range specified in IEC 60068-2-14 Test Na. Brass inserts with M4 or M5 threads moulded into bosses of 6 mm nominal wall are subjected to hoop stresses generated by the difference between the CLTE of the polymer and the brass. Short-glass ASA CLTE typically falls between 30 µm/m·K and 40 µm/m·K in the flow direction, while brass is 18–20 µm/m·K. After 1000 cycles, radial cracking appears at the boss base unless the boss diameter is at least 2.5× the insert outer diameter and the packing pressure is held above 70 MPa. Moulded-in inserts reduce initial clearance but increase assembly scrap when insert location shifts during injection; ultrasonic insertion reduces moulding stress but increases creep under continuous clamp load because the surrounding polymer flows away from the knurl over time. For outdoor enclosures that must pass IK08 impact per IEC 62262, the boss root radius below the insert should not be less than 0.8 mm to avoid brittle crack propagation from the notch.

    Surface temperature on dark grey enclosures mounted in direct sun can exceed air temperature by 20–30 °C, so boss and snap-fit retention must be evaluated at 85 °C rather than 23 °C. Flexural modulus at 80 °C for short-glass ASA drops to roughly 70 % of the 23 °C value, and latch deflection calculations that ignore this shift produce field loosening after the first summer. For this reason, load-bearing snap arms are designed with a wall thickness of 2.5 mm or greater and a deflection limit below 1.0 mm at 85 °C. Because the recycled fraction in ASA-X can drift between production lots, incoming melt flow rate should be checked per ISO 1133-1 at 220 °C with a 10 kg load. A drift of more than ±15 % from the qualified lot signals a regrind blend shift that changes pack pressure, fibre orientation, and insert hoop stress. On a two-cavity enclosure tool, hold-pressure profile changes of more than 5 MPa between lots are sufficient to shift boss diameter and require re-validation of insert torque retention.

    RequirementStandardTest ConditionPass Criterion
    WeatheringISO 4892-2:20130.35 W/m²·sr at 340 nm, 3000 hΔE < 3.0, gloss retention > 50 %
    ImpactIEC 62262:2002IK08 5 J hammerNo crack penetrating enclosure wall
    Thermal shockIEC 60068-2-14:2009-40 °C to 85 °C, 1000 cyclesNo insert loosening > 0.15 N·m
    FlammabilityUL 94Vertical burn on 3.0 mm plaqueTo be confirmed; ASA-GF is typically HB unless a flame-retardant package is specified

    For photovoltaic combiner box shells intended to survive 20-year field lifetimes, the combination of direct rooftop UV exposure, internal busbar heat rise, and differential thermal expansion at cable glands makes isotropic shrinkage predictions misleading. The 20 wt% glass fibre in the recycled ASA-X compound lowers the CLTE closer to the copper busbar support than unfilled ASA, but it introduces anisotropic warpage because fibres align along the melt flow direction. A combiner box base measuring 300 mm × 200 mm × 3 mm can exhibit corner lift above 1.0 mm on a flat granite plate if the gate is placed at one end rather than a central flash gate. Tool compensation by reverse camber of 0.5–0.8 mm across the long axis is applied, but this correction is valid only for a single moulding temperature and fibre orientation state. Changes in injection speed that alter the frozen skin thickness shift the effective shrinkage and render the camber correction inadequate.

    Gland nut sealing torque is specified at 2.0–2.5 N·m for PG13.5 polyamide glands. The creep modulus of ASA-GF at 60 °C under a compressive load of 10 MPa should be measured by ISO 899-2; if the 1000 h creep strain exceeds 1.5 %, the sealing gasket loses compression set and moisture ingress occurs at the enclosure corners. Because published long-term UV data for this exact recycled ASA-X glass fibre configuration is limited, accelerated xenon testing per ISO 4892-2 and natural Florida exposure per ASTM G7 should be run in parallel before release. Batch acceptance for combiner box applications should also include a 1000 h damp heat test at 85 °C and 85 % RH per IEC 60068-2-78, with post-exposure creep and torque retention evaluated on assembled glands rather than moulded plaques.

    Rooftop Condenser Fan Guard Fracture Behaviour after Accelerated Surface Erosion

    Surface erosion of glass-filled ASA fan guards does not proceed uniformly on rooftops; wind-driven dust and hail produce local removal of the ASA matrix, leaving exposed glass fibres that act as moisture wicks and crack initiation sites. Impact testing after xenon arc ageing is therefore conducted on notched Charpy specimens cut from guards that have been weathered for 3000 h under ISO 4892-2. The notched Charpy value after weathering may fall to 60–80 % of the dry as moulded value, while the unweathered core retains more than 90 %. Fan guard ribs are designed with a root radius above 1.5 mm to compensate for surface embrittlement and to prevent crack propagation from the eroded zone into the structural rib network. Instrumented puncture testing per ISO 6603-2 at 4.4 m/s and 23 °C is used on flat plaques cut from the guard; total energy absorption below 10 J after 2000 h of xenon ageing indicates excessive surface degradation or fibre sizing hydrolysis at the matrix interface.

    Moulders producing fan guards from recycled ASA-X 20% glass fibre must also manage fibre accumulation at the last fill point. Fibre-rich regions at the end of flow show lower impact strength and higher moisture uptake; this zone should be located away from the guard mounting bosses where cyclic wind loading is highest. A two-point gating scheme with a flow split ratio of 60:40 is used on large fan guards to avoid a single advancing flow front pushing fibre-rich material into a weld line at the central hub. Weld line tensile strength in fan guard spokes is specified at no less than 35 MPa by ISO 527-2, and post-mould annealing at 70 °C for 2 h is applied to reduce residual stress before fan balance testing. Unbalanced fans can impose vibration loads above 0.5 g on the guard, which accelerates fatigue cracking at fibre-rich knit lines that were not visible on dry as moulded parts.

    If Hydrolysis in Pump Wet Ends Is a Go/No-Go Criterion, Feedstock Variability Must Be Bounded

    Pump wet ends for salt-chlorine and bromine-sanitised spa water combine cyclic pressure, 40–50 °C water, and intermittent aeration. ASA has a hydrophobic backbone relative to polyamide, but the glass fibre sizing and recycled ASA-X acrylate content can introduce hydrolysable ester segments at the fibre-matrix interface. Parts moulded with high internal stress and exposed to 3 ppm free chlorine show microcracking at knit lines after 500 h immersion if the mould temperature is below 60 °C. A mould temperature of 80 °C improves fibre wet-out and moves the dominant failure mechanism from interfacial debonding to matrix microcracking at a longer interval. Before hydrolysis testing, the incoming compound is dried to 0.02 % moisture and its melt viscosity is checked by capillary rheometry at 250 °C and 1000 s⁻¹. Batches with viscosity below the lower control limit are rejected for wet-end parts because short shot flow into thin impeller vane sections produces excessive residual shear and interface stress.

    Long-term hydrolysis data for 20 wt% glass fibre ASA in chlorinated water is limited. Qualification therefore imposes a two-stage protocol: first, tensile bars are immersed in 50 °C deionized water for 7 days per ISO 62 and tested per ISO 527-2; second, assembled pump housings are pressure cycled at 0–300 kPa for 10 000 cycles with 3 ppm free chlorine. A drop in tensile strength greater than 15 % after the first stage, or any visible surface microcrack after the second stage, stops the lot. Moulders must also control screw decompression to avoid air entrapment in the melt, because air pockets at the fibre-matrix interface expand during water immersion and create surface blisters that are mistaken for chemical attack. For pump wet-end applications, the recycled content limit should be fixed at the same lot-to-lot ratio as the qualified material, and regrind addition above 15 % is not recommended without repeating the full hydrolysis protocol.

    Radome Frame Overmoulding Requires Differential Shrinkage Compensation

    Radome frame overmoulding requires differential shrinkage compensation when an amorphous polycarbonate radome base is joined to a glass-filled ASA-X frame. Polycarbonate and 20 wt% glass ASA have different post-mould shrinkage histories; polycarbonate continues to densify at 80 °C while ASA-GF has already passed through the styrenic-phase glass transition and approaches its final dimensional state earlier in the cooling cycle. A two-shot tool with the ASA-X frame injected over a PC insert must maintain the PC insert at 120–130 °C to prevent thermal shock while staying below the PC heat deflection threshold. The ASA-X melt temperature is set to 250–265 °C, and interfacial fusion is driven not by deep melt penetration but by surface solubility of the acrylate phase into the polycarbonate skin. Adhesion testing per ISO 19095-2 is used; a peel strength below 2 N/mm triggers tool temperature adjustment, increased packing pressure, or surface roughening of the insert. Because the glass fibre in ASA-X creates anisotropic CLTE, the frame is gated from two points to orient fibres circumferentially and reduce radial mismatch between the frame and the PC base. Published data for this exact recycled content grade in two-shot overmoulding is limited, so initial trials should include wet conditioning at 80 °C and 95 % RH for 7 days before peel testing and optical interferometry for surface deformation.

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